Kohei Fukuda, Yuki Hibiya, Craig R. Kastelle, Katsuhiko Suzuki, Tsuyoshi Iizuka, Katsuyuki Yamashita, Thomas E. Helser, Noriko T. Kita
Understanding the material transport and mixing processes in the Solar protoplanetary disk provides important constraints on the origin of chemical and isotopic diversities of our planets. The limited extent of radial transport and mixing between the inner and outer Solar System has been suggested based on a fundamental isotopic dichotomy between non-carbonaceous (NC) and carbonaceous (CC) meteorite groups. The limited transport and mixing could be further tested by tracing the formation regions of individual meteoritic components, such as Ca-Al-rich inclusions (CAIs) and chondrules. Here, we show further evidence for the outward transport of CAIs and chondrules from the inner and subsequent thermal processing in the outer region of the protoplanetary disk based on the petrography and combined Cr-Ti-O isotope systematics of chondrules from the Vigarano-like (CV) carbonaceous chondrite Allende. One chondrule studied consists of an olivine core that exhibits NC-like Ti and O, but CC-like Cr isotopic signatures, which is enclosed by a pyroxene igneous rim with CC-like O isotope ratios. These observations indicate that the olivine core formed in the inner Solar System. The olivine core then migrated into the outer Solar System and experienced nebular thermal processing that generated the pyroxene igneous rim. The nebular thermal processing would result in Cr isotope exchange between the olivine core and CC-like materials, but secondary alteration effects on the parent body are also responsible for the CC-like Cr isotope signature. By combining previously reported Cr-Ti-O isotope systematics of CV chondrules, we show that some CV chondrules larger than ~1 mm would have formed in the inner Solar System. The accretion of the millimeter-sized, inner Solar System solids onto the CV carbonaceous chondrite parent body would require their very early migration into the outer Solar System within the first 1 million years after the Solar System formation.
{"title":"Radial transport and nebular thermal processing of millimeter-sized solids in the Solar protoplanetary disk inferred from Cr-Ti-O isotope systematics of chondrules","authors":"Kohei Fukuda, Yuki Hibiya, Craig R. Kastelle, Katsuhiko Suzuki, Tsuyoshi Iizuka, Katsuyuki Yamashita, Thomas E. Helser, Noriko T. Kita","doi":"10.1111/maps.14276","DOIUrl":"https://doi.org/10.1111/maps.14276","url":null,"abstract":"<p>Understanding the material transport and mixing processes in the Solar protoplanetary disk provides important constraints on the origin of chemical and isotopic diversities of our planets. The limited extent of radial transport and mixing between the inner and outer Solar System has been suggested based on a fundamental isotopic dichotomy between non-carbonaceous (NC) and carbonaceous (CC) meteorite groups. The limited transport and mixing could be further tested by tracing the formation regions of individual meteoritic components, such as Ca-Al-rich inclusions (CAIs) and chondrules. Here, we show further evidence for the outward transport of CAIs and chondrules from the inner and subsequent thermal processing in the outer region of the protoplanetary disk based on the petrography and combined Cr-Ti-O isotope systematics of chondrules from the Vigarano-like (CV) carbonaceous chondrite Allende. One chondrule studied consists of an olivine core that exhibits NC-like Ti and O, but CC-like Cr isotopic signatures, which is enclosed by a pyroxene igneous rim with CC-like O isotope ratios. These observations indicate that the olivine core formed in the inner Solar System. The olivine core then migrated into the outer Solar System and experienced nebular thermal processing that generated the pyroxene igneous rim. The nebular thermal processing would result in Cr isotope exchange between the olivine core and CC-like materials, but secondary alteration effects on the parent body are also responsible for the CC-like Cr isotope signature. By combining previously reported Cr-Ti-O isotope systematics of CV chondrules, we show that some CV chondrules larger than ~1 mm would have formed in the inner Solar System. The accretion of the millimeter-sized, inner Solar System solids onto the CV carbonaceous chondrite parent body would require their very early migration into the outer Solar System within the first 1 million years after the Solar System formation.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"59 12","pages":"3282-3304"},"PeriodicalIF":2.2,"publicationDate":"2024-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/maps.14276","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142862165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. L. MacArthur, K. H. Joy, R. H. Jones, T. A. Harvey, N. V. Almeida
The field of advanced curation is important for existing astromaterials collections, which includes samples returned by space missions, and meteorites and cosmic dust samples that have been recovered from here on Earth. In order to maximize the scientific return of the samples, contamination needs to be minimized at all stages of sample collection, preliminary examination, classification, and curation. Utilizing best practice methods, a detailed acquisition and curation plan was implemented during the UK's first two expeditions to collect Antarctic meteorites from two new blue icefields, Hutchison Icefields and Outer Recovery Icefields. This article documents the design and execution of the procedures used during the project's curation and classification processes. It describes two case studies showing the processes applied to the recovered meteorites, and reviews our experiences and lessons learned for the future.
{"title":"Curation and classification procedures for the UK Antarctic meteorite collection","authors":"J. L. MacArthur, K. H. Joy, R. H. Jones, T. A. Harvey, N. V. Almeida","doi":"10.1111/maps.14273","DOIUrl":"https://doi.org/10.1111/maps.14273","url":null,"abstract":"<p>The field of advanced curation is important for existing astromaterials collections, which includes samples returned by space missions, and meteorites and cosmic dust samples that have been recovered from here on Earth. In order to maximize the scientific return of the samples, contamination needs to be minimized at all stages of sample collection, preliminary examination, classification, and curation. Utilizing best practice methods, a detailed acquisition and curation plan was implemented during the UK's first two expeditions to collect Antarctic meteorites from two new blue icefields, Hutchison Icefields and Outer Recovery Icefields. This article documents the design and execution of the procedures used during the project's curation and classification processes. It describes two case studies showing the processes applied to the recovered meteorites, and reviews our experiences and lessons learned for the future.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"59 12","pages":"3215-3228"},"PeriodicalIF":2.2,"publicationDate":"2024-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/maps.14273","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142862164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Juulia-Gabrielle Moreau, Argo Jõeleht, Aleksandra N. Stojic, Christopher Hamann, Felix E. D. Kaufmann, Peeter Somelar, Jüri Plado, Satu Hietala, Tomas Kohout
Iron sulfide and metal melt veins in chondritic materials are associated with advanced stages of dynamic shock. The shock-induced residual temperatures liquefy the sulfide component and enable melt distribution. However, the distribution mechanism is not yet fully understood. Capillary forces are proposed as agents of melt distribution; yet, no laboratory experiments were conducted to assess the role that capillary forces play in the redistribution of iron sulfide in post-shock conditions. To investigate this further, we conducted thermal experiments under reducing conditions (N2(g)) using dunitic fragments, suitable chondritic analog materials that were doped with synthesized troilite (stoichiometric exact FeS). We observed extensive iron sulfide (troilite) migration that partially resembles that of ordinary chondrites, without the additional influence of shock pressure-induced fracturing. The iron sulfide melt infiltrated grain boundaries and pre-existing fractures that darkened the analog material pervasively. We also observed that the iron sulfide melt, which mobilized into grain boundaries, got systematically enriched in Ni from the surrounding host olivine. Consequently, FeNi metal fractionated from the melt in several places. Our results indicate that capillary forces majorly contribute to melt migration in the heated post-shock environment.
{"title":"Experimentally induced troilite melt pervasion in chondritic analog materials: A study for FeNi-FeS darkening in chondrites","authors":"Juulia-Gabrielle Moreau, Argo Jõeleht, Aleksandra N. Stojic, Christopher Hamann, Felix E. D. Kaufmann, Peeter Somelar, Jüri Plado, Satu Hietala, Tomas Kohout","doi":"10.1111/maps.14274","DOIUrl":"https://doi.org/10.1111/maps.14274","url":null,"abstract":"<p>Iron sulfide and metal melt veins in chondritic materials are associated with advanced stages of dynamic shock. The shock-induced residual temperatures liquefy the sulfide component and enable melt distribution. However, the distribution mechanism is not yet fully understood. Capillary forces are proposed as agents of melt distribution; yet, no laboratory experiments were conducted to assess the role that capillary forces play in the redistribution of iron sulfide in post-shock conditions. To investigate this further, we conducted thermal experiments under reducing conditions (N<sub>2</sub>(g)) using dunitic fragments, suitable chondritic analog materials that were doped with synthesized troilite (stoichiometric exact FeS). We observed extensive iron sulfide (troilite) migration that partially resembles that of ordinary chondrites, without the additional influence of shock pressure-induced fracturing. The iron sulfide melt infiltrated grain boundaries and pre-existing fractures that darkened the analog material pervasively. We also observed that the iron sulfide melt, which mobilized into grain boundaries, got systematically enriched in Ni from the surrounding host olivine. Consequently, FeNi metal fractionated from the melt in several places. Our results indicate that capillary forces majorly contribute to melt migration in the heated post-shock environment.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"59 12","pages":"3229-3249"},"PeriodicalIF":2.2,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. J. G. Jurewicz, A. M. Amarsi, D. S. Burnett, N. Grevesse
CI chondrites have been a proxy for the solar system since the mid-20th century. The photospheric and CI chondrite abundances (P and CI, respectively) show a strong correlation. CI as a proxy is also justified by the (i) smoothness of their abundances plotted as a function of odd mass number and (ii) agreement within the error of P as determined spectroscopically. But our statistical assessment of spectroscopic studies and solar wind from the Genesis mission indicates that the small, ~10%–30%, differences (residuals) between CI and P depend on the 50% condensation temperature (Tc50). So, if CI is to be used as a proxy for P, Cosmochemists may want to add a correction to individual elements. Our work is consistent with two published hypotheses: that (i) residuals are linear with Tc50 and (ii) that elements having Tc50 > 1343 K are depleted relative to those with 495 K < Tc50 < 1343 K in CI. We discuss other interpretations which are also feasible. Understanding these small differences of the CI and P for different elements and their variation with Tc50 can help constrain future models of solar system formation and the history of CI chondrites.
自20世纪中期以来,CI软玉一直是太阳系的替代物。光球和 CI 硬玉丰度(分别为 P 和 CI)显示出很强的相关性。CI作为替代物的理由还包括:(i)其丰度与奇数质量数的函数关系曲线的平滑性;(ii)在光谱测定的P误差范围内的一致性。但我们对创世纪任务的光谱研究和太阳风的统计评估表明,CI 和 P 之间的微小差异(约 10%-30%)取决于 50%的冷凝温度(Tc50)。因此,如果将 CI 用作 P 的替代值,宇宙化学家可能需要对个别元素进行修正。我们的工作符合两个已发表的假设:(i)残差与 Tc50 呈线性关系;(ii)在 CI 中,Tc50 > 1343 K 的元素相对于 495 K < Tc50 < 1343 K 的元素是贫化的。我们还讨论了其他可行的解释。了解不同元素的CI和P的微小差异及其随Tc50的变化,有助于制约太阳系形成的未来模型和CI软玉的历史。
{"title":"Differences in elemental abundances between CI chondrites and the solar photosphere","authors":"A. J. G. Jurewicz, A. M. Amarsi, D. S. Burnett, N. Grevesse","doi":"10.1111/maps.14272","DOIUrl":"https://doi.org/10.1111/maps.14272","url":null,"abstract":"<p>CI chondrites have been a proxy for the solar system since the mid-20th century. The photospheric and CI chondrite abundances (<b><i>P</i></b> and <b><i>CI</i></b>, respectively) show a strong correlation. <b><i>CI</i></b> as a proxy is also justified by the (i) smoothness of their abundances plotted as a function of odd mass number and (ii) agreement within the error of <b><i>P</i></b> as determined spectroscopically. But our statistical assessment of spectroscopic studies and solar wind from the Genesis mission indicates that the small, ~10%–30%, differences (residuals) between <b><i>CI</i></b> and <b><i>P</i></b> depend on the 50% condensation temperature (Tc<sub>50</sub>). So, if <b><i>CI</i></b> is to be used as a proxy for <b><i>P</i></b>, Cosmochemists may want to add a correction to individual elements. Our work is consistent with two published hypotheses: that (i) residuals are linear with Tc<sub>50</sub> and (ii) that elements having Tc<sub>50</sub> > 1343 K are depleted relative to those with 495 K < Tc<sub>50</sub> < 1343 K in <b><i>CI</i></b>. We discuss other interpretations which are also feasible. Understanding these small differences of the <b><i>CI</i></b> and <b><i>P</i></b> for different elements and their variation with Tc<sub>50</sub> can help constrain future models of solar system formation and the history of CI chondrites.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"59 12","pages":"3193-3214"},"PeriodicalIF":2.2,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/maps.14272","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142862024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Liam S. T. McGovern, Bruce L. A. Charlier, Colin J. N. Wilson
Stepwise acid leaching experiments were performed on the pre-rain CM2 fall Aguas Zarcas to interrogate release patterns and isolate fractions with isotopic anomalies. Acid leachates and a bulk sample were analyzed for elemental abundances via solution ICP-MS, and Sr and Ba isotopic compositions were measured using TIMS. Isotopic systematics reveal diverse values for the bulk sample and leachates, interpreted to reflect the Aguas Zarcas parent body history. Compared with the NBS987 standard, μ84Sr values for the bulk sample average + 90, while the leach fractions yield +326 to −2089, with the largest μ84Sr depletions in the strongest acid leachates. For Ba isotopes, the bulk sample shows resolvable depletions (μ values) in 130Ba (−210), 135Ba (−64), 137Ba (−73) and 138Ba (−89). Early leachates show positive anomalies in 130Ba (up to +2295), 132Ba, 135Ba, 137Ba, and 138Ba. In contrast, final leachates show strong depletions for the same nuclides (up to −60,000 ppm μ130Ba). The Sr and Ba isotopic anomalies found in the earlier leachates suggest that nucleosynthetic signatures were redistributed to more soluble phases during parent body alteration. Moreover, contrasting p-nuclide Sr and Ba nucleosynthetic anomalies suggest that presolar contributions came from a variety of nucleosynthetic sources, including possibly a rotating massive star undergoing a core-collapse supernova or an electron capture supernova.
{"title":"Ba and Sr isotopic patterns from step-leaching experiments on the pristine Aguas Zarcas CM2 meteorite","authors":"Liam S. T. McGovern, Bruce L. A. Charlier, Colin J. N. Wilson","doi":"10.1111/maps.14278","DOIUrl":"https://doi.org/10.1111/maps.14278","url":null,"abstract":"<p>Stepwise acid leaching experiments were performed on the pre-rain CM2 fall Aguas Zarcas to interrogate release patterns and isolate fractions with isotopic anomalies. Acid leachates and a bulk sample were analyzed for elemental abundances via solution ICP-MS, and Sr and Ba isotopic compositions were measured using TIMS. Isotopic systematics reveal diverse values for the bulk sample and leachates, interpreted to reflect the Aguas Zarcas parent body history. Compared with the NBS987 standard, μ<sup>84</sup>Sr values for the bulk sample average + 90, while the leach fractions yield +326 to −2089, with the largest μ<sup>84</sup>Sr depletions in the strongest acid leachates. For Ba isotopes, the bulk sample shows resolvable depletions (μ values) in <sup>130</sup>Ba (−210), <sup>135</sup>Ba (−64), <sup>137</sup>Ba (−73) and <sup>138</sup>Ba (−89). Early leachates show positive anomalies in <sup>130</sup>Ba (up to +2295), <sup>132</sup>Ba, <sup>135</sup>Ba, <sup>137</sup>Ba, and <sup>138</sup>Ba. In contrast, final leachates show strong depletions for the same nuclides (up to −60,000 ppm μ<sup>130</sup>Ba). The Sr and Ba isotopic anomalies found in the earlier leachates suggest that nucleosynthetic signatures were redistributed to more soluble phases during parent body alteration. Moreover, contrasting <i>p</i>-nuclide Sr and Ba nucleosynthetic anomalies suggest that presolar contributions came from a variety of nucleosynthetic sources, including possibly a rotating massive star undergoing a core-collapse supernova or an electron capture supernova.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"59 12","pages":"3353-3369"},"PeriodicalIF":2.2,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. C. Nottingham, N. M. Curran, J. Pernet-Fisher, R. Burgess, I. A. Crawford, J. D. Gilmour, R. Tartèse, K. H. Joy
The Apollo 16 regolith breccia sample suite provides a record of lunar regolith formation from the basin-forming epoch (~3.9 Ga) through to a time of declining impactor flux (~2 Ga). These rocks have been characterized into three groups: the “ancient,” “young,” and “soil-like” regolith breccias on the basis of their petrographic characteristics, and, in the case of the “ancient” and “young” regolith breccias, noble gas inventory. This study investigates the as-yet unexamined noble gas records of the “soil-like” regolith breccias to understand more recent regolith evolution processes that occurred at the Apollo 16 landing site. The range of gas concentrations measured for each noble gas in these samples is comparable to those previously reported for the local Apollo 16 soils. The “soil-like” regolith breccias were found to be more gas rich than the gas poor “young” and “ancient” regolith breccias, consistent with them having formed from comparatively mature soil(s). Our results further confirm the scientific value of lunar regolith breccias and bulk regolith samples as probes of the impact history and the space environment of the lunar surface across a wide range of time.
{"title":"Constraints on the impact history of the Apollo 16 landing site: Implications of soil-like breccia noble gas records","authors":"M. C. Nottingham, N. M. Curran, J. Pernet-Fisher, R. Burgess, I. A. Crawford, J. D. Gilmour, R. Tartèse, K. H. Joy","doi":"10.1111/maps.14244","DOIUrl":"https://doi.org/10.1111/maps.14244","url":null,"abstract":"<p>The Apollo 16 regolith breccia sample suite provides a record of lunar regolith formation from the basin-forming epoch (~3.9 Ga) through to a time of declining impactor flux (~2 Ga). These rocks have been characterized into three groups: the “ancient,” “young,” and “soil-like” regolith breccias on the basis of their petrographic characteristics, and, in the case of the “ancient” and “young” regolith breccias, noble gas inventory. This study investigates the as-yet unexamined noble gas records of the “soil-like” regolith breccias to understand more recent regolith evolution processes that occurred at the Apollo 16 landing site. The range of gas concentrations measured for each noble gas in these samples is comparable to those previously reported for the local Apollo 16 soils. The “soil-like” regolith breccias were found to be more gas rich than the gas poor “young” and “ancient” regolith breccias, consistent with them having formed from comparatively mature soil(s). Our results further confirm the scientific value of lunar regolith breccias and bulk regolith samples as probes of the impact history and the space environment of the lunar surface across a wide range of time.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"59 11","pages":"2883-2921"},"PeriodicalIF":2.2,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/maps.14244","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142642016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}