Abstract In the Permian rhyodacite quarry at Zalas near Krakow, southern Poland, thallium-bearing Mn oxides occur in a small fault zone cutting Middle Jurassic sandy limestone poorly encrusted by an oxidized polymetallic mineralization. The encrustation comprises sulphides (pyrite, chalcopyrite, chalcocite, covellite, galena, marcasite), native bismuth, hematite, goethite, cuprite, mottramite, iodargyrite, unrecognized Cu sulphates and Bi oxychlorides as supergene minerals, barite and rare tiny grains of gold. It is most likely connected with rejuvenation of Early-Paleozoic faults during the Alpine orogeny on the Oligocene–Miocene boundary. Rare Tlbearing Mn oxides occur in an outside zone of the encrustations, filling small fractures and voids in limestone forming the fault breccia. Tl contents, reaching 20.82wt% as Tl2O, exceed by more than two orders of magnitude those reported in similar minerals before, making the oxides unique on a world scale. The Tl-bearing Mn oxides from Zalas reflect intensive weathering of an older Tl-bearing sulphide mineralization in an arid climate, involving saline fluids delivered to the groundwater system as the nappe structure of the Carpathians was developing during the Sava tectonic phase Oligocene/Miocene boundary.
{"title":"Exceptional Tl-bearing manganese oxides from Zalas, Krakow area, southern Poland","authors":"B. Gołębiowska, G. Rzepa, A. Pieczka","doi":"10.1515/mipo-2016-0002","DOIUrl":"https://doi.org/10.1515/mipo-2016-0002","url":null,"abstract":"Abstract In the Permian rhyodacite quarry at Zalas near Krakow, southern Poland, thallium-bearing Mn oxides occur in a small fault zone cutting Middle Jurassic sandy limestone poorly encrusted by an oxidized polymetallic mineralization. The encrustation comprises sulphides (pyrite, chalcopyrite, chalcocite, covellite, galena, marcasite), native bismuth, hematite, goethite, cuprite, mottramite, iodargyrite, unrecognized Cu sulphates and Bi oxychlorides as supergene minerals, barite and rare tiny grains of gold. It is most likely connected with rejuvenation of Early-Paleozoic faults during the Alpine orogeny on the Oligocene–Miocene boundary. Rare Tlbearing Mn oxides occur in an outside zone of the encrustations, filling small fractures and voids in limestone forming the fault breccia. Tl contents, reaching 20.82wt% as Tl2O, exceed by more than two orders of magnitude those reported in similar minerals before, making the oxides unique on a world scale. The Tl-bearing Mn oxides from Zalas reflect intensive weathering of an older Tl-bearing sulphide mineralization in an arid climate, involving saline fluids delivered to the groundwater system as the nappe structure of the Carpathians was developing during the Sava tectonic phase Oligocene/Miocene boundary.","PeriodicalId":18686,"journal":{"name":"Mineralogia","volume":"37 1","pages":"17 - 3"},"PeriodicalIF":0.0,"publicationDate":"2015-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80154832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Several types of coal waste (freshly-dumped waste, self-heated waste and waste eroded by rain water), river sediments and river water were sampled. The aim was to identify the types of phenols present on the dumps together with their relative abundances. Gas chromatography-mass spectrometry (GC-MS) analyses of a large number of samples (234) statistically underpin the phenol distributions in the sample sets. The largest average relative contents (1.17-13.3%) of phenols occur in the self-heated samples. In these, relatively high amounts of phenol, C1- and C2-phenols reflect the thermal destruction of vitrinite. In fresh coal waste, C2- and C3-phenols that originated from the bacterial/fungal degradation and oxidation of vitrinite particles are the most common (0.6 rel.%). Water-washed coal waste and water samples contain lower quantities of phenols. In the river sediments, the phenols present are the result of bacterial- or fungal decay of coaly organic matter or are of industrial origin.
{"title":"Distribution of phenols related to self-heating and water washing on coal-waste dumps and in coaly material from the Bierawka river (Poland)","authors":"Á. Nádudvari, M. Fabiańska, M. Misz-Kennan","doi":"10.1515/mipo-2016-0005","DOIUrl":"https://doi.org/10.1515/mipo-2016-0005","url":null,"abstract":"Abstract Several types of coal waste (freshly-dumped waste, self-heated waste and waste eroded by rain water), river sediments and river water were sampled. The aim was to identify the types of phenols present on the dumps together with their relative abundances. Gas chromatography-mass spectrometry (GC-MS) analyses of a large number of samples (234) statistically underpin the phenol distributions in the sample sets. The largest average relative contents (1.17-13.3%) of phenols occur in the self-heated samples. In these, relatively high amounts of phenol, C1- and C2-phenols reflect the thermal destruction of vitrinite. In fresh coal waste, C2- and C3-phenols that originated from the bacterial/fungal degradation and oxidation of vitrinite particles are the most common (0.6 rel.%). Water-washed coal waste and water samples contain lower quantities of phenols. In the river sediments, the phenols present are the result of bacterial- or fungal decay of coaly organic matter or are of industrial origin.","PeriodicalId":18686,"journal":{"name":"Mineralogia","volume":"40 1","pages":"29 - 40"},"PeriodicalIF":0.0,"publicationDate":"2015-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90549723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract The green colour of prasiolite, defined as naturally occurring transparent macrocrystalline α-quartz with primary colouration, results from the optical absorption centred at ~13,660 cm−1 and attributed to the FeVI2+→FeVI3+ intervalence charge transfer (Platonov et al. 1992). However, optical absorption spectroscopy of blue-green to green quartz from Rakowice Wielkie, Sudetes, south-western Poland, shows that its primary colouration results from the combination of this band and absorptions at ~18,500 cm−1 and ~16,250 cm−1. The first is assigned to a hole centre Fe4+s(Fe3+s-e−) combined with an electron centre Fe2+I6(Fe3+I6+e−), while the second from AlO44− defects. The quartz is blue-green if the 18,500 cm−1 prevails and becomes pale green if the 16,250 cm−1 band predominates. These colours seem to represent intermediate colour varieties between amethyst and prasiolite. We also suggest that spectral features of coloured quartz varieties might be useful indicators of changes in the physical- and chemical characteristics of the mineral-forming fluids.
绿橄榄石的绿色被定义为天然存在的具有原色的透明大晶α-石英，其绿色来自于以~13,660 cm−1为中心的光学吸收，并归因于FeVI2+→FeVI3+价间电荷转移(Platonov et al. 1992)。然而，来自波兰西南部苏德德斯Rakowice Wielkie的蓝绿色到绿色石英的光学吸收光谱表明，它的原色是由该波段和~ 18500 cm - 1和~ 16250 cm - 1吸收的组合产生的。第一个缺陷由空穴中心Fe4+s(Fe3+s-e−)和电子中心Fe2+I6(Fe3+I6+e−)组成，第二个缺陷由AlO44−组成。如果18500 cm−1波段占优势，石英呈蓝绿色;如果16250 cm−1波段占优势，石英呈淡绿色。这些颜色似乎代表了紫水晶和橄榄石之间的中间颜色变化。我们还认为，彩色石英品种的光谱特征可能是成矿流体物理和化学特征变化的有用指标。
{"title":"Green to blue-green quartz from Rakowice Wielkie (Sudetes, south-western Poland) – a re-examination of prasiolite-related colour varieties of quartz","authors":"A. Platonov, A. Szuszkiewicz","doi":"10.1515/mipo-2016-0004","DOIUrl":"https://doi.org/10.1515/mipo-2016-0004","url":null,"abstract":"Abstract The green colour of prasiolite, defined as naturally occurring transparent macrocrystalline α-quartz with primary colouration, results from the optical absorption centred at ~13,660 cm−1 and attributed to the FeVI2+→FeVI3+ intervalence charge transfer (Platonov et al. 1992). However, optical absorption spectroscopy of blue-green to green quartz from Rakowice Wielkie, Sudetes, south-western Poland, shows that its primary colouration results from the combination of this band and absorptions at ~18,500 cm−1 and ~16,250 cm−1. The first is assigned to a hole centre Fe4+s(Fe3+s-e−) combined with an electron centre Fe2+I6(Fe3+I6+e−), while the second from AlO44− defects. The quartz is blue-green if the 18,500 cm−1 prevails and becomes pale green if the 16,250 cm−1 band predominates. These colours seem to represent intermediate colour varieties between amethyst and prasiolite. We also suggest that spectral features of coloured quartz varieties might be useful indicators of changes in the physical- and chemical characteristics of the mineral-forming fluids.","PeriodicalId":18686,"journal":{"name":"Mineralogia","volume":"50 1","pages":"19 - 28"},"PeriodicalIF":0.0,"publicationDate":"2015-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83838483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Due to increasing emissions of greenhouse gases into the atmosphere number of methods are being proposed to mitigate the risk of climate change. One of them is mineral carbonation. Blast furnace and steel making slags are co-products of metallurgical processes composed of minerals which represent appropriate source of cations required for mineral carbonation. Experimental studies were performed to determine the potential use of slags in this process. Obtained results indicate that steel making slag can be a useful material in CO2 capture procedures. Slag components dissolved in water are bonded as stable carbonates in the reaction with CO2 from ambient air. In case of blast furnace slag, the reaction is very slow and minerals are resistant to chemical changes. More time is needed for minerals dissolution and release of cations essential for carbonate crystallisation and thus makes blast furnace slags less favourable in comparison with steel making slag.
{"title":"Mineral carbonation of metallurgical slags","authors":"M. Kasina, P. Kowalski, M. Michalik","doi":"10.1515/mipo-2015-0002","DOIUrl":"https://doi.org/10.1515/mipo-2015-0002","url":null,"abstract":"Abstract Due to increasing emissions of greenhouse gases into the atmosphere number of methods are being proposed to mitigate the risk of climate change. One of them is mineral carbonation. Blast furnace and steel making slags are co-products of metallurgical processes composed of minerals which represent appropriate source of cations required for mineral carbonation. Experimental studies were performed to determine the potential use of slags in this process. Obtained results indicate that steel making slag can be a useful material in CO2 capture procedures. Slag components dissolved in water are bonded as stable carbonates in the reaction with CO2 from ambient air. In case of blast furnace slag, the reaction is very slow and minerals are resistant to chemical changes. More time is needed for minerals dissolution and release of cations essential for carbonate crystallisation and thus makes blast furnace slags less favourable in comparison with steel making slag.","PeriodicalId":18686,"journal":{"name":"Mineralogia","volume":"13 1","pages":"27 - 45"},"PeriodicalIF":0.0,"publicationDate":"2015-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78105440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Argentopentlandite has been found in samples collected on the dump of the Michael mine, an old silver mine in Zagórze Śląskie in the northern part of the Góry Sowie mountains. Though argentopentlandite is not a very common mineral, it is well known from high-temperature hydrothermal veins and from Ni-Cu deposits hosted in ultramafic rocks also containing platinum-group minerals. The argentopentlandite has been recognized in a sulphide nest in association with pyrrhotite and chalcopyrite in massive barite. In comparison to other occurrences (see Table 2), this mineral is characterized by a low Ni content (ave. 16.02wt% - EDS; 16.43wt% - WDS), a lack of cobalt and a relatively high copper content (ave. 2.13wt% - EDS; 1.55wt% - WDS). Based on these data, it can be concluded that the argentopentlandite, and the associated sulphides, were precipitated from hydrothermal fluids shortly after barite, the major vein constituent. As the optical properties of the argentopentlandite in reflected light are rather similar to those of bornite, it can be overlooked during routine observations. Thus, argentopentlandite or associated ore mineralization may also occur in other barite veins in the area.
{"title":"Argentopentlandite from barite vein in Zagórze Śląskie, Lower Silesia; a first occurrence in Poland","authors":"A. Piestrzynski, Krzysztof Kowalik","doi":"10.1515/mipo-2015-0001","DOIUrl":"https://doi.org/10.1515/mipo-2015-0001","url":null,"abstract":"Abstract Argentopentlandite has been found in samples collected on the dump of the Michael mine, an old silver mine in Zagórze Śląskie in the northern part of the Góry Sowie mountains. Though argentopentlandite is not a very common mineral, it is well known from high-temperature hydrothermal veins and from Ni-Cu deposits hosted in ultramafic rocks also containing platinum-group minerals. The argentopentlandite has been recognized in a sulphide nest in association with pyrrhotite and chalcopyrite in massive barite. In comparison to other occurrences (see Table 2), this mineral is characterized by a low Ni content (ave. 16.02wt% - EDS; 16.43wt% - WDS), a lack of cobalt and a relatively high copper content (ave. 2.13wt% - EDS; 1.55wt% - WDS). Based on these data, it can be concluded that the argentopentlandite, and the associated sulphides, were precipitated from hydrothermal fluids shortly after barite, the major vein constituent. As the optical properties of the argentopentlandite in reflected light are rather similar to those of bornite, it can be overlooked during routine observations. Thus, argentopentlandite or associated ore mineralization may also occur in other barite veins in the area.","PeriodicalId":18686,"journal":{"name":"Mineralogia","volume":"1 1","pages":"13 - 25"},"PeriodicalIF":0.0,"publicationDate":"2015-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81156834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract As part of the characterization of the petrified wood of East Cairo at the New Cairo Petrified Forest, representative samples collected from the area were studied by X-ray powder diffraction (XRD) and optical microscopy. The samples, as indicated by XRD analysis, are composed of quartz ± some goethite ± minor moganite ± minor gypsum ± trace calcite. The absence of moganite in some samples has been attributed to the transformation of moganite to quartz or to leaching processes. Under the optical microscope, some of the 10 petrified-wood samples are permineralized with mainly microcrystalline quartz (chalcedony), some with a combination of chalcedony and microgranular quartz, and some with microgranular quartz. The sequence of silicification is likely to have been either opaline precursor to chalcedony and quartz, or directly to chalcedony and quartz. The crystallinity indices (C.I.) of the quartz in the samples studied, measured using a standard X-ray powder diffraction procedure, are consistent with the petrographic findings. The chalcedonic samples have the least C.I. values, and the microgranular quartz samples the highest values.
{"title":"The fossil wood of East Cairo, Egypt: A mineralogical view","authors":"K. Hassan","doi":"10.1515/mipo-2015-0003","DOIUrl":"https://doi.org/10.1515/mipo-2015-0003","url":null,"abstract":"Abstract As part of the characterization of the petrified wood of East Cairo at the New Cairo Petrified Forest, representative samples collected from the area were studied by X-ray powder diffraction (XRD) and optical microscopy. The samples, as indicated by XRD analysis, are composed of quartz ± some goethite ± minor moganite ± minor gypsum ± trace calcite. The absence of moganite in some samples has been attributed to the transformation of moganite to quartz or to leaching processes. Under the optical microscope, some of the 10 petrified-wood samples are permineralized with mainly microcrystalline quartz (chalcedony), some with a combination of chalcedony and microgranular quartz, and some with microgranular quartz. The sequence of silicification is likely to have been either opaline precursor to chalcedony and quartz, or directly to chalcedony and quartz. The crystallinity indices (C.I.) of the quartz in the samples studied, measured using a standard X-ray powder diffraction procedure, are consistent with the petrographic findings. The chalcedonic samples have the least C.I. values, and the microgranular quartz samples the highest values.","PeriodicalId":18686,"journal":{"name":"Mineralogia","volume":"66 1","pages":"47 - 57"},"PeriodicalIF":0.0,"publicationDate":"2015-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86298472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Mimetite Pb5(AsO4)3Cl is the most insoluble lead arsenate mineral and could be used in remediation techniques to reduce As(V) mobility in soils. However, low-molecular-weight organic acids such as malic acid increase its solubility. The effect of malic acid on the dissolution of mimetite strongly depends on the pH of the equilibrium solution. At low pH, mimetite is decomposed mostly by the mechanism of protonation. With increasing pH, the solubility of mimetite decreases and a greater influence in its dissolution is ascribed to complexation of Pb(II) by organic ligands. During dissolution experiments, the amount of arsenic released to solution was > 26% higher in organic solutions than in inorganic solutions, and the amount of lead was > 8% greater. The solubility product of mimetite (KSP) was calculated in order to quantify the thermodynamic stability of the investigated mineral. The value obtained, i.e., -24.52 ± 0.49 fluctuates between the values of -21.69 ± 1.05 and -27.87 ± 0.42 reported in the literature.
{"title":"Dissolution of mimetite Pb5(AsO4)3Cl in malic acid solutions","authors":"P. Turek, T. Bajda, M. Manecki","doi":"10.2478/mipo-2014-0001","DOIUrl":"https://doi.org/10.2478/mipo-2014-0001","url":null,"abstract":"Abstract Mimetite Pb5(AsO4)3Cl is the most insoluble lead arsenate mineral and could be used in remediation techniques to reduce As(V) mobility in soils. However, low-molecular-weight organic acids such as malic acid increase its solubility. The effect of malic acid on the dissolution of mimetite strongly depends on the pH of the equilibrium solution. At low pH, mimetite is decomposed mostly by the mechanism of protonation. With increasing pH, the solubility of mimetite decreases and a greater influence in its dissolution is ascribed to complexation of Pb(II) by organic ligands. During dissolution experiments, the amount of arsenic released to solution was > 26% higher in organic solutions than in inorganic solutions, and the amount of lead was > 8% greater. The solubility product of mimetite (KSP) was calculated in order to quantify the thermodynamic stability of the investigated mineral. The value obtained, i.e., -24.52 ± 0.49 fluctuates between the values of -21.69 ± 1.05 and -27.87 ± 0.42 reported in the literature.","PeriodicalId":18686,"journal":{"name":"Mineralogia","volume":"107 1","pages":"12 - 3"},"PeriodicalIF":0.0,"publicationDate":"2015-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77425248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract We report on the occurrence of peculiar Ba- and Ti-enriched dark mica in metasedimentary rocks that underwent high-pressure metamorphism in the diamond stability field followed by decompression to granulite facies conditions. The mica occurs as well-developed preserved laths in a quartzofeldspathic matrix. The mean concentrations of BaO and TiO2 in the mica are 11.54 and 7.80wt%, respectively. The maximum amounts of these components are 13.38wt% BaO and 8.45wt% TiO2. The mean crystallochemical formula can be expressed as (K0.54Ba0.39Na0.02Ca0.01)Σ0.96(Fe1.37Mg0.85Ti0.50Al0.29Mn0.01Cr0.01)Σ3.03(Si2.59Al1.41)Σ4.00O10(OH1.30O0.66F0.02S0.01)Σ1.99, with oxyannite, oxy-ferrokinoshitalite and siderophyllite as dominating end-members. Based on the petrographical observations, it is proposed that the dark mica was formed at a rather late stage in the evolution of the parental rock, i.e. under granulite facies conditions.
{"title":"Ba- and Ti-enriched dark mica from the UHP metasediments of the Seve Nappe Complex, Swedish Caledonides","authors":"J. Majka, Ł. Kruszewski, Å. Rosén, I. Klonowska","doi":"10.1515/mipo-2017-0001","DOIUrl":"https://doi.org/10.1515/mipo-2017-0001","url":null,"abstract":"Abstract We report on the occurrence of peculiar Ba- and Ti-enriched dark mica in metasedimentary rocks that underwent high-pressure metamorphism in the diamond stability field followed by decompression to granulite facies conditions. The mica occurs as well-developed preserved laths in a quartzofeldspathic matrix. The mean concentrations of BaO and TiO2 in the mica are 11.54 and 7.80wt%, respectively. The maximum amounts of these components are 13.38wt% BaO and 8.45wt% TiO2. The mean crystallochemical formula can be expressed as (K0.54Ba0.39Na0.02Ca0.01)Σ0.96(Fe1.37Mg0.85Ti0.50Al0.29Mn0.01Cr0.01)Σ3.03(Si2.59Al1.41)Σ4.00O10(OH1.30O0.66F0.02S0.01)Σ1.99, with oxyannite, oxy-ferrokinoshitalite and siderophyllite as dominating end-members. Based on the petrographical observations, it is proposed that the dark mica was formed at a rather late stage in the evolution of the parental rock, i.e. under granulite facies conditions.","PeriodicalId":18686,"journal":{"name":"Mineralogia","volume":"34 1","pages":"41 - 50"},"PeriodicalIF":0.0,"publicationDate":"2015-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81662052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract A number of independent methods have been used to measure the thermal maturity of Silurian rocks from the Holy Cross Mountains in Poland. Black shales are characterized by diverse TOC values varying from 0.24-7.85%. Having calculated vitrinite equivalent reflectance using three different formulas, we propose that the most applicable values for the Silurian rocks are those based on Schmidt et al. (2015) equation. Based on this formula, the values range from % 0.71 VReqvVLR (the vitrinite equivalent reflectance of the vitrinite-like macerals) to % 1.96 VReqvVLR. Alternative, complementary methods including Rock Eval pyrolysis and parameters based on organic compounds (CPI, Pr/n-C17, Ph/n-C18, MPI1, and MDR) from extracts did not prove adequate as universal thermal maturity indicators. We have confirmed previous suggestions that Llandovery shales are the most likely Silurian source rocks for the generation of hydrocarbons in the HCM.
摘要:对波兰圣十字山志留系岩石热成熟度的测量采用了多种独立的方法。黑色页岩TOC值变化多样，范围在0.24 ~ 7.85%之间。通过使用三种不同的公式计算镜质组等效反射率，我们提出最适用于志留系岩石的值是基于Schmidt et al.(2015)方程的值。根据该公式，其取值范围为% 0.71 VReqvVLR(镜质组等效反射率)至% 1.96 VReqvVLR。替代的、互补的方法，包括岩石热解和基于有机化合物(CPI、Pr/n-C17、Ph/n-C18、MPI1和MDR)的萃取物参数，都不足以作为通用的热成熟度指标。我们已经证实了先前的建议，即llanddovery页岩最有可能是HCM中生成烃的志留系烃源岩。
{"title":"Vitrinite equivalent reflectance of Silurian black shales from the Holy Cross Mountains, Poland","authors":"J. Smolarek, L. Marynowski, K. Spunda, W. Trela","doi":"10.1515/mipo-2015-0006","DOIUrl":"https://doi.org/10.1515/mipo-2015-0006","url":null,"abstract":"Abstract A number of independent methods have been used to measure the thermal maturity of Silurian rocks from the Holy Cross Mountains in Poland. Black shales are characterized by diverse TOC values varying from 0.24-7.85%. Having calculated vitrinite equivalent reflectance using three different formulas, we propose that the most applicable values for the Silurian rocks are those based on Schmidt et al. (2015) equation. Based on this formula, the values range from % 0.71 VReqvVLR (the vitrinite equivalent reflectance of the vitrinite-like macerals) to % 1.96 VReqvVLR. Alternative, complementary methods including Rock Eval pyrolysis and parameters based on organic compounds (CPI, Pr/n-C17, Ph/n-C18, MPI1, and MDR) from extracts did not prove adequate as universal thermal maturity indicators. We have confirmed previous suggestions that Llandovery shales are the most likely Silurian source rocks for the generation of hydrocarbons in the HCM.","PeriodicalId":18686,"journal":{"name":"Mineralogia","volume":"18 3 1","pages":"79 - 96"},"PeriodicalIF":0.0,"publicationDate":"2015-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82878020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
W. Wilczyńska-Michalik, Kamil Rzeźnikiewicz, B. Pietras, M. Michalik
Abstract During single particle analysis of aerosol in Kraków (Poland) we noticed a new component, that is, aggregates of TiO2 particles. These aggregates are from 0.5 to 4 μm and are composed of individual particles whose size typically varies from between 100 and 350 nm. Smaller particles (below 100 nm) also occur. TiO2 particles are relatively abundant in the summer. The size distribution of the particles corresponds to “pigmentary” TiO2, which indicates that they could be derived from paints and building materials. TiO2 particles were not previously identified in aerosol samples in Kraków, and therefore this phenomenon is likely to be related to the common usage of new building materials and paints. A review of the literature suggests that TiO2 particles, especially within the nanosize range, could result in health and environmental impacts; however, evaluation of the actual threat is difficult.
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