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Application of nanomaterials in early diagnosis of cancer 纳米材料在癌症早期诊断中的应用
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0116
Yuyan Guo, Shuangyu Shao, Ruinan Gu, Xiubo Hu, Man Zhao, Yanbo Peng, Wenyuan Zhang, Beining Zhang, Jiaxin Ding, Na Wang, Haisheng Peng, Jinxia Han
Abstract Early diagnosis of cancer is beneficial to improve the outcomes of clinical treatment and reduce cancer mortality. Nanomaterials (NMs) have exhibited significant advantages in early diagnosis of cancer. Due to the integrated structure and features of NMs, they can easily penetrate the tissue for the in vivo diagnosis and identify cancer cells after specific conjugation with unique markers expressed on or within the cancer cells based on the biological imaging such as Raman imaging, fluorescence imaging, and near-infrared imaging, whereas the NMs for the in vitro diagnosis can detect signals based on the electrochemical reactions, immune reactions, and colorimetric reactions, analyzing cancer markers such as small molecules, proteins (or enzymes), genetic materials or cells in the blood, urine, and saliva. NMs with novel physical properties facilitate the detection and imaging of low concentrations and enable the sensitive capture of small cancer biomarkers, achieving early cancer detection. However, a comprehensive summary of such NMs has not been reported. This article provides a detailed review of the types and diagnostic mechanisms of NMs for early cancer diagnosis, emphasizing new perspectives on the use of the in vivo and the in vitro NMs for early cancer diagnosis and proposing the development prospects of such NMs. This will provide new ideas and scientific references for the application of NMs in early cancer diagnosis. Graphical abstract
摘要癌症的早期诊断有利于提高临床治疗效果,降低癌症死亡率。纳米材料(NMs)在癌症的早期诊断中显示出显著的优势。由于NMs的综合结构和特征,它们可以容易地穿透组织进行体内诊断,并在与癌症细胞上或细胞内表达的独特标记物特异性结合后,基于拉曼成像、荧光成像和近红外成像等生物成像,识别癌症细胞,而用于体外诊断的NMs可以基于电化学反应、免疫反应和比色反应检测信号,分析癌症标记物,例如血液、尿液和唾液中的小分子、蛋白质(或酶)、遗传物质或细胞。具有新物理性质的NMs有助于低浓度的检测和成像,并能够灵敏地捕获小型癌症生物标志物,实现癌症的早期检测。然而,尚未报告对此类NMs的全面总结。本文对NMs用于癌症早期诊断的类型和诊断机制进行了详细综述,强调了体内和体外NMs用于癌症早期诊断的新观点,并提出了此类NMs的发展前景。这将为NMs在癌症早期诊断中的应用提供新的思路和科学参考。图形摘要
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引用次数: 0
Applying solution of spray polyurea elastomer in asphalt binder: Feasibility analysis and DSR study based on the MSCR and LAS tests 喷涂聚脲弹性体在沥青结合料中的应用:基于MSCR和LAS试验的可行性分析和DSR研究
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0508
Xiaolong Sun, Zhengbing Yuan, Z. Huang, Qin Xu, Yongqiang Zhu, Xinquan Xu, Jun Yuan, Zhisheng Liu, Yikang Zhang, Qian Chen, Alex Hay-Man Ng
Abstract The polyurea elastomer (PUA) powder modifier was prepared by the method of spraying–initial crushing–fine grinding, and then, the PUA-modified asphalt was produced. The typical functional structure of PUA was identified and characterized. The apparent viscosity of PUA-modified asphalt was tested at different temperatures. The impact of particle size and content of PUA on creep and recovery properties of asphalt at high temperature was investigated through the multiple stress creep recovery test. The mesothermal fatigue behavior of PUA-modified asphalt was evaluated by means of time sweep and linear amplitude sweep. Results indicated that the high elastic properties of PUA materials might depend on the spherical structure inside PUA material. The diameter of functional structure was around 20 µm and presented as 3D ball structure. The increase in PUA particle size would lead to the increase in cracks and folds in the bonding surface PUA modifier could improve by about 50% of the apparent viscosity significantly. Furthermore, PUA modifier could promote the high-temperature rutting resistance and middle-temperature fatigue property of asphalt. The improving effect on R could reach almost 28% and the 0.075 mm could be the best application size of PUA.
摘要采用喷涂-初碎-细磨的方法制备了聚脲弹性体(PUA)粉末改性剂,制备了PUA改性沥青。对PUA的典型功能结构进行了鉴定和表征。测定了PUA改性沥青在不同温度下的表观粘度。通过多次应力蠕变恢复试验,研究了PUA的粒径和含量对沥青高温蠕变和恢复性能的影响。采用时间扫描法和线性振幅扫描法对PUA改性沥青的中温疲劳行为进行了评价。结果表明,PUA材料的高弹性性能可能取决于PUA材料内部的球形结构。功能结构的直径约为20 µm,并呈现为3D球结构。PUA颗粒尺寸的增加将导致结合表面裂纹和褶皱的增加。PUA改性剂可以显著提高约50%的表观粘度。PUA改性剂能提高沥青的耐高温车辙性能和中温疲劳性能。对R的改善效果可达28% mm可能是PUA的最佳应用尺寸。
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引用次数: 1
Electroporation effect of ZnO nanoarrays under low voltage for water disinfection 低压下氧化锌纳米阵列的电穿孔效应及其在水消毒中的应用
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0555
Yingzheng Yin, Jie Ding, Yu Cao, Shaozhi Li, Qingbo Ma, Jinyang Li, Xiaoling Xu, D. Hui, Zuowan Zhou
Abstract It is quite necessary to develop a safe and efficient technique for disinfection of drinking water to avoid waterborne pathogens of infectious diseases. Herein, ZnO nanoarray electrodes with different sizes were investigated for low-voltage and high-efficiency electroporation disinfection. The results indicated that the ZnO nano-pyramid with small tip width and proper length exhibited over 99.9% disinfection efficiency against Escherichia coli under 1 V and a flow rate of 10 mL/min (contact time of 1.2 s). The suitable size of the nanoarray for electroporation disinfection was optimized by establishing the correlation between four kinds of ZnO nanoarrays and their efficiency of electroporation disinfection, which can guide the preparation of next-generation electroporation-disinfecting electrodes.
摘要开发一种安全有效的饮用水消毒技术以避免水传播的传染病病原体是非常必要的。本文研究了不同尺寸的ZnO纳米阵列电极用于低压高效电穿孔消毒。结果表明,小尖端宽度、适当长度的ZnO纳米锥在1 V和10的流速 mL/min(接触时间1.2 s) 。通过建立四种ZnO纳米阵列与其电穿孔消毒效率之间的相关性,优化了用于电穿孔消毒的纳米阵列的合适尺寸,这可以指导下一代电穿孔消毒电极的制备。
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引用次数: 0
Comparative investigations of Ag/H2O nanofluid and Ag-CuO/H2O hybrid nanofluid with Darcy-Forchheimer flow over a curved surface Ag/H2O纳米流体与Ag- cuo /H2O混合纳米流体在曲面上Darcy-Forchheimer流动的对比研究
3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0136
Wenjie Lu, Umar Farooq, Muhammad Imran, Wathek Chammam, Sayed M. El Din, Ali Akgül
Abstract Nanofluid performed well and produced good results in heat transport phenomena, attracting scientists to suspend other combinations of nanoparticles, called “hybrid nanofluid. Hybrid nanofluids are superior than nanofluids due to their thermal capabilities and emerging benefits that contribute to the boost in the rate of heat transmission. Applications for these nanoparticles, including sophisticated lubricants, are increasing in the fields of bioengineering and electricity. The main prospective of this research is to inquire about the water-based dual nature nanofluid stream numerical simulation through the irregular stretched sheet with heat transfer. In this perspective, silver with base fluid water is used as nanoparticles for nanofluid, and for making hybrid nanofluid, copper oxide and silver particles are used with water-based fluid. Modified Fourier and Fick’s model for heat flux utilized the above phenomenon and observed the heat and mass transport. Similarity variables are needed to transform the partial differential equations into associated nonlinear ordinary differential equations, which are then computationally resolved by the technique of bvp4c which is a built-in function in MATLAB mathematical software. Based on the concurrent approximations, reformations are performed to determine the impact of various quantities on flow variables. The predicted outcomes are depicted in velocity, temperature, and concentration profiles through graphical depiction. The factors indicate that the hybrid nanofluid is more powerful in the transfer of heat than a basic nanofluid because of its superior thermal characteristics. The velocity profile decays for the increasing values of Darcy-Forchheimer parameter. The thermal profile increases for the higher magnitude of Darcy-Forchheimer parameter. The velocity distribution profile increases for the higher values of curvature parameter, while the thermal profile decreases. This unique work might benefit nanotechnology and related nanocomponents. This safe size-controlled biosynthesis of Ag and CuO nanoparticles has resulted in a low-cost nanotechnology that may be used in a variety of applications. Biosynthesized Ag and CuO particles have been used successfully in a variety of applications, including biomedical, antibacterial agents, biological, food safety, and biosensing, to mention a few.
纳米流体在热传递现象中表现良好,并产生了良好的结果,这吸引了科学家们悬浮其他纳米颗粒的组合,称为“混合纳米流体”。混合纳米流体比纳米流体优越,因为它们的热性能和新出现的好处有助于提高热传递率。这些纳米颗粒的应用,包括复杂的润滑剂,在生物工程和电力领域正在增加。本研究的主要前景是探讨水基双性质纳米流体通过带传热的不规则拉伸片的流动数值模拟。从这个角度来看,银与基液水一起被用作纳米流体的纳米颗粒,而为了制造混合纳米流体,氧化铜和银颗粒与水基流体一起使用。改进的傅里叶和菲克热流模型利用了上述现象,观察了热和质量的传递。利用相似变量将偏微分方程转化为相关的非线性常微分方程,然后利用MATLAB数学软件中的内置函数bvp4c进行计算求解。在并行近似的基础上,进行了改造,以确定各种量对流量变量的影响。预测结果通过图形描述以速度、温度和浓度剖面来描述。综上所述,混合纳米流体具有比普通纳米流体更强的传热特性。速度剖面随Darcy-Forchheimer参数的增大而衰减。随着Darcy-Forchheimer参数的增大,热廓线增大。曲率参数越高,速度分布越明显,热分布越明显。这项独特的工作可能有利于纳米技术和相关的纳米组件。Ag和CuO纳米颗粒的这种安全的尺寸控制生物合成导致了一种低成本的纳米技术,可用于各种应用。生物合成Ag和CuO颗粒已成功地应用于各种应用,包括生物医学,抗菌剂,生物,食品安全和生物传感等。
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引用次数: 0
Self-template synthesis of hollow flower-like NiCo2O4 nanoparticles as an efficient bifunctional catalyst for oxygen reduction and oxygen evolution in alkaline media 自模板合成中空花状NiCo2O4纳米颗粒作为碱性介质中氧还原和析氧的高效双功能催化剂
3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0103
Lixiang Fu, Jingling Ma, Zhikang Zhang, Guangxin Wang, Yuliang Liu, Wuhui Li
Abstract A method was proposed to synthesize hollow flower-like NiCo 2 O 4 composed of porous nanosheets using a self-template approach. The unique structure is attributed to the synergistic effect of the Kirkendall effect and the Ostwald ripening mechanism. The sheet-like and porous structure endowed the material with a specific surface area of 137.1 m 2 g −1 and a pore volume of 0.418 cm 3 g −1 . The distinctive structure and high-density active sites imparted excellent catalytic performance in oxygen reduction (ORR) and oxygen evolution (OER) reactions. Electrochemical tests showed that the limit current density of ORR reached 5.58 mA cm −2 , comparable to that of the noble metal Pt/C (20 wt%). The overpotential of OER at a current density of 10 mA cm −2 was only 380 mV, significantly lower than that of the noble metal RuO 2 . These results indicate that the synthesized hollow flower-like NiCo 2 O 4 has the potential to replace noble metals in ORR and OER catalytic applications.
摘要:提出了一种利用自模板法合成多孔纳米片空心花状nico2o4的方法。这种独特的结构归因于Kirkendall效应和Ostwald成熟机制的协同作用。片状多孔结构使材料的比表面积为137.1 m 2 g−1,孔体积为0.418 cm 3 g−1。独特的结构和高密度的活性位点使其在氧还原(ORR)和析氧(OER)反应中具有优异的催化性能。电化学测试表明,ORR的极限电流密度达到5.58 mA cm−2,与贵金属Pt/C的极限电流密度相当(20% wt%)。在电流密度为10 mA cm−2时,OER的过电位仅为380 mV,明显低于贵金属若o2。这些结果表明,合成的空心花状nico2o4在ORR和OER催化应用中具有取代贵金属的潜力。
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引用次数: 0
Exploring the potential of biogenic magnesium oxide nanoparticles for cytotoxicity: In vitro and in silico studies on HCT116 and HT29 cells and DPPH radical scavenging 探索生物氧化镁纳米颗粒的细胞毒性潜力:体外和硅研究对HCT116和HT29细胞和DPPH自由基清除的影响
3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0141
Nurul Huda Abd Kadir, Nur Anniesa Farhana Mohd Roza, Azmat Ali Khan, Azhar U. Khan, Mahboob Alam
Abstract The goal of this work was to assess the cytotoxicity, chemical characteristics, thermal stability, and antioxidant activity of green-synthesized MgO nanoparticles (MgO NPs) produced from pumpkin seed extract for their potential therapeutic implications in cancer treatment. The shape, chemical properties, and thermal stability of MgO NPs made with green synthesis were looked at with Fourier-transform infrared spectroscopic analysis, scanning electron microscopy (SEM) and transmission electron microscopic (TEM) imaging, energy-dispersive X-ray spectroscopy (EDX), ultraviolet-visible, X-ray diffraction (XRD), and thermogravimetric analysis. Three cell lines, HCT-116, HT29, and Vero, were used to test the cytotoxicity of MgO NPs. The AlamarBlue® assay was used for HCT-116 and Vero cells, and the Neutral Red (NR) Uptake Assay was used for HT29 cells. A molecular docking study was done to find out how MgO nanoparticles and cyclin-dependent kinase 2 (CDK2), a protein linked to cancerous cells growing out of control, interact. The morphological properties, size, aggregation, shapeless pores, and high surface-to-area volume ratio of biosynthesized MgO NPs were shown using SEM and TEM imagings. The elemental composition of Mg and O in green-synthesized MgO NPs was validated using EDX. The AlamarBlue ® assay did not yield IC 50 values for HCT-116 and Vero cells, suggesting minimal cytotoxicity in these cell lines. However, the NR Uptake Assay showed an IC 50 of 164.1 µg/mL for HT29 cells, indicating a significant impact. The DPPH experiment revealed that MgO nanoparticles had high antioxidant activity, with a scavenging capacity of 61% and an IC 50 of 170 μg/mL. In conclusion, MgO nanoparticles produced utilizing green chemistry demonstrated a wide range of biological features, including antioxidant activity and cytotoxicity against three cell lines. According to molecular docking studies, these nanoparticles may interact with CDK2, a protein implicated in cancer cell growth. These findings emphasize MgO nanoparticles’ potential for cancer treatment. However, further study is needed to understand the underlying processes and investigate therapeutic applications.
摘要:本研究的目的是评估南瓜籽提取物绿色合成MgO纳米颗粒(MgO NPs)的细胞毒性、化学特性、热稳定性和抗氧化活性,以探讨其在癌症治疗中的潜在应用价值。采用傅里叶变换红外光谱分析、扫描电子显微镜(SEM)和透射电子显微镜(TEM)成像、能量色散x射线能谱(EDX)、紫外可见光谱、x射线衍射(XRD)和热重分析对绿色合成MgO纳米粒子的形状、化学性质和热稳定性进行了研究。采用HCT-116、HT29和Vero三种细胞系检测MgO NPs的细胞毒性。HCT-116和Vero细胞采用AlamarBlue®检测,HT29细胞采用中性红(NR)摄取检测。一项分子对接研究是为了发现氧化镁纳米颗粒和细胞周期蛋白依赖性激酶2 (CDK2)是如何相互作用的,CDK2是一种与癌细胞生长失控相关的蛋白质。通过扫描电镜(SEM)和透射电镜(TEM)观察了生物合成MgO纳米粒子的形态特征、大小、聚集、无形孔和高表面积体积比。用EDX对绿色合成的MgO NPs中Mg和O的元素组成进行了验证。AlamarBlue®检测对HCT-116和Vero细胞没有产生IC 50值,表明这些细胞系的细胞毒性很小。然而,NR摄取实验显示HT29细胞的ic50为164.1µg/mL,表明有显著影响。DPPH实验表明,MgO纳米颗粒具有较高的抗氧化活性,其清除能力为61%,ic50为170 μg/mL。总之,利用绿色化学制备的氧化镁纳米颗粒具有广泛的生物学特性,包括抗氧化活性和对三种细胞系的细胞毒性。根据分子对接研究,这些纳米颗粒可能与CDK2相互作用,CDK2是一种与癌细胞生长有关的蛋白质。这些发现强调了氧化镁纳米颗粒治疗癌症的潜力。然而,需要进一步的研究来了解潜在的过程和研究治疗应用。
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引用次数: 0
Significance of gyrotactic microorganisms on the MHD tangent hyperbolic nanofluid flow across an elastic slender surface: Numerical analysis 旋回微生物对MHD切线双曲纳米流体在弹性细长表面上流动的意义:数值分析
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0106
K. Alharbi, M. Bilal, Aatif Ali, S. M. Eldin, A. Alburaikan, H. A. Khalifa
Abstract In the current study, we numerically analyze the significance of motile microbes on the magnetohydrodynamic steady convective streams of tangent hyperbolic (TH) nanofluid flow across an elastic nonlinearly stretching surface of an irregular thickness. The consequences of an external magnetic field, thermal radiation, and thermal conductivity are also examined on the TH nanofluid. The governing system of equations (nonlinear set of partial differential equations) is transfigured into a system of ordinary differential equations (ODEs) by using the similarity variable conversions. Furthermore, the reduced form of nonlinear ODEs is numerically computed through the parametric continuation method (PCM) using MATLAB software. The relative evaluation is carried out to authenticate the numerical outcomes. It has been observed that the energy field accelerates with the Rayleigh number, Weissenberg number, and Brownian motion. The mass propagation ratio improves with the effect of activation energy and decreases with the influence of chemical reactions. Furthermore, the motile microbes’ profile declined with the outcome of the Peclet and Lewis numbers. The skin friction increases up to 7.3% with various magnetic values ranging from 0.5 to 1.5. However, the energy transfer rate declines to 5.92%. The thermal radiation boosts the energy propagation rate and flow velocity by up to 11.23 and 8.17%, respectively.
摘要在本研究中,我们用数值方法分析了移动微生物对正切双曲(TH)纳米流体流过不规则厚度的弹性非线性拉伸表面的磁流体力学稳定对流流的意义。外部磁场、热辐射和导热性的影响也在TH纳米流体上进行了研究。利用相似变量变换将控制方程组(非线性偏微分方程组)转化为常微分方程组(ode)。在此基础上,利用MATLAB软件通过参数延拓法(PCM)对非线性微分方程的化简形式进行了数值计算。对数值结果进行了相应的评价。已经观察到能量场随瑞利数、魏森伯格数和布朗运动加速。质量传播比随活化能的影响而增大,随化学反应的影响而减小。此外,随着Peclet和Lewis计数的结果,活动微生物的分布也有所下降。当磁性值在0.5 ~ 1.5之间变化时,表面摩擦力可增加7.3%。能量转移率下降到5.92%。热辐射可使能量传播速率和流速分别提高11.23%和8.17%。
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引用次数: 2
Study of mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites 环氧/石墨烯及环氧/高岭土纳米复合材料力学性能研究
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0520
L. Lapčík, Harun Sepetcioglu, Yousef Murtaja, B. Lapčíková, M. Vašina, M. Ovsik, M. Stanek, S. Gautam
Abstract This article aimed to compare various mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites. Graphene nanoplatelets (GnPs) and halloysite nanotubes (HNTs) were used as fillers at different concentrations. The studied fillers were dispersed in the epoxy resin matrices. Elastic–plastic mechanical behavior modulation was observed utilizing the fillers’ nanoparticles and carboxyl-terminated butadiene–acrylonitrile copolymer rubber-modified epoxy resin. The hypothesis of the possible preceding inter-particle gliding of the individual GnPs in the complex resin nanocomposite matrix during mechanical testings was also confirmed. Increased ductility (elongation at break increased from 0.33 mm [neat matrix] to 0.46 mm [1 wt% GnPs] [39% increase]) and plasticity of the GnP nanocomposite samples were observed. In contrast, the decreasing mechanical stiffness as reflected in the decreased Young’s modulus of elasticity (from 3.4 to 2.7 GPa [20% decrease]) was found for the epoxy/HNT nanocomposites. The obtained dynamic stiffness of the investigated nanocomposites confirmed the complexity of the mechanical response of the studied material systems as a combination of the ductile and brittle phenomena.
摘要本文旨在比较环氧/石墨烯和环氧/高岭土纳米复合材料的各种力学性能。采用不同浓度的石墨烯纳米片(GnPs)和高岭土纳米管(HNTs)作为填料。所研究的填料分散在环氧树脂基体中。利用纳米填料和端羧基丁二烯-丙烯腈共聚物橡胶改性环氧树脂对弹塑性力学行为进行了调节。在力学测试中,单个GnPs在复合树脂纳米复合材料基体中可能预先发生粒子间滑动的假设也得到了证实。结果表明,GnP纳米复合材料的延展性(断裂伸长率从0.33 mm[纯基体]提高到0.46 mm [1 wt% GnPs][提高39%])和塑性均有所提高。相比之下,环氧树脂/HNT纳米复合材料的机械刚度下降,反映在杨氏弹性模量下降(从3.4到2.7 GPa[降低20%])。所获得的纳米复合材料的动刚度证实了所研究材料系统力学响应的复杂性,即韧性和脆性现象的结合。
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引用次数: 3
Critical review on experimental and theoretical studies of elastic properties of wurtzite-structured ZnO nanowires 纤锌矿结构ZnO纳米线弹性性能的实验与理论研究述评
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0505
S. Vlassov, D. Bocharov, B. Polyakov, Mikk Vahtrus, A. Šutka, S. Oras, Veronika Zadin, A. Kyritsakis
Abstract In this critical review, we call attention to a widespread problem related to the vast disagreement in elastic moduli values reported by different authors for nanostructures made of the same material. As a particular example, we focus on ZnO nanowires (NWs), which are among the most intensively studied nanomaterials due to their remarkable physical properties and promising applications. Since ZnO NWs possess piezoelectric effects, many applications involve mechanical deformations. Therefore, there are plenty of works dedicated to the mechanical characterization of ZnO NWs using various experimental and computational techniques. Although the most of works consider exactly the same growth direction and wurtzite crystal structure, reported values of Young’s modulus vary drastically from author to author ranging from 20 to 800 GPa. Moreover, both – diameter dependent and independent – Young’s modulus values have been reported. In this work, we give a critical overview and perform a thorough analysis of the available experimental and theoretical works on the mechanical characterization of ZnO NWs in order to find out the most significant sources of errors and to bring out the most trustable results.
摘要在这篇批评性综述中,我们提请注意一个普遍存在的问题,该问题与不同作者报道的由相同材料制成的纳米结构的弹性模量值存在巨大分歧有关。作为一个特别的例子,我们关注ZnO纳米线(NWs),由于其显著的物理性质和有前景的应用,它是研究最深入的纳米材料之一。由于ZnO纳米颗粒具有压电效应,许多应用涉及机械变形。因此,有大量的工作致力于使用各种实验和计算技术对ZnO纳米颗粒进行力学表征。尽管大多数工作都考虑了完全相同的生长方向和纤锌矿晶体结构,但报告的杨氏模量值因作者而异,从20到800不等 GPa。此外,还报道了直径相关和独立的杨氏模量值。在这项工作中,我们对ZnO纳米颗粒力学特性的现有实验和理论工作进行了全面的概述和分析,以找出最重要的误差来源,并得出最可靠的结果。
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引用次数: 3
Melting rheology in thermally stratified graphene-mineral oil reservoir (third-grade nanofluid) with slip condition 热分层石墨烯矿物油藏(三级纳米流体)在滑移条件下的熔融流变
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0511
Z. Raizah, Sadique Rehman, A. Saeed, Mohammad Akbar, S. M. Eldin, A. Galal
Abstract More effective and lengthy energy storage systems have been highly desired by researchers. Waste heat recovery, renewable energy, and combined heating and power reactors all utilize energy storage technologies. There are three techniques that are more effective for storing thermal energy: Latent heat storage is one type of energy storage, along with sensible heat storage and chemical heat storage. Latent thermal energy storage is far more efficient and affordable with these methods. A method of storing heat energy in a substance is melting. The substance is frozen to release the heat energy it had been storing. A ground-based pump’s heat exchanger coils around the soil freezing, tundra melting, magma solidification, and semiconducting processes are examples of melting phenomenon. Due to the above importance, the present study scrutinizes the behavior of third-grade nanofluid in a stagnation point deformed by the Riga plate. The Riga plate, an electromagnetic actuator, is made up of alternating electrodes and a permanent magnet that is positioned on a flat surface. Graphene nanoparticles are put in the base fluid (Mineral oil) to make a homogenous mixture. Mathematical modeling is acquired in the presence of melting phenomenon, quadratic stratification, viscous dissipation, and slippage velocity. Suitable transformations are utilized to get the highly non-linear system of ODEs. The remedy of temperature and velocity is acquired via the homotopic approach. Graphical sketches of various pertinent parameters are obtained through Mathematica software. The range of various pertinent parameters is 1 ≤ B 1 ≤ 4 , B 2 = 1 , 3 , 5 , 7 , B 3 = 0.1 , 0.5 , 0.9 , 1.3 , 0.8 ≤ A ≤ 1.2 , Re = 1 , 3 , 5 , 7 , S 1 = 1 , 3 , 5 , 7 , M 1 = 1 , 6 , 11 , 16 , 0.1 ≤ ϑ ≤ 0.4 , 0.1 ≤ Q ≤ 0.4 , Ec = 1 , 3 , 5 , 7 , 0.1 ≤ S ≤ 0.4 and Nr = 1 , 6 , 11 , 16 1le {B}_{1}le 4,hspace{.5em}{B}_{2}=1,3,5,7,{B}_{3}=0.1,0.5,0.9,1.3,hspace{.5em}0.8le Ale 1.2,mathrm{Re}=1,3,5,7,hspace{.2em}{S}_{1}=1,3,5,7,hspace{.5em}{M}_{1}=1,6,11,16,hspace{.25em}0.1le {vartheta }le 0.4,hspace{.33em}0.1le Qle 0.4,text{Ec}=1,3,5,7,hspace{.5em}0.1le Sle 0.4hspace{.65em}text{and}hspace{.65em}text{Nr}=1,6,11,16 . Skin friction (drag forces) and Nusselt number (rate of heat transfer) are explained via graphs. The velocity is enhancing the function against melting parameter while temperature is the decelerating function as melting factor is amplified. The temperature field reduces with the accelerating estimations of stratified parameter. The energy and velocity profiles de-escalate with intensifying values of volume fraction parameter.
摘要更有效和更长的储能系统一直是研究人员的高度期望。废热回收、可再生能源以及热电联产反应堆都使用储能技术。有三种技术更有效地储存热能:潜热储存是一种储能类型,与显热储存和化学储热一样。使用这些方法,潜在热能存储的效率和价格要高得多。一种在物质中储存热能的方法是熔化。这种物质被冷冻以释放其储存的热能。地面泵的热交换器在土壤冻结、苔原融化、岩浆凝固和半导体过程周围盘旋,就是融化现象的例子。由于上述重要性,本研究仔细研究了三级纳米流体在里加板变形驻点中的行为。里加板是一种电磁致动器,由交替电极和位于平面上的永磁体组成。石墨烯纳米颗粒被放入基础流体(矿物油)中以形成均匀的混合物。在存在熔融现象、二次分层、粘性耗散和滑移速度的情况下,获得了数学模型。利用适当的变换得到了高度非线性的常微分方程系统。温度和速度的补救是通过同位论方法获得的。通过Mathematica软件可以获得各种相关参数的图形草图。各种相关参数的范围为1≤B1≤4,B2=1,3,5,7,B3=0.1,0.5,0.9,1.3,0.8≤A≤1.2,Re=1,3,5,7,S1=1,3,5,7,M1=1,6,11,16,0.1≤Ş≤0.4,0.1≤Q≤0.4,Ec=1,3,5,7,0.1≤S≤0.4,Nr=1,6,11,16 1le{B}_{1} 第4页,第{.5em}页{B}_{2} =1,3,5,7,{B}_{3} =0.1,0.5,0.9,1.3,space{.5em}0.8le Ale 1.2,mathrm{Re}=1,3,5,7, hspace{.2em}{S}_{1} =1,3,5,7,空间{.5em}{M}_{1} =1,6,11,16,space{.25em}0.1le{vartheta}le 0.4,space{.33em}0.1le Qle 0.4,text{Ec}=1,3,5,7,space{.5em}0.1le Sle 0.4hspace{.65em}text{and}space{.665em}text{Nr}=1,6,11,16。通过图表解释了表面摩擦力(阻力)和努塞尔数(传热率)。随着熔融因子的增大,速度是对熔融参数的增强函数,而温度是对熔融因子的减速函数。温度场随着分层参数的加速估计而减小。能量和速度剖面随体积分数参数值的增大而减小。
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引用次数: 1
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Nanotechnology Reviews
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