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Brownian and thermal diffusivity impact due to the Maxwell nanofluid (graphene/engine oil) flow with motile microorganisms and Joule heating 麦克斯韦纳米流体(石墨烯/发动机油)与运动微生物和焦耳加热流动的布朗和热扩散率影响
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0540
E. A. Algehyne, Sadique Rehman, Rashid Ayub, A. Saeed, S. M. Eldin, A. Galal
Abstract Nanofluids have many applications in industries as well as engineering such as biomedicine, manufacturing, and electronics. Nanofluid is used for improvement of thermal and mass transmission. Based on the aforementioned applications, in the present study, a two-dimensional Maxwell nanofluid with thermal radiation effect on the existence of motile microorganisms over a vertically stretchable surface is explored. The consequence of heat absorption, the efficiency of heat flux in a porous medium, viscous dissipations, and Joule heating impacts are considered. The Brownian and thermophoretic diffusion effects have been evaluated. In addition, the binary chemical reaction is taken into account to evaluate the magnetohydrodynamics (MHD) mixed convection flow. Graphene nanoparticles are suspended in so-called engine oil (base fluid). The proposed liquid model depends on the governing nonlinear equations of velocity, temperature, the concentration of nanoparticles, and motile gyrotactic microorganisms. In order to transform highly nonlinear partial differential equations into nonlinear ordinary differential equations, an appropriate similarity transformation is exploited. For the solution of the present study, the homotopy analysis method-technique in Mathematica-12 is used. The fluctuation of velocity, temperature, concentration, and gyrotactic microorganisms’ characteristics for numerous flow parameters is discussed in detail. Some important fallouts of the existing study are that the Maxwell liquid parameter, Eckert number, and magnetic parameter lessen the nanoliquid velocity. But the fluid temperature becomes higher for growing estimates of the Brownian motion and thermophoretic factors. The radiation and chemical reaction parameters have declining impacts on the solutal profile. The motile microorganism profile shows a decrement in bioconvection Lewis and Rayleigh numbers. The nanofluid thermal profile is improved but the nanofluid velocity declined through the augmentation of volume fraction. Also, the coefficient of skin friction and Nusselt number are obtained versus various flow parameters.
纳米流体在生物医药、制造、电子等工业和工程领域有着广泛的应用。纳米流体被用于改善热传导和传质。基于上述应用,本研究探索了具有热辐射效应的二维麦克斯韦纳米流体在垂直可拉伸表面上对活动微生物存在的影响。考虑了热吸收的后果,多孔介质中的热流效率,粘性耗散和焦耳加热影响。对布朗扩散效应和热泳扩散效应进行了评价。此外,还考虑了二元化学反应对磁流体动力学混合对流流动的影响。石墨烯纳米颗粒悬浮在所谓的发动机油(基础液)中。提出的液体模型依赖于控制非线性方程的速度,温度,纳米颗粒的浓度,和可移动的回旋式微生物。为了将高度非线性的偏微分方程转化为非线性的常微分方程,利用了适当的相似变换。本文利用Mathematica-12中的同伦分析方法——技术来求解本研究的问题。详细讨论了流速、温度、浓度的波动,以及陀螺微生物在各种流动参数下的特性。现有研究的一些重要后果是麦克斯韦液体参数、埃克特数和磁参数降低了纳米液体的速度。但由于布朗运动和热泳因子的估计不断增加,流体温度变得更高。辐射和化学反应参数对溶质剖面的影响逐渐减小。运动微生物剖面显示出生物对流路易斯数和瑞利数的递减。体积分数的增加改善了纳米流体的热分布,但降低了纳米流体的速度。得到了不同流动参数下的表面摩擦系数和努塞尔数。
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引用次数: 5
Bioconvection transport of upper convected Maxwell nanoliquid with gyrotactic microorganism, nonlinear thermal radiation, and chemical reaction 具有旋向微生物、非线性热辐射和化学反应的上对流Maxwell纳米液体的生物转化传输
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0569
Shuguang Li, M. Nasir, M. Waqas, Shaimaa A M Abdelmohsen, S. M. Eldin, S. S. Abdullaev, W. Khan
Abstract The microorganisms’ concept has appealed substantial consideration of modern researchers because of its utilization in commercial and industrial products, for illustration, biofuel (prepared from the waste), drug delivery, and fertilizers. Keeping such utilizations of microorganisms in mind, an analysis based on gyrotactic microorganisms featuring the mixed convective nonlinear radiative Maxwell nanoliquid stagnation point flow configured by permeable stretching surface is presented. Boundary layer stretching flow subjected to transpiration effects is formulated. Modeling is based on Buongiorno’s nanoliquid model. This model captures Brownian diffusion along with thermophoresis aspects. Energy expression is formulated under nonlinear version of radiative heat-flux, heat source, thermal Robin conditions, and heat sink. Mass transport analysis is presented considering solutal Robin conditions and chemical reaction. In addition, the Robin conditions for motile microorganisms are also considered. The complex mathematical expressions of Maxwell liquid are simplified utilizing the Boundary layer concept and then suitable transformations assist to obtain the mathematical problems in ordinary differential forms. The analytical approach (that is homotopy analysis methodology) is utilized for computational analysis. The outcomes obtained are presented graphically and numerically. The detailed description of emerging physical non-dimensional parameters is included. Our findings indicate that the motile density field strongly boosted with the increment in Peclet number and microorganisms Biot number; however, they are suppressed with the increase in the values of bioconvection Schmidt number and motile microorganism concentration difference parameter.
微生物的概念吸引了现代研究人员的大量考虑,因为它在商业和工业产品中的应用,例如,生物燃料(从废物中制备),药物输送和肥料。考虑到微生物的这种利用,本文提出了一种基于回旋微生物的分析,该分析具有可渗透拉伸表面配置的混合对流非线性辐射麦克斯韦纳米液体驻点流动。导出了受蒸腾作用影响的边界层拉伸流动。建模是基于Buongiorno的纳米液体模型。该模型捕捉了布朗扩散和热泳现象。在辐射热通量、热源、热罗宾条件和散热器的非线性情况下,建立了能量表达式。提出了考虑溶质罗宾条件和化学反应的质量输运分析。此外,还考虑了活动微生物的罗宾条件。利用边界层概念对麦克斯韦流体的复杂数学表达式进行了简化,然后用适当的变换辅助得到常微分形式的数学问题。分析方法(即同伦分析方法)被用于计算分析。所得结果以图形和数值形式给出。详细描述了新出现的物理无量纲参数。结果表明:随着Peclet数和微生物Biot数的增加,运动密度场显著增强;但随着生物对流施密特数和活动微生物浓度差参数的增大,它们被抑制。
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引用次数: 0
Role of localized magnetic field in vortex generation in tri-hybrid nanofluid flow: A numerical approach 局部磁场在三混合纳米流体流动中涡生成中的作用:一个数值方法
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0561
Shabbir Ahmad, H. Takana, K. Ali, Yasmeen Akhtar, Ahmed M. Hassan, A. Ragab
Abstract Tri-hybrid nanofluid (THNF) can achieve a higher heat transfer rate than conventional hybrid nanofluid by combining three different nanoparticles with synergistic effects. It can have more diverse physical and thermal properties by choosing different combinations of nanoparticles. That is why it has more potential applications in various fields such as solar thermal, biomedical, and industrial processes. On the other hand, vortices are circular motions of liquid or gas that occur when there is a velocity difference. They are important for understanding how fluids mix and transport mass. They can be found in nature, such as in tornadoes and hurricanes. The aim of the current study is to mainly investigate the complex interaction of Lorentz force with the tri-hybrid nanoparticles inside a lid-driven square cavity. It can be seen that the magnetic field has caused the evolution of new vortices (which are very important while analyzing any flow model due to their importance in interpreting fluid mixing and mass transport phenomena) in the flow field, thus adding much more significance to our work. Most of the scientific literature is enriched with investigations dealing with the problems assuming a uniform magnetic field occupying the flow field, but in this research, a vertical strip of magnetism within the flow field will be introduced. It may be the first effort to interpret the role of the applied magnetic field in the formation of the new vortices in the flow field. A single-phase model is utilized to describe THNF whereas a numerical solution to the governing differential equations has been obtained by employing an algorithm based on the central difference discretization and the alternating direction implicit method. The analysis reveals that the magnetic field intensity may result in up to 13 and 119% increase in the skin friction and Nusselt number, respectively. Similarly, a remarkable change in the Nusselt number and the skin friction is also observed by raising the Reynolds number Re. Moreover, the localization or confinement of the magnetic field does not always increase or decrease the Nusselt number. Thus, it is concluded that there will be a certain width of the magnetic corridor for which the Nusselt number would be optimal. Further, the THNF containing Al2O3, Ag, and TiO2 outperforms in terms of enhancing the average Nusselt number, compared to the simple nanofluid containing the abovementioned particles.
三混合纳米流体(THNF)通过将三种不同的纳米颗粒结合在一起,发挥协同效应,实现了比传统混合纳米流体更高的换热速率。通过选择不同的纳米颗粒组合,它可以具有更多样化的物理和热性能。这就是为什么它在太阳能热、生物医学和工业过程等各个领域具有更大的潜在应用。另一方面,涡旋是液体或气体的圆周运动,当存在速度差时就会发生。它们对于理解流体如何混合和传递质量很重要。它们可以在自然界中找到,比如龙卷风和飓风。本研究的主要目的是研究在盖驱动的方形腔内三杂化纳米粒子与洛伦兹力的复杂相互作用。可以看出,磁场引起了流场中新涡旋的演化(这在分析任何流动模型时都是非常重要的,因为它对解释流体混合和质量输运现象很重要),从而为我们的工作增加了更多的意义。大多数科学文献都丰富了对假设均匀磁场占据流场的问题的研究,但在本研究中,将引入流场内的垂直磁条。这可能是解释外加磁场在流场新涡形成中的作用的第一次努力。采用单相模型来描述THNF,并采用基于中心差分离散化和交替方向隐式方法的算法得到了控制微分方程的数值解。分析表明,磁场强度可使皮肤摩擦力和努塞尔数分别增加13%和119%。同样,通过提高雷诺数Re,也可以观察到努塞尔数和表面摩擦力的显著变化。此外,磁场的局部化或限制并不总是增加或减少努塞尔数。因此,可以得出结论,存在一定宽度的磁廊,使努塞尔数最优。此外,与含有上述颗粒的简单纳米流体相比,含有Al2O3、Ag和TiO2的THNF在提高平均努塞尔数方面表现更好。
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引用次数: 6
Chitosan-capped silver nanoparticles with potent and selective intrinsic activity against the breast cancer cells 壳聚糖包覆的银纳米粒子对乳腺癌细胞具有有效和选择性的内在活性
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0546
A. Abdellatif, A. Abdelfattah, M. Younis, Saed M. Aldalaan, Hesham M. Tawfeek
Graphical abstract Abstract Herein, we report on the development of chitosan-capped silver nanoparticles (AgNPs-CHI) with an intrinsic activity against breast cancer cells. Following chemical synthesis via a simple, one-pot reaction, the chitosan coating of AgNPs was verified using Fourier-transform infrared and ultraviolet–visible spectroscopies. The physicochemical properties and morphology were characterized using dynamic light scattering, scanning electron microscopy, and transmission electron microscopy. The shelf stability of the optimized platform was tracked for 3 months upon storage at either room temperature or 4°C. Then, the anticancer activities of AgNPs-CHI on human breast cancer cells, MCF-7, versus normal human cells, human skin fibroblasts (HSF), were evaluated via 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide cytotoxicity assay and tumor-associated biomarkers determination by enzyme-linked immunosorbent assay, in comparison with plain silver nitrate (AgNO3) solution. AgNPs were successfully coated with chitosan and demonstrated acceptable physicochemical properties, with a spherical morphology and high stability upon long-term storage. Although AgNPs-CHI and AgNO3 demonstrated comparable cytotoxicity to MCF-7 cells, AgNPs-CHI resulted in 10-fold lower toxicity to HSF cells, suggesting a higher selectivity. In addition, AgNPs-CHI lowered IL-6 and tumor necrosis factor-alpha levels in MCF-7 cells by 90 and 30%, respectively, compared to 60 and 10% in the case of plain AgNO3. The interesting therapeutic modality presented in this study is promising for potential clinical applications.
摘要本文报道了壳聚糖包覆银纳米颗粒(AgNPs-CHI)的开发,该纳米颗粒具有抗乳腺癌细胞的内在活性。通过简单的单锅化学合成,利用傅里叶变换红外光谱和紫外可见光谱对壳聚糖包覆AgNPs进行了验证。采用动态光散射、扫描电镜和透射电镜对其理化性质和形貌进行了表征。在室温或4℃条件下,对优化后的平台进行了3个月的货架稳定性跟踪。然后,通过3-(4,5-二甲基噻唑-2-基)-2,5-二苯基溴化四氮唑细胞毒性试验和酶联免疫吸附法测定肿瘤相关生物标志物,比较AgNPs-CHI对人乳腺癌细胞MCF-7和正常人皮肤成纤维细胞(HSF)的抗癌活性,并与普通硝酸银(AgNO3)溶液进行比较。壳聚糖包被AgNPs后,AgNPs具有良好的物理化学性质,具有球形结构,长期保存稳定性好。虽然AgNPs-CHI和AgNO3表现出与MCF-7细胞相当的细胞毒性,但AgNPs-CHI对HSF细胞的毒性降低了10倍,表明其具有更高的选择性。此外,AgNPs-CHI使MCF-7细胞中的IL-6和肿瘤坏死因子- α水平分别降低了90%和30%,而普通AgNO3则分别降低了60%和10%。本研究提出的有趣的治疗方式具有潜在的临床应用前景。
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引用次数: 5
Appraising the dielectric properties and the effectiveness of electromagnetic shielding of graphene reinforced silicone rubber nanocomposite 石墨烯增强硅橡胶纳米复合材料的介电性能和电磁屏蔽效果评价
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0558
Avinash Shinde, I. Siva, Y. Munde, Irulappasamy Sankar, M. Sultan, Farah Syazwani Shahar, M. Gaff, D. Hui
Abstract The aim of this research is to measure the dielectric properties and electromagnetic interference (EMI) shielding effectiveness (SE) of silicone rubber reinforced with graphene nanoplates. In a two-roll mill, different amounts of graphene are mixed together. This is followed by compression moulding at 170°C and post-curing for 4 h at 200°C. Between 1 MHz and 1 GHz, the waveguide transmission line method and a vector network analyser are used to measure the dielectric and EMI SE parameters. As the amount of graphene is increased from 0 to 7 wt%, AC conductivity goes up, reaching 1.19 × 10−3 S/cm at 7 wt%. The same composition gives the highest EMI SE of 43.22 dB at 1 GHz. The high-frequency structural simulation of different compositions shows how shielding works, and the results agree with what has been seen in experiments.
摘要本研究的目的是测量石墨烯纳米板增强硅橡胶的介电性能和电磁干扰屏蔽效果。在两辊轧机中,不同数量的石墨烯混合在一起。然后在170°C下进行压缩成型并进行4次后固化 h。介于1之间 MHz和1 GHz、波导传输线法和矢量网络分析仪用于测量电介质和EMI SE参数。随着石墨烯的数量从0增加到7 wt%,交流电导率上升,达到1.19×10−3 S/cm,7 重量%。相同成分的EMI SE最高,为43.22 1时的dB GHz。不同成分的高频结构模拟显示了屏蔽的工作原理,结果与实验结果一致。
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引用次数: 1
Progress in FEM modeling on mechanical and electromechanical properties of carbon nanotube cement-based composites 碳纳米管水泥基复合材料力学和机电性能有限元建模研究进展
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0522
Tao Xuejun, Luo Jianlin, Zhang Jigang, Zhu Min, Zhang Liqing, Gao Yibo
Abstract Carbon nanotubes (CNTs) reinforced cementitious composite (CNRC) with excellent electrical and self-sensing properties, which enables it to serve as an intrinsic sensor for structural health monitoring (SHM). However, the requirements of modern industry for accurate calculation and performance design of engineering materials are not met by traditional experimental studies alone. The finite element method (FEM) has the advantages of simplicity of operation, accuracy, and cost-effectiveness, and it has been widely used in the property verification and prediction of various composite materials. In this article, the constitutive model, FEM modeling method, and simulation process of CNRC along with existing model types, innate relations, and model parameters are reviewed, and the corresponding mechanical, electrical, and electromechanical coupling properties of CNRC under different parameters are systematically analyzed by FEM method. By combining different uncertainty parameters and model types, the advantages and disadvantages of FEM for mechanical, electromechanical coupling, and SHM applications of CNRC modeling are explored. The results are in good agreement with those in the existing CNRC experiment, which effectively proves the reliability of the FEM method in CNRC research. This work is important to develop a sound theoretical model verification and performance prediction for early applications in SHM of CNRC.
摘要碳纳米管(CNTs)增强水泥基复合材料(CNRC)具有优异的电学和自传感性能,可作为结构健康监测(SHM)的固有传感器。然而,仅靠传统的实验研究并不能满足现代工业对工程材料精确计算和性能设计的要求。有限元法具有操作简单、精度高、成本效益好的优点,已广泛应用于各种复合材料的性能验证和预测。本文综述了CNRC的本构模型、有限元建模方法和仿真过程,以及现有的模型类型、固有关系和模型参数,并用有限元方法系统地分析了不同参数下CNRC相应的机械、电气和机电耦合特性。结合不同的不确定性参数和模型类型,探讨了有限元法在CNRC建模的机械、机电耦合和SHM应用中的优缺点。结果与现有的CNRC试验结果吻合较好,有效地证明了有限元方法在CNRC研究中的可靠性。这项工作对于开发一个完善的理论模型验证和性能预测,以早期应用于CNRC的SHM具有重要意义。
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引用次数: 2
A comprehensive review and clinical guide to molecular and serological diagnostic tests and future development: In vitro diagnostic testing for COVID-19 分子和血清学诊断检测的综合综述和临床指南及未来发展:COVID-19体外诊断检测
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0513
Yonrapach Areerob, Suresh Sagadevan, W. Oh
Abstract COVID-19 is a contagious syndrome caused by SARS Coronavirus 2 (SARS-CoV-2) that requires rapid diagnostic testing to identify and manage in the affected persons, characterize epidemiology, and promptly make public health decisions and manage the virus present in the affected person and promptly make public health decisions by characterizing the epidemiology. Technical problems, especially contamination occurring during manual real-time polymerase chain reaction (RT-PCR), can result in false-positive NAAT results. In some cases, RNA detection technology and antigen testing are alternatives to RT-PCR. Sequencing is vital for tracking the SARS-CoV-2 genome’s evolution, while antibody testing is beneficial for epidemiology. SARS-CoV-2 testing can be made safer, faster, and easier without losing accuracy. Continued technological advancements, including smartphone integration, will help in the current epidemic and prepare for the next. Nanotechnology-enabled progress in the health sector has aided disease and pandemic management at an early stage. These nanotechnology-based analytical tools can be used to quickly diagnose COVID-19. The SPOT system is used to diagnose the coronavirus quickly, sensibly, accurately, and with portability. The SPOT assay consists of RT-LAMP, followed by pfAgo-based target sequence detection. In addition, SPOT system was used to detect both positive and negative SARS-CoV-2 samples. This combination of speed, precision, sensitivity, and mobility will allow for cost-effective and high-volume COVID-19 testing.
摘要新冠肺炎是由SARS冠状病毒2(SARS-CoV-2)引起的一种传染性综合征,需要快速诊断检测来识别和管理受影响的人,确定流行病学特征,并及时做出公共卫生决策,管理受影响人身上存在的病毒,并通过流行病学特征及时做出公共健康决策。技术问题,特别是在手动实时聚合酶链式反应(RT-PCR)过程中发生的污染,可能导致NAAT结果呈假阳性。在某些情况下,RNA检测技术和抗原检测是RT-PCR的替代品。测序对于追踪严重急性呼吸系统综合征冠状病毒2型基因组的进化至关重要,而抗体检测对流行病学有益。严重急性呼吸系统综合征冠状病毒2型检测可以在不损失准确性的情况下变得更安全、更快、更容易。包括智能手机集成在内的持续技术进步将有助于应对当前的疫情,并为下一次疫情做好准备。纳米技术推动了卫生部门的进步,在早期阶段帮助了疾病和流行病的管理。这些基于纳米技术的分析工具可用于快速诊断新冠肺炎。SPOT系统用于快速、灵敏、准确、便携地诊断冠状病毒。SPOT检测包括RT-LAMP,然后是基于pfAgo的靶序列检测。此外,SPOT系统用于检测阳性和阴性的严重急性呼吸系统综合征冠状病毒2型样本。这种速度、精度、灵敏度和机动性的结合将使新冠肺炎检测具有成本效益和高容量。
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引用次数: 1
Study on nanocrystalline coating prepared by electro-spraying 316L metal wire and its corrosion performance 316L金属丝电喷涂纳米晶涂层及其腐蚀性能的研究
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0531
Ye Liu, Qiuzhi Song, Pengwan Chen, Kun Huang, Yixun Yang
Abstract In this work, we study the corrosion performance of coatings prepared by electrical explosion spraying of metal wires. 316L metal wire with a diameter of 1.5 mm is used as spray material, and the coating is prepared on the 45# steel substrate by electrical explosion spraying. The oil–water corrosion experiment of the coating is carried out in a constant temperature water bath of 60°C for 168 h. The scanning electron microscopy and energy-dispersive spectroscopy results of the experimental samples have shown that some metal oxides are found inside the coating, most of which are distributed at the grain boundaries with a size range of 30–50 nm. The corrosion rate of the coating is measured by weight loss method with a corrosion rate of 0.079 mm/annum. XRD results show that the corrosion generates CaCO3, Fe3O4, and MgFe2O4. Coating corrosion is mainly caused by the formation of electrochemical corrosion between oxides and non-oxides in the coating, and pitting corrosion and intergranular corrosion in the presence of chloride ions.
摘要本文研究了金属丝电爆炸喷涂涂层的腐蚀性能。316L金属丝,直径1.5 mm作为喷涂材料,通过电爆炸喷涂在45#钢基体上制备涂层。涂层的油水腐蚀实验在60°C的恒温水浴中进行168 h.实验样品的扫描电子显微镜和能量色散光谱结果表明,在涂层内部发现了一些金属氧化物,其中大部分分布在晶粒边界,尺寸范围为30–50 nm。涂层的腐蚀速率通过失重法测量,腐蚀速率为0.079 mm/年。XRD结果表明,腐蚀产生CaCO3、Fe3O4和MgFe2O4。涂层腐蚀主要是由涂层中氧化物和非氧化物之间形成电化学腐蚀,以及在氯离子存在下的点蚀和晶间腐蚀引起的。
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引用次数: 0
Performance and mechanism of CO2 reduction by DBD-coupled mesoporous SiO2 DBD偶联介孔SiO2还原CO2的性能及机理
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2023-0577
Jiangming Wang, Yongshi Yang, Jinxin Yu, Zhongzhou Ye, Zhen Li, Zhaolian Ye, Songjian Zhao
Abstract In the process of CO2 reduction with dielectric barrier discharge (DBD)-coupled catalysis, the existing material presents unsatisfactory synergy, such as high cost, complicated preparation processes, and low conversion rates. An inexpensive and environmentally friendly mesoporous SiO2 with different morphologies by gel–sol method was synthesized and then introduced for synergistic conversion of CO2 with DBD. The physicochemical properties of the synthesized mesoporous SiO2 materials were analyzed using X-ray diffraction, thermogravimetric analysis, scanning electron microscopy and Brunauer-Emmett-Teller method, indicated the prepared mesoporous materials manifested large specific surface areas, ordered pore channels and pore size, and good stability. The CO2 reduction performance, CO selectivity, and energy efficiency of DBD alone and DBD-coupled mesoporous SiO2 were investigated at different input powers. The SiO2 prepared with 1.05 g cetyltrimethylammonium bromide addition had the highest activity, in which the conversion of CO2, CO yield and energy efficiency were increased by 56.73, 68.41, and 122.31%, respectively, compared with DBD alone. The primary CO2 conversion mechanism of the mesoporous SiO2-coupled DBD was analyzed. It is shown that the suitable pore capacity structure, the large specific surface area, and the presence of filament discharge within the pore size of suitable mesoporous material can promote the decomposition of CO2 on its surface.
摘要在介电阻挡放电(DBD)耦合催化还原CO2的过程中,现有材料存在成本高、制备工艺复杂、转化率低等不理想的协同作用。采用凝胶-溶胶法合成了一种价格低廉、环境友好的不同形貌的介孔SiO2,并将其用于CO2与DBD的协同转化。利用X射线衍射、热重分析、扫描电子显微镜和Brunauer-Emmett-Teller方法对合成的介孔SiO2材料的理化性质进行了分析,表明所制备的介孔材料具有比表面积大、孔道和孔径有序、稳定性好的特点。研究了DBD单独和DBD偶联的介孔SiO2在不同输入功率下的CO2还原性能、CO选择性和能量效率。用1.05制备的SiO2 g十六烷基三甲基溴化铵的添加具有最高的活性,其中与单独的DBD相比,CO2转化率、CO产率和能源效率分别提高了56.73%、68.41%和122.31%。分析了介孔SiO2偶联DBD的主要CO2转化机理。结果表明,合适的孔容量结构、大的比表面积以及在合适的介孔材料的孔径内存在细丝放电可以促进CO2在其表面的分解。
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引用次数: 0
Graphene nanofibers: A modern approach towards tailored gypsum composites 石墨烯纳米纤维:定制石膏复合材料的现代方法
IF 7.4 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-01-01 DOI: 10.1515/ntrev-2022-0559
Alejandro Martinez Gordon, M. I. Prieto Barrio, Alfonso Cobo Escamilla
Abstract Energy poverty is a global challenge that demands sustainable and affordable solutions. This study investigates the use of commercial graphene nanofibers (GNFs) as a reinforcing agent in gypsum composites for energy-efficient building retrofitting. The GNFs were manually dispersed in the gypsum matrix, and the composites were fabricated by casting and curing. The thermomechanical properties were systematically studied using various characterization techniques, including scanning electron microscopy, X-ray diffraction, and thermal analysis. The results show that the addition of 1% GNFs reduces the thermal conductivity of the composites by more than 40% and improves their flexural and compressive strength by up to 23 and 42%, respectively, compared to neat gypsum. The enhancements are attributed to the effective phonon scattering of the GNFs and their ability to act as crystal seeding sites, resulting in a denser and more homogeneous structure. The dynamic thermal analysis further demonstrates that the GNF-reinforced composites could reduce heating and cooling requirements by 14 and 11%, respectively, indicating their potential for energy-efficient building retrofitting. However, the cost effectiveness and safety issues of the GNF-reinforced composites should be carefully considered before their large-scale implementation. Achieving uniform dispersion of nanoparticles in high concentrations is also a significant challenge that will be addressed in future studies.
摘要能源贫困是一项全球性挑战,需要可持续和负担得起的解决方案。本研究调查了商业石墨烯纳米纤维(GNFs)在石膏复合材料中作为增强剂的应用,用于节能建筑改造。将GNFs手动分散在石膏基体中,并通过铸造和固化制备复合材料。使用各种表征技术,包括扫描电子显微镜、X射线衍射和热分析,系统地研究了热机械性能。结果表明,与纯石膏相比,1%GNFs的加入使复合材料的热导率降低了40%以上,弯曲强度和抗压强度分别提高了23%和42%。这种增强归因于GNF的有效声子散射及其作为晶体晶种位点的能力,从而产生更致密、更均匀的结构。动态热分析进一步表明,GNF增强复合材料可分别将供暖和制冷需求降低14%和11%,表明其在节能建筑改造方面的潜力。然而,在大规模实施之前,应仔细考虑GNF增强复合材料的成本效益和安全问题。实现高浓度纳米颗粒的均匀分散也是一个重大挑战,将在未来的研究中解决。
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