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The Future of Scandium Recovery from Wastes 从废物中回收钪的前景
Pub Date : 2021-12-03 DOI: 10.3390/materproc2021005055
Olga Chernoburova, A. Chagnes
With growing demand for renewable and clean energy technologies, the need in rare earth metals is increasing. Scandium, which is often considered a rare earth element (REE), is a critical metal mainly used in solid oxide fuel cells (SOFCs) and high strength aluminum alloys used in aerospace and 3D printing applications. Furthermore, scandium supply is limited due to its scarcity and the high cost of its production in Asia and Russia while Europe has no production of scandium. Therefore, scandium extraction from alternative resources such as secondary resources located in Europe is of great concern. Within this context, this work provides a condensed state-of-art review of the issue of scandium recovery from industrial wastes. Priority was given to addressing the technological and economic challenges associated with the recovery of scandium from the said residues, with particular emphasis on the bauxite residue from alumina production, which represents nearly 5 million tons on dry basis per year in Europe.
随着对可再生能源和清洁能源技术的需求不断增长,对稀土金属的需求也在增加。钪通常被认为是稀土元素(REE),是一种关键金属,主要用于固体氧化物燃料电池(sofc)和航空航天和3D打印应用中使用的高强度铝合金。此外,由于亚洲和俄罗斯的稀缺和生产成本高,钪的供应有限,而欧洲没有钪的生产。因此,从欧洲的二次资源等替代资源中提取钪备受关注。在此背景下,本工作提供了从工业废物中回收钪问题的浓缩状态的最新审查。优先处理与从上述残留物中回收钪有关的技术和经济挑战,特别强调氧化铝生产中的铝土矿残留物,在欧洲每年占近500万吨干基。
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引用次数: 6
Rational and Sustainable Water Resource Management in the Ptolemais Lignite Basin Using Remotely Sensed Data 基于遥感数据的托勒密褐煤盆地水资源合理可持续管理
Pub Date : 2021-12-02 DOI: 10.3390/materproc2021005044
G. Louloudis, C. Roumpos, Eleni Mertiri, Georgios Kasfikis, F. Pavloudakis
Future investment feasibility studies concerning post-mining repurposing utilities and economic transitions should focus on regional water resource management and the hydraulic protection of any utilities. Satellite images in different bands and Digital Elevation Models (DEM) of the Ptolemais basin were processed, leading to a more accurate estimation of the runoff ratio and percolation ratio. Furthermore, the saturated and unsaturated areas were delineated, leading to the recognition of potential artificial ground water recharge zones and zones where appropriate hydraulic protection measures are necessary.
今后关于采矿后重新利用公用事业和经济转型的投资可行性研究应集中于区域水资源管理和任何公用事业的水力保护。利用不同波段卫星影像和数字高程模型(DEM)对托勒密盆地径流比和渗流比进行了较为精确的估算。此外,划定了饱和和不饱和区域,从而识别了潜在的人工地下水补给区和需要采取适当水力保护措施的区域。
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引用次数: 0
A Review about the Sustainability of Pit Lakes as a Rehabilitation Factor after Mine Closure 坑湖作为矿山关闭后恢复因子的可持续性研究进展
Pub Date : 2021-12-02 DOI: 10.3390/materproc2021005052
Chara Sakellari, C. Roumpos, G. Louloudis, E. Vasileiou
At the end of surface mining activities, the remnant voids are of great concern regarding rehabilitating the final open pits. The investigation of the sustainability of pit lakes in post-mining regions constitutes a challenging research problem. This paper aims to highlight the effectiveness of pit lakes as a rehabilitation factor. In this framework, several cases worldwide and in Greece were examined in detail and evaluated. The results indicate that mine pit lakes must be evaluated as dynamic systems, natural or artificial, which demand rational mine water management to ensure their sustainability. Specifically in Greece, it is of great importance during the transition to the post-lignite era.
在露天采矿活动结束时,残余空洞是修复最后露天矿坑的重要问题。开采后地区坑湖的可持续性研究是一个具有挑战性的研究课题。本文旨在突出坑湖作为恢复因子的有效性。在这一框架下,对世界各地和希腊的几个案例进行了详细审查和评估。结果表明,矿山坑湖必须作为动态系统进行评价,无论是自然的还是人工的,都需要合理的矿山水管理,以保证其可持续性。特别是在希腊,它在向后褐煤时代过渡的过程中非常重要。
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引用次数: 5
Simulating the Use of a Smelter Off-Gas in the Precipitation Stage of the Pedersen Process 模拟Pedersen法沉淀阶段冶炼废气的使用
Pub Date : 2021-12-02 DOI: 10.3390/materproc2021005053
Andriani Manataki, J. Mwase, C. van der Eijk
The Pedersen process is an alumina production process, which combines pyrometallurgical and hydrometallurgical methods. In the pyrometallurgical stage, limestone is calcined and CO2 is generated. This off-gas can be captured with a high CO2 concentration. At the end of the hydrometallurgical process, aluminum hydroxides, like bayerite, are precipitated using CO2. In this paper, experimental work on precipitation of aluminum hydroxides through the addition of a mixture of CO2, O2 and N2 is presented. The parameters varied, as were the percentages of each gas and the temperature. The indicators measured were the time until the beginning of precipitation and the time that the precipitation lasts. These tests simulate the use of a smelter furnace off-gas in the precipitation stage of the Pedersen process and have shown promising results.
Pedersen法是一种氧化铝生产工艺,它结合了火法冶金和湿法冶金方法。在火法冶炼阶段,石灰石被煅烧,产生二氧化碳。这种废气可以用高浓度的二氧化碳捕获。在湿法冶金过程的最后,氢氧化铝,如拜耳石,使用二氧化碳沉淀。本文介绍了通过添加CO2、O2和N2的混合物来沉淀氢氧化铝的实验工作。参数变化,每种气体的百分比和温度也不同。测量指标为降水开始前的时间和降水持续的时间。这些试验模拟了在Pedersen法的沉淀阶段使用冶炼厂炉废气,并显示了有希望的结果。
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引用次数: 0
Comparison of Static and Dynamic Young’s Modulus of Prasinites Prasinites静态与动态杨氏模量的比较
Pub Date : 2021-12-02 DOI: 10.3390/materproc2021005054
Dimitrios Kotsanis, P. Nomikos, D. Rozos
This study aimed to investigate the statistical correlation between the static and dynamic Young’s modulus of prasinites, a metabasic rock type that outcrops at various localities in the southern part of the Attica peninsula. A total of 39 cylindrical specimens was prepared and an extensive experimental program was carried out to determine the static and dynamic deformational properties for each specimen. Using ordinary least squares regression techniques, a new empirical linear equation was established between the aforementioned properties that can be used in the study region, or elsewhere where metabasic rocks with similar characteristics are investigated.
该研究旨在研究在阿提卡半岛南部不同地方露头的变质基性岩石类型-扁质岩的静态和动态杨氏模量之间的统计相关性。总共制备了39个圆柱形试件,并进行了广泛的实验程序,以确定每个试件的静态和动态变形特性。利用普通最小二乘回归技术,在上述性质之间建立了一个新的经验线性方程,该方程可用于研究区域或其他具有相似特征的变质基性岩的研究。
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引用次数: 2
Opportunities of AI and ICME in Metals Recycling, Production and Processing AI和ICME在金属回收、生产和加工中的机遇
Pub Date : 2021-12-01 DOI: 10.3390/materproc2021005049
S. Papaefthymiou, M. Bouzouni, Vasilis Loukadakis
The rapid penetration of Artificial Intelligence (AI) and all related developments of the fourth industrial revolution is paving the way for a more sophisticated production sequence that strives for higher quality, lower emissions and lower cost production. This work reviews and discusses these developments and correlates them with state-of-the-art changes in materials engineering. We highlight penetration paradigms of modern computation tools. These technologies sound very promising in terms of maximizing the production efficiency of modern industries and, thus, minimizing the required energy input, greenhouse gas emissions and leading the way to a more ecofriendly economy.
人工智能(AI)的迅速渗透和第四次工业革命的所有相关发展正在为追求更高质量、更低排放和更低成本生产的更复杂的生产顺序铺平道路。这项工作回顾和讨论了这些发展,并将它们与材料工程中最先进的变化联系起来。我们强调现代计算工具的渗透范式。这些技术听起来非常有前途,可以最大限度地提高现代工业的生产效率,从而最大限度地减少所需的能源投入和温室气体排放,并引领更环保的经济发展。
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引用次数: 0
Hydrometallurgical Treatment for the Extraction and Separation of Indium and Gallium from End-of-Life CIGS Photovoltaic Panels 从报废CIGS光伏板中提取和分离铟镓的湿法冶金处理
Pub Date : 2021-12-01 DOI: 10.3390/materproc2021005051
M. Theocharis, P. Tsakiridis, P. Kousi, A. Hatzikioseyian, I. Zarkadas, E. Remoundaki, G. Lyberatos
This study presents experimental results for the development of a process for the recovery of indium and gallium from EoL CIGS (CuGa1−xInxSe2) panels. The process consists of a thermal treatment of the panels, followed by a hydrometallurgical treatment, where quantitative leaching of In, Ga, Mo, Cu and Zn is achieved. The elements are subsequently separated and recovered from the leachate by solvent extraction. For the development of the process, samples of EoL CIGS PV panels were used, which contained a thin film of Mo (metal base electrode), sputtered on the supporting soda-lime glass and covered by the thin film containing In, Ga, Cu and Se (1 μm). These films were detected by SEM-EDS in polished sections. The thermal treatment at 550 °C for 15 min, in excess of air, led to the successful disintegration of ethyl vinyl acetate (EVA) and delamination of the thin film-coated glass from the front protective glass. The glass fragments coated by the thin film contained the following: Se: 0.03–0.05%; In: 0.02%; Cu: 0.05%; Ga: 0.004–0.006%; and Mo: 0.04%. Following thermal treatment, thin film-coated glass fragments of about 1.5 cm × 1.5 cm were used in acid leaching experiments using HNO3, HCl and H2SO4. Quantitative leaching of Cu, Ga, In, Mo, Zn and Cu was achieved by HNO3 at ambient temperature. The effects of pulp density and acid concentration on the efficiency of metal leaching were investigated. Part of Se volatilized during the thermal treatment, whereas the rest was insoluble and separated from the solution by filtration. Finally, the separation of the elements was achieved via solvent extraction by D2EHPA.
本研究为开发从EoL CIGS (CuGa1−xInxSe2)面板中回收铟和镓的工艺提供了实验结果。该工艺包括对面板进行热处理,然后进行湿法冶金处理,其中实现了In, Ga, Mo, Cu和Zn的定量浸出。这些元素随后通过溶剂萃取从渗滤液中分离和回收。为了开发该工艺,使用EoL CIGS光伏板样品,将含有Mo(金属基电极)薄膜的样品溅射在支撑的钠石灰玻璃上,并覆盖含有In, Ga, Cu和Se (1 μm)的薄膜。在抛光切片上用SEM-EDS检测这些膜。在550°C下进行15分钟的热处理,在过量的空气中,导致乙酸乙酯(EVA)的成功分解和薄膜涂层玻璃从前面的保护玻璃上分层。薄膜镀膜后的玻璃碎片含有:Se: 0.03-0.05%;: 0.02%;铜:0.05%;Ga: 0.004 - -0.006%;莫:0.04%。热处理后,用约1.5 cm × 1.5 cm的薄膜镀膜玻璃碎片进行HNO3、HCl和H2SO4酸浸实验。采用常温HNO3对Cu、Ga、In、Mo、Zn、Cu进行了定量浸出。研究了矿浆浓度和酸浓度对金属浸出效率的影响。部分Se在热处理过程中挥发,其余不溶,通过过滤从溶液中分离出来。最后采用D2EHPA溶剂萃取分离元素。
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引用次数: 4
H2-Based Processes for Fe and Al Recovery from Bauxite Residue (Red Mud): Comparing the Options 从铝土矿渣(赤泥)中回收铁和铝的h2基工艺:方案比较
Pub Date : 2021-12-01 DOI: 10.3390/materproc2021005045
S. Kapelari, P. Gamaletsos, T. Van der Donck, Y. Pontikes, B. Blanpain
To tackle the challenge of bauxite residue (BR), generated during the alumina production, as well as to recover some of its metal content, three combinatory H2-based processes were utilized. Firstly, Greek BR was mixed with NaOH to produce water soluble Na-aluminates and was roasted under pure H2 gas in order to reduce the Fe+3 content. Then the first process combined water leaching and magnetic separation, the second water leaching and melting and the last included wet magnetic separation. The water media resulted in the dissolution of Na-aluminate phases and the production of Al, Na-ion rich leachates. From these, pregnant leaching solutions recovery of Al was 78%, 84% and for the third case it reached 91%. Concerning Na recovery, it could reach 94%. Both melting process and magnetic separation aimed for Fe recovery from the material. The former case however still needs to be optimized, here its concept is introduced. The magnetic fraction, after the dry magnetic separation, varied in Fe content from 31.57 wt.% to 38.50 wt.%, while after the wet magnetic separation it reached 31.85 wt.%.
为了解决氧化铝生产过程中产生的铝土矿渣(BR)的挑战,并回收其部分金属含量,采用了三种组合h2基工艺。首先,将希腊BR与NaOH混合生成水溶性na -铝酸盐,并在纯H2气体下焙烧以降低Fe+3含量。第一道工序为水浸-磁选,第二道工序为水浸-熔融,最后一道工序为湿式磁选。水介质导致na -铝酸盐相的溶解,生成富Al、na离子的渗滤液。从这些浸出液中,铝的回收率为78%,84%,第三种浸出液的回收率达到91%。钠回收率可达94%。熔炼工艺和磁选工艺都旨在从材料中回收铁。但前一种情况仍需优化,这里介绍其概念。干式磁选后的磁选组分铁含量为31.57 ~ 38.50 wt.%,湿式磁选后的磁选组分铁含量为31.85 wt.%。
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引用次数: 5
Possibility of Using Wind and Solar Sources for Electric Power Generation on Serbian Opencast Coal Mines 塞尔维亚露天煤矿利用风能和太阳能发电的可能性
Pub Date : 2021-12-01 DOI: 10.3390/materproc2021005050
Natalija Pavlovic, D. Ignjatović, T. Šubaranović
The rapid technology advancement and the significant decline of investment costs in wind and solar energy generation have opened up a significant opportunity to build these facilities on closed opencast mines or mines in the phase of closure around the world, where large available areas are almost ideal for such projects. In that sense, it is necessary to give an analysis of the possible application of wind and/or solar energy production in the Republic of Serbia’s mines, as well as the dynamics of such a generally ambitious and long-term project with conceptual solutions.
技术的迅速进步和风能和太阳能发电投资成本的显著下降,为在世界各地已关闭的露天矿山或处于关闭阶段的矿山上建造这些设施提供了一个重要的机会,在这些地方,可利用的大片地区几乎是这种项目的理想选择。在这个意义上,有必要分析在塞尔维亚共和国的矿山中可能应用风能和(或)太阳能生产的情况,以及这种具有概念性解决办法的总体上雄心勃勃的长期项目的动力。
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引用次数: 2
GUNITECH®: An Innovative Pumice Based Dry Shotcrete Application GUNITECH®:一种创新的浮石干喷混凝土应用
Pub Date : 2021-12-01 DOI: 10.3390/materproc2021005046
M. Nomikou, V. Kaloidas, Christos Triantafyllos Galmpenis, Nicolaos Anagnostopoulos, Georgios Tzouvalas
Pumice quarried by LAVA MINING AND QUARRYING SA from Yali Island, Dodecanese, is used in domestic and foreign markets mainly as concrete lightweight aggregate, masonry unit constituents, road substrate, and loose soil stabilization. It is a porous natural volcanic rock with low density, low thermal and noise transmission, and the highest strength among all the natural or artificial lightweight materials of mineral origin. Nowadays, pumice is of additional interest as it has a reduced CO2 footprint because thermal energy is not needed for its expansion compared with the artificial lightweight aggregates. In this context, HERACLES GROUP in collaboration with Sika Hellas has launched a new product containing pumice stone under the brand name GUNITECH®. GUNITECH® is an innovative bagged material for spraying concrete applications. It is a ready lightweight concrete, for building repairs certified as EN 1504-3.
由LAVA MINING AND QUARRYING SA采石公司从十二岛亚里岛开采的浮石,在国内外市场上主要用作混凝土轻骨料、砌体单元成分、道路基材、松散土稳定等。它是一种多孔的天然火山岩,密度低,热传导和噪声传导低,是所有天然或人工轻质矿物材料中强度最高的。如今,浮石引起了人们的额外兴趣,因为与人造轻质骨料相比,浮石的膨胀不需要热能,因此它的二氧化碳足迹减少。在此背景下,HERACLES集团与西卡海拉斯(Sika Hellas)合作推出了一种新的含浮石的产品,品牌名为GUNITECH®。GUNITECH®是一种用于喷射混凝土应用的创新袋装材料。它是一种现成的轻质混凝土,用于通过EN 1504-3认证的建筑维修。
{"title":"GUNITECH®: An Innovative Pumice Based Dry Shotcrete Application","authors":"M. Nomikou, V. Kaloidas, Christos Triantafyllos Galmpenis, Nicolaos Anagnostopoulos, Georgios Tzouvalas","doi":"10.3390/materproc2021005046","DOIUrl":"https://doi.org/10.3390/materproc2021005046","url":null,"abstract":"Pumice quarried by LAVA MINING AND QUARRYING SA from Yali Island, Dodecanese, is used in domestic and foreign markets mainly as concrete lightweight aggregate, masonry unit constituents, road substrate, and loose soil stabilization. It is a porous natural volcanic rock with low density, low thermal and noise transmission, and the highest strength among all the natural or artificial lightweight materials of mineral origin. Nowadays, pumice is of additional interest as it has a reduced CO2 footprint because thermal energy is not needed for its expansion compared with the artificial lightweight aggregates. In this context, HERACLES GROUP in collaboration with Sika Hellas has launched a new product containing pumice stone under the brand name GUNITECH®. GUNITECH® is an innovative bagged material for spraying concrete applications. It is a ready lightweight concrete, for building repairs certified as EN 1504-3.","PeriodicalId":18729,"journal":{"name":"Materials Proceedings","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89538253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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