Phosphate minerals are significant carriers of volatiles (e.g., OH) and halogens in chondritic material; however, their origin in most groups of carbonaceous chondrites remains poorly characterized. We have determined the abundance, morphology, texture, and composition of phosphate grains in aqueously altered CI chondrites and in hydrated and thermally metamorphosed Antarctic CY chondrites using scanning electron microscopy and electron probe microanalysis. Phosphates include apatite (formula Ca5(PO4)3X, where X = F-, Cl-, OH- or other anions) and sodium-bearing magnesium phosphate, both of which formed during episodes of aqueous alteration on the CI and CY parent bodies. Apatite grains in the CI chondrites range up to 40 μm in size with a modal abundance of ~0.10 area%, while in the CYs, the largest grains are ~50 μm in size and the modal abundance is ≤0.70 area%. Analysis by secondary ion mass spectrometry (SIMS) indicates that apatite in the CYs contains ~1.0–1.8 wt% H2O, with δD values of −84‰ to 393‰ likely reflecting aqueous and thermal processing. Apatite in both the CI and CY chondrites is rich in fluorine, with fluorine abundances that range from 20 to 80 mole% of the X (anion) site. This contrasts with apatite in other chondrite groups, which is predominantly Cl-rich. Estimated bulk chondrite F abundances based on F abundance in apatite are 12–21 ppm F for the CI chondrites and 61 ppm F for the CY chondrites. This is comparable to bulk CI chondrite F abundances in the literature, suggesting that most fluorine is hosted in apatite. However, the chlorine content of CI chondrite apatite (<0.05 wt%) is too low to account for the bulk chondrite Cl abundance, indicating that Cl is hosted in other phases. Mg,Na-phosphate, a rare extraterrestrial mineral, has a modal abundance of ~0.02 area% in both the CI and CY chondrites. Mg,Na-phosphates in the CI and CY chondrites are halogen-poor (<0.15 wt%) and are typically hydrated in the CIs (analytical totals as low as 67 wt%) and dehydrated in the CYs (analytical totals >96.0 wt%). The occurrence of Mg,Na-phosphates in the CI and Antarctic CY chondrites is indicative of brines on their respective parent bodies. Similarities between the two groups, as well as with the phosphate mineral assemblage in asteroids Ryugu and Bennu, indicate that comparable fluid compositions and environmental conditions were prevalent on numerous parent bodies in the early Solar System.
{"title":"Petrography of phosphates in CI and CY carbonaceous chondrites","authors":"C. S. Harrison, A. J. King, R. H. Jones, L. Piani","doi":"10.1111/maps.70052","DOIUrl":"https://doi.org/10.1111/maps.70052","url":null,"abstract":"<p>Phosphate minerals are significant carriers of volatiles (e.g., OH) and halogens in chondritic material; however, their origin in most groups of carbonaceous chondrites remains poorly characterized. We have determined the abundance, morphology, texture, and composition of phosphate grains in aqueously altered CI chondrites and in hydrated and thermally metamorphosed Antarctic CY chondrites using scanning electron microscopy and electron probe microanalysis. Phosphates include apatite (formula Ca5(PO<sub>4</sub>)3X, where X = F-, Cl-, OH- or other anions) and sodium-bearing magnesium phosphate, both of which formed during episodes of aqueous alteration on the CI and CY parent bodies. Apatite grains in the CI chondrites range up to 40 μm in size with a modal abundance of ~0.10 area%, while in the CYs, the largest grains are ~50 μm in size and the modal abundance is ≤0.70 area%. Analysis by secondary ion mass spectrometry (SIMS) indicates that apatite in the CYs contains ~1.0–1.8 wt% H2O, with δ<i>D</i> values of −84‰ to 393‰ likely reflecting aqueous and thermal processing. Apatite in both the CI and CY chondrites is rich in fluorine, with fluorine abundances that range from 20 to 80 mole% of the X (anion) site. This contrasts with apatite in other chondrite groups, which is predominantly Cl-rich. Estimated bulk chondrite F abundances based on F abundance in apatite are 12–21 ppm F for the CI chondrites and 61 ppm F for the CY chondrites. This is comparable to bulk CI chondrite F abundances in the literature, suggesting that most fluorine is hosted in apatite. However, the chlorine content of CI chondrite apatite (<0.05 wt%) is too low to account for the bulk chondrite Cl abundance, indicating that Cl is hosted in other phases. Mg,Na-phosphate, a rare extraterrestrial mineral, has a modal abundance of ~0.02 area% in both the CI and CY chondrites. Mg,Na-phosphates in the CI and CY chondrites are halogen-poor (<0.15 wt%) and are typically hydrated in the CIs (analytical totals as low as 67 wt%) and dehydrated in the CYs (analytical totals >96.0 wt%). The occurrence of Mg,Na-phosphates in the CI and Antarctic CY chondrites is indicative of brines on their respective parent bodies. Similarities between the two groups, as well as with the phosphate mineral assemblage in asteroids Ryugu and Bennu, indicate that comparable fluid compositions and environmental conditions were prevalent on numerous parent bodies in the early Solar System.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"60 11","pages":"2594-2622"},"PeriodicalIF":2.4,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/maps.70052","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145719759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gabriel Zachén, Carl Alwmark, Sanna Alwmark, Ludovic Ferrière, Roger H. Hewins
Mesosiderites are rare, differentiated meteorites, so-called stony-iron meteorites—they are impact breccias composed of an unusual mix of crustal basalt and pyroxenite, core-derived metal, but no mantle materials. This odd mixture makes their origin enigmatic and has inspired many different formation theories over the last several decades. Some of the outstanding questions have regarded the origin of the metal, whether it came from another celestial body or from within the main parent body, and the puzzlingly low abundance, or absence, of mantle material in mesosiderites. The role of impacts has been central to most of the suggested theories, but mesosiderites show little to no evidence of shock metamorphism. The mystery of the origin of mesosiderites is further compounded by the relatively limited amount of published data, as well as the restricted number of samples available for research. With the detailed investigation and reclassification of the mesosiderites Lamont, Acfer 265, Queen Alexandra Range 86900 (QUE 86900), and MacAlpine Hills 88102 (MAC 88102) presented herein, our new observations shine some much-needed light on this meteorite group. Based on their petrologic and metamorphic characteristics, Lamont is classified as a B3/4, Acfer 265 and QUE 86900 as A1, and MAC 88102 as an A4 mesosiderite. The observation of multiple sets of parallel thin lamellae in high-Ca plagioclase and cristobalite in Lamont, and a silicate emulsion in QUE 86900 is proposed to be shock-related features. In both Lamont and QUE 86900, these features are interpreted to be subsequent to the initial impact, which mixed crustal and core material, and prior to deep burial. No shock-related features were noted in Acfer 265 and MAC 88102.
{"title":"Investigation and reclassification of four mesosiderites—Implications for their formation","authors":"Gabriel Zachén, Carl Alwmark, Sanna Alwmark, Ludovic Ferrière, Roger H. Hewins","doi":"10.1111/maps.70051","DOIUrl":"https://doi.org/10.1111/maps.70051","url":null,"abstract":"<p>Mesosiderites are rare, differentiated meteorites, so-called stony-iron meteorites—they are impact breccias composed of an unusual mix of crustal basalt and pyroxenite, core-derived metal, but no mantle materials. This odd mixture makes their origin enigmatic and has inspired many different formation theories over the last several decades. Some of the outstanding questions have regarded the origin of the metal, whether it came from another celestial body or from within the main parent body, and the puzzlingly low abundance, or absence, of mantle material in mesosiderites. The role of impacts has been central to most of the suggested theories, but mesosiderites show little to no evidence of shock metamorphism. The mystery of the origin of mesosiderites is further compounded by the relatively limited amount of published data, as well as the restricted number of samples available for research. With the detailed investigation and reclassification of the mesosiderites Lamont, Acfer 265, Queen Alexandra Range 86900 (QUE 86900), and MacAlpine Hills 88102 (MAC 88102) presented herein, our new observations shine some much-needed light on this meteorite group. Based on their petrologic and metamorphic characteristics, Lamont is classified as a B3/4, Acfer 265 and QUE 86900 as A1, and MAC 88102 as an A4 mesosiderite. The observation of multiple sets of parallel thin lamellae in high-Ca plagioclase and cristobalite in Lamont, and a silicate emulsion in QUE 86900 is proposed to be shock-related features. In both Lamont and QUE 86900, these features are interpreted to be subsequent to the initial impact, which mixed crustal and core material, and prior to deep burial. No shock-related features were noted in Acfer 265 and MAC 88102.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"60 11","pages":"2574-2593"},"PeriodicalIF":2.4,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/maps.70051","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145719760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Atsushi Takenouchi, Hirochika Sumino, Hideyuki Hayashi, Takashi Mikouchi, Martin Bizzarro
Angrites and eucrites are among the oldest basaltic rocks in the solar system. However, the shock histories of these meteorite groups differ markedly, as most angrites show little to no evidence of shock metamorphism. While some angrites exhibit weak wavy extinction in olivine, indicative of low-level shock, only two—Northwest Africa (NWA) 1670 and NWA 7203—are known to preserve significant shock features such as shock melt veins. To better constrain the shock history of angrites, we performed noble gas analyses on the rare shock-metamorphosed angrite NWA 7203 to determine its cosmic ray exposure and gas retention ages. Neon in NWA 7203 is entirely cosmogenic, and combined neon and argon data yield a cosmic ray exposure age of 22.7 ± 3.1 Ma (2σ). This age nominally differs from that of the other shocked angrite, NWA 1670, but is comparable to that of the unshocked angrite NWA 7812. NWA 7203 may have been ejected from a rubble pile-like asteroid composed of both shocked and unshocked materials. Two distinct 40Ar/39Ar apparent ages, 3.38 ± 0.10 Ga and 1.41 ± 0.11 Ga, were obtained, likely reflecting variable argon loss during a single impact-induced thermal event that occurred no earlier than 1.41 ± 0.11 Ga (2σ). This is the first report for the shock metamorphic age of an angrite. Our results reinforce the view that even shocked angrites lack clear evidence of a catastrophic disruption of their parent body (>100 km) hypothesized to have occurred in the early solar system. To resolve this conundrum, we propose that angrites may have experienced extensive melting during such an event, which suppressed or erased conventional shock features. If this impact occurred near the time of their crystallization (>4564 Ma), it may have been a “hot shock” event driven by heat from short-lived radionuclides. Such an event could have generated large volumes of shock melt, from which quenched angrites subsequently formed. We suggest that differentiated planetary bodies may have commonly undergone such early-stage disruption events during the formative epoch of the solar system.
辉长岩和绿长岩是太阳系中最古老的玄武岩。然而,这些陨石群的激波历史明显不同,因为大多数陨石几乎没有激波变质的证据。虽然一些花岗岩在橄榄石中表现出微弱的波状消光,表明低水平的冲击,但只有两个-西北非洲(NWA) 1670和NWA 7203 -已知保留了显著的冲击特征,如冲击融化脉。为了更好地约束菱辉岩的激波历史,我们对罕见的激波变质菱辉岩NWA 7203进行了稀有气体分析,以确定其宇宙射线暴露和气体保留年龄。NWA 7203中的氖完全是宇宙形成的,结合氖和氩的数据得出宇宙射线暴露年龄为22.7±3.1 Ma (2σ)。这个年龄在名义上不同于另一个受冲击的安格丽石NWA 1670,但与未受冲击的安格丽石NWA 7812相当。NWA 7203可能是从一颗由受冲击和未受冲击物质组成的碎石堆状小行星中喷射出来的。40Ar/39Ar两个不同的表观年龄分别为3.38±0.10 Ga和1.41±0.11 Ga,这可能反映了单次撞击引起的热事件中不早于1.41±0.11 Ga (2σ)的可变氩损失。本文首次报道了一种花岗岩的冲击变质年龄。我们的研究结果强化了这样一种观点,即即使是受到冲击的愤怒星也缺乏明确的证据,证明它们的母体(100公里)发生了灾难性的破坏,这种破坏被假设发生在太阳系早期。为了解决这个难题,我们提出在这样的事件中,愤怒岩可能经历了广泛的融化,这抑制或消除了传统的冲击特征。如果这次撞击发生在它们的结晶期(4564毫安)附近,它可能是一次由短寿命放射性核素产生的热量驱动的“热冲击”事件。这样的事件可能产生了大量的激波熔体,随后形成了淬硬岩。我们认为,在太阳系形成时期,分化的行星体可能通常经历过这样的早期破坏事件。
{"title":"Cosmic ray exposure and gas retention ages of the shocked angrite Northwest Africa 7203: Implications for a collisional history of angrites' parent body","authors":"Atsushi Takenouchi, Hirochika Sumino, Hideyuki Hayashi, Takashi Mikouchi, Martin Bizzarro","doi":"10.1111/maps.70055","DOIUrl":"https://doi.org/10.1111/maps.70055","url":null,"abstract":"<p>Angrites and eucrites are among the oldest basaltic rocks in the solar system. However, the shock histories of these meteorite groups differ markedly, as most angrites show little to no evidence of shock metamorphism. While some angrites exhibit weak wavy extinction in olivine, indicative of low-level shock, only two—Northwest Africa (NWA) 1670 and NWA 7203—are known to preserve significant shock features such as shock melt veins. To better constrain the shock history of angrites, we performed noble gas analyses on the rare shock-metamorphosed angrite NWA 7203 to determine its cosmic ray exposure and gas retention ages. Neon in NWA 7203 is entirely cosmogenic, and combined neon and argon data yield a cosmic ray exposure age of 22.7 ± 3.1 Ma (2σ). This age nominally differs from that of the other shocked angrite, NWA 1670, but is comparable to that of the unshocked angrite NWA 7812. NWA 7203 may have been ejected from a rubble pile-like asteroid composed of both shocked and unshocked materials. Two distinct <sup>40</sup>Ar/<sup>39</sup>Ar apparent ages, 3.38 ± 0.10 Ga and 1.41 ± 0.11 Ga, were obtained, likely reflecting variable argon loss during a single impact-induced thermal event that occurred no earlier than 1.41 ± 0.11 Ga (2σ). This is the first report for the shock metamorphic age of an angrite. Our results reinforce the view that even shocked angrites lack clear evidence of a catastrophic disruption of their parent body (>100 km) hypothesized to have occurred in the early solar system. To resolve this conundrum, we propose that angrites may have experienced extensive melting during such an event, which suppressed or erased conventional shock features. If this impact occurred near the time of their crystallization (>4564 Ma), it may have been a “hot shock” event driven by heat from short-lived radionuclides. Such an event could have generated large volumes of shock melt, from which quenched angrites subsequently formed. We suggest that differentiated planetary bodies may have commonly undergone such early-stage disruption events during the formative epoch of the solar system.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"60 11","pages":"2560-2573"},"PeriodicalIF":2.4,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/maps.70055","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145719647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Stephanie L. Halwa, Katherine H. Joy, Romain Tartèse, Samantha K. Bell
The lunar regolith contains a rich history of Solar System impact events and solar activity. Many future missions will land in the south polar region of the Moon, a heavily impact cratered highland terrain, similar to the Apollo 16 landing site. In preparation, it is important to understand regolith processes and the upper stratigraphy of the regolith in typical highlands regions. In this study, we used a nondestructive scanning electron microscope with the QEMSCAN software to analyze the mineralogical compositions and maturities of regolith samples from various depths within four Apollo 16 double drive tubes. Our results support previous analyses made using other techniques that there is a lack of stratigraphic correlation across the central and southern regions of the Apollo 16 landing site, where the cores show lateral and vertical heterogeneities. Our results also show that QEMSCAN is a powerful tool for rapid, quantitative assessment of regolith characteristics. Our findings can serve as an analog for south polar regolith, providing context for upcoming missions looking to sample the subsurface regolith in the south polar region.
{"title":"Analysis of four Apollo 16 double drive tubes using QEMSCAN® mapping techniques: Implications for sampling the lunar regolith in highland terrains","authors":"Stephanie L. Halwa, Katherine H. Joy, Romain Tartèse, Samantha K. Bell","doi":"10.1111/maps.70057","DOIUrl":"https://doi.org/10.1111/maps.70057","url":null,"abstract":"<p>The lunar regolith contains a rich history of Solar System impact events and solar activity. Many future missions will land in the south polar region of the Moon, a heavily impact cratered highland terrain, similar to the Apollo 16 landing site. In preparation, it is important to understand regolith processes and the upper stratigraphy of the regolith in typical highlands regions. In this study, we used a nondestructive scanning electron microscope with the QEMSCAN software to analyze the mineralogical compositions and maturities of regolith samples from various depths within four Apollo 16 double drive tubes. Our results support previous analyses made using other techniques that there is a lack of stratigraphic correlation across the central and southern regions of the Apollo 16 landing site, where the cores show lateral and vertical heterogeneities. Our results also show that QEMSCAN is a powerful tool for rapid, quantitative assessment of regolith characteristics. Our findings can serve as an analog for south polar regolith, providing context for upcoming missions looking to sample the subsurface regolith in the south polar region.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"60 10","pages":"2504-2523"},"PeriodicalIF":2.4,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/maps.70057","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145297255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Patrick M. Shober, Jeremie Vaubaillon, Hadrien A. R. Devillepoix, Eleanor K. Sansom, Sophie E. Deam, Simon Anghel, Francois Colas, Pierre Vernazza, Brigitte Zanda
Instrumentally determined pre-atmospheric orbits of meteorites offer crucial constraints on the provenance of extraterrestrial material and the dynamical pathways that deliver it to Earth. However, recovery efforts are focused on larger and slower impacts due to their higher survival probabilities and ease of detection. In this study, we investigate the prevalence of these biases in the population of recovered meteorites with known orbits. We compiled a data set of 75 meteorites with triangulated trajectories and compared their orbits to 538 potential