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Organic solvent-free in-situ polymerization of waterborne polyurethane with amino-grafted silica for carbon dioxide separation 水性聚氨酯与氨基接枝二氧化硅的无有机溶剂原位聚合,用于二氧化碳分离
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924410033
Kai-Yen Chin, Angus Shiue, Li-Chun Wu, Shu-Mei Chang

The novel mixed-matrix membrane (MMMs) by incorporating covalently amino groups grafted nano-silica (Amino-NP) into an eco-friendly, organic solvent-free waterborne polyurethane (OSF-WPU) matrix for the separation application of CO2/N2. This investigation focused on the gas permeance and separation performance of the MMMs. The optimized CO2/N2 separation factor reached 8.21±0.47, with a CO2 permeance of 16.72±1.02 GPU under conditions of 1.0 bar and 25C in a wet mixed-gas state. Incorporating even a tiny amount of Amino-NP efficiently enhanced CO2 permeability and CO2/N2 selectivity. OSF-WPU/Amino-NP MMMs demonstrated superior performance, emphasize their potential for stable long-term operation in practical CO2 separation applications.

将共价氨基接枝纳米二氧化硅(Amino-NP)加入环保型无有机溶剂水性聚氨酯(OSF-WPU)基质中,制成新型混合基质膜(MMMs),用于分离 CO2/N2。这项研究的重点是 MMM 的气体渗透性和分离性能。在 1.0 巴和 25∘C 条件下,湿混合气体状态下的 CO2/N2 分离系数达到 8.21±0.47,CO2 渗透率为 16.72±1.02 GPU。即使加入极少量的 Amino-NP 也能有效提高二氧化碳渗透率和 CO2/N2 选择性。OSF-WPU/Amino-NP MMMs 表现出卓越的性能,强调了它们在实际二氧化碳分离应用中长期稳定运行的潜力。
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引用次数: 0
Heat transfer analysis of ternary hybrid nanofluid through variable characteristic porous medium: Non-similar approach 三元混合纳米流体通过可变特性多孔介质的传热分析:非相似方法
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924502993
Farwa Haider, Metib Alghamdi, Taseer Muhammad

This paper aims at developing non-similar solutions for heat transfer augmentation in ternary hybrid nanofluids. Nanofluid is composed of three distinct (Silver, Copper, Aluminum oxide) nanosize particles while water is considered as a base fluid. Darcy–Forchheimer expression with variable porosity and permeability is adopted. Joule heating and viscous dissipations are also considered. Non-similar approach is utilized. Numerical solutions are computed by bvp4c solver of MATLAB. Graphical illustrations for flow and thermal fields behavior are provided. Comparative results are obtained for ternary hybrid nanofluid and nanoliquid. Physical quantities such as skin drag coefficient and Nusselt number are computed and interpreted. Our results reveal that rate of heat transfer augments substantially for Ag/water nanofluid in comparison to other classes of nanofluid.

本文旨在为三元混合纳米流体的传热增强开发非相似解决方案。纳米流体由三种不同的纳米颗粒(银、铜、氧化铝)组成,水被视为基础流体。采用了具有可变孔隙率和渗透率的达西-福克海默表达式。还考虑了焦耳加热和粘性耗散。采用了非相似方法。数值解由 MATLAB 的 bvp4c 求解器计算。提供了流动和热场行为的图表说明。获得了三元混合纳米流体和纳米液体的比较结果。计算并解释了皮肤阻力系数和努塞尔特数等物理量。结果表明,与其他类型的纳米流体相比,Ag/水纳米流体的传热速率大幅提高。
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引用次数: 0
New soliton solutions of fractional Biswas–Milovic equation with Kerr, parabolic and cubic-quartic nonlinearities 具有克尔、抛物和三次方非线性的分数比斯沃斯-米洛维奇方程的新孤子解
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924503561
Esra Pekönür, Mutlu Akar

This paper presents new explicit solutions of hyperbolic and trigonometric functions, obtained from the conformable fractional Biswas–Milovic equation, characterizing the long distance optical communications with three types nonlinearities: Kerr law, parabolic law and cubic-quartic ones. The Sardar sub-equation method is used, which gives the results that are of significant potential in a nonlinear system, providing a clear physical interpretation of the model under study. The resulting solutions are novel for the fractional Biswas–Milovic equation with the help of the method used, a powerful instrument for exploring precise solitary wave solutions for various other nonlinear equations in a nonlinear medium.

本文介绍了双曲函数和三角函数的新显式解法,这些解法是从共形分式比斯沃斯-米洛维奇方程中获得的,用于描述具有三种非线性的长距离光通信:该方程描述了具有三种非线性的长距离光通信的特征:克尔定律、抛物线定律和三次方-四次方定律。所使用的 Sardar 子方程方法给出了在非线性系统中具有重要潜力的结果,为所研究的模型提供了清晰的物理解释。在所使用方法的帮助下,分数比斯瓦斯-米洛维奇方程得到了新颖的解,这是探索非线性介质中各种其他非线性方程精确孤波解的有力工具。
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引用次数: 0
Electronic structure and optical properties of alkali metal X (X=Li, Na, K, Rb, Cs) adsorbed in the Te vacancy-deficient molybdenum ditelluride system: A first-principles study 碱金属 X(X=Li、Na、K、Rb、Cs)吸附在缺 Te 空位的二碲化钼体系中的电子结构和光学性质:第一原理研究
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924502713
Ying Dai, Guili Liu, Jianlin He, Junjie Ni, Guoying Zhang

In the framework of density functional theory, based on first principles, the plane wave pseudopotential technique was utilized to investigate the electrical and optical properties of MoTe2 adjusted by alkali metal X adsorption on Te vacancy defects (X=Li, Na, K, Rb, Cs). The adsorption of alkali metals on Te vacancy-deficient MoTe2 monolayers has been computationally analyzed. Charge transfer, electronic structure, and optical properties of alkali metal adsorption were systematically studied. It is shown that the MoTe2 bandgap is significantly reduced under Te vacancies. Te vacancies are frequently active sites in TMDs materials. With the adsorption of alkali metal atoms X (X = Li, Na, K, Rb, Cs) in the Te vacancy MoTe2 system, Li atoms have the most substantial geometrical deformation and the minor adsorption energy and can improve the adsorption properties more effectively. The MoTe2 system undergoes a change from semiconductor to metal after adsorption. Regarding optical properties, firm absorption and reflection peaks appeared, and a blueshift phenomenon was observed in the mountains. It is expected that these discoveries are likely to guide the use of molybdenum ditelluride in optoelectronics.

在密度泛函理论的框架内,基于第一性原理,利用平面波伪势技术研究了碱金属 X 在 Te 空位缺陷(X=Li、Na、K、Rb、Cs)上的吸附所调整的 MoTe2 的电学和光学性质。计算分析了碱金属对 Te 空位缺陷 MoTe2 单层的吸附。系统研究了碱金属吸附的电荷转移、电子结构和光学性质。结果表明,在 Te 空位的作用下,MoTe2 带隙显著减小。Te 空位是 TMDs 材料中常见的活性位点。随着碱金属原子 X(X = Li、Na、K、Rb、Cs)在 Te 空位 MoTe2 体系中的吸附,Li 原子的几何形变最大,吸附能最小,能更有效地改善吸附性能。吸附后的 MoTe2 体系发生了从半导体到金属的转变。在光学性质方面,出现了坚固的吸收峰和反射峰,并在山体中观察到蓝移现象。这些发现有望为二碲化钼在光电子领域的应用提供指导。
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引用次数: 0
Perturbation solution of multiphase flow of Williamson fluid through convergent and divergent conduits: Electro-osmotic effects 威廉姆森流体通过会聚和发散导管的多相流的扰动解:电渗效应
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924503482
Shahah Almutairi, Farooq Hussain, Mubbashar Nazeer, S. Saleem, Rubina Sultana Mohammed

Problem Statement: The hafnium particles are suspended through carrier fluid (Williamson fluid) to discuss the momentum analysis in multiphase flow in two different types of configurations.

Research gap: The analysis of the interaction of hafnium nanoparticles with the Williamson fluid model through the convergent and divergent conduits has not been discussed before.

Methodology: The equation of continuity and momentum equations are used for this analysis. The solution of both fluid and particle velocities is obtained through the perturbation analytical technique. The perturbation solution is also compared with the numerical solution.

Computational results: The Weissenberg number decays the velocity distribution. The suspension of hafnium particles updates the flow distribution through the conduits. The magnitude of the stream function decreases via the Weissenberg number.

Applications: This study can help develop a new approach to cancer therapy by using a high atomic number of nanoparticles.

Originality: This analysis is original and has neither been submitted nor published before.

问题陈述:通过载流体流体(Williamson 流体)悬浮铪颗粒,讨论两种不同类型配置下多相流的动量分析:纳米铪颗粒与威廉姆森流体模型通过会聚导管和发散导管的相互作用分析以前从未讨论过:本分析采用连续性方程和动量方程。通过扰动分析技术获得流体和粒子速度的解。计算结果:魏森堡数使速度分布衰减。铪颗粒的悬浮更新了流经导管的流量分布。流函数的大小随着魏森堡数的增加而减小:应用:这项研究有助于通过使用高原子序数的纳米粒子开发一种新的癌症治疗方法:原创性:本分析具有原创性,之前既未提交也未发表。
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引用次数: 0
Thermodynamic survey of a reactive MHD couple stress fluid through saturated porous substances with convective boundary conditions 具有对流边界条件的反应性 MHD 耦合应力流体通过饱和多孔物质的热力学研究
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924503536
Huda Alsaud, Anthony R. Hassan, Mustafa Inc, Akeem B. Disu, A. S. Oke, Shahram Rezapour

This study explores the thermodynamic behavior of a reactive hydromagnetic liquid flowing through permeable materials, with convective cooling applied to the walls. This study holds practical significance in optimization of thermal management systems and it is crucial for enhancing the efficiency of controlling thermal runaway. The flow is modeled as a system of partial differential equations which are numerically solved. The modified Adomian Decomposition Method and Pade approximation technique are utilized in solving the equations. The results acquired for velocity and temperature distributions are thereby employed to estimate entropy generation rate with critical values over numerous effects of various boundaries over improvement of thermal runaway utilizing Pade approximation technique to show the significant impact of convective cooling term (Biot number) and other thermophysical parameters on the fluid flow. The outcomes show that fluid velocity continuously increases with rising values of inverse couple stress and fluid temperature increases Biot number.

本研究探讨了反应性水磁性液体流经渗透性材料时的热力学行为,并在壁面上施加了对流冷却。这项研究对优化热管理系统具有实际意义,对提高控制热失控的效率至关重要。流动被模拟为一个偏微分方程系统,并对其进行数值求解。在求解方程时使用了改进的阿多米分解法和帕德近似技术。速度和温度分布的结果被用于估算熵产生率,其临界值与各种边界对改善热失控的众多影响有关,利用帕德近似技术来显示对流冷却项(比奥特数)和其他热物理参数对流体流动的重大影响。结果表明,流体速度随着反偶应力值的增加而持续增加,流体温度也会增加比奥特数。
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引用次数: 0
Effect of functionalized carbon nanotube on cement mortar: From experiment to DFT research 功能化碳纳米管对水泥砂浆的影响:从实验到 DFT 研究
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924502774
Lin Wei, GuiLi Liu, JiaXin Wang, ZhongHua Yang, GuoYing Zhang

In this paper, functionalized nanotube-reinforced cementitious composites were prepared, and the mechanical property test results showed that the 28d flexural strength of the composite was increased by 41.58% at a hydroxylated carbon nanotube mass fraction of 0.08wt.% compared to the original cement mortar. Carboxylated carbon nanotubes with a mass fraction of 0.02%, on the other hand, increased the 28d compressive strength by 99.12%. Probing the effect of the presence of functional groups on carbon nanotubes on the CNT/C–S–H interface by first principles. The results showed that the shear strengths (11.392MPa and 14.130MPa) of hydroxylated carbon nanotubes and plain carbon nanotubes at the interface with cementitious (CNT-OH/CSH and CNT/CSH) were lower than the shear strengths (21.584MPa) of carboxylated carbon nanotubes at the interface with cementitious (CNT-COOH/CSH). The adsorption of functional groups on carbon nanotubes changes the electron distribution on the surface of carbon nanotubes. The introduction of carboxyl groups exacerbates the charge transfer between carbon nanotubes and cementitious groups and promotes the generation of solid chemical bonds. This is the reason that carboxylated nanotubes added as reinforcement to cement mortar give better strength to the composite than hydroxylated nanotubes.

本文制备了功能化纳米管增强水泥基复合材料,力学性能测试结果表明,与原始水泥砂浆相比,羟基化碳纳米管质量分数为 0.08wt.% 时,复合材料的 28d 抗折强度提高了 41.58%。而质量分数为 0.02% 的羧化碳纳米管则使 28d 抗压强度提高了 99.12%。通过第一原理探究碳纳米管上存在的官能团对 CNT/C-S-H 界面的影响。结果表明,羟基化碳纳米管和普通碳纳米管与水泥基界面(CNT-OH/CSH 和 CNT/CSH)的剪切强度(11.392MPa 和 14.130MPa)低于羧基化碳纳米管与水泥基界面(CNT-COOH/CSH)的剪切强度(21.584MPa)。碳纳米管上吸附的官能团改变了碳纳米管表面的电子分布。羧基的引入加剧了碳纳米管与胶凝基团之间的电荷转移,促进了固体化学键的生成。这就是在水泥砂浆中添加羧基纳米管作为加固材料能比羟基纳米管获得更好的复合材料强度的原因。
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引用次数: 0
Heat and mass transfer analysis of conducting non-Newtonian nanofluid flows over an elongating sheet with a non-uniform heat source 非牛顿纳米流体在非均匀热源拉伸片上的传导流的传热传质分析
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924503494
M. Vinodkumar Reddy, R. Meenakumari, G. Sucharitha, F. Ali, S. S. Zafar, P. Lakshminarayana

Nanofluids help in many fields to improve the performance of thermal systems by augmenting heat transfer rates through their thermophysical properties. The performance of the nanofluids with various base fluids may be different. Therefore, the study and comparison of behaviors of various nanofluids are useful in several applications such as fuel as a coolant in automobiles, and in medical and electronic equipment to reduce the thermal resistance. This research proposed a novel model to investigate the flow behavior of three different nanofluids over an elongating surface in the presence of a non-uniform heat source and thermal radiation effects. This investigation describes how the considered nanofluids behave in the presence of a transverse magnetic field, and other effects. The proposed governing boundary layer partial differential equations (PDEs) are reformed into a system of nonlinear ordinary differential equations (ODEs) by introducing the proper similarity transformation. The finalized equations are solved numerically with the help of the ND solve package in Mathematica software. We intended how the fluid flow and heat transfer are affected by non-dimensional controlling factors with the help of graphics. Further, the calculations and discussions are accompanied by the numerical values of the skin friction coefficient and heat and mass transfer rates. According to the current findings, the Maxwell nanofluid exhibits superior performance in velocity, and the Oldroyd-B nanofluid shows more concentration and less temperature. As a special case, the results of this investigation are compared with the existing results, and found a good agreement between the results.

纳米流体通过其热物理性质提高传热率,有助于在许多领域提高热系统的性能。纳米流体与各种基础流体的性能可能不同。因此,研究和比较各种纳米流体的性能在许多应用中都非常有用,例如作为汽车冷却剂的燃料,以及用于医疗和电子设备以降低热阻的纳米流体。本研究提出了一个新模型,用于研究三种不同的纳米流体在存在非均匀热源和热辐射效应的拉伸表面上的流动行为。该研究描述了所考虑的纳米流体在横向磁场和其他效应下的行为。通过引入适当的相似性转换,将所提出的边界层偏微分方程(PDEs)转换为非线性常微分方程(ODEs)系统。借助 Mathematica 软件中的 ND 求解包,对最终确定的方程进行数值求解。我们打算借助图形说明流体流动和传热如何受到非尺寸控制因素的影响。此外,计算和讨论还附有表皮摩擦系数、传热和传质速率的数值。根据目前的研究结果,Maxwell 纳米流体在速度方面表现优异,而 Oldroyd-B 纳米流体则表现出更高的浓度和更低的温度。作为一个特例,本研究结果与现有结果进行了比较,发现结果之间具有良好的一致性。
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引用次数: 0
Generalized vortex flow of nanoparticle shapes over a permeable disc surface with generalized slip conditions 纳米颗粒形状在具有广义滑移条件的可渗透圆盘表面上的广义涡流
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924503469
Muhammad Rahman, Aqib Ali, Mustafa Turkyilmazoglu

This paper investigates the generalized vortex flow of nanofluid consisting of titanium dioxide (TiO2) with base fluid (H2O) over a permeable disk surface that generates a heat transfer process in the thermal boundary layer of the disk. Four types of non-spherical shapes of nanoparticles (blade, brick, cylinder and platelet) are considered for the research. The motion is produced when the fluid is far from the disk surface and rotates like a solid body with a constant angular velocity Ω. The partial differential equations (PDEs) are obtained using boundary layer approximations and then converted into ordinary differential equations (ODEs) using suitable similarity transformations. These nonlinear ODEs are solved using the bvp4c MATLAB solver. The effect of different parameters (n, A, α, ϕ, R and Pr) on the velocity components and temperature profile is shown graphically and in tabular results. This analysis concludes that for all non-spherical shapes, the velocity spectrum of all nanoparticles decreases when the values of factors such as power-law, suction, volume fraction and slip parameter increase. All non-spherical shapes of a nanofluid experience a decrease in fluid temperature due to the Prandtl number, while radiation numbers have the opposite effect.

本文研究了由二氧化钛(TiO2)和基础流体(H2O)组成的纳米流体在可渗透圆盘表面上的广义涡流,该涡流在圆盘的热边界层中产生热传递过程。研究考虑了四种非球形纳米粒子(叶片、砖块、圆柱和小板)。当流体远离圆盘表面并以恒定角速度 Ω 像固体一样旋转时,就会产生运动。使用边界层近似法获得偏微分方程(PDE),然后使用适当的相似变换将其转换为常微分方程(ODE)。使用 bvp4c MATLAB 求解器求解这些非线性 ODE。不同参数(n、A、α、j、R 和 Pr)对速度分量和温度曲线的影响以图形和表格形式显示。分析得出的结论是,对于所有非球形形状,当幂律、吸力、体积分数和滑移参数等因素的值增加时,所有纳米粒子的速度谱都会减小。由于普朗特数的影响,所有非球形纳米流体的流体温度都会下降,而辐射数的影响则相反。
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引用次数: 0
Modern technique to study Cauchy-type problem of fractional variable order differential equations with infinite delay via phase space 通过相空间研究具有无限延迟的分数变阶微分方程的 Cauchy 型问题的现代技术
IF 1.9 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-04-09 DOI: 10.1142/s0217984924503433
Marwa Benaouda, Souhila Sabit, Hatıra Günerhan, Mohammed Said Souid

In this paper, we use a novel approach to study the existence, uniqueness, and stability of solutions (EUSS) to a Cauchy-type problem of nonlinear fractional differential equations (FrDiEq) of variable order with infinite delay (CPNFDEVOID). Contrary to the techniques taken in the literature, which were centered on the usage of the concept of generalized intervals and the idea of piecewise constant functions, our approach is straightforward and based on a novel fractional operator that is more appropriate and demonstrates the solvability and stability of the main problem under less restrictive presumptions. The results are achieved in this paper by using Fixed Point Theory (FPT). The application, which includes an example and supporting images, concludes the paper.

在本文中,我们采用一种新方法来研究具有无限延迟的变阶非线性分数微分方程(FrDiEq)的考奇型问题(CPNFDEVOID)的解的存在性、唯一性和稳定性(EUSS)。与文献中以使用广义区间概念和片断恒定函数思想为中心的技术相反,我们的方法简单明了,基于一个新颖的分式算子,更加合适,并证明了主问题在限制较少的假设条件下的可解性和稳定性。本文利用定点理论(FPT)取得了上述结果。本文最后介绍了应用,包括一个示例和辅助图像。
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引用次数: 0
期刊
Modern Physics Letters B
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