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Wrinkled hierarchical porous carbon spheres with interconnected multi-cavity for ultrahigh capacitive deionization 用于超高电容去离子的多腔互联皱褶分层多孔碳球
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-28 DOI: 10.1038/s41545-024-00372-z
Xinyi Gong, Qingtao Ma, Luxiang Wang, Dianzeng Jia, Nannan Guo, Xin Du, Xuemei Wang
As one of the most promising electrode materials for capacitive deionization (CDI), the development of carbon materials with controllable pore structure and continuous mass production is essential for their practical application. Herein, a facile ultrasonic spray pyrolysis method was developed to synthesize surface-functionalized wrinkled hierarchical porous carbon spheres (HCS) with unique interconnected multi-cavity structures. The wrinkled and interconnected multi-cavity hierarchical pores of the HCS play a crucial role in providing accessible ion adsorption sites and promoting ion diffusion and storage in the “multi-cavity warehouse”. The carboxyl groups on the surface of HCS generate a negative charge that promotes the adsorption of cations. The optimized HCS possesses outstanding desalination capacity (114.25 mg g−1), fast adsorption rate (6.57 mg g−1 min−1), and superior cycling stability (95%). Meanwhile, the HCS exhibited impressive desalination capacities in brackish water. Furthermore, the density functional theory calculation results confirmed that the synergistic effect of carboxyl groups and defects significantly enhanced the Na+ adsorption capacity and facilitated ion diffusion. This study extends the synthesis method of surface-functionalized hierarchical porous carbon, which is expected to facilitate the development of CDI electrode materials.
作为最有前途的电容式去离子化(CDI)电极材料之一,开发孔隙结构可控且可连续量产的碳材料对其实际应用至关重要。本文开发了一种简便的超声喷射热解方法,用于合成具有独特互连多腔结构的表面功能化皱褶分层多孔碳球(HCS)。HCS 的起皱和相互连接的多腔分层孔隙在提供可访问的离子吸附位点以及促进离子在 "多腔仓库 "中的扩散和存储方面起着至关重要的作用。HCS 表面的羧基会产生负电荷,从而促进阳离子的吸附。优化后的 HCS 具有出色的脱盐能力(114.25 mg g-1)、快速的吸附速率(6.57 mg g-1 min-1)和卓越的循环稳定性(95%)。同时,该 HCS 在苦咸水中的脱盐能力也令人印象深刻。此外,密度泛函理论计算结果证实,羧基和缺陷的协同作用显著提高了 Na+ 的吸附能力,并促进了离子的扩散。该研究拓展了表面功能化分层多孔碳的合成方法,有望促进 CDI 电极材料的发展。
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引用次数: 0
A novel-approach for identifying sources of fluvial DOM using fluorescence spectroscopy and machine learning model 利用荧光光谱学和机器学习模型识别河流 DOM 来源的新方法
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-22 DOI: 10.1038/s41545-024-00370-1
Dongping Liu, Lei Nie, Beidou Xi, Hongjie Gao, Fang Yang, Huibin Yu
Rivers are well known as one of the most threatened aquatic environments, whose structure and water quality can be deeply impacted by intensive anthropogenic activities. Despite the fact that anthropogenic influences on river ecosystems could indeed be deduced from the composition and chemistry of fluvial dissolved organic matter (DOM), sources of anthropogenic loading to DOM are still poorly explored. Here, by uniting fluorescence excitation-emission matrices (EEM) and principal component absolute coefficient, four sources of DOM from seventeen rivers in major drainage basins of China could be identified, i.e., originating from municipal sewage, domestic wastewater, livestock wastewater, and natural origins, and thus being defined as MS-DOM, DW-DOM, LW-DOM, NO-DOM, respectively. Based on the random forest model, special nodes in EEM could be traced from four sources, respectively. According to parallel factor analysis, DOM mainly contained protein-like, microbial humic-like, and fulvic-like fluorescence substances, among which protein-like was dominant in MS-DOM and DW-DOM, microbial humic-like in LW-DOM, and fulvic-like in NO-DOM. Based on key peaks and essential nodes in EEM, the identifying source indices were first proposed, which could be introduced to simply distinguish the different anthropogenic-derived sources of fluvial DOM. It was associated with intensity ratios of the key peaks and the essential nodes of EEM spectra from four sources, i.e., municipal sewage (MS-SI: Ex/Em = 280/(335, 410) nm), domestic wastewater (DW-SI: Ex/Em = 280/(340, 410) nm), livestock wastewater (LW-SI: Ex/Em = 235/(345, 380) nm), and natural origins (NO-SI: Ex/Em = 260/(380, 430) nm). By statistical analysis, the high identifying source indices of municipal sewage (>0.5) and natural origins (>0.4) values could be related to MS-DOM and NO-DOM, respectively. The identifying source indices of domestic wastewater with 0.1–0.3 might be linked to DW-DOM and the identifying source indices of livestock wastewater with 0.3–0.4 to LW-DOM. Compared with conventional optical indices, the novel identifying source indices showed remarkable discrimination for the sources of fluvial DOM with different forms of anthropogenic disturbances. Hence the innovative approach could be relatively convenient and accurate to evaluate water quality or pollution risk in river ecosystems.
众所周知,河流是最受威胁的水生环境之一,其结构和水质会受到人类密集活动的严重影响。尽管可以从河流溶解有机物(DOM)的成分和化学性质推断出人类活动对河流生态系统的影响,但人类活动对 DOM 负荷来源的探索仍然很少。本文通过荧光激发-发射矩阵(EEM)和主成分绝对系数相结合的方法,确定了中国主要流域17条河流的4种DOM来源,即来源于城市污水、生活污水、畜禽养殖废水和自然界,分别定义为MS-DOM、DW-DOM、LW-DOM和NO-DOM。根据随机森林模型,EEM 中的特殊节点可分别追溯到四个来源。根据平行因子分析,DOM主要包含蛋白质类、微生物腐殖质类和富勒烯类荧光物质,其中蛋白质类荧光物质在MS-DOM和DW-DOM中占优势,微生物腐殖质类荧光物质在LW-DOM中占优势,富勒烯类荧光物质在NO-DOM中占优势。根据 EEM 中的关键峰和重要节点,首次提出了识别源指数,该指数可用于简单区分河道 DOM 的不同人为来源。该指数与四个来源的 EEM 光谱关键峰和重要节点的强度比相关联,即城市污水(MS-SI:Ex/Em = 280/(335, 410) nm)、生活废水(DW-SI:Ex/Em = 280/(340, 410) nm)、畜牧废水(LW-SI:Ex/Em = 235/(345, 380) nm)和自然来源(NO-SI:Ex/Em = 260/(380, 430) nm)。通过统计分析,城市污水(>0.5)和天然来源(>0.4)的高识别源指数值可能分别与 MS-DOM 和 NO-DOM 有关。0.1-0.3的生活污水识别源指数可能与DW-DOM有关,0.3-0.4的畜禽污水识别源指数可能与LW-DOM有关。与传统的光学指数相比,新的识别源指数对不同人为干扰形式的河道 DOM 的来源具有显著的识别能力。因此,这种创新方法可以相对方便、准确地评估河流生态系统的水质或污染风险。
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引用次数: 0
Photo responsive single layer MoS2 nanochannel membranes for photocatalytic degradation of contaminants in water 用于光催化降解水中污染物的光响应单层 MoS2 纳米通道膜
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-22 DOI: 10.1038/s41545-024-00366-x
Hafiza Hifza Nawaz, Muhammad Umar, Iqra Nawaz, Rao Muhammad Ihsan, Humaira Razzaq, Hugh Gong, Xuqing Liu
The major polluting aspects of our global fashion industries are the textile wastewater that turns black all our freshwater reservoirs. Nano-filtration through membrane technology is one of the biggest solutions of industrial wastewater treatment but the fouling of membrane is the major limitation of previous work. In this research, novel PVDF/MoS2-TNT (PMT) nanocomposite membranes were fabricated through a modified In-situ polymerisation phase inversion method. X-ray diffraction (XRD) analysis also confirmed the β-phase of PVDF within the developed PVDF/MoS2-TNT membrane. XPS analysis provides evidence about the presence of a specific chemical states of titanium nanotube and molybdenum disulphide which is involved in the photocatalytic degradation of pollutant molecules. Scanning electron microscope (SEM) shows that our membranes are porous in nature. PVDF/MoS2-TNT membranes exhibit excellent filtration efficiency (∼97%) for textile wastewater. The results and outcomes of the research demonstrate that PMT membranes have enormous potential in the commercial application of textile wastewater treatment.
纺织废水是全球时尚产业的主要污染源,它使我们所有的淡水水库变黑。通过膜技术进行纳滤是工业废水处理的最大解决方案之一,但膜结垢是以往工作的主要局限。本研究采用改良的原位聚合反相法制造了新型 PVDF/MoS2-TNT (PMT)纳米复合膜。X 射线衍射 (XRD) 分析也证实了在开发的 PVDF/MoS2-TNT 膜中存在 PVDF 的 β 相。XPS 分析提供了纳米钛管和二硫化钼特定化学态存在的证据,这些化学态参与了污染物分子的光催化降解。扫描电子显微镜(SEM)显示,我们的膜具有多孔性。PVDF/MoS2-TNT 膜对纺织废水的过滤效率极高(97%)。研究结果和成果表明,PMT 膜在纺织废水处理的商业应用中具有巨大潜力。
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引用次数: 0
Author Correction: Combined advanced oxidation dye-wastewater treatment plant: design and development with data-driven predictive performance modeling 作者更正:高级氧化染料废水联合处理厂:利用数据驱动的性能预测模型进行设计和开发
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-21 DOI: 10.1038/s41545-024-00374-x
Pankaj Singh Chauhan, Kirtiman Singh, Aditya Choudhary, Urmila Brighu, S. K. Singh, Shantanu Bhattacharya
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引用次数: 0
Disparity between global drought hazard and awareness 全球干旱危害与认识之间的差距
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-20 DOI: 10.1038/s41545-024-00373-y
Dar Murtaza Ahmad, Jonghun Kam
Drought is a pervasive natural hazard, which can profoundly affect ecosystems and societies globally. To strengthen the global community’s resilience to droughts, a multi-dimensional understanding of global drought awareness is imperative. Here we investigate global drought awareness at local (awareness of local droughts in the affected country), remote (awareness of remote droughts in other countries), and global levels (awareness from non-exposed countries). This study uses relevant search activity volumes of a country to drought as a proxy of national-level drought awareness. We find that the recent decade has experienced no change in drought hazard over the globe, but the global community has been increasingly seeking information about drought online, that is, elevated awareness of the global community on drought. We further find that long-lasting droughts enhance local- and global-level awareness and high gross domestic product are associated with remote-level awareness. This study provides an observational evidence of global disparities in the awareness/interest regarding drought, underscoring a continuing role of European nations in enhancing global drought awareness.
干旱是一种普遍存在的自然灾害,可对全球生态系统和社会产生深远影响。为了加强全球社会抵御干旱的能力,必须从多维度了解全球干旱意识。在此,我们从本地(对受影响国家本地干旱的认识)、远程(对其他国家远程干旱的认识)和全球(非受影响国家的认识)三个层面对全球干旱认识进行了调查。本研究使用一个国家对干旱的相关搜索活动量来代表国家层面的干旱意识。我们发现,近十年来全球范围内的干旱危害没有发生变化,但全球社会却越来越多地在网上寻求有关干旱的信息,即全球社会对干旱的认识有所提高。我们进一步发现,持续时间长的干旱提高了地方和全球层面的意识,而高国内生产总值则与远程层面的意识相关。这项研究为全球对干旱的认识/兴趣差异提供了观察证据,强调了欧洲国家在提高全球干旱意识方面的持续作用。
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引用次数: 0
Impact of temperature and water source on drinking water microbiome during distribution in a pilot-scale study 在一项试点研究中,温度和水源对饮用水分配过程中微生物群的影响
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-20 DOI: 10.1038/s41545-024-00371-0
Fien Waegenaar, Thomas Pluym, Laura Coene, Jozefien Schelfhout, Cristina García-Timermans, Bart De Gusseme, Nico Boon
This study utilized a pilot-scale distribution network to examine the impact of temperature increases (16 °C, 20 °C, 24 °C) and source variations (treated ground- and surface water) on bulk and biofilm communities over 137 days. Microbial characterization employed flow cytometry and 16 S rRNA gene-based amplicon sequencing to elucidate bulk-biofilm interactions. Bacterial bulk cell densities increased with higher temperatures, while water source variations significantly influenced bulk cell densities as well as the community composition. Additionally, growth curves were fitted on the flow cytometry results, and growth rates and carrying capacities were higher with treated groundwater at elevated temperatures. Conversely, biofilm cell densities remained unaffected by temperature. A mature biofilm was observed from day 70 onwards and a core biofilm microbiome, resilient to temperature and water source changes, was identified. These findings emphasize the importance of water source quality for maintaining biological stability in drinking water systems, particularly in the face of changing environmental conditions.
本研究利用一个试点规模的分配网络,在 137 天内考察了温度升高(16 °C、20 °C、24 °C)和水源变化(处理过的地下水和地表水)对散装水和生物膜群落的影响。微生物特征描述采用了流式细胞仪和基于 16 S rRNA 基因的扩增子测序技术,以阐明体膜与生物膜之间的相互作用。细菌体细胞密度随温度升高而增加,而水源的变化对体细胞密度和群落组成有显著影响。此外,根据流式细胞仪的结果拟合了生长曲线,在温度升高时,经过处理的地下水的生长率和承载能力更高。相反,生物膜细胞密度不受温度影响。从第 70 天起,就能观察到成熟的生物膜,并确定了核心生物膜微生物群,它们对温度和水源的变化具有抵抗力。这些发现强调了水源质量对保持饮用水系统生物稳定性的重要性,尤其是在环境条件不断变化的情况下。
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引用次数: 0
Advances in point-of-care and molecular techniques to detect waterborne pathogens 检测水传播病原体的护理点和分子技术的进步
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-12 DOI: 10.1038/s41545-024-00368-9
Meysam Khodaparast, Dave Sharley, Stephen Marshall, Travis Beddoe
Rapid and precise detection of waterborne pathogens is critical for effective public health management and environmental safety. Traditional methods for water quality monitoring, considered the “Gold Standard,” are time-consuming, costly, and rely on centralized laboratories and expertise. These methods are impractical for on-site, real-time monitoring, and requiring further improvements. This review explores various waterborne pathogens and cutting-edge molecular detection techniques. It highlights the growing importance of point-of-care and point-of-application methods to expedite results and improve health risk management. Loop-mediated isothermal amplification emerges as a reliable, rapid, and accessible tool in the realms of on-site diagnostics and surveillance. Moreover, the review emphasizes the crucial role of water sample preparation and in-field nucleic acid isolation in augmenting pathogen detection to enable precise assessments of water quality. The advancement of these techniques will guarantee access to safe water and improve the management of waterborne diseases.
快速、精确地检测水传播病原体对于有效的公共卫生管理和环境安全至关重要。被视为 "黄金标准 "的传统水质监测方法耗时长、成本高,而且依赖于集中实验室和专业知识。这些方法不适合现场实时监测,需要进一步改进。本综述探讨了各种水传播病原体和最先进的分子检测技术。它强调了护理点和应用点方法在加快检测结果和改善健康风险管理方面日益增长的重要性。在现场诊断和监测领域,环介导等温扩增技术是一种可靠、快速、易用的工具。此外,综述还强调了水样制备和现场核酸分离在增强病原体检测以实现水质精确评估方面的关键作用。这些技术的进步将保证人们能够获得安全的饮用水,并改善水传播疾病的管理。
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引用次数: 0
Attention improvement for data-driven analyzing fluorescence excitation-emission matrix spectra via interpretable attention mechanism 通过可解释的注意力机制提高数据驱动分析荧光激发-发射矩阵光谱的注意力
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-08 DOI: 10.1038/s41545-024-00367-w
Run-Ze Xu, Jia-Shun Cao, Jing-Yang Luo, Bing-Jie Ni, Fang Fang, Weijing Liu, Peifang Wang
Analyzing three-dimensional excitation-emission matrix (3D-EEM) spectra through machine learning models has drawn increasing attention, whereas the reliability of these machine learning models remains unclear due to their “black box” nature. In this study, the convolutional neural network (CNN) for classifying numbers of fluorescent components in 3D-EEM spectra was interpreted by gradient-weighted class activation mapping (Grad-CAM), guided Grad-CAM, and structured attention graphs (SAGs). Results showed that the original CNN classifier with high classification accuracy may make a classification based on misleading attention to the non-fluorescence area in 3D-EEM spectra. By removing Rayleigh scatterings in 3D-EEM spectra and integrating convolutional block attention module (CBAM) in CNN classifiers, the correct attention of the trained CNN classifier with CBAM greatly increased from 17.6% to 57.2%. This work formulated strategies for improving CNN classifiers associated with environmental fields and would provide great help for water determination in both natural and artificial environments.
通过机器学习模型分析三维激发-发射矩阵(3D-EEM)光谱已引起越来越多的关注,但由于其 "黑箱 "性质,这些机器学习模型的可靠性仍不明确。本研究通过梯度加权类激活图谱(Grad-CAM)、引导 Grad-CAM 和结构化注意力图谱(SAGs)对卷积神经网络(CNN)进行了解释,以对 3D-EEM 光谱中的荧光成分数量进行分类。结果表明,原始 CNN 分类器的分类准确率很高,但可能会误导对 3D-EEM 光谱中非荧光区域的关注而进行分类。通过去除三维电子显微镜光谱中的瑞利散射,并在 CNN 分类器中集成卷积块注意模块(CBAM),使用 CBAM 训练的 CNN 分类器的正确注意率从 17.6% 大幅提高到 57.2%。这项工作为改进与环境领域相关的 CNN 分类器制定了策略,将为自然和人工环境中的水判定提供巨大帮助。
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引用次数: 0
Examining geographic variation in the prevalence of household drainage types across India in 2019-2021 研究 2019-2021 年印度各地家庭排水类型流行率的地域差异
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-02 DOI: 10.1038/s41545-024-00355-0
Anoop Jain, Caleb Harrison, Akhil Kumar, Rockli Kim, S. V. Subramanian
The proportion of Indian households with access to a toilet has grown considerably over the past decade. Many of these toilets rely on on-site containment, either in the form of a septic tank or soak pit. If the waste from these containers is not removed using some type of mechanized method, it can overflow into drains before flowing into treatment facilities or being discharged into water bodies. Therefore, drains are a critical part of the sanitation chain. What remains unknown, however, is what types of drains are available to households in India. Understanding this is critical given that people are at a greater risk of ingesting contaminated water and making dermal contact with pathogens if waste flows in open drains. For the first time, India’s National Family Health Survey from 2019–2021 contains data on the type of drainage available to households. Thus, the purpose of this paper is to estimate the prevalence of households relying on no drainage, open drainage, drains to soak pits, and closed drainage. We also estimate these prevalence values for each of India’s 720 districts and by urban/rural communities to understand the geographic clustering of drainage types throughout India. Overall, we found that the most common drainage type was open drains (37.5% | 95% CI: 37.3–37.6), followed by closed drains (33.9% | 95% CI: 33.7–34.0). The household prevalence of open drainage was above 42% in more than half of India’s 720 districts. Similarly, the household prevalence of closed drainage was below 24% in more than half of India’s 720 districts. We also found that open drains were more common in rural communities, while closed drains were more common in urban communities. We also found a socioeconomic gradient in terms of drainage types, with those lower on the socioeconomic spectrum more likely to have open drains or no drainage. Our results underscore the need to both geographically and socioeconomically target interventions that ensure households have access to adequate drainage. Doing so is vital to remove contamination from the environment as a means of preventing morbidity.
在过去十年中,使用厕所的印度家庭比例大幅增加。其中许多厕所依靠化粪池或渗坑形式的现场容器。如果不使用某种机械化方法清除这些容器中的废物,废物就会溢流到排水沟中,然后流入处理设施或排入水体。因此,排水沟是环境卫生链条中的关键部分。然而,印度家庭有哪些类型的下水道仍然是个未知数。了解这一点至关重要,因为如果废物在露天排水沟中流动,人们摄入受污染的水和皮肤接触病原体的风险就更大。印度 2019-2021 年全国家庭健康调查首次包含了家庭可用排水系统类型的数据。因此,本文旨在估算不使用排水系统、露天排水系统、排水至渗坑和封闭排水系统的家庭的普遍程度。我们还估算了印度 720 个县中每个县以及城市/农村社区的这些普遍程度值,以了解印度各地排水类型的地理分布情况。总体而言,我们发现最常见的排水类型是明渠(37.5% | 95% CI:37.3-37.6),其次是暗渠(33.9% | 95% CI:33.7-34.0)。在印度的 720 个县中,一半以上的县的家庭露天排水普及率超过 42%。同样,在印度的 720 个县中,一半以上的县的封闭式排水系统家庭普及率低于 24%。我们还发现,开放式排水系统在农村社区更为常见,而封闭式排水系统在城市社区更为常见。我们还发现,在排水类型方面存在社会经济梯度,社会经济水平较低的人群更有可能使用露天排水沟或不使用排水沟。我们的研究结果表明,有必要从地理和社会经济两方面采取有针对性的干预措施,以确保家庭能够获得充足的排水系统。这样做对于消除环境污染,预防发病至关重要。
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引用次数: 0
Longitudinal study on the multifactorial public health risks associated with sewage reclamation 与污水再生利用相关的多因素公共卫生风险纵向研究
IF 10.4 1区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-08-02 DOI: 10.1038/s41545-024-00365-y
Inés Girón-Guzmán, Santiago Sánchez-Alberola, Enric Cuevas-Ferrando, Irene Falcó, Azahara Díaz-Reolid, Pablo Puchades-Colera, Sandra Ballesteros, Alba Pérez-Cataluña, José María Coll, Eugenia Núñez, María José Fabra, Amparo López-Rubio, Gloria Sánchez
This year-long research analyzed emerging risks in influent, effluent wastewaters and biosolids from six wastewater treatment plants in Spain’s Valencian Region. Specifically, it focused on human enteric and respiratory viruses, bacterial and viral faecal contamination indicators, extended-spectrum beta-lactamases-producing Escherichia coli, and antibiotic-resistance genes. Additionally, particles and microplastics in biosolid and wastewater samples were assessed. Human enteric viruses were prevalent in influent wastewater, with limited post-treatment reduction. Wastewater treatment effectively eliminated respiratory viruses, except for low levels of SARS-CoV-2 in effluent and biosolid samples, suggesting minimal public health risk. Antibiotic resistance genes and microplastics were persistently found in effluent and biosolids, thus indicating treatment inefficiencies and potential environmental dissemination. This multifaced research sheds light on diverse contaminants present after water reclamation, emphasizing the interconnectedness of human, animal, and environmental health in wastewater management. It underscores the need for a One Health approach to address the United Nations Sustainable Development Goals.
这项为期一年的研究分析了西班牙巴伦西亚大区六家污水处理厂的进水、出水废水和生物固体中新出现的风险。具体来说,研究重点是人类肠道病毒和呼吸道病毒、细菌和病毒粪便污染指标、产生广谱β-内酰胺酶的大肠杆菌以及抗生素耐药性基因。此外,还对生物固体和废水样本中的微粒和微塑料进行了评估。进水废水中普遍含有人类肠道病毒,但经过处理后,病毒数量减少有限。废水处理可有效消除呼吸道病毒,但污水和生物固体样本中的 SARS-CoV-2 病毒含量较低,这表明对公众健康的风险极低。在污水和生物固体中持续发现抗生素耐药性基因和微塑料,这表明污水处理效率低下,并可能向环境传播。这项多方面的研究揭示了水再生后存在的各种污染物,强调了废水管理中人类、动物和环境健康的相互关联性。它强调了采用 "一体健康 "方法来实现联合国可持续发展目标的必要性。
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引用次数: 0
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