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Unlocking the Potential of Trans-Himalayan High-Altitude Seabuckthorn (Hippophae rhamnoides) Plants in the Green Synthesis of Silver Nanoparticles Against Drug-Resistant Foodborne Pathogens: A Step Towards Sustainable Food Safety Goals 发掘跨喜马拉雅高海拔沙棘(Hippophae rhamnoides)植物在绿色合成银纳米粒子中的潜力,对抗耐药性食源性病原体:向可持续食品安全目标迈进
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-27 DOI: 10.1142/s1793292024500243
Richa Arora, Vijay Kumar Bharti, Shubhankhi Dey

Controlling foodborne pathogens is challenging due to the new emergence of antimicrobial resistance to conventional antimicrobials. Therefore, new alternative antimicrobials need to be developed to control foodborne pathogens and avoid microbial resistance. Furthermore, the potential of trans-Himalayan high-altitude seabuckthorn (Hippophae rhamnoides ) plants has not been explored much for the synthesis of silver nanoparticles having antibacterial properties. Hence, this study investigated the development of long-term stable silver nanomaterials using the aqueous extract of seabuckthorn leaves through a green-synthesis approach and evaluated their antibacterial efficacy. These synthesized nanomaterials were characterized along with their stability using UV spectrometry for lambda max (λmax) characteristics. Further, the nanoparticles were evaluated for zeta potential (mV), polydispersity index, particle size distribution (nm), electrophoretic mobility (μmcm/Vs) and conductivity (mS/cm). The seabuckthorn silver nanoparticles are of 260nm size and stable (−15mV zeta potential) with good antioxidant and antibacterial properties against two typical food pathogens, e.g., Escherichia coli (MTCC 3222) and Salmonella typhimurium (MTCC 3224). Hence, this study developed an eco-friendly, rapid, low-cost green synthesis method for the development of seabuckthorn-coated, stable silver nanoparticles with good antibacterial activity against foodborne pathogens.

由于新出现的对传统抗菌剂的抗药性,控制食源性病原体面临挑战。因此,需要开发新的替代抗菌剂来控制食源性病原体,避免微生物产生抗药性。此外,跨喜马拉雅高海拔地区的沙棘(Hippophae rhamnoides)植物在合成具有抗菌特性的银纳米粒子方面的潜力尚未得到充分发掘。因此,本研究采用绿色合成方法,利用沙棘叶的水提取物开发了长期稳定的银纳米材料,并评估了其抗菌功效。利用紫外光谱法测定了这些合成的纳米材料的最大λ值(λmax)特征,并对其稳定性进行了表征。此外,还对纳米颗粒的 zeta 电位(mV)、多分散指数、粒度分布(nm)、电泳迁移率(μmcm/Vs)和电导率(mS/cm)进行了评估。沙棘银纳米粒子的粒径为 260 纳米,且稳定(zeta 电位为 -15mV),对两种典型的食品病原体(如大肠杆菌(MTCC 3222)和鼠伤寒沙门氏菌(MTCC 3224))具有良好的抗氧化和抗菌特性。因此,本研究开发了一种环保、快速、低成本的绿色合成方法,用于研制对食源性病原体具有良好抗菌活性的稳定银纳米粒子。
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引用次数: 0
Arc Discharge Synthesis and Multistep Purification of Multiwall Carbon Nanotubes 多壁碳纳米管的电弧放电合成与多步纯化
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-02-27 DOI: 10.1142/s1793292024500073
Madni Shifa, Zaigham Saeed Toor, Fawad Tariq

This research work describes the cost-effective synthesis and purification of multiwall carbon nanotubes (MWCNTs). Synthesis of CNTs was carried out in distilled water between two electrodes using the electric arc discharge (EAD) method. EAD is a simple and straightforward route in which an electric arc is generated between graphite electrodes through DC power source to produce soot which contains MWCNTs along with impurities. The deposited soot containing MWCNTs was then chipped off and purified. In this case, multistep purification scheme was opted to remove unwanted impurities from produced MWCNTs. Purification route comprised thermal treatment, chemical treatment and a combination of both to yield pure MWCNTs. Thermal treatments were carried out in normal air and under controlled flow of oxygen at different temperatures whereas chemical treatment was performed using acidic solution. Thermo gravimetric analysis (TGA), field emission scanning electron microscopy (FE-SEM) and X-ray diffraction (XRD) were carried out before and after purification treatments to investigate the outcome of employed treatments. Results showed that the thermal or chemical treatment alone is not sufficient to remove impurities from soot. Moreover, the introduction of an oxide group through chemical treatment reduces the oxidization temperature of graphitic particles. It was found that the chemical treatment followed by thermal annealing under the controlled flow of oxygen is the most appropriate method for successful purification of MWCNTs synthesized via EAD method.

这项研究工作介绍了具有成本效益的多壁碳纳米管(MWCNTs)的合成和提纯。采用电弧放电(EAD)法在两个电极之间的蒸馏水中合成 CNT。电弧放电法是一种简单直接的方法,通过直流电源在石墨电极之间产生电弧,从而产生含有 MWCNT 和杂质的烟尘。含有 MWCNT 的沉积烟尘随后被削去并净化。在这种情况下,选择了多步纯化方案来去除所产生的 MWCNT 中不需要的杂质。纯化路线包括热处理、化学处理和两者结合,以获得纯净的 MWCNT。热处理是在正常空气中和不同温度下的受控氧气流中进行的,而化学处理则是使用酸性溶液进行的。在纯化处理前后进行了热重分析(TGA)、场发射扫描电子显微镜(FE-SEM)和 X 射线衍射(XRD),以研究采用的处理方法的结果。结果表明,仅靠热处理或化学处理不足以去除烟尘中的杂质。此外,通过化学处理引入氧化物基团会降低石墨颗粒的氧化温度。研究发现,要成功净化通过 EAD 方法合成的 MWCNTs,最合适的方法是先进行化学处理,然后在受控氧气流下进行热退火。
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引用次数: 0
Electromagnetic Characteristics and Microwave Absorbing Properties of a Novel Stainless Steel Powder 新型不锈钢粉末的电磁特性和微波吸收性能
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-02-27 DOI: 10.1142/s1793292024500061
Jun Zhang, Xiaoying Liu, Jiangbo Huang, Hua Chen, Haochuan Wan, Pingan Yang
<p>In order to solve the problem of insufficient oxidation resistance and corrosion resistance of magnetic metal absorbent represented by carbonyl iron powder, a wave absorbing composite material which consists of different filling mass proportions of the atomized electrolytic stainless steel powder and paraffin wax is investigated. The electromagnetic (EM) characteristics and absorbing performance of the proposed composite material were tested with Agilent N5234A vector network analyzer in a frequency range of 2–18<span><math altimg="eq-00001.gif" display="inline" overflow="scroll"><mspace width=".17em"></mspace></math></span><span></span>GHz. The experimental results show that the real and imaginary parts of the dielectric permittivity of stainless steel powder/paraffin composites will increase with the filling mass fraction in the test frequency band, while the real part of the permeability <span><math altimg="eq-00002.gif" display="inline" overflow="scroll"><msup><mrow><mi>μ</mi></mrow><mrow><mi>′</mi></mrow></msup></math></span><span></span> decreases with the increase of the mass fraction, and the imaginary part <span><math altimg="eq-00003.gif" display="inline" overflow="scroll"><msup><mrow><mi>μ</mi></mrow><mrow><mi>′</mi><mi>′</mi></mrow></msup></math></span><span></span> increases with the increase of the mass fraction. At a thickness of 3<span><math altimg="eq-00004.gif" display="inline" overflow="scroll"><mspace width=".17em"></mspace></math></span><span></span>mm, with the filling mass fraction increasing from 20<span><math altimg="eq-00005.gif" display="inline" overflow="scroll"><mspace width=".17em"></mspace></math></span><span></span>wt.% to 60<span><math altimg="eq-00006.gif" display="inline" overflow="scroll"><mspace width=".17em"></mspace></math></span><span></span>wt.%, the peak frequency of reflection loss (RL) moves to low frequency from 17.92<span><math altimg="eq-00007.gif" display="inline" overflow="scroll"><mspace width=".17em"></mspace></math></span><span></span>GHz to 16<span><math altimg="eq-00008.gif" display="inline" overflow="scroll"><mspace width=".17em"></mspace></math></span><span></span>GHz. Meanwhile, the minimum reflection loss (RL<span><math altimg="eq-00009.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mstyle><mtext mathvariant="normal">min</mtext></mstyle></mrow></msub></math></span><span></span>) also shows a downward trend, and the RL<span><math altimg="eq-00010.gif" display="inline" overflow="scroll"><msub><mrow></mrow><mrow><mstyle><mtext mathvariant="normal">min</mtext></mstyle></mrow></msub></math></span><span></span> value with a filling mass fraction of 60<span><math altimg="eq-00011.gif" display="inline" overflow="scroll"><mspace width=".17em"></mspace></math></span><span></span>wt.% is −8.93<span><math altimg="eq-00012.gif" display="inline" overflow="scroll"><mspace width=".17em"></mspace></math></span><span></span>dB. It can be seen that stainless steel powder shows good micr
为了解决以羰基铁粉为代表的磁性金属吸波材料抗氧化性和耐腐蚀性不足的问题,研究了一种由不同填充质量比例的雾化电解不锈钢粉和石蜡组成的吸波复合材料。使用安捷伦 N5234A 矢量网络分析仪在 2-18GHz 频率范围内测试了所提出的复合材料的电磁(EM)特性和吸波性能。实验结果表明,在测试频段内,不锈钢粉/石蜡复合材料的介电常数的实部和虚部都会随着填充质量分数的增加而增加,而磁导率的实部μ′随着质量分数的增加而减小,虚部μ′随着质量分数的增加而增大。在厚度为 3 毫米时,随着填充质量分数从 20wt.% 增加到 60wt.%,反射损耗(RL)的峰值频率从 17.92GHz 降到 16GHz。同时,最小反射损耗(RLmin)也呈下降趋势,填充质量分数为 60wt.% 时的 RLmin 值为 -8.93dB。由此可见,不锈钢粉末具有良好的微波吸收性能,并且具有优异的抗氧化和抗腐蚀性能。基于不锈钢粉末的优异性能,有望通过多层优化设计进一步提高其吸收性能,从而满足恶劣环境下的电磁防护需求。
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引用次数: 0
Milling Processing, Morphology, and Optical Characterization of Powders from Natural Pigments as a Potential Sensitizing Material for Optical Sensors and Dye-Sensitized Solar Cells 作为光学传感器和染料敏化太阳能电池潜在感光材料的天然颜料粉末的铣削加工、形态学和光学特性分析
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-02-27 DOI: 10.1142/s1793292024500085
José Adalberto Castillo-Robles, Eddie Nahúm Armendáriz-Mireles, Carlos Adrián Calles-Arriaga, Enrique Rocha-Rangel, Wilian Jesús Pech-Rodríguez, Ivanovich Estrada Guel, Erick Santiago Mata Herrera, José Alberto Ramírez-de-León

Dye-Sensitized Solar Cells (DSSC) and optical fiber-based-sensors sensitized with organic dyes play a fundamental role in modern technology, particularly in the family of photovoltaic power generation devices and measurement of chemical variables. DSSC is low-cost, highly efficient, and easy to manufacture. Therefore, they are a suitable option for many engineering applications. This paper deals with natural pigment extraction (spirulina, carrots (beta-carotene), and beetroot) at different milling and temperature conditions. Nanoparticles were fabricated using an SPEX mill and a planetary ball mill. The particle size distribution, absorbance (UV-Vis), and powder morphology were obtained using Field Emission Scanning Electron Microscopy (FESEM). Herein, the optical characterization of modified TiO2 powder at different temperatures and milling conditions is performed. Results indicate that each natural dye is sensitive to operational temperature. In addition, the absorbance of the pigments is affected by milling conditions and particle size distribution. During SEM characterization, rounded particles were observed in the starting materials with average sizes of more than 15 microns in diameter until they were reduced to nanometer ranges close to 100 using SPEX milling. The observed absorption spectra range from 400 nm to 642 nm for spirulina. Moreover, the experimental results show that the intensity of the absorption peaks is affected by the temperature, which indicates a degradation of the dye. Therefore, different combinations of natural dyes will be feasible to improve the wide range of light absorption of the visible spectra and stability of DSSCs and optical fiber-based sensors.

染料敏化太阳能电池(DSSC)和基于光纤的有机染料敏化传感器在现代科技中发挥着重要作用,尤其是在光伏发电设备和化学变量测量领域。DSSC 成本低、效率高、易于制造。因此,它们是许多工程应用的合适选择。本文论述了在不同研磨和温度条件下提取天然色素(螺旋藻、胡萝卜(β-胡萝卜素)和甜菜根)的方法。使用 SPEX 研磨机和行星球磨机制造了纳米颗粒。使用场发射扫描电子显微镜(FESEM)获得了粒度分布、吸光度(紫外可见光)和粉末形态。本文对不同温度和研磨条件下的改性 TiO2 粉末进行了光学表征。结果表明,每种天然染料对操作温度都很敏感。此外,颜料的吸光度也受研磨条件和粒度分布的影响。在扫描电子显微镜表征过程中,观察到初始材料中存在平均直径超过 15 微米的圆形颗粒,直到使用 SPEX 研磨技术将其缩小到接近 100 纳米的范围。螺旋藻的吸收光谱范围为 400 纳米到 642 纳米。此外,实验结果表明,吸收峰的强度受温度影响,这表明染料发生了降解。因此,天然染料的不同组合将可改善可见光谱的宽范围光吸收以及 DSSC 和基于光纤的传感器的稳定性。
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引用次数: 0
Ionic Liquids Nanoliposomes Based on Targeted and Active Permeability for Enhanced Combination Chemotherapy Efficiency 基于靶向性和活性渗透性的离子液体纳米脂质体可提高联合化疗效率
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-29 DOI: 10.1142/s1793292023501151
Kai Su, Peng Chen, Hao Gao, Yuan Zhai, Youbei Qiao, Chaoli Wang, Feng Yang

Tumor microenvironment severely restricts the delivery of chemotherapy drugs. The microenvironment responsive nanoparticles often have complex designs with hampered clinical translatability. Here, we show a kind of ionic liquids (ILs) with soybean lecithin (SL) as cation, folic acid (FA) as anion, in particular, it could formulate nanoliposome by film evaporation method to deliver cis-Diamineplatinum (II) dichloride (cisplatin, Cis) and doxorubicin hydrochloride (DOX). These special ILs liposome could target tumor cells via folate receptor-mediated endocytosis by enhancing the cellular uptake, and significantly improve the deep permeability by actively infiltrating throughout the tumor tissue owing to the special noncovalent bond between SL–FA ILs with cell membrane. Moreover, ILs liposomes improve delivery efficiency of Cis and DOX and enhance the combined chemotherapeutic effect. The simple preparation process of the ILs nanoliposome should facilitate the clinical transformation of nanodrugs.

肿瘤微环境严重限制了化疗药物的输送。微环境响应型纳米粒子往往设计复杂,临床转化能力有限。在这里,我们展示了一种以大豆卵磷脂(SL)为阳离子、叶酸(FA)为阴离子的离子液体(ILs),特别是它可以通过薄膜蒸发法制成纳米脂质体,用于递送顺式二氯二氨铂(顺铂,Cis)和盐酸多柔比星(DOX)。这些特殊的ILs脂质体可通过叶酸受体介导的内吞作用靶向肿瘤细胞,提高细胞摄取率,并由于SL-FA ILs与细胞膜之间的特殊非共价键作用,可积极渗透到整个肿瘤组织,从而显著提高深层渗透性。此外,ILs 脂质体还能提高顺式和 DOX 的递送效率,增强联合化疗效果。ILs纳米脂质体的制备工艺简单,有助于纳米药物的临床转化。
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引用次数: 0
Color-tunable emission of ZnO/Ag2O/MnO2 nanocomposite phosphor for solid-state lighting applications 用于固态照明应用的 ZnO/Ag2O/MnO2 纳米复合荧光粉的颜色可调发射
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-08 DOI: 10.1142/s179329202350114x
Shafi ul Islam, Urosa Latief, Javid Ali, Mohd. Shahid Khan
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引用次数: 0
Effectiveness of Graphene Nano-Ribbon Tunnel Field Effect Transistor for Bio-Molecular Identification 石墨烯纳米带隧道场效应晶体管在生物分子识别中的功效
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-12-08 DOI: 10.1142/s1793292023501138
G. Nayana, P. Vimala
{"title":"Effectiveness of Graphene Nano-Ribbon Tunnel Field Effect Transistor for Bio-Molecular Identification","authors":"G. Nayana, P. Vimala","doi":"10.1142/s1793292023501138","DOIUrl":"https://doi.org/10.1142/s1793292023501138","url":null,"abstract":"","PeriodicalId":18978,"journal":{"name":"Nano","volume":"5 2","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139011548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Co@MoS2 nanocatalyst: enhanced activation of peroxymonosulfate for effective degradation of sulfadiazine Co@MoS2 纳米催化剂:增强过氧单硫酸盐的活化,有效降解磺胺嘧啶
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-23 DOI: 10.1142/s1793292023501102
Sai Wang, En-Ni Wu, Liang Meng, Zhenjun Wang, Tuan-Tuan Wang
{"title":"Co@MoS2 nanocatalyst: enhanced activation of peroxymonosulfate for effective degradation of sulfadiazine","authors":"Sai Wang, En-Ni Wu, Liang Meng, Zhenjun Wang, Tuan-Tuan Wang","doi":"10.1142/s1793292023501102","DOIUrl":"https://doi.org/10.1142/s1793292023501102","url":null,"abstract":"","PeriodicalId":18978,"journal":{"name":"Nano","volume":"4 7","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139244129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Studies on the biocompatibility of carbon dots prepared utilizing aquatic waste 利用水生废弃物制备碳点的生物相容性研究
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-23 DOI: 10.1142/s1793292023501126
Yi Zhang, Ge Tian, Guosheng Luo, Ping Dong, Ruifang Hua, Fanping Wang, Yun Zhang
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引用次数: 0
Photoelectrochemical sensor based on MoS2/Bi2MoO6 heterojunction for triptriolide detection 基于 MoS2/Bi2MoO6 异质结的光电化学传感器用于检测三氯苯酚
IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-11-23 DOI: 10.1142/s1793292023501114
Pengcheng Shuang, Yongming Luo
{"title":"Photoelectrochemical sensor based on MoS2/Bi2MoO6 heterojunction for triptriolide detection","authors":"Pengcheng Shuang, Yongming Luo","doi":"10.1142/s1793292023501114","DOIUrl":"https://doi.org/10.1142/s1793292023501114","url":null,"abstract":"","PeriodicalId":18978,"journal":{"name":"Nano","volume":"33 7","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139244952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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