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Petrography of phosphates in CI and CY carbonaceous chondrites CI和CY碳质球粒陨石中磷酸盐的岩石学研究
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-26 DOI: 10.1111/maps.70052
C. S. Harrison, A. J. King, R. H. Jones, L. Piani

Phosphate minerals are significant carriers of volatiles (e.g., OH) and halogens in chondritic material; however, their origin in most groups of carbonaceous chondrites remains poorly characterized. We have determined the abundance, morphology, texture, and composition of phosphate grains in aqueously altered CI chondrites and in hydrated and thermally metamorphosed Antarctic CY chondrites using scanning electron microscopy and electron probe microanalysis. Phosphates include apatite (formula Ca5(PO4)3X, where X = F-, Cl-, OH- or other anions) and sodium-bearing magnesium phosphate, both of which formed during episodes of aqueous alteration on the CI and CY parent bodies. Apatite grains in the CI chondrites range up to 40 μm in size with a modal abundance of ~0.10 area%, while in the CYs, the largest grains are ~50 μm in size and the modal abundance is ≤0.70 area%. Analysis by secondary ion mass spectrometry (SIMS) indicates that apatite in the CYs contains ~1.0–1.8 wt% H2O, with δD values of −84‰ to 393‰ likely reflecting aqueous and thermal processing. Apatite in both the CI and CY chondrites is rich in fluorine, with fluorine abundances that range from 20 to 80 mole% of the X (anion) site. This contrasts with apatite in other chondrite groups, which is predominantly Cl-rich. Estimated bulk chondrite F abundances based on F abundance in apatite are 12–21 ppm F for the CI chondrites and 61 ppm F for the CY chondrites. This is comparable to bulk CI chondrite F abundances in the literature, suggesting that most fluorine is hosted in apatite. However, the chlorine content of CI chondrite apatite (<0.05 wt%) is too low to account for the bulk chondrite Cl abundance, indicating that Cl is hosted in other phases. Mg,Na-phosphate, a rare extraterrestrial mineral, has a modal abundance of ~0.02 area% in both the CI and CY chondrites. Mg,Na-phosphates in the CI and CY chondrites are halogen-poor (<0.15 wt%) and are typically hydrated in the CIs (analytical totals as low as 67 wt%) and dehydrated in the CYs (analytical totals >96.0 wt%). The occurrence of Mg,Na-phosphates in the CI and Antarctic CY chondrites is indicative of brines on their respective parent bodies. Similarities between the two groups, as well as with the phosphate mineral assemblage in asteroids Ryugu and Bennu, indicate that comparable fluid compositions and environmental conditions were prevalent on numerous parent bodies in the early Solar System.

磷酸盐矿物是球粒状物质中挥发物(如OH)和卤素的重要载体;然而,它们在大多数碳质球粒陨石群中的起源仍然缺乏特征。我们利用扫描电子显微镜和电子探针显微分析确定了水蚀CI球粒陨石和水合和热变质南极CY球粒陨石中磷酸盐颗粒的丰度、形态、结构和组成。磷酸盐包括磷灰石(式Ca5(PO4)3X,其中X = F-, Cl-, OH-或其他阴离子)和含钠磷酸镁,它们都是在CI和CY母体的水蚀变中形成的。CI球粒中磷灰石晶粒尺寸最大可达40 μm,模态丰度为~0.10 area%,而CYs中磷灰石晶粒尺寸最大为~50 μm,模态丰度≤0.70 area%。次级离子质谱(SIMS)分析表明,CYs中磷灰石的H2O含量为~1.0 ~ 1.8 wt%, δD值为- 84‰~ 393‰,可能反映了水处理和热处理。CI和CY球粒陨石中的磷灰石都富含氟,氟丰度在X(阴离子)位点的20 - 80摩尔%之间。这与其他球粒陨石群中的磷灰石形成对比,后者主要富含cl。根据磷灰石中的F丰度估计,CI球粒陨石的体积F丰度为12-21 ppm F, CY球粒陨石的体积F丰度为61 ppm F。这与文献中大量CI球粒陨石F丰度相当,表明大多数氟是在磷灰石中承载的。然而,CI球粒石磷灰石的氯含量(<0.05 wt%)太低,无法解释整体球粒石Cl丰度,表明Cl被寄存于其他相中。Mg,Na-phosphate是一种稀有的地外矿物,在CI和CY球粒陨石中的丰度为~0.02 area%。Mg、na -磷酸盐在CI和CY球粒陨石中缺乏卤素(0.15 wt%),通常在CI中水合(分析总量低至67% wt%),在CYs中脱水(分析总量96.0% wt%)。在CI和南极CY球粒陨石中镁、钠磷酸盐的存在表明它们各自的母体中存在卤水。这两组之间的相似性,以及与小行星龙宫和贝努的磷矿组合的相似性,表明在太阳系早期的许多母体中,类似的流体组成和环境条件是普遍存在的。
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引用次数: 0
Investigation and reclassification of four mesosiderites—Implications for their formation 四种中铜矿的调查与再分类及其形成意义
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-26 DOI: 10.1111/maps.70051
Gabriel Zachén, Carl Alwmark, Sanna Alwmark, Ludovic Ferrière, Roger H. Hewins

Mesosiderites are rare, differentiated meteorites, so-called stony-iron meteorites—they are impact breccias composed of an unusual mix of crustal basalt and pyroxenite, core-derived metal, but no mantle materials. This odd mixture makes their origin enigmatic and has inspired many different formation theories over the last several decades. Some of the outstanding questions have regarded the origin of the metal, whether it came from another celestial body or from within the main parent body, and the puzzlingly low abundance, or absence, of mantle material in mesosiderites. The role of impacts has been central to most of the suggested theories, but mesosiderites show little to no evidence of shock metamorphism. The mystery of the origin of mesosiderites is further compounded by the relatively limited amount of published data, as well as the restricted number of samples available for research. With the detailed investigation and reclassification of the mesosiderites Lamont, Acfer 265, Queen Alexandra Range 86900 (QUE 86900), and MacAlpine Hills 88102 (MAC 88102) presented herein, our new observations shine some much-needed light on this meteorite group. Based on their petrologic and metamorphic characteristics, Lamont is classified as a B3/4, Acfer 265 and QUE 86900 as A1, and MAC 88102 as an A4 mesosiderite. The observation of multiple sets of parallel thin lamellae in high-Ca plagioclase and cristobalite in Lamont, and a silicate emulsion in QUE 86900 is proposed to be shock-related features. In both Lamont and QUE 86900, these features are interpreted to be subsequent to the initial impact, which mixed crustal and core material, and prior to deep burial. No shock-related features were noted in Acfer 265 and MAC 88102.

中黄铁矿是一种罕见的、分化的陨石,即所谓的石铁陨石——它们是撞击角砾岩,由地壳玄武岩和辉石岩组成,这是一种不寻常的混合物,由地核衍生的金属组成,但没有地幔物质。这种奇怪的混合物使它们的起源变得神秘,在过去的几十年里激发了许多不同的形成理论。一些悬而未决的问题涉及到金属的起源,它是来自另一个天体还是来自主母体内部,以及中黄铁矿中地幔物质的令人困惑的低丰度或缺失。撞击的作用是大多数提出的理论的核心,但中橄榄石几乎没有显示出冲击变质作用的证据。公布的数据相对有限,可供研究的样本数量也有限,这进一步加剧了中黄铁矿起源之谜。本文对中黄铁矿拉蒙特、阿克弗265、亚历山德拉女王山脉86900 (QUE 86900)和MacAlpine山88102 (MAC 88102)进行了详细的调查和重新分类,我们的新观测为这一陨石群提供了一些急需的信息。根据岩石学和变质学特征,将Lamont划分为B3/4中黄铁矿,Acfer 265和QUE 86900为A1中黄铁矿,mac88102为A4中黄铁矿。在Lamont的高钙斜长石和方英石中观察到多组平行薄片层,在QUE 86900中观察到一种硅酸盐乳液,提出了与冲击相关的特征。在Lamont和QUE 86900中,这些特征被解释为在地壳和核心物质混合的初始撞击之后,在深埋之前。在Acfer 265和MAC 88102中没有注意到与冲击相关的功能。
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引用次数: 0
Cosmic ray exposure and gas retention ages of the shocked angrite Northwest Africa 7203: Implications for a collisional history of angrites' parent body 西北非洲7203震波盎格里岩的宇宙射线暴露和气体保留年龄:盎格里岩母体碰撞历史的启示
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-25 DOI: 10.1111/maps.70055
Atsushi Takenouchi, Hirochika Sumino, Hideyuki Hayashi, Takashi Mikouchi, Martin Bizzarro

Angrites and eucrites are among the oldest basaltic rocks in the solar system. However, the shock histories of these meteorite groups differ markedly, as most angrites show little to no evidence of shock metamorphism. While some angrites exhibit weak wavy extinction in olivine, indicative of low-level shock, only two—Northwest Africa (NWA) 1670 and NWA 7203—are known to preserve significant shock features such as shock melt veins. To better constrain the shock history of angrites, we performed noble gas analyses on the rare shock-metamorphosed angrite NWA 7203 to determine its cosmic ray exposure and gas retention ages. Neon in NWA 7203 is entirely cosmogenic, and combined neon and argon data yield a cosmic ray exposure age of 22.7 ± 3.1 Ma (2σ). This age nominally differs from that of the other shocked angrite, NWA 1670, but is comparable to that of the unshocked angrite NWA 7812. NWA 7203 may have been ejected from a rubble pile-like asteroid composed of both shocked and unshocked materials. Two distinct 40Ar/39Ar apparent ages, 3.38 ± 0.10 Ga and 1.41 ± 0.11 Ga, were obtained, likely reflecting variable argon loss during a single impact-induced thermal event that occurred no earlier than 1.41 ± 0.11 Ga (2σ). This is the first report for the shock metamorphic age of an angrite. Our results reinforce the view that even shocked angrites lack clear evidence of a catastrophic disruption of their parent body (>100 km) hypothesized to have occurred in the early solar system. To resolve this conundrum, we propose that angrites may have experienced extensive melting during such an event, which suppressed or erased conventional shock features. If this impact occurred near the time of their crystallization (>4564 Ma), it may have been a “hot shock” event driven by heat from short-lived radionuclides. Such an event could have generated large volumes of shock melt, from which quenched angrites subsequently formed. We suggest that differentiated planetary bodies may have commonly undergone such early-stage disruption events during the formative epoch of the solar system.

辉长岩和绿长岩是太阳系中最古老的玄武岩。然而,这些陨石群的激波历史明显不同,因为大多数陨石几乎没有激波变质的证据。虽然一些花岗岩在橄榄石中表现出微弱的波状消光,表明低水平的冲击,但只有两个-西北非洲(NWA) 1670和NWA 7203 -已知保留了显著的冲击特征,如冲击融化脉。为了更好地约束菱辉岩的激波历史,我们对罕见的激波变质菱辉岩NWA 7203进行了稀有气体分析,以确定其宇宙射线暴露和气体保留年龄。NWA 7203中的氖完全是宇宙形成的,结合氖和氩的数据得出宇宙射线暴露年龄为22.7±3.1 Ma (2σ)。这个年龄在名义上不同于另一个受冲击的安格丽石NWA 1670,但与未受冲击的安格丽石NWA 7812相当。NWA 7203可能是从一颗由受冲击和未受冲击物质组成的碎石堆状小行星中喷射出来的。40Ar/39Ar两个不同的表观年龄分别为3.38±0.10 Ga和1.41±0.11 Ga,这可能反映了单次撞击引起的热事件中不早于1.41±0.11 Ga (2σ)的可变氩损失。本文首次报道了一种花岗岩的冲击变质年龄。我们的研究结果强化了这样一种观点,即即使是受到冲击的愤怒星也缺乏明确的证据,证明它们的母体(100公里)发生了灾难性的破坏,这种破坏被假设发生在太阳系早期。为了解决这个难题,我们提出在这样的事件中,愤怒岩可能经历了广泛的融化,这抑制或消除了传统的冲击特征。如果这次撞击发生在它们的结晶期(4564毫安)附近,它可能是一次由短寿命放射性核素产生的热量驱动的“热冲击”事件。这样的事件可能产生了大量的激波熔体,随后形成了淬硬岩。我们认为,在太阳系形成时期,分化的行星体可能通常经历过这样的早期破坏事件。
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引用次数: 0
Analysis of four Apollo 16 double drive tubes using QEMSCAN® mapping techniques: Implications for sampling the lunar regolith in highland terrains 使用QEMSCAN®测绘技术对四个阿波罗16号双驱动管进行分析:对高原地区月球风化层采样的影响
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-24 DOI: 10.1111/maps.70057
Stephanie L. Halwa, Katherine H. Joy, Romain Tartèse, Samantha K. Bell

The lunar regolith contains a rich history of Solar System impact events and solar activity. Many future missions will land in the south polar region of the Moon, a heavily impact cratered highland terrain, similar to the Apollo 16 landing site. In preparation, it is important to understand regolith processes and the upper stratigraphy of the regolith in typical highlands regions. In this study, we used a nondestructive scanning electron microscope with the QEMSCAN software to analyze the mineralogical compositions and maturities of regolith samples from various depths within four Apollo 16 double drive tubes. Our results support previous analyses made using other techniques that there is a lack of stratigraphic correlation across the central and southern regions of the Apollo 16 landing site, where the cores show lateral and vertical heterogeneities. Our results also show that QEMSCAN is a powerful tool for rapid, quantitative assessment of regolith characteristics. Our findings can serve as an analog for south polar regolith, providing context for upcoming missions looking to sample the subsurface regolith in the south polar region.

月球风化层包含了太阳系撞击事件和太阳活动的丰富历史。许多未来的任务将在月球的南极地区着陆,这是一个严重撞击的高地地形,类似于阿波罗16号的着陆点。在准备工作中,了解典型高原地区的风化过程和风化层的上地层是很重要的。在这项研究中,我们使用无损扫描电子显微镜和QEMSCAN软件分析了四个阿波罗16号双驱动管中不同深度的风化样品的矿物组成和成熟度。我们的结果支持先前使用其他技术所做的分析,即在阿波罗16号着陆点的中部和南部地区缺乏地层相关性,那里的岩心显示出横向和垂直的不均匀性。我们的研究结果还表明,QEMSCAN是快速、定量评估风化层特征的有力工具。我们的发现可以作为南极风化层的模拟,为即将进行的南极地区地下风化层取样任务提供背景。
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引用次数: 0
What falls versus what we recover: Quantifying search and recovery bias for orbital meteorites 坠落的与我们恢复的:量化轨道陨石的搜索和恢复偏差
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-22 DOI: 10.1111/maps.70041
Patrick M. Shober, Jeremie Vaubaillon, Hadrien A. R. Devillepoix, Eleanor K. Sansom, Sophie E. Deam, Simon Anghel, Francois Colas, Pierre Vernazza, Brigitte Zanda

Instrumentally determined pre-atmospheric orbits of meteorites offer crucial constraints on the provenance of extraterrestrial material and the dynamical pathways that deliver it to Earth. However, recovery efforts are focused on larger and slower impacts due to their higher survival probabilities and ease of detection. In this study, we investigate the prevalence of these biases in the population of recovered meteorites with known orbits. We compiled a data set of 75 meteorites with triangulated trajectories and compared their orbits to 538 potential >1 g meteorite-dropping fireballs detected by the Global Fireball Observatory, the European Fireball Network, and the Fireball Recovery and InterPlanetary Observation Network. Our results reveal that objects with small semi-major axis values (a<1.8 au) appear 2–3× more often than expected. The current sample of meteorites with known orbits does not reflect the sources of meteorites in our collections, and it is essential to account for search and recovery biases to obtain a more representative understanding of meteorite source contributions.

仪器确定的陨石的大气前轨道对地外物质的来源和将其输送到地球的动力学途径提供了至关重要的限制。然而,恢复工作的重点是更大、更慢的影响,因为它们的生存概率更高,更容易被发现。在这项研究中,我们调查了这些偏差在已知轨道的回收陨石群体中的流行程度。我们收集了75颗具有三角轨迹的陨石的数据集,并将它们的轨道与全球火球天文台、欧洲火球网络和火球恢复和行星际观测网络探测到的538颗可能的1g陨星坠落火球进行了比较。我们的结果显示,具有小半长轴值(a < 1.8 au)的物体出现的频率比预期高2-3倍。目前已知轨道的陨石样本并不能反映我们收集的陨石的来源,为了获得对陨石来源贡献的更有代表性的理解,必须考虑搜索和恢复偏差。
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引用次数: 0
Correction to “Chemical, isotopic (O, He, U), and petrological characteristics of a slowly cooled enriched gabbroic shergottite, Northwest Africa 13134” 修正“西北非洲13134缓慢冷却富集辉长岩辉长岩的化学、同位素(O、He、U)和岩石学特征”
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-19 DOI: 10.1111/maps.70053

Saper, L., Liu, Y., Kipp, M. A., Burney, D., Ma, C., Tissot, F. L. H., Young, E., Treffkorn, J. and Farley, K. A. (2025) Chemical, Isotopic (O, He, U), and Petrological Characteristics of a Slowly Cooled Enriched Gabbroic Shergottite, Northwest Africa 13134. Meteoritics & Planetary Science, 60: 1119–1150. https://doi.org/10.1111/maps.14345

In Table 6, the two glasses analyzed using the phosphate EPMA routine had Na2O contents erroneously reported as K2O contents. We have provided an updated Table 6 corrected for these two entries.

We apologize for this error.

Saper, L., Liu, Y., Kipp, M. A., Burney, D., Ma, C., Tissot, F. L. H., Young, E., Treffkorn, J., Farley, K. A.(2025)西北非洲慢冷富集辉长岩辉长岩的化学、同位素(O, He, U)和岩石学特征。地球科学进展,26(2):379 - 379。https://doi.org/10.1111/maps.14345In表6,使用磷酸EPMA常规分析的两种玻璃将Na2O含量错误地报告为K2O含量。我们提供了更新后的表6,更正了这两个条目。我们为这个错误道歉。
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引用次数: 0
Cover 封面
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-17 DOI: 10.1111/maps.14211

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引用次数: 0
87th Annual Meeting of the Meteoritical Society 2025: Abstracts 2025年第87届气象学会年会:摘要
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-09 DOI: 10.1111/maps.70033
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引用次数: 0
Century-scale effect of climate change on meteorite falls 气候变化对陨石坠落的百年效应
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-09 DOI: 10.1111/maps.70046
Eloy Peña-Asensio, Denis Vida, Ingrid Cnossen, Esteban Ferrer

Climate change is inducing a global atmospheric contraction above the tropopause (~10 km), leading to systematic decrease in neutral air density. The impact of climate change on small meteoroids has already been observed over the last two decades, with documented shifts in their ablation altitudes in the mesosphere (~50–85 km) and lower thermosphere (~85–120 km). This study evaluates the potential effect of these changes on meteorite-dropping fireballs, which typically penetrate the stratosphere (~10–50 km). As a case study, we simulate the atmospheric entry of the fragile Winchcombe carbonaceous chondrite under projected atmospheric conditions for the year 2100 assuming a moderate future emission scenario. Using a semi-empirical fragmentation and ablation model, we compare the meteoroid's light curve and deceleration under present and future atmospheric density profiles. The results indicate a modest variation of the ablation heights, with the catastrophic fragmentation occurring 300 m lower and the luminous flight terminating 190 m higher. The absolute magnitude peak remains unchanged, but the fireball would appear 0.5 dimmer above ~120 km. The surviving meteorite mass is reduced by only 0.1 g. Our findings indicate that century-scale variations in atmospheric density caused by climate change moderately influence bright fireballs and have a minimal impact on meteorite survival.

气候变化正在诱导对流层顶以上(~10公里)的全球大气收缩,导致中性空气密度的系统性降低。气候变化对小型流星体的影响在过去二十年中已经被观测到,它们在中间层(~ 50-85千米)和低层热层(~ 85-120千米)的消融高度发生了有记录的变化。这项研究评估了这些变化对陨石坠落火球的潜在影响,这些火球通常穿透平流层(~ 10-50公里)。作为一个案例研究,我们模拟了脆弱的温奇库姆碳质球粒陨石在2100年预估大气条件下进入大气的过程,假设未来的排放情况适中。利用半经验碎裂和烧蚀模型,我们比较了流星体在当前和未来大气密度剖面下的光曲线和减速度。结果表明,烧蚀高度变化不大,灾变破碎发生在300 m以下,发光飞行结束在190 m以上。绝对星等峰值保持不变,但火球在~120公里以上的位置会变暗0.5。幸存的陨石质量只减少了0.1 g。我们的研究结果表明,气候变化引起的大气密度的世纪尺度变化对明亮的火球有中等影响,对陨石存活的影响最小。
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引用次数: 0
87th Annual Meeting of the Meteoritical Society 2025: Contents 2025年第87届气象学会年会:内容
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-09-09 DOI: 10.1111/maps.70032
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引用次数: 0
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Meteoritics & Planetary Science
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