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2025 Jessberger Award to Prof. Vinciane Debaille 2025年杰斯伯格奖:Vinciane Debaille教授
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-14 DOI: 10.1111/maps.70011
Allan Treiman, Susanne P. Schwenzer, Alan Brandon, James M. D. Day, Richard J. Walker
<p>Prof. Vinciane Debaille is the 2025 Jessberger awardee.</p><p>Back in 2020, a group of us, who had first met at the Lunar and Planetary Institute in Houston, reunited through the only means possible at the time: online. It not only bridged the geographic gap, but it also led us to reminisce about how much time had elapsed since we could sit around a table—usually also involving food—and chat in person. It was then that we remarked on how Vinciane had progressed, how she had developed from the postdoc we shared the table with in Houston to a world-leading researcher and professor of Isotope Geochemistry at Université de Libre Bruxelles in Belgium. We are delighted today that our colleagues share our judgment and that Vinciane will receive the 2025 Jessberger Award.</p><p>She then discovered that other planetary bodies have basalts, too, and need isotope geochemists! This is when she came to Houston in 2005 as a postdoc, working with Dr. Alan Brandon at NASA JSC to learn about (among others) extinct radioisotope chronometry and geochemistry. That collaboration led to three foundational papers that demonstrated Dr. Debaille's analytical prowess, her ability to make sense of complementary short- and long-lived isotope systems, and her skill at presenting elegant and understandable interpretations. Those three laid the foundation for her hugely successful career in meteorite and planetary sciences.</p><p>The first paper from her post-doctoral work, published in <i>Nature</i> (Debaille et al., <span>2007</span>) in 2007, used high-precision analyses of the <sup>142</sup>Nd/<sup>144</sup>Nd and <sup>143</sup>Nd/<sup>144</sup>Nd ratios of shergottite martian meteorite to show that Mars likely experienced differentiation through progressive crystallization of a magma ocean within about 100 million years of core formation.</p><p>The second paper, in 2008 in <i>Earth and Planetary Science Letters</i> (Debaille et al., <span>2008</span>), added <sup>176</sup>Hf/<sup>177</sup>Hf data to the shergottite Nd story. There, she showed that the shergottites developed from mixtures of material enriched and depleted in incompatible trace elements, and implicated garnet fractionation in their sources.</p><p>The third of these seminal papers, 2009 in <i>Nature Geoscience</i> (Debaille et al., <span>2009</span>), attacked the other martian meteorites, the nakhlites. From their isotopic systematics, short- and long-lived, Dr. Debaille inferred an early overturn of the martian mantle. These three papers have become the background, the environment, for all subsequent studies of Mars' early evolution.</p><p>After her enormously successful time in Houston, Dr. Debaille returned to Belgium to the Université Libre de Bruxelles, first as a postdoc and then to her current position as Senior Research Associate (Maître de recherche). In Brussels, she has continued her work on the isotopic characteristics of both meteorites and terrestrial systems, many in collaboration with stu
文西安·德巴耶教授是2025年杰斯伯格奖获得者。早在2020年,我们一群人第一次在休斯顿的月球和行星研究所见面,通过当时唯一可能的手段重聚:网上。它不仅弥合了地理上的鸿沟,而且还让我们回忆起自从我们能够围坐在一张桌子旁——通常还有食物——面对面聊天以来,已经过去了多少时间。就在那时,我们谈到了文西安的进步,她是如何从我们在休斯顿同桌的博士后,成长为比利时布鲁塞尔自由大学(universit<s:1> de Libre Bruxelles)世界一流的研究员和同位素地球化学教授的。今天,我们很高兴我们的同事们同意我们的判断,文西安将获得2025年杰斯伯格奖。然后她发现其他行星体也有玄武岩,并且需要同位素地球化学家!2005年,她作为博士后来到休斯敦,与NASA JSC的艾伦·布兰登博士一起学习(以及其他)已灭绝的放射性同位素计时和地球化学。在那次合作中,德巴耶发表了三篇基础论文,展示了她的分析能力、她对互补的短寿命和长寿命同位素系统的理解能力,以及她提出优雅而易懂的解释的技巧。这三件事为她在陨石和行星科学领域取得巨大成功奠定了基础。她博士后工作的第一篇论文于2007年发表在《自然》杂志上(Debaille et al., 2007),通过对火星陨石的142 /144Nd和143Nd/144Nd比率的高精度分析,表明火星可能在岩心形成约1亿年的时间里,通过岩浆海洋的逐步结晶经历了分化。第二篇论文发表在2008年的《地球与行星科学快报》(Debaille et al., 2008)上,将176Hf/177Hf的数据添加到长石Nd的故事中。在那里,她证明了这些辉高石是由富含和缺乏不相容微量元素的物质混合而成的,并且暗示了它们来源中的石榴石分馏。第三篇开创性论文发表于2009年的《自然地球科学》(Debaille et al., 2009),攻击了另一种火星陨石——nakhlites。根据他们的同位素系统,短期和长期存在,德巴耶博士推断出火星地幔的早期翻转。这三篇论文成为后来所有关于火星早期演化的研究的背景和环境。在休斯顿取得巨大成功后,德巴耶博士回到比利时布鲁塞尔自由大学,先是博士后,然后担任高级研究助理(matre de recherche)。在布鲁塞尔,她继续研究陨石和陆地系统的同位素特征,其中许多是与学生合作的,其中至少有14名博士和18名硕士。她的作品太多了,无法在这里一一阅读;它们从熟悉的行星和陨石主题延伸到不太令人期待的主题,如非传统同位素(如铁和锌)、铁钛矿床、带状铁地层、太古代花岗岩类和蓝冰。在Debaille博士的论文中,有一篇特别(对我来说特别)将地球和行星领域联系起来(Debaille et al., 2013)。2013年,她发表了来自加拿大的2.7 Ga玄武岩的142 /144Nd数据,Theo's Flow是最接近nakhlite陨石的陆地模拟物。这些岩石的142 /144Nd比值与地球的标称值不同,表明玄武岩喷发时,早期地幔的不均匀性并未被消除。与纳克里岩一样,西奥流中的Nd同位素比率限制了它们行星的早期地幔动力学;对于早期地球来说,这意味着地幔没有强烈的对流。(作为Theo’s Flow样本的来源,我对那篇论文做出了些许贡献。)德巴耶博士和克雷格·奥尼尔(Craig O'Neill)在第二年发表了一篇“综述”论文(O'Neill &; Debaille, 2014),该论文表明,冥古宙的地球构造大部分处于停滞状态,地壳的活动期有限。德巴耶已经五次来到南极洲,一次是和安斯梅特一起,四次是到比利时基地伊丽莎白公主站。这些探险的主要目标是收集蓝色冰原上的陨石。这包括在冰雪上露营,并将注意力集中在这片壮丽但无情的景观中潜在的陨石上。她不仅把自己的专业知识带到了这些探险中,而且还把她的领导能力带到了她周围的团队,让她保持专注和良好的精神状态。除了陨石,比利时团队还试图通过收集冰样本来了解陨石在某些特定地点的集中机制。此外,这些小组还收集了沉积物,以便在比利时站周围回收微陨石。 回到家后,她对取回的陨石的管理以及如何确保它们在博物馆中保持良好的状态以供世界各地的科学家使用感兴趣。正是这些管理技能,加上她的主要研究,使她加入了火星样本返回的测量定义团队(Bridges & Debaille, 2024年),我们从LPI时代起就对火星样本返回感兴趣(Beaty等人,2019年)。当这些珍贵的样本到达地球时,德巴耶博士为最大限度地提高它们的科学回报所做的贡献是基础性的、大量的,而且总是有见地的。她在优化我们的思考和准备火星样本抵达地球以及未来几个世纪的研究方面发挥了重要作用。德巴耶的专业知识和科学贡献得到了广泛的认可,无论是奖项还是资助。2012年,她因在地质学、同位素地球化学和行星科学方面的工作而获得比利时皇家科学院的范·厄特恩男爵奖。2014年,她因在了解早期地球方面的工作而成为第一位获得“原子”奖的人,该奖项由布鲁塞尔科学研究部颁发给一位年轻的女科学家。她的工作也得到了重要资助的认可,包括2014年的ERC启动资助,“太阳系的初始起始成分”;卓越科学联盟资助“火星和古代地球宜居性的进化和示踪剂”;并支持作为返回样本科学家和超级相机团队成员加入2020年火星毅力号火星车团队。她在2024年被选为我们气象学会的会员,当然,她还是去年在布鲁塞尔召开的年会的主持人。有了Jessberger奖,我们现在增加了协会对debaille博士的认可和荣誉。主席,官员们,理事会,气象学会的成员们,科学家们的同事们,来宾们,我向你们推荐2025年杰斯伯格奖的得主:文西安·德巴耶教授。
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引用次数: 0
The azimuthal distribution of ejecta mass from oblique impacts into sand 斜冲砂抛射物的方位分布
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-10 DOI: 10.1111/maps.70006
Alice C. Quillen, Sean Doran

We measure ejecta mass as a function of azimuthal and impact angle for 104 m/s oblique impacts into sand. We find that the ejecta mass distribution is strongly sensitive to azimuthal angle, with as high as eight times more mass in ejecta on the downrange side compared to the uprange side. Crater radii, measured from the impact point, are measured at different impact and azimuthal angles. Crater ejecta scaling laws are modified to depend on azimuthal and impact angle. We find that crater radii are sensitive to both impact and azimuthal angle, but the ejecta mass as a function of both angles can be estimated from the cube of the crater radius without an additional angular dependent function. The ejecta distributions are relevant for processes that depend upon the integrated properties of approximately 100 m/s impacts occurring in the outer solar system and possibly during planetesimal formation.

我们测量了抛射物质量作为方位角和撞击角的函数,以104m /s的斜撞击沙子。我们发现,弹射物的质量分布对方位角非常敏感,弹射物的质量在下界面是上界面的8倍。从撞击点开始测量的陨石坑半径是在不同的撞击角和方位角下测量的。修正了弹坑喷射物的尺度规律,使之与方位角和撞击角有关。我们发现陨石坑半径对撞击角和方位角都很敏感,但抛射物质量作为两个角度的函数可以由陨石坑半径的立方来估计,而不需要额外的角度依赖函数。抛射物分布与依赖于发生在外太阳系和可能在星子形成期间的大约100m /s撞击的综合特性的过程有关。
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引用次数: 0
A feasibility assessment of micromill sampling for Rb-Sr and Sm-Nd geochronology of shergottites 微磨取样测定菱辉石rb - sr和Sm-Nd年代学的可行性评价
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-07 DOI: 10.1111/maps.70002
A. I. Sheen, C. D. K. Herd, K. T. Tait

Accurate dating of Martian meteorites is crucial for understanding key events in the planet's evolution. However, not all Martian meteorites are amenable to dating techniques currently in use for these rocks. The priority of sample preservation precludes mineral separation methods for low-volume specimens, whereas the less destructive in situ SIMS U-Pb method depends on the availability of U-bearing accessory minerals. Micromilling allows for spatially guided sampling of target phases down to the sub-mm scale, therefore enabling chromatography-based analysis while preserving the overall specimen. This study presents an evaluation of micromill sampling for extracting individual mineral fractions in situ from shergottites, the most common group of Martian meteorites, for Rb-Sr and Sm-Nd geochronology. Based on trace element content in major minerals in shergottites (pyroxene, plagioclase, olivine, and merrillite) and assuming that a minimum load size of 0.25 ng Sr and 1 ng Nd is required to achieve baseline isotopic precision (2σ of ~240 ppm on 87Sr/86Sr and ~100 ppm on 143Nd/144Nd), the minimum required sample volume ranges in the orders of 105–107 μm3 for one Sr isotopic analysis and 105–109 μm3 for one Nd isotopic analysis. Considering the need for sample purity, significant limitations exist in the maximum sampling resolution of the micromill instrument (~40 μm for the conical carbide drill bit chosen for this study) with respect to shergottite petrography. Insufficient grain size, irregular morphology, and the presence of small inclusions may reduce the area that can be drilled per grain. Shock-induced fractures, which sometimes act as pathways for terrestrial alteration, are pervasive in shergottites and create additional challenges for effective high-purity sampling of the target phase. In addition, variation in trace element content in the target phases may result in the realistically required drilling volumes being orders of magnitude greater than the minimum estimates. Lastly, estimated drilling time per fraction may reach over 5 h for pyroxene (Sr, Nd), plagioclase (Nd), and olivine (Sr, Nd), increasing the susceptibility to a larger procedural blank as well as requiring constant, labor-intensive monitoring for long durations. Based on these technical and physical constraints, we do not consider micromill sampling to be currently compatible with Sr isotopic analysis of olivine and Nd isotopic analysis of pyroxene, plagioclase, and olivine in shergottites. The feasibility of geochronology applications may be improved with future advances in analytical development, such as increasing the micromill sampling resolution and reducing the load size required for isotopic analysis.

火星陨石的准确测年对于了解火星演化的关键事件至关重要。然而,并不是所有的火星陨石都适用于目前对这些岩石使用的年代测定技术。样品保存的优先性排除了小体积样品的矿物分离方法,而破坏性较小的原位SIMS U-Pb方法取决于含u辅助矿物的可用性。微铣削允许对目标相进行空间引导采样到亚毫米尺度,因此可以在保留整体样品的同时进行基于色谱的分析。本研究提出了一种微磨取样评估方法,用于从火星陨石中最常见的一组菱辉石中原位提取单个矿物组分,用于Rb-Sr和Sm-Nd的地质年代学。根据辉石、斜长石、橄榄石和美银石等主要矿物的微量元素含量,假设达到基线同位素精度(87Sr/86Sr为~240 ppm, 143Nd/144Nd为~100 ppm)所需的最小载荷尺寸为0.25 ng Sr和1 ng Nd,则一次Sr同位素分析所需的最小样本量为105 ~ 107 μm3,一次Nd同位素分析所需的最小样本量为105 ~ 109 μm3。考虑到样品纯度的需要,微磨仪的最大采样分辨率(本研究选用的锥形硬质合金钻头为~40 μm)在长辉石岩相学方面存在显著限制。晶粒尺寸不足、形态不规则以及小夹杂物的存在可能会减少每粒可钻的面积。冲击诱发的裂缝有时是陆地蚀变的途径,在铝土矿中普遍存在,这给目标相的有效高纯度采样带来了额外的挑战。此外,目标相中微量元素含量的变化可能导致实际所需的钻井体积比最小估计值大几个数量级。最后,对于辉石(Sr, Nd)、斜长石(Nd)和橄榄石(Sr, Nd),估计每粒的钻井时间可能超过5小时,这增加了对更大的程序空白的敏感性,并且需要长时间的持续、劳动密集型监测。基于这些技术和物理限制,我们不认为微磨取样目前与橄榄石的Sr同位素分析和辉石、斜长石和橄榄石的Nd同位素分析兼容。地质年代学应用的可行性可能会随着分析发展的未来进步而得到改善,例如增加微磨取样分辨率和减少同位素分析所需的负载大小。
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引用次数: 0
In Memoriam: Bevan M. French (March 8, 1937–May 10, 2025) 纪念:贝文·m·弗兰奇(1937年3月8日- 2025年5月10日)
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-04 DOI: 10.1111/maps.70010
Steven Jaret, Peter Schultz, Ludovic Ferrière, Christian Koeberl
<p>Bevan French (Figure 1) is most widely known for his pioneering work in planetary science and the field of impact cratering. He was one of the early workers on terrestrial impact materials along with Gene Shoemaker, Robert Dietz, Nick Short, Richard Grieve, Mike Dence, Dieter Stöffler, Ed Chao, and others. Throughout his career, Bevan was a champion for impact science, particularly centered on petrography and geologic observations at terrestrial craters. His 1998 book, Traces of Catastrophe, published by the Lunar and Planetary Institute in Houston, is still used today in classrooms across the world as one of the standard introduction texts for impact cratering.</p><p>Bevan French was born on March 8, 1937, in East Orange, NJ, USA. At age 15, he was already actively involved in collecting rare minerals at Franklin, NJ, for his own mineral studies group. A few years later, in 1954, his minerals got him into the Top 40 of the Westinghouse Science Talent Search, which also led to a summer job at the National Bureau of Standards during the same year. He obtained an A.B. degree in geology from Dartmouth College, Hanover, NH, USA (1958), a M.S. in geochemistry from the California Institute of Technology, Pasadena, CA, USA (1960), and a Ph.D. in geology at The Johns Hopkins University, Baltimore, MD, USA (1964), with a thesis titled “Stability of Siderite, FeCO<sub>3</sub>, and Progressive Metamorphism of Iron Formation,” on metamorphic petrology of iron formations in the Minnesota Iron Range. At a geological conference in Minneapolis in the mid-60s, Bevan gave a talk about his thesis work which attracted a smart lady geologist who was working for an iron-mining company. Two years later, in 1967, they married. Mary-Hill French became a close partner in editing Bevan's manuscripts and joined in all the travels around the world, in a total of 32 different countries (Figure 2). Bevan joked about robbing the cradle: Bevan was much younger. Together, they supported young investigators interested in terrestrial impacts until her passing in 2019 at the age of 102.</p><p>Amusingly, Bevan's work in the 1960s on the Iron Range was done well before recognition of the Sudbury as an impact structure and the subsequent discovery of Sudbury ejecta in the Iron Range. In recent years, Bevan joked about how, 50 years later, he was returning to his geologic roots with renewed interest in Sudbury and associated rocks on the Canadian Shield. Bevan's work on Sudbury, starting in the mid to late 1960s, was essential in confirming the impact origin of this structure. Starting with his pioneering work on shock-metamorphic studies, especially on quartz, in the later 1960s, he then collaborated with several colleagues to provide evidence for the impact origin of several other promising structures around the world, such as Rochechouart, B.P., Oasis, Tenoumer, Aouelloul, Araguainha, and Serra da Canghala. His impact pedigree is actually shared: he is a distant cousin of Don Gaul
贝文·弗兰奇(图1)因其在行星科学和撞击坑领域的开创性工作而广为人知。他和吉恩·舒梅克、罗伯特·迪茨、尼克·肖特、理查德·格里夫、迈克·丹斯、迪特尔Stöffler、埃德·赵等人一起,是研究地球撞击物质的早期工作者之一。在他的职业生涯中,贝文一直是撞击科学的拥护者,特别是在岩石学和地球陨石坑的地质观测方面。他1998年出版的《灾难的痕迹》一书,由休斯顿的月球和行星研究所出版,至今仍被世界各地的教室作为标准的撞击坑入门教材之一使用。贝文·弗兰奇于1937年3月8日出生在美国新泽西州东奥兰治。15岁时,他就已经在新泽西州富兰克林市为自己的矿物研究小组积极参与收集稀有矿物。几年后,1954年,他的矿物使他进入了西屋科学人才评选的前40名,并在同年获得了在国家标准局的暑期工作。他于1958年在美国新罕布什尔州汉诺威达特茅斯学院获得地质学学士学位,1960年在加州帕萨迪纳加州理工学院获得地球化学硕士学位,1964年在美国马里兰州巴尔的摩约翰霍普金斯大学获得地质学博士学位,论文题为“Siderite的稳定性,FeCO3和铁地层的渐进变质”,研究明尼苏达州铁地层的变质岩石学。60年代中期,在明尼阿波利斯举行的一次地质会议上,贝文做了一个关于他的论文工作的演讲,吸引了一位在一家铁矿公司工作的聪明的女地质学家。两年后的1967年,他们结婚了。玛丽-希尔·弗兰奇成为贝文手稿编辑的亲密伙伴,并参加了贝文在世界各地的旅行,总共去了32个不同的国家(图2)。比文拿抢摇篮开玩笑:比文比他年轻得多。他们一起支持对地球影响感兴趣的年轻研究人员,直到她于2019年去世,享年102岁。有趣的是,在认识到萨德伯里是一个撞击构造和随后在铁山脉发现萨德伯里喷发物之前,贝文在20世纪60年代对铁山脉的研究已经做得很好了。近年来,贝文开玩笑说,50年后,他对萨德伯里和加拿大地盾上的相关岩石重新产生了兴趣,回到了他的地质根源。贝文在萨德伯里的研究始于20世纪60年代中后期,对于确认这种结构的撞击起源至关重要。从20世纪60年代后期他在冲击变质研究方面的开创性工作开始,特别是在石英方面,然后他与几位同事合作,为世界上其他几个有希望的构造的撞击起源提供证据,如Rochechouart, b.p., Oasis, Tenoumer, Aouelloul, Araguainha和Serra da anghala。他的影响谱系实际上是共同的:他是另一位影响研究先驱唐·高尔特(Don Gault)的远亲,他会在会议上用“cuz”称呼唐。从约翰霍普金斯大学毕业后,贝文很快转向行星科学,并于1964年加入美国宇航局戈达德太空飞行中心。在那里,他继续研究陨石坑,并共同召开了一次关于地球撞击的会议,并与尼古拉斯·m·肖特(Nicholas M. Short)合编了《自然物质的冲击变质论》专著,被称为“陨石坑的绿色圣经”,其中介绍了许多关于陨石坑的初步工作。1968年,他作为达特茅斯学院(NH, USA)的客座教授休假,教授火成岩岩石学和陆地撞击结构的课程。贝文随后加入了阿波罗计划,作为阿波罗11号和12号样本的联合调查员,并作为阿波罗16号和17号任务的宇航员教练。在20世纪70年代早期,他参与了一些关于月球眼镜的第一批出版物,并继续研究月球材料。1991年,他与格兰特·海肯(Grant Heiken)和戴夫·瓦尼曼(Dave Vaniman)合编了经典出版物《月球资源手册:月球用户指南》,这是一本关于月球科学和技术信息的一卷参考百科全书。在1975年回到NASA总部之前,Bevan在美国国家科学基金会(NSF)做了几年地球化学项目主任。在NASA, Bevan担任过许多角色(图3),包括行星材料学科科学家(管理月球样本、陨石和宇宙尘埃的研究)、高级项目科学家、特殊项目学科科学家,以及火星观察者任务的项目科学家。他还代表NASA参加了1977年的三机构会议,建立了美国南极陨石计划(ANSMET),以及NASA、NSF和史密森学会之间的长期合作伙伴关系。 从事科学管理工作当然是一项要求很高的工作——一方面,你有贪婪的科学家,他们想要越来越多的钱来研究来自外太空的灰色小岩石。另一方面,你们又受到一些不懂科学的政客的骚扰,比如臭名昭著的参议员蒲克斯麦尔(Proxmire),他给比万的计划颁发了所谓的“金羊奖”,因为“联邦基金的无用支出”要花费280万美元,“在月球实验室的基础上增加一个设施,以容纳100磅的月球岩石”。有些事情似乎永远不会改变。贝文于1994年正式从美国国家航空航天局退休,并迅速返回地球撞击结构,首先是作为维也纳大学的客座教授(1994年;1997年和2001年返回),后来作为史密森学会矿物科学系(1994 - 2004年)和古生物学系(2004-2022年)的研究合作者。即使在NASA任职期间,他也一直参与撞击研究。例如,早在希克苏鲁伯陨石坑被确定为源陨石坑之前,他就密切关注了关于K-T边界撞击(现在的K-Pg)的争论。他鼓励对曼森影响结构(在美国爱荷华州)进行更详细的研究,这导致了一本全面的书籍出版。最初,它被认为大约有6500万年的历史,但后来确定了一个更古老的形成年龄。他对南非弗里德堡撞击构造的研究、布什维尔德杂岩以及早期太古代球粒层的讨论做出了重要贡献,他指出了一个难题(至今仍未真正解决):球粒在较年轻的撞击中相当罕见,但在早期太古代的喷出物沉积物中占主导地位。他还参与了其他各种影响结构的设计,如挪威的Gardnos,澳大利亚的Woodleigh, Decorah(美国爱荷华州),Rock Elm(美国威斯康星州),以及萨德伯里。他和玛丽-希尔是对撞击地质学感兴趣的学生的坚定支持者,无论是通过在他们家里的动手教程,还是在布朗大学和卡内基研究所的研究种子基金,专门研究陆地撞击。Bevan和Mary-Hill广泛地参加了许多会议,并参加了世界各地的实地考察(图4和5)。为了表彰他在行星科学和陨石坑方面的杰出贡献,贝文于2002年被陨石学会授予巴林杰奖章(图6)。2004年,他在《陨石与行星科学》(meteortics and Planetary Science)上发表了一篇有点自传式的评论论文,后来又写了一篇被广泛引用的评论论文(与我们中的一个人C.K.一起),内容是用来确定地质结构或物质是撞击起源的标准。尽管贝文从未正式指导过学生的论文或论文,但他是我们社区中许多人(年轻人和老年人)的伟大导师。他亲自指导年轻的研究人员如何识别冲击变质的特征。通过在会议上的长时间、详细的交谈、电话交谈和书面讨论,Bevan在整个影响力社区留下了自己的印记。他有一个庞大的国际合作者网络,在科学界有着根深蒂固的地位,这一点从他为前同事写的纪念文章的数量也可以看出。除了科学,贝文还喜欢很多东西,包括古典音乐和阅读(神秘和幽默是他最喜欢的东西)。贝文的机智和创造力经常给我们的社区带来微笑。两个最好的例子是他为尤金·舒梅克(Eugene Shoemaker)退休而创作的原创歌曲和表演——《在去往月球的路上路过的人》(The Man Passing on his Way to The Moon),以及他在巴林杰奖(Barringer Medal)上发表的题为《被撞击
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引用次数: 0
Documenting microbial populations within the University of Alberta Meteorite Curation Facility using 16S rRNA gene sequencing: Implications for the curation of astromaterials 使用16S rRNA基因测序记录阿尔伯塔大学陨石管理设施内的微生物种群:对天体材料管理的影响
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-04 DOI: 10.1111/maps.70008
Libby D. Tunney, Aaron B. Regberg, Christopher D. K. Herd, Richard E. Davis, Christian L. Castro

Meteorites are easily contaminated at the Earth's surface by microbial activity. Here, DNA extracts from two meteorite specimens and samples from curation laboratory surfaces are analyzed with amplicon sequencing, to understand microbial communities that contaminate meteorites and that may be resident in curation facilities. In addition, two different DNA extraction kits, the PowerSoil DNA Isolation Kit and the QIAamp UCP Pathogen Mini Kit, are utilized to determine if certain kits are more favorable for low biomass studies of meteorites. We find that, regardless of the type of kit used, the majority of microbial taxa that dominate meteorite and meteorite curation environments include those that are prevalent in soils or in the human microbiome. Our results have implications for advanced curation methods to protect the intrinsic properties of meteorites, such as extraterrestrial organics and minerals, from microbes. Preserving meteorites in pristine states and understanding the complex relationship between meteorites and terrestrial microbes can inform our search for the origin of life or life elsewhere in the universe.

陨石在地球表面很容易受到微生物活动的污染。在这里,从两个陨石标本中提取的DNA和从博物馆实验室表面提取的样本用扩增子测序进行分析,以了解污染陨石和可能居住在博物馆设施中的微生物群落。此外,还使用了两种不同的DNA提取试剂盒,PowerSoil DNA分离试剂盒和QIAamp UCP病原体迷你试剂盒,以确定某些试剂盒是否更适合于陨石的低生物量研究。我们发现,无论使用哪种类型的试剂盒,大多数主导陨石和陨石管理环境的微生物类群包括那些在土壤或人类微生物组中普遍存在的微生物类群。我们的研究结果对先进的管理方法具有启示意义,以保护陨石的内在特性,如外星有机物和矿物质,免受微生物的侵害。将陨石保存在原始状态,了解陨石与陆地微生物之间的复杂关系,可以为我们寻找生命起源或宇宙其他地方的生命提供信息。
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引用次数: 0
Petrographic and geochemical analysis of inversely zoned chondrules 逆分带球粒的岩石学和地球化学分析
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-02 DOI: 10.1111/maps.14381
Fabio Joseph, Igor Drozdovsky, Malte Junge, Joanna Brau, Melanie Kaliwoda

Chondrules are one of the oldest objects in our solar system. Therefore, they play an important role as messengers, offering new insights into the early stage of the solar system processes and potential understanding of formation. Therefore, the investigation of all detailed structures, especially not well-known inversely zoned chondrules (IZ chondrules), is crucial. In this paper, we describe the chemical as well as the structural composition of inversely zoned chondrules with EDX, light microscopy, BSE, and Raman spectroscopy, which reveal a new process in the early solar system. Inversely zoned chondrules consist of a pyroxene core surrounded by an olivine rim. The olivines have a higher Fe content (Fa, 39%–41%) compared to those found in most other chondrules. The core displays a radial pyroxene chondrule with sometimes olivines (Fa34). These IZ chondrules have originated during the early stages of our solar system and do not show the typical known forming process of chondrules. Minor fluctuations in the SiO₂ content of chondritic melts can lead to SiO₂ depletion of the residual melt at a constant temperature due to crystallization of pyroxene, which shifts the phase equilibrium in favor of fayalite-enriched olivine, which forms a rim.

球粒是太阳系中最古老的物体之一。因此,它们作为信使发挥着重要作用,为太阳系早期过程和对形成的潜在理解提供了新的见解。因此,对所有详细结构的研究,特别是不为人所知的逆分区球粒(IZ球粒),是至关重要的。本文利用EDX、光学显微镜、BSE和拉曼光谱等手段对逆带球粒的化学成分和结构组成进行了描述,揭示了太阳系早期形成的新过程。相反分带的球粒由辉石核和橄榄石边缘组成。橄榄石的铁含量(Fa, 39%-41%)高于大多数其他球粒。岩心呈放射状辉石球粒,有时含有橄榄石(Fa34)。这些IZ球粒起源于我们太阳系的早期阶段,并没有显示出典型的已知球粒形成过程。球粒体熔体中SiO₂含量的微小波动可导致残余熔体在恒温下由于辉石的结晶而导致SiO₂耗损,从而使相平衡向富含铁矾石的橄榄石转移,形成一个边缘。
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引用次数: 0
Origin of the metal in chondritic and achondritic lithologies of the Sierra Gorda 013 СBa-like chondrite 戈达山013 СBa-like球粒陨石球粒岩和球粒岩岩性中金属的起源
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-06-27 DOI: 10.1111/maps.70005
Marina A. Ivanova, Svetlana N. Teplyakova, Cyril A. Lorenz, Shuying Yang, Munir Humayun

Sierra Gorda 013 (SG 013) is an unusual CBa-like chondrite containing two texturally different, isotopically identical lithologies—chondritic (L1) and achondritic (L2), which should have a common origin. The metal globules of the L1 metal preserved the magmatic pattern of the siderophile element distribution that indicates they had a fractionated precursor. In this work, the trace element metal composition of lithology 2 was studied, and the revisited LA-ICP-MS data on the L1 metal was presented. Lithologies 1 and 2 have Ni and Co in the range of CB chondrites. The Ni-Co distribution in L1 and depletion in Cr of both lithologies with a negative Cr-Ni correlation are similar to that of the magmatic irons. Highly refractory siderophile element (HRSE) (W, Re, Os, Ir, Pt, Ru, Rh, and Mo) compositions of the L1 metal are highly fractionated relative to CI, but the L2 metal has a nearly uniform HRSE distribution similar to the depleted patterns of some HRSE-poor L1 metal compositions. Metal from both lithologies is depleted in volatile siderophile elements. In the L1 metal globules, the metal composition shows definite linear correlations of the HRSE elements versus Ni similar to those observed in many magmatic iron meteorites, distinct from those of the CH/CBb-zoned metal. Meanwhile, the L2 metal compositions are systematically plotted as limited clusters in the middle of the L1 trends. Based on a fractional crystallization (FC) model of the CR-like metal composition, it was shown that the distribution of siderophile elements in the metal globules of L1 can cover the full range of the fractional crystallization products of a metallic (Fe-Ni-S) liquid from the core of a differentiated body at S content 13 wt%. In contrast, the metal from L2 corresponds to a more limited range of fractional crystallization products and indicates a mixture of the fractionated metal with the primitive metal from the chondritic colliding body. Our results suggest that during a catastrophic impact event when the metallic core of a differentiated body was disrupted, the L1 lithology was quickly cooled in the impact plume, more reduced than that of CB chondrites and avoided equilibration with plume gas and preserved its fractionated HRSE patterns. The distribution of siderophile volatile elements and Au was likely overprinted by high-temperature processes of volatilization and recondensation to different degrees in the impact plume under disequilibrium conditions. The L2 metal probably avoided equilibration with the plume gas and was affected by thermal metamorphism up to 900°C in the SG 013 parent body, which possibly resulted in the higher W abundance compared to the L1 metal with a magmatic Ir-W trend due to the redox reactions with silicates under reducing conditions.

Sierra Gorda 013 (SG 013)是一种罕见的cba样球粒陨石,含有两种结构不同、同位素相同的岩性——球粒岩(L1)和球粒岩(L2),它们应该有共同的起源。L1金属的金属球保留了亲铁元素分布的岩浆模式,表明它们具有分馏前驱体。本文对岩性2的微量元素金属组成进行了研究,并对L1金属的LA-ICP-MS数据进行了重访。岩性1和2在CB球粒陨石范围内含有Ni和Co。两种岩性的L1中Ni-Co分布与Cr- ni负相关特征与岩浆铁相似。相对于CI, L1金属的高难熔亲铁元素(W、Re、Os、Ir、Pt、Ru、Rh和Mo)组成具有高度分异,但L2金属的HRSE分布几乎均匀,类似于一些HRSE较差的L1金属组成的耗尽模式。两种岩性的金属在挥发性亲铁元素中被耗尽。在L1金属球中,HRSE元素与Ni的线性关系与许多岩浆铁陨石中观察到的相似,与CH/ cbb带金属的线性关系不同。同时,L2金属成分被系统地绘制为L1趋势中间的有限簇。基于cr类金属组成的分数结晶(FC)模型,结果表明,在S含量为13 wt%时,L1金属球中亲铁元素的分布可以覆盖从分化体核心产生的金属(Fe-Ni-S)液体的全部分数结晶产物。相比之下,L2中的金属对应于更有限范围的分馏结晶产物,表明分馏金属与球粒状碰撞体中的原始金属的混合物。我们的研究结果表明,在灾难性的撞击事件中,当分化体的金属核被破坏时,L1岩性在撞击羽流中迅速冷却,比CB球粒陨石更少,避免了与羽流气体的平衡,并保留了其分异的HRSE模式。在不平衡条件下,撞击羽流中亲铁挥发元素和Au的分布可能不同程度地叠加了高温挥发和再冷凝过程。在SG 013母体中,L2金属可能由于与硅酸盐在还原条件下发生氧化还原反应,避免了与烟羽气体的平衡,并受到高达900℃的热变质作用的影响,导致其W丰度高于L1金属,并呈现岩浆Ir-W趋势。
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引用次数: 0
Oxygen isotopic heterogeneities in refractory inclusions in the ungrouped carbonaceous chondrite Acfer 094 未分组碳质球粒陨石acer094中难熔包裹体的氧同位素非均质性
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-06-24 DOI: 10.1111/maps.70003
Timothy J. Fagan, Sachio Kobayashi, Alexander N. Krot, Hisayoshi Yurimoto

Oxygen isotopic compositions of minerals in three Ca-Al-rich inclusions (CAIs), one amoeboid olivine aggregate (AOA) and one Al-rich chondrule (ARC) from the pristine ungrouped carbonaceous chondrite Acfer 094 were analyzed by secondary ion mass spectrometry (SIMS), including conventional spot analyses and O-isotope imaging. Most of the ARC minerals analyzed in this study are 16O-poor (Δ17O ≥ −5.4‰), with one outlier in high-Ca pyroxene (Δ17O = −10.6 ± 2.8‰), indicating that if the ARC precursors formed initially in an 16O-rich setting, isotopic compositions were mostly reset during chondrule melting in an 16O-poor environment. The CAIs and AOA analyzed are dominated by 16O-rich compositions, consistent with previous work, but partial isotopic resetting to 16O-poor compositions has been identified. Melilite with a moderately 16O-depleted composition (Δ17O = −15.7 ± 3.0‰) was identified in an AOA, and 16O-poor diopside (Δ17O = −1.9 ± 2.5‰) was identified as the outermost layer of a Wark–Lovering-like rim of an 16O-rich CAI (Δ17O ranges from −18 to −22 ± 2.5‰). The diopside layer is bounded by an inner rim of anorthite replacing melilite, which is in turn bounded by the grossite-hibonite-perovskite-spinel-bearing core of the CAI. Isotopic imaging shows that the diopside/anorthite boundary coincides with a steep gradient in O isotopic composition. Based on modeling of O diffusion in the temperature range of 1400–1500 K, thermal events that formed the diopside and anorthite rim layers were limited to durations of no more than approximately 100 days and were probably much shorter. Given the weak metamorphic alteration of Acfer 094, the partial to nearly complete O-isotope resetting of AOA, CAI, and ARC minerals analyzed in this study occurred by short-term thermal events in the solar nebula prior to the formation of the Acfer 094 parent body. Therefore, the isotopic variations identified in this study show that at least some refractory materials were transported from 16O-rich environments, where initial crystallization took place, to 16O-poor environments in the solar nebula, where subsequent crystallization and/or isotopic resetting occurred.

采用二次离子质谱(SIMS)分析了原始无组碳质球粒陨石Acfer 094中3个富钙铝包裹体(CAIs)、1个变形虫橄榄石集合体(AOA)和1个富铝球粒(ARC)矿物的氧同位素组成,包括常规斑点分析和o同位素成像。本研究分析的大部分ARC矿物为贫16o (Δ17O≥−5.4‰),高钙辉石(Δ17O =−10.6±2.8‰)为例外,说明如果ARC前体最初形成于富16o环境,那么在贫16o环境下球粒熔融过程中,其同位素组成大多被重置。分析的CAIs和AOA以富16o组分为主,与前人的研究结果一致,但部分同位素重设为贫16o组分。在AOA中鉴定出中等贫16o成分的千晶石(Δ17O =−15.7±3.0‰),富16o的CAI (Δ17O范围为−18 ~−22±2.5‰)的Wark-Lovering-like边缘的最外层鉴定出贫16o的透辉石(Δ17O =−1.9±2.5‰)。透辉石层的内缘由钙长石代替千英石组成,而千英石的内缘又由钙钛矿-钙钛矿-尖晶石组成的钙钛矿-钙钛矿-尖晶石岩心组成。同位素成像显示透辉石/钙长岩边界在O同位素组成上具有陡峭的梯度。基于在1400-1500 K温度范围内的O扩散模型,形成透辉石和钙长石边缘层的热事件的持续时间不超过大约100天,可能要短得多。考虑到Acfer 094的弱变质蚀变,本研究分析的AOA、CAI和ARC矿物的部分至近乎完全的o同位素重置发生在Acfer 094母体形成之前太阳星云中的短期热事件。因此,本研究中发现的同位素变化表明,至少有一些耐火材料是从富含16o的环境(最初发生结晶)转移到太阳星云中缺乏16o的环境(随后发生结晶和/或同位素重置)。
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引用次数: 0
2025 Barringer Medal for Sarah Stewart 莎拉·斯图尔特获得2025年巴林杰奖章
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-06-21 DOI: 10.1111/maps.70004
R. Terik Daly

Sarah is a Professor at Arizona State University's School of Earth and Space Exploration. Before this, she was tenured faculty at both the University of California, Davis, and Harvard University. Her academic journey began at Harvard, where she earned two A.B. degrees in Astrophysics and Physics in 1995. Sarah then pursued a Ph.D. in Planetary Science from Caltech under the supervision of Tom Ahrens, completing her degree in 2002. Later, she held a G. K. Gilbert postdoctoral fellowship at the Carnegie Institution of Washington. This foundation equipped Sarah with the skills and deep understanding necessary for her groundbreaking work.

Sarah's achievements are numerous. Beyond the Barringer Medal we celebrate today, Sarah has received a MacArthur “Genius” Fellowship, the Urey Prize, and a Presidential Early Career Award for Scientists and Engineers. She is a Fellow of the American Association for the Advancement of Science and the American Physical Society. She has advised and mentored a dozen graduate students, nine postdoctoral fellows, and many undergraduates. Sarah cares about the people who do research, in addition to research itself. She has also led or co-led over 20 grants from NASA, the Army Research Office, the Department of Energy, and the National Science Foundation.

Sarah's work is best known for two things: her fiendishly complicated shock physics experiments and her mastery of numerical impact modeling. This marriage of methods sets her apart from most other people who study planetary cratering. And this dual approach is part of the secret sauce that empowers Sarah and her group to make such meaningful contributions. For example, numerical impact models struggle with the limited quality of equations of state and constitutive models, which describe how materials behave under extreme conditions. Sarah tackles this limitation head-on. When gas gun experiments cannot reach the needed pressures and temperatures, she turns to Z machine experiments. Sarah and her team analyze these innovative shock physics experiments to derive new equations of state. These revisions aren't just minor tweaks; these new equations of state fundamentally advance our knowledge of material behavior. Her research group then takes these improved equations of state and meticulously integrates them into numerical impact models. This blend of shock experiments and numerical modeling has transformed how we think about, for example, melting and vaporization during planet formation.

Some of Sarah's highest-impact work centers on the Earth-Moon system. In 2012, she and Matija Cuk published a pivotal paper in Science. They proposed that the Moon formed via a giant impact into a fast-spinning Earth, followed by a period of resonant despinning. This scenario successfully explains the isotopic similarities between the Earth and Moon, though other scenarios have been proposed. Since then, Sarah's group has modeled the aftermath of the Moon-forming impact

萨拉是亚利桑那州立大学地球与太空探索学院的教授。在此之前,她是加州大学戴维斯分校和哈佛大学的终身教授。她的学术之旅始于哈佛大学,1995年获得天体物理学和物理学两个学士学位。随后,莎拉在汤姆·阿伦斯的指导下在加州理工学院攻读行星科学博士学位,并于2002年完成学位。后来,她在华盛顿卡内基研究所获得g.k.吉尔伯特博士后奖学金。这个基础为莎拉的开创性工作提供了必要的技能和深刻的理解。莎拉的成就数不胜数。除了我们今天庆祝的巴林杰奖章,莎拉还获得了麦克阿瑟“天才”奖学金、尤里奖和总统科学家和工程师早期职业奖。她是美国科学促进会和美国物理学会的会员。她指导和指导了12名研究生、9名博士后和许多本科生。除了研究本身,莎拉还关心做研究的人。她还领导或共同领导了来自美国国家航空航天局、陆军研究办公室、能源部和国家科学基金会的20多项资助。莎拉的工作以两件事而闻名:她极其复杂的冲击物理实验和她对数值冲击建模的精通。这种方法的结合使她与其他大多数研究行星陨石坑的人不同。这种双重方法是莎拉和她的团队做出如此有意义的贡献的秘密武器的一部分。例如,数值冲击模型与描述材料在极端条件下的行为的状态方程和本构模型的有限质量作斗争。Sarah正面解决了这个限制。当气枪实验无法达到所需的压力和温度时,她转向Z机实验。莎拉和她的团队分析了这些创新的冲击物理实验,得出了新的状态方程。这些修改不仅仅是细微的调整;这些新的状态方程从根本上提高了我们对物质行为的认识。然后,她的研究小组将这些改进的状态方程仔细地整合到数值影响模型中。这种冲击实验和数值模拟的结合改变了我们对行星形成过程中熔化和蒸发的看法。莎拉的一些影响最大的工作集中在地月系统上。2012年,她和Matija Cuk在《科学》杂志上发表了一篇重要论文。他们提出,月球是通过对快速旋转的地球的巨大撞击形成的,随后是一段时间的共振鄙视。这种假设成功地解释了地球和月球之间同位素的相似性,尽管也有人提出了其他的假设。从那以后,Sarah的团队对月球形成的影响进行了精细的建模,这使得Sarah的团队创造了“synestia”这个术语来描述地球在高角动量的巨大撞击后的形态。莎拉正在进行的研究正在改写这个我们都称之为“家”的星球的创造故事。除了她多产的研究成果(近100篇同行评议出版物被引用&gt;7000次),她还担任《地球物理研究行星杂志》的副主编,美国地球物理联合会行星科学分会主席,以及美国国家科学院、工程院和医学院天体生物学和行星科学委员会成员。Sarah是NASEM和能源部多个报告的委员会成员或审稿人,包括最近的行星科学和天体生物学十年调查的审稿人。萨拉擅长把不同的领域联系起来。她将材料科学、高能量密度物理学和行星科学联系起来。这种跨学科的方法使Sarah能够解锁对影响现象的见解,否则将无法获得。她看到的是联系,而其他人看到的是界限。Sarah支持合作。这种倾向既适用于她的研究,也适用于她对社区的参与。一个典型的例子就是她创建的impact .wiki。这个社区项目旨在推动陨石坑社区的开放科学实践,并确定战略需求。如今,莎拉是为数不多的培养下一代撞击实验学家的人之一。她认识到这种培训不足对影响领域的长期健康构成风险。萨拉自愿付出了大量的时间和专业知识来降低这种风险。这种无私的努力不仅有利于行星科学,也有利于更广泛的冲击物理学界。Sarah对合作和跨学科工作的关注推动了她的研究和科学界的发展。如果我不提莎拉广泛的公众宣传,那就太失职了。 她为哈佛自然历史博物馆的一个展览提供建议,担任一个教育视频系列的科学顾问,并在一部IMAX电影和各种纪录片中担任主题专家或受访者。她的TED沙龙演讲题目是“月球从何而来?”《一个新理论》的点击量已超过300万次。最后,Sarah的研究无疑加深了我们对撞击现象的理解。莎拉从根本上提高了我们对空间尺度上撞击过程的认识,从你可以在手掌上的实验到形成或破坏行星的巨大撞击。但是,莎拉不仅仅是一位才华横溢的研究者;她是行星科学界的支柱。在这种情况下,萨拉对我的生活产生了最直接的影响。我期待着她未来在撞击坑和行星科学方面取得突破。但最重要的是,我期待她继续在行星陨石坑社区发挥领导作用:建立社区,加强社区,统一社区。
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引用次数: 0
The breathing of clay-rich astromaterials on Earth: Insights from the Tarda (C2-ung) and Aguas Zarcas (CM2) meteorites 地球上富含粘土的天体物质的呼吸:来自塔尔达(C2-ung)和阿瓜斯扎卡斯(CM2)陨石的见解
IF 2.4 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-06-20 DOI: 10.1111/maps.70000
Laurence A. J. Garvie, László Trif, Christian G. Hoover

Meteorites arriving on Earth possess indigenous organic, isotopic, mineralogic, and magnetic properties that reveal conditions and processes from their formation. However, these properties can rapidly change when exposed to the Earth's environment. Asteroids, which formed nearly 4.5 billion years ago, inhabit the ultrahigh vacuum of interplanetary space, with a pressure of around 1.3 × 10−11 Pa, equivalent to only a few tens of atoms per cubic centimeter. Fragments of these asteroids, which land on Earth as meteorites, immediately adsorb atmospheric gases into their pore spaces, which can subsequently adsorb into and onto the minerals. In this study, we show that adsorption of atmospheric water can significantly increase the mass of the smectite-rich Tarda (C2-ung) meteorite, with mass gains reaching around 30 wt% at 100% relative humidity (RH) and between 5 and 10 wt% under typical laboratory conditions (up to ~50% RH). In contrast, the serpentine-rich Aguas Zarcas meteorite gains approximately 11 wt% at 100% RH and around 2 wt% at ~50% RH. This water adsorption leads to observable mass fluctuations in clay-rich carbonaceous chondrites (CCs), especially those with high smectite content, which undergo a “breathing-like” process. This process involves the uptake and release of water, influenced by atmospheric humidity. Although this mass change is reversible in the short term, prolonged “breathing” can alter the mineral composition and physical properties of these materials, complicating our understanding of their origins and evolution. For instance, gypsum forms in Tarda after 10 min of exposure to 100% RH at room temperature, while the Aguas Zarcas meteorite forms significant gypsum within 24 h under similar conditions. In addition, mass changes for Tarda are measured with thermal gravimetry in a He atmosphere, by heating the sample at 100°C in a high vacuum, and after curation under an ultradry atmosphere. These experiments show that samples exposed to the atmosphere rapidly adsorb significant water that is not removed by curation under dry N2. Our findings indicate that this “breathing” process can profoundly and rapidly affect the properties of astromaterials, including samples returned from asteroids Ryugu and Bennu. Maintaining these materials in a stable, low-humidity environment can help prevent such changes and preserve their indigenous properties.

到达地球的陨石具有原生的有机、同位素、矿物学和磁性,揭示了它们形成的条件和过程。然而,当暴露在地球环境中时,这些特性会迅速改变。小行星形成于近45亿年前,居住在行星际空间的超高真空中,压力约为1.3 × 10−11 Pa,相当于每立方厘米只有几十个原子。这些小行星的碎片以陨石的形式降落在地球上,会立即将大气气体吸附到它们的孔隙空间中,这些气体随后会吸附到矿物上。在这项研究中,我们发现大气水的吸附可以显著增加富蒙脱石Tarda (co2 -ung)陨石的质量,在100%相对湿度(RH)下质量增加约30 wt%,在典型的实验室条件下(高达~50% RH)质量增加5 ~ 10 wt%。相比之下,富含蛇纹岩的Aguas Zarcas陨石在100%相对湿度下增加了约11%,在~50%相对湿度下增加了约2%。这种水吸附导致富粘土碳质球粒陨石(CCs)中可观察到的质量波动,特别是那些蒙脱石含量高的碳质球粒陨石,它们经历了一个“类似呼吸”的过程。这个过程包括水的吸收和释放,受大气湿度的影响。虽然这种质量变化在短期内是可逆的,但长时间的“呼吸”会改变这些材料的矿物组成和物理性质,使我们对它们的起源和演变的理解复杂化。例如,Tarda陨石在100% RH的室温下暴露10分钟后形成石膏,而Aguas Zarcas陨石在类似条件下24小时内形成大量石膏。此外,Tarda的质量变化是用热重法在He气氛中测量的,通过在100°C高真空中加热样品,并在超干燥气氛下保存。这些实验表明,暴露在大气中的样品迅速吸附了大量的水,而这些水在干燥的N2下不能通过养护来去除。我们的研究结果表明,这种“呼吸”过程可以深刻而迅速地影响天体材料的特性,包括从小行星龙宫和本努返回的样本。将这些材料保持在稳定、低湿度的环境中可以帮助防止这种变化,并保持其原有的特性。
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引用次数: 0
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Meteoritics & Planetary Science
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