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IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-02-16 DOI: 10.1111/maps.14197

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引用次数: 0
CM carbonaceous chondrite petrofabrics and their implications for understanding the relative chronologies of parent body deformation and aqueous alteration
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-20 DOI: 10.1111/maps.14303
C. J. Floyd, L. E. Jenkins, P.-E. Martin, L. Daly, M. R. Lee

CM chondrites have been subjected to numerous alteration processes including brecciation and ductile deformation. Here, we present the results of 2D and 3D petrofabric analysis across a suite of meteorites: Aguas Zarcas, Cold Bokkeveld, Lewis Cliff (LEW) 85311, Murchison, and Winchcombe. We find that chondrule-defined petrofabrics are commonplace, but not ubiquitous. Where petrofabrics are present, alignment is typically observed in the chondrule long axes defining foliation fabrics. Alongside previous authors we interpolate the shock pressures to generate such fabrics between 27.8 and 41.8 GPa. Impacts capable of generating these shock pressures should ordinarily produce shock microstructures in olivine something not observed in the CMs. Whilst high calculated pre-compaction porosities may have had a role in attenuating energy transfer during collisions, we suggest the assumption of chondrule sphericity used in these calculations is misplaced and that a non-spherical pre-deformation chondrule shape is likely responsible for the dichotomy. We also reveal that the relative timings of aqueous alteration, brecciation, and deformation vary between CMs. Within Aguas Zarcas, we find multiple lithic clasts interpreted as having experienced different degrees of aqueous alteration, with opposing fabrics that formed after water/rock interaction but prior to brecciation. Meanwhile, within Cold Bokkeveld, we find a consistent fabric between clasts suggesting the fabric was imposed after both aqueous alteration and brecciation.

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引用次数: 0
Systematic meteorite collection in the Catalina Dense Collection area (Chile): Description and statistics
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-10 DOI: 10.1111/maps.14307
Carine Sadaka, Jérôme Gattacceca, Matthieu Gounelle, Mathieu Roskosz, Anthony Lagain, Romain Tartese, Lydie Bonal, Clara Maurel, Rodrigo Martinez, Millarca Valenzuela

We present the outcome of search campaigns conducted in the Catalina Dense Collection area (DCA) located in the central depression of the Atacama Desert, Chile. The “Catalina Systematic Collection” (CSC) was assembled through systematic on-foot searches, resulting in a total of 1599 meteorites, before pairing, collected over a surface of 6.80 km2. This yielded a recovery density of 235 meteorites per km2 (67 meteorites >20 g per km2), making it the densest among hot deserts, even higher than the neighboring El Médano DCA collection. This confirms that the central depression of the Atacama Desert holds the highest meteorite density among hot deserts. We classified 457 meteorites weighing more than 20 g. After correcting for various recovery biases, we estimated a true meteorite density on the ground of 131 meteorites per km2 for meteorites >20 g before pairing. Using a probabilistic approach, we calculated an average pairing likelihood, yielding 71 meteorites >20 g per km2 after pairing. This high density is likely linked to an old age of the CSC, which would also explain the absence of carbonaceous chondrites, as they are more prone to alteration by abrasion. This long meteorite accumulation period is related to the long-term hyper-aridity and surface stability of the Atacama Desert, which have persisted for several million years. Meteorites from the CSC show less chemical weathering on average than in other hot deserts, despite the long accumulation period. The H/L ratio in the CSC is higher than in meteorites from other hot deserts, Antarctica, and falls, but similar to the El Médano collection, potentially reflecting variations in the composition of the meteorite flux over the past Myr.

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引用次数: 0
Cover
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-10 DOI: 10.1111/maps.14195

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引用次数: 0
Petrology and shock history of hybrid lunar feldspathic–troctolitic breccia Northwest Africa 11515
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-09 DOI: 10.1111/maps.14301
Y. Li, P. J. A. McCausland, R. L. Flemming, G. R. Osinski

Lunar impact breccia meteorites contain clasts from unknown lunar regions, including areas not studied by past missions. These meteorites offer a unique opportunity to expand our knowledge of the Moon's crustal and mantle composition and processes. The recently classified lunar meteorite Northwest Africa (NWA) 11515 is a moderately shocked feldspathic breccia with anorthite plagioclase and mafic minerals. In this work, we report the shock history of lithic clasts using 2-D micro-X-ray diffraction, detailed mineralogy from micro-X-ray fluorescence, and electron probe microanalysis. NWA 11515 shows moderately shocked anorthite and highly shocked olivine and pyroxene. The plagioclase composition is invariant (An96.4 ± 0.7, n = 52), with variable mafic clasts overlapping Mg- and FAN-suite lithologies (Mg# 84.5 to 45.6 for olivine; Mg# 85.6 to 32.2 for pyroxene), similar to KREEP-depleted troctolites in Allan Hills A81005. Spinel-group oxides vary from aluminous spinel to chromite and ulvöspinel. We also observed slow-cooled augite Ca-poor pyroxene exsolution clasts and fast-quenched fine-grained anorthite–olivine co-crystallized clasts (<5 μm), indicating different cooling histories. Combining petrological observations with published geochemical data, we show NWA 11515 has the mixed lithology of ferroan anorthosites with KREEP-poor magnesian rock fragments. With shock analysis, the materials are likely from a crater with minimum size of 7 km. Finally, we examined the published geochemical data for other lunar meteorites and hypothesize that other typical feldspathic breccias could contain magnesian clasts, suggesting the subdivision of typical feldspathic breccia into magnesian clast-hosting breccia and ferroan feldspathic breccia. This implies that non-KREEP magnesian magmatism might be more widespread in the post-LMO era on lunar highlands.

{"title":"Petrology and shock history of hybrid lunar feldspathic–troctolitic breccia Northwest Africa 11515","authors":"Y. Li,&nbsp;P. J. A. McCausland,&nbsp;R. L. Flemming,&nbsp;G. R. Osinski","doi":"10.1111/maps.14301","DOIUrl":"https://doi.org/10.1111/maps.14301","url":null,"abstract":"<p>Lunar impact breccia meteorites contain clasts from unknown lunar regions, including areas not studied by past missions. These meteorites offer a unique opportunity to expand our knowledge of the Moon's crustal and mantle composition and processes. The recently classified lunar meteorite Northwest Africa (NWA) 11515 is a moderately shocked feldspathic breccia with anorthite plagioclase and mafic minerals. In this work, we report the shock history of lithic clasts using 2-D micro-X-ray diffraction, detailed mineralogy from micro-X-ray fluorescence, and electron probe microanalysis. NWA 11515 shows moderately shocked anorthite and highly shocked olivine and pyroxene. The plagioclase composition is invariant (An96.4 ± 0.7, <i>n</i> = 52), with variable mafic clasts overlapping Mg- and FAN-suite lithologies (Mg# 84.5 to 45.6 for olivine; Mg# 85.6 to 32.2 for pyroxene), similar to KREEP-depleted troctolites in Allan Hills A81005. Spinel-group oxides vary from aluminous spinel to chromite and ulvöspinel. We also observed slow-cooled augite Ca-poor pyroxene exsolution clasts and fast-quenched fine-grained anorthite–olivine co-crystallized clasts (&lt;5 μm), indicating different cooling histories. Combining petrological observations with published geochemical data, we show NWA 11515 has the mixed lithology of ferroan anorthosites with KREEP-poor magnesian rock fragments. With shock analysis, the materials are likely from a crater with minimum size of 7 km. Finally, we examined the published geochemical data for other lunar meteorites and hypothesize that other typical feldspathic breccias could contain magnesian clasts, suggesting the subdivision of typical feldspathic breccia into magnesian clast-hosting breccia and ferroan feldspathic breccia. This implies that non-KREEP magnesian magmatism might be more widespread in the post-LMO era on lunar highlands.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"60 2","pages":"347-370"},"PeriodicalIF":2.2,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143423720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Search for pre-accretionary irradiation effects in calcium-aluminum inclusions from the CV3 chondrite Allende
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-07 DOI: 10.1111/maps.14300
P. Ghaznavi, C. Burkhardt, F. L. H. Tissot, I. Leya

Calcium-aluminum-rich inclusions (CAIs) are the first objects that formed in the solar accretion disk and therefore provide valuable insights into the evolution of the early solar system. A long-standing question regarding this earliest formative period relates to the storage of CAIs in the 1–4 Myr time period between their formation and later accretion into chondrite parent bodies. Were the CAIs stored in a pre-existing parent body, or in distant parts of the solar accretion disk? In the latter scenario, CAIs might have been exposed to cosmic rays, either from the galaxy or from the Sun and such pre-accretion irradiation effects might be detectable. We searched for such pre-accretional irradiation effects in 7 fine- and 11 coarse-grained CAIs from the CV 3.6 carbonaceous chondrite Allende. The extracted samples were analyzed for their major chemical composition and all samples were analyzed using μCT techniques. Using physical model calculations, 21Necos and (22Ne/21Ne)cos production rate ratios were calculated for each CAI by fully considering their individual chemical composition. Measured He, Ne, Ar, and Kr isotope compositions of the CAIs show cosmogenic signals; clear signals for He and Ne isotopes; and detectable signals for some of the Ar and Kr isotopes. In addition, most samples show clear indications for radiogenic 4He and some samples show evidence for radiogenic 40Ar. Higher 36Ar/38Ar, 22Ne/21Ne, 80Kr/84Kr, and 82Kr/84Kr ratios together with lower cosmogenic 38Arcos concentrations in fine-grained CAIs compared to coarse-grained CAIs are consistent with more alteration of the former compared to the latter. The CRE ages for the CAIs range between 4.12 ± 0.41 Myr and 6.40 ± 0.63 Myr. Statistical tests indicate that the data are normally distributed with no outliers, indicating that all CAIs share a common irradiation history, likely the irradiation in the Allende meteoroid. The average CRE age of 4.87 ± 0.19 Myr agrees with the nominally accepted CRE age of Allende of ~5.2 Myr. There is no correlation between 21Necos concentrations and indicators of aqueous alteration like Na and/or U concentrations. The lack of correlation together with the finding of normally distributed modeled CRE ages indicates that either none of the studied CAIs experienced a pre-accretion irradiation before parent body compaction and/or that any pre-accretion irradiation effects have been completely erased during aqueous alteration events. Taking alteration aside, the findings are not in favor of X-wind type models but are more consistent with the idea of CAI outward transport in an expanding disk.

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引用次数: 0
Geology, gravity, and numerical modeling of the Nova Colinas impact structure, Parnaíba Basin, Brazil
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-07 DOI: 10.1111/maps.14306
Pietro Demattê Avona, Alvaro Penteado Crósta, Marcos Alberto Rodrigues Vasconcelos, Evan Bjonnes, Fernando Lessa Pereira, Ana Maria Góes

Nova Colinas, centered at 07°09′33″ S/46°06′30″ W, is the ninth confirmed complex impact structure in Brazil and the fifth in the Parnaíba Basin, with a diameter of ~6.5–7 km and a nearly circular shape. Impactites include shocked siltstones from the Pedra de Fogo Fm. found at the central peak, brecciated sandstone from the Sambaíba Fm. bearing microscopic shock features, and brecciated basalt from the Mosquito Fm. bearing shatter cones. The impact event's age has been constrained to the interval from ~130 to ~199 Ma based on the local stratigraphy. Due to its moderate to advanced stage of erosion, geophysical modeling combined with geological field data were employed for its characterization. A new geological map was produced through field observations and remote sensing image interpretation, as well as a 3-D model based on ground gravity data and numerical modeling. iSALE2D shock physics code was employed to simulate the formation of Nova Colinas crater. The results revealed its main structural zones: the central uplift, annular basin, and outer rim, each associated with specific lithostratigraphic units from the Parnaíba Basin. Bouguer residual anomalies ranged from −3.6 to 1.2 mGal, with a nearly circular positive anomaly at the center of the structure, surrounded by a negative anomaly. 3-D gravity data inversion indicated a buried high-density body, likely due to the uplift of a diabase sill. Results of the numerical modeling point out that the final crater reached gravitational stability with a diameter of ~7 km and a depth of ~240 m, suggesting that a narrow outcrop strip of the Motuca Fm. was uplifted to a higher level compared to the Sambaíba Fm. strata, forming an antiform-like “arch” that creates an inner ring that exposes rocks of the Motuca Formation.

Nova Colinas位于南纬07°09′33″/西经46°06′30″,是巴西第九个被证实的复杂撞击结构,也是帕尔奈巴盆地的第五个,直径约为6.5-7千米,形状近似圆形。撞击岩包括位于中心山峰的福戈山地层(Pedra de Fogo Fm.)中的冲击粉砂岩、桑巴伊巴地层(Sambaíba Fm.)中带有微观冲击特征的碎屑砂岩以及蚊子地层(Mosquito Fm.)中带有碎裂锥的碎屑玄武岩。根据当地地层,撞击事件的年龄被推定为约 130 至约 199 Ma 之间。由于其侵蚀程度处于中高级阶段,因此采用了地球物理模型结合实地地质数据来确定其特征。通过实地观测和遥感图像判读绘制了新的地质图,并根据地面重力数据和数值建模建立了三维模型。研究结果揭示了火山口的主要结构区:中央隆起区、环形盆地和外缘区,每个结构区都与帕尔奈巴盆地的特定岩石地层单位有关。布格尔残余异常介于-3.6 到 1.2 mGal 之间,结构中心有一个近似圆形的正异常,周围是负异常。三维重力数据反演显示出一个埋藏的高密度岩体,很可能是由于辉绿岩山体的隆起造成的。数值建模结果表明,最终陨石坑在直径约 7 千米和深度约 240 米处达到重力稳定,这表明莫图卡地层的一条狭窄露头带被抬升到了比桑巴伊巴地层更高的位置,形成了一个类似蚁状的 "拱门",形成了一个暴露莫图卡地层岩石的内环。
{"title":"Geology, gravity, and numerical modeling of the Nova Colinas impact structure, Parnaíba Basin, Brazil","authors":"Pietro Demattê Avona,&nbsp;Alvaro Penteado Crósta,&nbsp;Marcos Alberto Rodrigues Vasconcelos,&nbsp;Evan Bjonnes,&nbsp;Fernando Lessa Pereira,&nbsp;Ana Maria Góes","doi":"10.1111/maps.14306","DOIUrl":"https://doi.org/10.1111/maps.14306","url":null,"abstract":"<p>Nova Colinas, centered at 07°09′33″ S/46°06′30″ W, is the ninth confirmed complex impact structure in Brazil and the fifth in the Parnaíba Basin, with a diameter of ~6.5–7 km and a nearly circular shape. Impactites include shocked siltstones from the Pedra de Fogo Fm. found at the central peak, brecciated sandstone from the Sambaíba Fm. bearing microscopic shock features, and brecciated basalt from the Mosquito Fm. bearing shatter cones. The impact event's age has been constrained to the interval from ~130 to ~199 Ma based on the local stratigraphy. Due to its moderate to advanced stage of erosion, geophysical modeling combined with geological field data were employed for its characterization. A new geological map was produced through field observations and remote sensing image interpretation, as well as a 3-D model based on ground gravity data and numerical modeling. iSALE2D shock physics code was employed to simulate the formation of Nova Colinas crater. The results revealed its main structural zones: the central uplift, annular basin, and outer rim, each associated with specific lithostratigraphic units from the Parnaíba Basin. Bouguer residual anomalies ranged from −3.6 to 1.2 mGal, with a nearly circular positive anomaly at the center of the structure, surrounded by a negative anomaly. 3-D gravity data inversion indicated a buried high-density body, likely due to the uplift of a diabase sill. Results of the numerical modeling point out that the final crater reached gravitational stability with a diameter of ~7 km and a depth of ~240 m, suggesting that a narrow outcrop strip of the Motuca Fm. was uplifted to a higher level compared to the Sambaíba Fm. strata, forming an antiform-like “arch” that creates an inner ring that exposes rocks of the Motuca Formation.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"60 2","pages":"286-307"},"PeriodicalIF":2.2,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143423522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Petrologic characterization of CO3.0 chondrites: Implications for 60Fe-60Ni analyses
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-01-02 DOI: 10.1111/maps.14299
Myriam Telus, Tyler D. Wickland, Kyle Kim, Steven Simon

Samples in which Fe and Ni isotopes have not been disturbed by secondary processing are essential for constraining the initial solar system abundance of short-lived radionuclide 60Fe, (60Fe/56Fe)SS. However, Fe- and Ni-enriched veins and fractures within chondrules in unequilibrated ordinary chondrites (UOCs) imply late-stage open-system alteration that poses a potential problem for both bulk and in situ 60Fe-60Ni systematics. This study focuses on petrologic characterization of CO3.0s, which show significantly less secondary alteration than UOCs, potentially making them better targets for studying 60Fe-60Ni systematics. We determined the petrologic type of several CO3.0 meteorites with two independent approaches, Raman spectroscopy of matrix material and Cr2O3 content of FeO-rich olivine grains. CO3 chondrites analyzed in this study range from 3.00 to 3.2 in petrologic type with slight variations between results from the two different methods. Upon analyzing two thin sections of DOM 08006, one of the most pristine CO3 chondrites known, we found a chemically anomalous region, indicative of parent body hydrothermal alteration. Using the X-ray fluorescence microscopy beamline at the Australian Synchrotron, we collected high-resolution quantitative element maps to evaluate Fe and Ni mobilization for several CO3.0s. These results indicate that late-stage Fe and Ni mobilization like that observed in UOC samples is minor for most CO3 chondrites, highly localized and mostly limited to chondrule rims. Our results support that CO3.0s are well suited for further investigation of 60Fe-60Ni systematics and that detailed characterization of both the petrologic type and late-stage Fe and Ni mobilization of samples is important for further development of this short-lived radionuclide system.

铁和镍同位素未受二次加工干扰的样品对于确定短寿命放射性核素 60Fe(60Fe/56Fe)SS 在太阳系的初始丰度至关重要。然而,不平衡普通软玉(UOCs)中软玉体内富含铁和镍的矿脉和裂缝意味着晚期开放系统的蚀变,这对块体和原位 60Fe-60Ni 系统学都构成了潜在的问题。本研究的重点是 CO3.0s 的岩石学特征,与 UOCs 相比,CO3.0s 的二次蚀变明显较少,这可能使它们成为研究 60Fe-60Ni 系统学的更好目标。我们采用两种独立的方法确定了几块 CO3.0 陨石的岩石类型,即基质材料的拉曼光谱和富含氧化铁橄榄石颗粒的 Cr2O3 含量。本研究分析的 CO3 鑛的岩石类型从 3.00 到 3.2 不等,两种不同方法得出的结果略有差异。DOM 08006 是已知最原始的 CO3 啁啾岩之一,在分析 DOM 08006 的两个薄片时,我们发现了一个化学异常区域,表明母体发生了热液蚀变。利用澳大利亚同步加速器的 X 射线荧光显微镜光束线,我们收集了高分辨率定量元素图,以评估几颗 CO3.0s 的铁和镍迁移情况。这些结果表明,在大多数 CO3.0s 中,像在 UOC 样品中观察到的晚期铁和镍迁移是轻微的、高度局部化的,并且主要局限于软骨边缘。我们的研究结果表明,CO3.0s非常适合进一步研究60Fe-60Ni的系统学,而对样品的岩石类型以及后期铁和镍的动员进行详细描述对于进一步开发这种短寿命放射性核素系统非常重要。
{"title":"Petrologic characterization of CO3.0 chondrites: Implications for 60Fe-60Ni analyses","authors":"Myriam Telus,&nbsp;Tyler D. Wickland,&nbsp;Kyle Kim,&nbsp;Steven Simon","doi":"10.1111/maps.14299","DOIUrl":"https://doi.org/10.1111/maps.14299","url":null,"abstract":"<p>Samples in which Fe and Ni isotopes have not been disturbed by secondary processing are essential for constraining the initial solar system abundance of short-lived radionuclide <sup>60</sup>Fe, (<sup>60</sup>Fe/<sup>56</sup>Fe)<sub>SS</sub>. However, Fe- and Ni-enriched veins and fractures within chondrules in unequilibrated ordinary chondrites (UOCs) imply late-stage open-system alteration that poses a potential problem for both bulk and <i>in situ</i> <sup>60</sup>Fe-<sup>60</sup>Ni systematics. This study focuses on petrologic characterization of CO3.0s, which show significantly less secondary alteration than UOCs, potentially making them better targets for studying <sup>60</sup>Fe-<sup>60</sup>Ni systematics. We determined the petrologic type of several CO3.0 meteorites with two independent approaches, Raman spectroscopy of matrix material and Cr<sub>2</sub>O<sub>3</sub> content of FeO-rich olivine grains. CO3 chondrites analyzed in this study range from 3.00 to 3.2 in petrologic type with slight variations between results from the two different methods. Upon analyzing two thin sections of DOM 08006, one of the most pristine CO3 chondrites known, we found a chemically anomalous region, indicative of parent body hydrothermal alteration. Using the X-ray fluorescence microscopy beamline at the Australian Synchrotron, we collected high-resolution quantitative element maps to evaluate Fe and Ni mobilization for several CO3.0s. These results indicate that late-stage Fe and Ni mobilization like that observed in UOC samples is minor for most CO3 chondrites, highly localized and mostly limited to chondrule rims. Our results support that CO3.0s are well suited for further investigation of <sup>60</sup>Fe-<sup>60</sup>Ni systematics and that detailed characterization of both the petrologic type and late-stage Fe and Ni mobilization of samples is important for further development of this short-lived radionuclide system.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"60 2","pages":"225-246"},"PeriodicalIF":2.2,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/maps.14299","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143424020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Methylene-to-methyl ratio variability in Ryugu samples: Clues to a heterogeneous aqueous alteration
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-24 DOI: 10.1111/maps.14304
Zélia Dionnet, Zahia Djouadi, Lukas Delaye, Lucas Caron, Rosario Brunetto, Alice Aléon-Toppani, Cateline Lantz, Stefano Rubino, Donia Baklouti, Tomoki Nakamura, Ferenc Borondics, Christophe Sandt, Megumi Matsumoto, Kana Amano, Tomoyo Morita, Hisayoshi Yurimoto, Takaaki Noguchi, Ryuji Okazaki, Hikaru Yabuta, Hiroshi Naraoka, Kanako Sakamoto, Shogo Tachibana, Toru Yada, Masahiro Nishimura, Aiko Nakato, Akiko Miyazaki, Kasumi Yogata, Masanao Abe, Tatsuaki Okada, Tomohiro Usui, Makoto Yoshikawa, Takanao Saiki, Satoshi Tanaka, Fuyuto Terui, Satoru Nakazawa, Seiichiro Watanabe, Yuichi Tsuda, the Hayabusa2-initial-analysis Stone team

Understanding the processes of aqueous alteration within primitive bodies is crucial for unraveling the complex history of early planetesimals. To better identify the signs of this process and its consequences, we have studied the heterogeneity at a micrometric scale of the structure of the aliphatic organic compounds and its relationship to its mineralogical environment. Here, we report an analysis performed on two micrometric grains of Ryugu (C0002-FC027 and C0002-FC028). The samples were crushed in a diamond compression cell and analyzed using high-spatial resolution Fourier Transform InfraRed (FT-IR) hyperspectral imaging measurements conducted in transmission mode. We showed here the spatial distributions of the main components and the structural heterogeneity of the aliphatic organic matter highlighting a micrometer-scale variability in the methylene-to-methyl ratio. Moreover, we connected this heterogeneity to the one of the phyllosilicate band positions. Our findings indicate that the organic matter within Ryugu's micrometric grains underwent varying degrees of aqueous alteration in distinct microenvironments resulting in an elongation of the length of their aliphatic chains, and/or a reduction in their branching and/or cross-linking.

{"title":"Methylene-to-methyl ratio variability in Ryugu samples: Clues to a heterogeneous aqueous alteration","authors":"Zélia Dionnet,&nbsp;Zahia Djouadi,&nbsp;Lukas Delaye,&nbsp;Lucas Caron,&nbsp;Rosario Brunetto,&nbsp;Alice Aléon-Toppani,&nbsp;Cateline Lantz,&nbsp;Stefano Rubino,&nbsp;Donia Baklouti,&nbsp;Tomoki Nakamura,&nbsp;Ferenc Borondics,&nbsp;Christophe Sandt,&nbsp;Megumi Matsumoto,&nbsp;Kana Amano,&nbsp;Tomoyo Morita,&nbsp;Hisayoshi Yurimoto,&nbsp;Takaaki Noguchi,&nbsp;Ryuji Okazaki,&nbsp;Hikaru Yabuta,&nbsp;Hiroshi Naraoka,&nbsp;Kanako Sakamoto,&nbsp;Shogo Tachibana,&nbsp;Toru Yada,&nbsp;Masahiro Nishimura,&nbsp;Aiko Nakato,&nbsp;Akiko Miyazaki,&nbsp;Kasumi Yogata,&nbsp;Masanao Abe,&nbsp;Tatsuaki Okada,&nbsp;Tomohiro Usui,&nbsp;Makoto Yoshikawa,&nbsp;Takanao Saiki,&nbsp;Satoshi Tanaka,&nbsp;Fuyuto Terui,&nbsp;Satoru Nakazawa,&nbsp;Seiichiro Watanabe,&nbsp;Yuichi Tsuda,&nbsp;the Hayabusa2-initial-analysis Stone team","doi":"10.1111/maps.14304","DOIUrl":"https://doi.org/10.1111/maps.14304","url":null,"abstract":"<p>Understanding the processes of aqueous alteration within primitive bodies is crucial for unraveling the complex history of early planetesimals. To better identify the signs of this process and its consequences, we have studied the heterogeneity at a micrometric scale of the structure of the aliphatic organic compounds and its relationship to its mineralogical environment. Here, we report an analysis performed on two micrometric grains of Ryugu (C0002-FC027 and C0002-FC028). The samples were crushed in a diamond compression cell and analyzed using high-spatial resolution Fourier Transform InfraRed (FT-IR) hyperspectral imaging measurements conducted in transmission mode. We showed here the spatial distributions of the main components and the structural heterogeneity of the aliphatic organic matter highlighting a micrometer-scale variability in the methylene-to-methyl ratio. Moreover, we connected this heterogeneity to the one of the phyllosilicate band positions. Our findings indicate that the organic matter within Ryugu's micrometric grains underwent varying degrees of aqueous alteration in distinct microenvironments resulting in an elongation of the length of their aliphatic chains, and/or a reduction in their branching and/or cross-linking.</p>","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"60 2","pages":"273-285"},"PeriodicalIF":2.2,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143424253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cafeosite, Ca4Fe2+3Fe3+2□O6S4, a new meteoritic oxysulfide, a redox indicator of metamorphic alteration of carbonaceous asteroids
IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-24 DOI: 10.1111/maps.14296
Marina A. Ivanova, Sergey N. Britvin, Roza I. Gulyaeva, Sofia A. Petrova, Nina G. Zinovieva, Vladimir V. Kozlov, Stanislav N. Tyushnyakov, Anatoly V. Kasatkin
<p>A natural iron-bearing oxysulfide, named сafeosite after its chemical composition, is a unique example of a mineral that simultaneously contains iron in three oxidation states: Fe<sup>3+</sup>, Fe<sup>2+</sup>, and intermediate between Fe<sup>2+</sup> and Fe<sup>0</sup> involved in metallic-type Fe<span></span>Fe bonding. Cafeosite was discovered in metamorphosed carbonaceous chondrite Dhofar 225, which is classified as CM-anomalous but likely related to the CY (Yamato-type) group. The mineral occurs as tiny anhedral grains that coalesce into irregular aggregates up to 20 μm, commonly encrusted by micrometer-thick troilite or pyrrhotite rims. The grains are randomly disseminated within a chondrite matrix composed of thermally altered phyllosilicates. Associated accessory minerals are troilite, pyrrhotite, Fe-rich, Al-bearing olivine, unknown Al-bearing Fe sulfide, Al-rich chromite, kamacite, awaruite, pentlandite, escolaite, and perovskite. In reflected light, cafeosite is gray, with no internal reflections. Anisotropy is moderate, bireflectance in gray hues. Infrared microspectroscopy did not reveal any bands attributable to (OH)<sup>−</sup>, H<sub>2</sub>O or CO<sub>3</sub><sup>2−</sup> vibrations. Owing to the small grain size, the crystal structure of the mineral has been studied using synthetic analog, which was found to be isostructural with natural cafeosite based on electron backscatter diffraction (EBSD) data. Cafeosite is orthorhombic, space group <i>Cmce</i> (#64), <i>a</i> 17.4856(9), <i>b</i> 11.1516(5), <i>c</i> 11.1543(5) Å, <i>V</i> 2175.0(2) Å<sup>3</sup>, <i>Z</i> = 8, <i>D</i><sub>x</sub> = 4.11 g cm<sup>−3</sup>. The crystal structure has been solved and refined to <i>R</i><sub>1</sub> = 0.039 for 1105 unique reflections. Chemical composition of both natural and synthetic cafeosite corresponds to the formula Ca<sub>4</sub>Fe<sup>2+</sup><sub>3</sub>Fe<sup>3+</sup><sub>2</sub>(□<sub>1−x</sub>Fe<sub>x</sub>)O<sub>6</sub>S<sub>4</sub> where (□<sub>1−<i>x</i></sub>Fe<sub><i>x</i></sub>) denotes structural vacancy partially occupied by semimetallic-type Fe (<i>x</i> = 0.2–0.3). The ideal endmember formula of the mineral is Ca<sub>4</sub>Fe<sup>2+</sup><sub>3</sub>Fe<sup>3+</sup><sub>2</sub>□O<sub>6</sub>S<sub>4</sub>. Cafeosite was likely formed from previously altered precursor material of Dhofar 225, which, like common CM chondrites, consisted of phyllosilicates, Ca-bearing carbonates, tochilinite-like sulfides–hydroxides and pyrrhotite. During thermal metamorphism at temperatures between 750 and 900°C, sulfides–hydroxides were partly sintered with calcined carbonates and iron oxides, resulting in cafeosite formation. Due to varying and redox-dependent contents of Fe<sup>3+</sup> and Fe<sup>2+</sup>, as well as the presence of metallic-type Fe in the structure, cafeosite could be regarded as a single-phase redox indicator alternative to the known triple-phase buffers, for example, iron–magnetite–pyrrhotite (IM-Po), iron–wüsti
{"title":"Cafeosite, Ca4Fe2+3Fe3+2□O6S4, a new meteoritic oxysulfide, a redox indicator of metamorphic alteration of carbonaceous asteroids","authors":"Marina A. Ivanova,&nbsp;Sergey N. Britvin,&nbsp;Roza I. Gulyaeva,&nbsp;Sofia A. Petrova,&nbsp;Nina G. Zinovieva,&nbsp;Vladimir V. Kozlov,&nbsp;Stanislav N. Tyushnyakov,&nbsp;Anatoly V. Kasatkin","doi":"10.1111/maps.14296","DOIUrl":"https://doi.org/10.1111/maps.14296","url":null,"abstract":"&lt;p&gt;A natural iron-bearing oxysulfide, named сafeosite after its chemical composition, is a unique example of a mineral that simultaneously contains iron in three oxidation states: Fe&lt;sup&gt;3+&lt;/sup&gt;, Fe&lt;sup&gt;2+&lt;/sup&gt;, and intermediate between Fe&lt;sup&gt;2+&lt;/sup&gt; and Fe&lt;sup&gt;0&lt;/sup&gt; involved in metallic-type Fe&lt;span&gt;&lt;/span&gt;Fe bonding. Cafeosite was discovered in metamorphosed carbonaceous chondrite Dhofar 225, which is classified as CM-anomalous but likely related to the CY (Yamato-type) group. The mineral occurs as tiny anhedral grains that coalesce into irregular aggregates up to 20 μm, commonly encrusted by micrometer-thick troilite or pyrrhotite rims. The grains are randomly disseminated within a chondrite matrix composed of thermally altered phyllosilicates. Associated accessory minerals are troilite, pyrrhotite, Fe-rich, Al-bearing olivine, unknown Al-bearing Fe sulfide, Al-rich chromite, kamacite, awaruite, pentlandite, escolaite, and perovskite. In reflected light, cafeosite is gray, with no internal reflections. Anisotropy is moderate, bireflectance in gray hues. Infrared microspectroscopy did not reveal any bands attributable to (OH)&lt;sup&gt;−&lt;/sup&gt;, H&lt;sub&gt;2&lt;/sub&gt;O or CO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;2−&lt;/sup&gt; vibrations. Owing to the small grain size, the crystal structure of the mineral has been studied using synthetic analog, which was found to be isostructural with natural cafeosite based on electron backscatter diffraction (EBSD) data. Cafeosite is orthorhombic, space group &lt;i&gt;Cmce&lt;/i&gt; (#64), &lt;i&gt;a&lt;/i&gt; 17.4856(9), &lt;i&gt;b&lt;/i&gt; 11.1516(5), &lt;i&gt;c&lt;/i&gt; 11.1543(5) Å, &lt;i&gt;V&lt;/i&gt; 2175.0(2) Å&lt;sup&gt;3&lt;/sup&gt;, &lt;i&gt;Z&lt;/i&gt; = 8, &lt;i&gt;D&lt;/i&gt;&lt;sub&gt;x&lt;/sub&gt; = 4.11 g cm&lt;sup&gt;−3&lt;/sup&gt;. The crystal structure has been solved and refined to &lt;i&gt;R&lt;/i&gt;&lt;sub&gt;1&lt;/sub&gt; = 0.039 for 1105 unique reflections. Chemical composition of both natural and synthetic cafeosite corresponds to the formula Ca&lt;sub&gt;4&lt;/sub&gt;Fe&lt;sup&gt;2+&lt;/sup&gt;&lt;sub&gt;3&lt;/sub&gt;Fe&lt;sup&gt;3+&lt;/sup&gt;&lt;sub&gt;2&lt;/sub&gt;(□&lt;sub&gt;1−x&lt;/sub&gt;Fe&lt;sub&gt;x&lt;/sub&gt;)O&lt;sub&gt;6&lt;/sub&gt;S&lt;sub&gt;4&lt;/sub&gt; where (□&lt;sub&gt;1−&lt;i&gt;x&lt;/i&gt;&lt;/sub&gt;Fe&lt;sub&gt;&lt;i&gt;x&lt;/i&gt;&lt;/sub&gt;) denotes structural vacancy partially occupied by semimetallic-type Fe (&lt;i&gt;x&lt;/i&gt; = 0.2–0.3). The ideal endmember formula of the mineral is Ca&lt;sub&gt;4&lt;/sub&gt;Fe&lt;sup&gt;2+&lt;/sup&gt;&lt;sub&gt;3&lt;/sub&gt;Fe&lt;sup&gt;3+&lt;/sup&gt;&lt;sub&gt;2&lt;/sub&gt;□O&lt;sub&gt;6&lt;/sub&gt;S&lt;sub&gt;4&lt;/sub&gt;. Cafeosite was likely formed from previously altered precursor material of Dhofar 225, which, like common CM chondrites, consisted of phyllosilicates, Ca-bearing carbonates, tochilinite-like sulfides–hydroxides and pyrrhotite. During thermal metamorphism at temperatures between 750 and 900°C, sulfides–hydroxides were partly sintered with calcined carbonates and iron oxides, resulting in cafeosite formation. Due to varying and redox-dependent contents of Fe&lt;sup&gt;3+&lt;/sup&gt; and Fe&lt;sup&gt;2+&lt;/sup&gt;, as well as the presence of metallic-type Fe in the structure, cafeosite could be regarded as a single-phase redox indicator alternative to the known triple-phase buffers, for example, iron–magnetite–pyrrhotite (IM-Po), iron–wüsti","PeriodicalId":18555,"journal":{"name":"Meteoritics & Planetary Science","volume":"60 2","pages":"175-189"},"PeriodicalIF":2.2,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143424254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Meteoritics & Planetary Science
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