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Discovery of fossil micrometeorites from the Deccan trap intertrappeans 德干陷阱岩层间微陨石化石的发现
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-30 DOI: 10.1111/maps.14256
V. P. Singh, N. G. Rudraswami, Nittala V. Chalapathi Rao, Matthew J. Genge, M. Pandey, S. Sreekuttan, S. Chattopadhaya

The Cretaceous–Paleogene (K-Pg) boundary represents the extinction of ~70% of species, a prominent Chicxulub impact event and Deccan volcanism. This work reports the first attempt to extract the micrometeorites (MMs) from the Deccan intertrappean horizons. Eighty-one spherical particles were studied for their morphological, textural, and chemical characteristics. Intact cosmic spherules with ferromagnesian silicates (6) and Fe-Ni oxide (7) compositions correspond to MMs from the deep sea and Antarctica. Silicate and Fe-Ni spherules in this study showcase remarkable preservation, a testament to the highly favorable conditions present. Fe spherules (38) with iron oxide compositions exhibit diagenetic alteration during preservation. Textural analysis of 30 Fe spherules reveals a dendritic, interlocking pattern and slightly elevated Mn content, suggesting these may be fossilized I-type MMs. However, eight Fe spherules with blocky and cubical granular textures resemble oxidized pyrite spherules. Al-Fe-Si spherules (30) possess a significant enrichment of Al and Si within their Fe-oxide-dominated composition. Group-I Al-Fe-Si spherules (15) display zoned Al-Fe-Si oxide composition, dendritic Mg-Cr spinel grains, and aerodynamic features, all indicative of impact spherules. The finding of these impact spherules from sampled Deccan intertrappean layer raises the possibility that these paleosols were deposited during the Chicxulub impact event, the only identified impact event with global distribution during the Deccan volcanism time frame. This unique location provides an opportunity for the simultaneous collection of well-preserved MMs, impact, and volcanic spherules. The exceptional preservation of the studied MMs is likely due to a combination of non-marine environments, atypical climatic conditions, and rapid deposition. This study further investigates the potential role of cosmic dust flux in the K-Pg extinction event. We propose that the enhanced cosmic dust flux, a likely scenario during the K-Pg boundary period, synergistically mixing with impact dust in the upper atmosphere, may have intensified and extended the harsh climatic conditions at the K-Pg boundary. Subsequently, the deposition of this dust, enriched in bioavailable iron, on Earth's surface might have contributed to the swift recovery of life and environmental conditions.

白垩纪-古近纪(K-Pg)边界代表了约 70% 的物种灭绝、突出的奇克苏吕布撞击事件和德干火山活动。本研究报告首次尝试从德干半岛岩层间提取微陨石(MMs)。对 81 个球形颗粒的形态、纹理和化学特征进行了研究。具有铁镁硅酸盐(6)和铁镍氧化物(7)成分的完整宇宙球粒与深海和南极洲的微陨石相对应。本研究中的硅酸盐和铁镍球体保存完好,证明了当时的条件非常有利。含氧化铁成分的铁球(38 个)在保存过程中表现出成岩蚀变。对 30 个铁球的纹理分析表明,这些铁球呈树枝状交错排列,锰含量略高,表明它们可能是 I 型 MMs 化石。然而,8 个具有块状和立方颗粒状纹理的铁球粒类似于氧化黄铁矿球粒。铝-铁-硅球化石(30)在其以铁氧化物为主的成分中,铝和硅的含量显著增加。第 I 组 Al-Fe-Si 球粒(15)显示了带状 Al-Fe-Si 氧化物成分、树枝状 Mg-Cr 尖晶石颗粒和空气动力学特征,所有这些都表明是撞击球粒。从德干半岛岩层间取样中发现的这些撞击球体提出了一种可能性,即这些古溶胶是在奇克苏卢布撞击事件期间沉积下来的,而奇克苏卢布撞击事件是在德干火山活动期间唯一确定的分布于全球的撞击事件。这一独特的位置为同时收集保存完好的 MMs、撞击和火山球提供了机会。所研究的 MMs 得以保存完好,很可能是由于非海洋环境、非典型气候条件和快速沉积的综合作用。这项研究进一步探讨了宇宙尘埃通量在 K-Pg 灭绝事件中的潜在作用。我们认为,在K-Pg边界时期,宇宙尘埃通量的增强很可能与高层大气中的撞击尘埃混合在一起,从而加剧并延长了K-Pg边界的恶劣气候条件。随后,这些富含生物可利用铁的尘埃沉积在地球表面,可能促进了生命和环境条件的迅速恢复。
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引用次数: 0
Cosmic-ray exposure age accumulated in near-Earth space: A carbonaceous chondrite case study 近地空间积累的宇宙射线暴露年龄:碳质软玉案例研究
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-27 DOI: 10.1111/maps.14246
Patrick M. Shober, Marc W. Caffee, Phil A. Bland

This study investigates the expected cosmic-ray exposure (CRE) of meteorites if they were to be ejected by a near-Earth object, that is, from an object already transferred to an Earth-crossing orbit by an orbital resonance. Specifically, we examine the CRE ages of CI and CM carbonaceous chondrites (CCs), which have some of the shortest measured CRE ages of any meteorite type. A steady-state near-Earth carbonaceous meteoroid probability density function is estimated based on the low-albedo near-Earth asteroid population, including parameters such as the near-Earth dynamic lifetime, the impact probability with the Earth, and the orbital parameters. This model was then compared to the orbits and CRE ages of the five CC falls with precisely measured orbits: Tagish Lake, Maribo, Sutter's Mill, Flensburg, and Winchcombe. The study examined two meteoroid ejection scenarios for CI/CM meteoroids: Main Belt collisions and ejections in near-Earth space. The results indicated that applying a maximum physical lifetime in near-Earth space of 2–10 Myr to meteoroids and eliminating events evolving onto orbits entirely detached from the Main Belt (Q < 1.78 au) significantly improved the agreement with the observed orbits of carbonaceous falls. Additionally, the CRE ages of three of the five carbonaceous falls have measured CRE ages one to three orders of magnitude shorter than expected for an object originating from the Main Belt with the corresponding semi-major axis value. This discrepancy between the expected CRE ages from the model and the measured ages of three of the carbonaceous falls indicates that some CI/CM meteoroids are being ejected in near-Earth space. This study proposes a nuanced hypothesis involving meteoroid impacts and tidal disruptions as significant contributors to the ejection and subsequent CRE age accumulation of CI/CM chondrites in near-Earth space.

本研究调查了如果陨石被近地天体(即已经通过轨道共振转移到地球穿越轨道上的天体)抛射出来时,陨石的预期宇宙射线暴露(CRE)。具体来说,我们研究了 CI 和 CM 碳质球粒陨石(CCs)的 CRE 年龄,在所有陨石类型中,CI 和 CM 碳质球粒陨石的实测 CRE 年龄是最短的。根据低地温近地小行星群,包括近地动态寿命、撞击地球概率和轨道参数等参数,估算了稳态近地碳质陨石概率密度函数。然后将这一模型与精确测量轨道的五颗CC坠落的轨道和CRE年龄进行比较:塔吉什湖、马里博、萨特磨坊、弗伦斯堡和温奇科姆。该研究考察了 CI/CM 流星体的两种流星体抛射情况:主带碰撞和近地空间抛射。结果表明,将流星体在近地空间的最大物理寿命定为 2-10 Myr,并剔除完全脱离主带(Q < 1.78 au)的轨道演化事件,大大提高了与碳质坠落观测轨道的一致性。此外,在五颗碳质坠落物中,有三颗测得的碳质坠落物的 CRE 年龄比预期的要短一到三个数量级。模型的预期 CRE 年龄与三个碳质坠落的测量年龄之间的这种差异表明,一些 CI/CM 流星体正在近地空间喷射。本研究提出了一个微妙的假说,即流星体撞击和潮汐扰动是导致近地空间 CI/CM 星体抛射和随后 CRE 年龄累积的重要因素。
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引用次数: 0
86th Annual Meeting of the Meteoritical Society (2024) 第 86 届气象学会年会(2024 年)
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-25 DOI: 10.1111/maps.14240
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引用次数: 0
86th Annual Meeting of the Meteoritical Society (2024) 第 86 届气象学会年会(2024 年)
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-25 DOI: 10.1111/maps.14239
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引用次数: 0
86th Annual Meeting of the Meteoritical Society (2024) 第 86 届气象学会年会(2024 年)
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-25 DOI: 10.1111/maps.14252

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引用次数: 0
Cover 封面
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-15 DOI: 10.1111/maps.14016

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引用次数: 0
Chondrule sizes within the CM carbonaceous chondrites and measurement methodologies CM 碳质软玉的软骨尺寸和测量方法
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-08 DOI: 10.1111/maps.14250
C. J. Floyd, S. Benito, P.-E. Martin, L. E. Jenkins, E. Dunham, L. Daly, M. R. Lee

The sizes of chondrules are a valuable tool for understanding relationships between meteorite groups and the affinity of ungrouped chondrites, documenting temporal/spatial variability in the solar nebula, and exploring the effects of parent body processing. Many of the recently reported sizes of chondrules within the CM carbonaceous chondrites differ significantly from the established literature average and are more closely comparable to those of chondrules within CO chondrites. Here, we report an updated analysis of chondrule dimensions within the CM group based on data from 1937 chondrules, obtained across a suite of CM lithologies ranging from petrologic subtypes CM2.2 to CM2.7. Our revised average CM chondrule size is 194 μm. Among the samples examined, a relationship was observed between petrologic subtype and chondrule size such that chondrule long-axis lengths are greater in the more highly aqueously altered lithologies. These findings suggest a greater similarity between the CM and CO chondrites than previously thought and support arguments for a genetic link between the two groups (i.e., the CM-CO clan). Using the 2-D and 3-D data gathered, we also apply numerous stereological corrections to examine their usefulness in correcting 2-D chondrule measurements within the CM chondrites. Alongside this analysis, we present the details of a standardized methodology for 2-D chondrule size measurement to facilitate more reliable inter-study comparisons.

对于了解陨石群之间的关系和未分类的软玉的亲缘关系、记录太阳星云的时间/空间变异性以及探索母体加工的影响,软玉的尺寸是一种宝贵的工具。最近报告的CM碳质软粒岩中的许多软粒的尺寸与文献中的平均值有很大不同,与CO软粒岩中的软粒的尺寸更接近。在此,我们根据从岩石学亚型CM2.2到CM2.7的一系列CM岩石中获得的1937颗软玉数据,报告了对CM类软玉尺寸的最新分析。我们修订后的 CM 软骨平均尺寸为 194 μm。在所研究的样品中,我们观察到岩石亚型与软骨大小之间的关系,即在水蚀变程度较高的岩性中,软骨的长轴长度较大。这些发现表明,CM和CO软玉之间的相似性比以前认为的要大,并支持这两类软玉之间存在遗传联系(即CM-CO家族)的论点。利用收集到的二维和三维数据,我们还应用了大量的立体学修正方法,以检验这些方法在修正 CM 硬质岩中的二维软骨测量值方面的实用性。在进行分析的同时,我们还详细介绍了二维软骨尺寸测量的标准化方法,以便进行更可靠的研究间比较。
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引用次数: 0
Petrographic and geochemical analysis of lunar meteorite NWA 11788: Parallels with Luna 20 and the Apollo magnesian granulites 月球陨石 NWA 11788 的岩石学和地球化学分析:与月球20号和阿波罗镁质花岗岩的相似之处
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-06 DOI: 10.1111/maps.14248
Craig R. Hulsey, Katie M. O'Sullivan

The first in-depth geochemical and petrological analyses of new lunar meteorite Northwest Africa (NWA) 11788 were conducted with the aim of better understanding the diversity of lunar rock types. Petrography, microcomputed tomography, electron probe microanalysis, and laser ablation inductively coupled plasma mass spectrometry were employed to analyze mineralogic/elemental makeup, petrologic profile, melt history, and inferred composition of the lunar mantle from which the crystals in this sample originated from. Geochemical maps of the lunar surface were generated to constrain potential lunar launch locations for NWA 11788. Potential launch locations are concentrated in the outer rims of impact basins on the lunar Eastern nearside limb (e.g., Crisium, Fecunditatis, Marginis, Smythii) and around the South Pole–Aitken Basin. Similarities in the major, minor, and trace element chemistry of NWA 11788 along with its potential launch locations suggest a petrogenetic relationship with regolith samples returned from the Luna 20 mission and the Apollo 16 and 17 magnesian granulites. Additionally, the results of this study add to the growing body of evidence that KREEP (potassium, rare earth elements, phosphorous)-poor, Mg-suite-“like” lithologies are common in non-Apollo-type locales, that KREEP may not be required to generate lithologies like the Mg-suite, and that KREEP is not globally distributed at present.

为了更好地了解月球岩石类型的多样性,首次对新月球陨石西北非洲(NWA)11788 进行了深入的地球化学和岩石学分析。研究采用了岩相学、微型计算机断层扫描、电子探针显微分析和激光烧蚀电感耦合等离子体质谱仪,分析了矿物学/元素构成、岩石学剖面、熔融历史以及推断的月幔成分,该样本中的晶体就来自月幔。绘制了月球表面地球化学图,以确定 NWA 11788 的潜在月球发射位置。潜在的发射地点集中在月球东侧近边缘撞击盆地的外缘(如 Crisium、Fecunditatis、Marginis、Smythii)和南极-Aitken 盆地周围。NWA 11788的主要元素、次要元素和微量元素化学成分与其潜在的发射地点相似,这表明它与月球20号任务返回的碎屑岩样本以及阿波罗16号和17号的镁质花岗岩存在岩石成因关系。此外,这项研究的结果增加了越来越多的证据,表明钾、稀土元素和磷(KREEP)贫乏、类似镁套件的岩性在非阿波罗类型的地方很常见,钾、稀土元素和磷可能不是产生类似镁套件的岩性所必需的,而且目前钾、稀土元素和磷并不是全球分布的。
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引用次数: 0
Cosmic pears from the Havelland (Germany): Ribbeck, the twelfth recorded aubrite fall in history 来自哈弗兰(德国)的宇宙梨:里贝克,历史上第十二次有记载的白玉坠落
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-31 DOI: 10.1111/maps.14245
Addi Bischoff, Markus Patzek, Jean-Alix Barrat, Jasper Berndt, Henner Busemann, Detlev Degering, Tommaso Di Rocco, Mattias Ek, Dennis Harries, Jose R. A. Godinho, Dieter Heinlein, Armin Kriele, Daniela Krietsch, Colin Maden, Oscar Marchhart, Rachael M. Marshal, Martin Martschini, Silke Merchel, Andreas Möller, Andreas Pack, Herbert Raab, Maximilian P. Reitze, Ina Rendtel, Miriam Rüfenacht, Oliver Sachs, Maria Schönbächler, Anja Schuppisser, Iris Weber, Alexander Wieser, Karl Wimmer

In 1889 the German poet and novelist Theodor Fontane wrote the popular literary ballad “Herr von Ribbeck auf Ribbeck im Havelland.” The Squire von Ribbeck is described as a gentle and generous person, who often gives away pears from his pear trees to children passing by and continued donating pears after his death. Now, 135 years later the rock called Ribbeck is giving us insight into processes that happened 4.5 billion years ago. The meteorite Ribbeck (official find location: 52°37′15″N, 12°45′40″E) fell January 21, 2024, and has been classified as a brecciated aubrite. This meteoroid actually entered the Earth's atmosphere at 00:32:38 UTC over Brandenburg, west of Berlin, and the corresponding fireball was recorded by professional all sky and video cameras. More than 200 pieces (two proved by radionuclide analysis to belong to this fresh fall) were recovered totaling about 1.8 kg. Long-lived radionuclide and noble gas data are consistent with long cosmic ray exposure (55–62 Ma) and a preatmospheric radius of Ribbeck between 20 and 30 cm. The heavily brecciated aubrite consists of major (76 ± 3 vol%) coarse-grained FeO-free enstatite (En99.1Fs<0.04Wo0.9), with a significant abundance (15.0 ± 2.5 vol%) of albitic plagioclase (Ab95.3 An2.0Or2.7), minor forsterite (5.5 ± 1.5 vol%; Fo99.9) and 3.5 ± 1.0 vol% of opaque phases (mainly sulfides and metals) with traces of nearly FeO-free diopside (En53.2Wo46.8) and K-feldspar (Ab4.6Or95.4). The rock has a shock degree of S3 (U-S3), and terrestrial weathering has affected metals and sulfides, resulting in the brownish appearance of rock pieces and the partial destruction of certain sulfides already within days after the fall. The bulk chemical data confirm the feldspar-bearing aubritic composition. Ribbeck is closely related to the aubrite Bishopville. Ribbeck does not contain solar wind implanted gases and is a fragmental breccia. Concerning the Ti- and O-isotope compositions, the data are similar to those of other aubrites. They are also similar to E chondrites and fall close to the data point for the bulk silicate Earth (BSE). Before the Ribbeck meteoroid entered Earth's atmosphere, it was observed in space as asteroid 2024 BX1. The aphelion distance of 2024 BX1's orbit lies in the innermost region of the asteroid belt, which is populated by the Hungaria family of minor planets characterized by their E/X-type taxonomy and considered as the likely source of aubrites. The spectral comparison of an average large-scale emission spectrum of Mercury converted into reflectance and of the Ribbeck meteorite spectrum does not show any meaningful similarities.

1889 年,德国诗人兼小说家 Theodor Fontane 写了一首脍炙人口的民谣 "Herr von Ribbeck auf Ribbeck im Havelland"。诗中描述的乡绅冯-里贝克是一个温柔慷慨的人,他经常把自己梨树上的梨送给路过的孩子,而且在他去世后还继续捐献梨子。135 年后的今天,这块名为 "里贝克 "的岩石让我们了解到 45 亿年前发生的一切。里贝克陨石(官方发现位置:北纬 52°37′15″,东经 12°45′40″)于 2024 年 1 月 21 日坠落,被归类为角砾岩。这颗流星体实际上是在世界协调时 00:32:38 在柏林以西的勃兰登堡上空进入地球大气层的,相应的火球被专业的全天空相机和摄像机记录了下来。回收的 200 多块碎片(其中两块经放射性核素分析证明属于这颗新坠落的陨石)总重量约为 1.8 千克。长寿命放射性核素和惰性气体数据与长期宇宙射线照射(55-62Ma)和大气层前的里贝克半径在 20 至 30 厘米之间相一致。严重角砾化的闪长岩主要由(76 ± 3 vol%)粗粒度无氧化铁的辉长岩(En99.1Fs<0.04Wo0.9)组成,并含有大量(15.0 ± 2.5 vol%)白云母斜长岩(Ab95.3 An2.0Or2.7)、少量绿柱石(5.5 ± 1.5 Vol%;Fo99.9)和 3.5 ± 1.0 Vol%的不透明相(主要是硫化物和金属),以及微量几乎不含 FeO 的透辉石(En53.2Wo46.8)和 K 长石(Ab4.6Or95.4)。这块岩石的震度为 S3(U-S3),陆地风化作用对金属和硫化物产生了影响,导致岩石碎片呈褐色,某些硫化物在坠落后几天内就已部分破坏。大块化学数据证实了长石含长岩成分。Ribbeck与奥长岩Bishopville关系密切。里贝克不含太阳风植入气体,是一块碎屑角砾岩。关于 Ti- 和 O-同位素组成,其数据与其他奥勃里特岩相似。这些数据也与 E 型软玉相似,并接近于大块硅酸盐地球(BSE)的数据点。在里贝克流星体进入地球大气层之前,它在太空中被观测为小行星 2024 BX1。2024 BX1 小行星轨道的远日点距离位于小行星带的最内侧区域,该区域内有以 E/X 型分类法为特征的 Hungaria 小行星家族,被认为可能是奥布里特星的来源。将水星的平均大尺度发射光谱转换成反射光谱与里贝克陨石光谱进行比较,没有发现任何有意义的相似之处。
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引用次数: 0
Characterization of bulk interior and fusion crust of Calama 009 L6 ordinary chondrite 卡拉马009 L6普通软玉体内部和熔融结壳的特征描述
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-30 DOI: 10.1111/maps.14249
E. V. Petrova, A. V. Chukin, G. Varga, Z. Dankházi, G. Leitus, I. Felner, E. Kuzmann, Z. Homonnay, V. I. Grokhovsky, M. I. Oshtrakh

Fragment of Calama 009 L6 ordinary chondrite recovered in the Atacama Desert was chosen for a complex study of the bulk interior and the fusion crust by scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), magnetization measurements, and Mössbauer spectroscopy. SEM demonstrated the presence of Fe-Ni-Co grains, troilite and chromite inclusions in both the bulk interior and the fusion crust as well as many veins with ferric compound. EDS showed variations in the Ni concentration within the metal grains and within one metal phase in the grain. XRD revealed some differences in the contents of various phases in the bulk interior and in the fusion crust. XRD indicated the presence of magnesioferrite in the fusion crust as well as the formation of goethite nanoparticles with the mean size of 9 nm in both the bulk interior and the fusion crust. Magnetization measurements demonstrated the ferrimagnetic–paramagnetic phase transition in chromite at 44 K and low values of the saturation magnetization moments (6.46 and 3.26 emu g−1 at 100 K) for the bulk interior and the fusion crust, respectively, due to the lack of Fe-Ni-Co alloy as a result of weathering. The Mössbauer spectra of the bulk interior and the fusion crust showed some differences in the number and relative areas of spectral components. The revealing of the Mössbauer spectral components related to 57Fe in the M1 and M2 sites in olivine and orthopyroxene as well as determining the Fe2+ occupations of these sites from XRD permitted us to estimate the temperature of equilibrium cation distribution for these silicates which are (i) 662 K (XRD) and 706 K (Mössbauer spectroscopy) for olivine and (ii) 893 K (XRD) and 910 K (Mössbauer spectroscopy) for orthopyroxene.

我们选择了在阿塔卡马沙漠发现的卡拉马 009 L6 普通软玉碎片,通过扫描电子显微镜(SEM)、能量色散光谱(EDS)、X 射线衍射(XRD)、磁化测量和莫斯鲍尔光谱,对其内部和熔融结壳进行了复杂的研究。扫描电子显微镜显示了铁-镍-钴晶粒、块状内部和熔融结壳中的铁锂石、铬铁矿包裹体以及许多含铁化合物的矿脉。EDS 显示,金属晶粒内部和晶粒中某一金属相内的镍浓度存在差异。X 射线衍射显示,内部和熔融结壳中各种相的含量存在一些差异。XRD 显示熔壳中存在菱镁铁,并且在主体内部和熔壳中都形成了平均尺寸为 9 纳米的网纹石纳米颗粒。磁化测量结果表明,铬铁矿在 44 K 时发生了铁磁-顺磁相变,由于风化导致铁-镍-钴合金缺乏,主体内部和熔壳的饱和磁化矩值较低(100 K 时分别为 6.46 和 3.26 emu g-1)。块体内部和熔融结壳的莫斯鲍尔光谱在光谱成分的数量和相对面积上存在一些差异。通过揭示橄榄石和正辉石 M1 和 M2 位点中与 57Fe 有关的莫斯鲍尔光谱成分,并通过 XRD 确定这些位点的 Fe2+ 占有率,我们可以估算出这些硅酸盐的平衡阳离子分布温度:(i) 橄榄石为 662 K(XRD)和 706 K(莫斯鲍尔光谱);(ii) 正辉石为 893 K(XRD)和 910 K(莫斯鲍尔光谱)。
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