Pub Date : 2024-03-07DOI: 10.1038/s41545-024-00312-x
Lewis Kamande Njaramba, Yeomin Yoon, Chang Min Park
Herein, we demonstrate the synthesis of beta-cyclodextrin (β–CD) functionalized polyvinylidene fluoride (PVDF) and iron-based metal-organic framework (Fe–MOF) mixed matrix membrane (MMM) for the enhanced removal of ciprofloxacin (CIP) from water. The membranes were prepared using the phase inversion technique with PVDF as the polymer matrix, Fe–MOF as the filler, and polyvinylpyrrolidone (PVP) as the porogen. The optimized MMM with 7% wt. Fe–MOF exhibited excellent performance with 87.6% removal efficiency. Moreover, the maximum adsorption capacity was 6.43 mg g–1. The β–CD functionalization improved the MMM hydrophilicity exhibited by the water contact angle (WCA) analysis (WCA = 55°). Furthermore, excellent adsorption performance can be attributed to the large Fe–MOF specific surface area (682.5 m2 g–1), the high porosity (77%), and the average pore diameter (395 nm) of the membrane. The inclusion of PVP (1% wt.) enhanced the porous nature of the MMM and, consequently, the adsorption performance for CIP. Notably, the hydrophilic and macroporous membrane showed good reusability with over 70% removal efficiency after five sequential adsorption–desorption cycles. The insights from this study suggest that the PMC–7 membrane can be an excellent candidate for the remediation of organic contaminants from aquatic environments.
{"title":"Fabrication of porous beta-cyclodextrin functionalized PVDF/Fe–MOF mixed matrix membrane for enhanced ciprofloxacin removal","authors":"Lewis Kamande Njaramba, Yeomin Yoon, Chang Min Park","doi":"10.1038/s41545-024-00312-x","DOIUrl":"10.1038/s41545-024-00312-x","url":null,"abstract":"Herein, we demonstrate the synthesis of beta-cyclodextrin (β–CD) functionalized polyvinylidene fluoride (PVDF) and iron-based metal-organic framework (Fe–MOF) mixed matrix membrane (MMM) for the enhanced removal of ciprofloxacin (CIP) from water. The membranes were prepared using the phase inversion technique with PVDF as the polymer matrix, Fe–MOF as the filler, and polyvinylpyrrolidone (PVP) as the porogen. The optimized MMM with 7% wt. Fe–MOF exhibited excellent performance with 87.6% removal efficiency. Moreover, the maximum adsorption capacity was 6.43 mg g–1. The β–CD functionalization improved the MMM hydrophilicity exhibited by the water contact angle (WCA) analysis (WCA = 55°). Furthermore, excellent adsorption performance can be attributed to the large Fe–MOF specific surface area (682.5 m2 g–1), the high porosity (77%), and the average pore diameter (395 nm) of the membrane. The inclusion of PVP (1% wt.) enhanced the porous nature of the MMM and, consequently, the adsorption performance for CIP. Notably, the hydrophilic and macroporous membrane showed good reusability with over 70% removal efficiency after five sequential adsorption–desorption cycles. The insights from this study suggest that the PMC–7 membrane can be an excellent candidate for the remediation of organic contaminants from aquatic environments.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00312-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140053265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-29DOI: 10.1038/s41545-024-00307-8
Alexandros Maziotis, Maria Molinos-Senante
Water treatment processes are known to consume substantial amounts of energy, making it crucial to understand their efficiency, drivers, and potential energy savings. In this study, we apply Efficiency Analysis Tree (EAT), which combines machine learning and linear programming techniques to assess the energy performance of 146 Chilean drinking water treatment plants (DWTPs) for 2020. Additionally, we utilize bootstrap regression techniques to examine the influence of operating characteristics on energy efficiency. The results indicate that the evaluated DWTPs exhibited poor energy performance, with an average energy efficiency score of 0.197. The estimated potential energy savings were found to be 0.005 kWh/m3. Several factors, such as the age of the facility, source of raw water, and treatment technology, were identified as significant drivers of energy efficiency in DWTPs. The insights gained from our study can be valuable for policymakers in making informed decisions regarding the adoption of practices that promote efficient and sustainable energy use within the water cycle.
{"title":"Understanding energy performance in drinking water treatment plants using the efficiency analysis tree approach","authors":"Alexandros Maziotis, Maria Molinos-Senante","doi":"10.1038/s41545-024-00307-8","DOIUrl":"10.1038/s41545-024-00307-8","url":null,"abstract":"Water treatment processes are known to consume substantial amounts of energy, making it crucial to understand their efficiency, drivers, and potential energy savings. In this study, we apply Efficiency Analysis Tree (EAT), which combines machine learning and linear programming techniques to assess the energy performance of 146 Chilean drinking water treatment plants (DWTPs) for 2020. Additionally, we utilize bootstrap regression techniques to examine the influence of operating characteristics on energy efficiency. The results indicate that the evaluated DWTPs exhibited poor energy performance, with an average energy efficiency score of 0.197. The estimated potential energy savings were found to be 0.005 kWh/m3. Several factors, such as the age of the facility, source of raw water, and treatment technology, were identified as significant drivers of energy efficiency in DWTPs. The insights gained from our study can be valuable for policymakers in making informed decisions regarding the adoption of practices that promote efficient and sustainable energy use within the water cycle.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-02-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00307-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139994015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Membrane biofouling poses an ongoing challenge in seawater reverse osmosis (SWRO) desalination. Here we delved into the impact of seasonal variations in microbial communities on membrane biofouling and innovatively fabricated quorum sensing inhibitors (acylase (AC) and methyl anthranilate (MA))-modified membranes to combat it. Results indicated that Proteobacteria dominated in seawater and membrane biofilm across all seasons, while other phyla varied seasonally. At the class level, the two leading bacteria on the membrane were Gamma- and Alphaproteobacteria, constituting 14–48% and 4–27%, respectively. Genera like Arcobacter, Vibrio, and Rhodobacteraceae were identified as keystone species that exhibited a significant positive correlation with extracellular polymeric substance (EPS) and biofilm formation, leading to a substantive reduction in membrane flux by 70 to 77%. The introduction of AC and MA inhibitors on the membrane suppressed keystone bacteria Rhodobacteraceae and Arcobacter and affected their metabolism, thereby significantly reducing EPS by 65–69% and 55–59%, respectively, and alleviating membrane flux decline by 30–32% and 18–22%, respectively, compared to the pristine membrane. These findings shed new light on the seasonal patterns of membrane biofouling and provide valuable insights into anti-biofouling strategies based on QS inhibition for collaborative biofilm formation.
{"title":"Cracking the code of seasonal seawater biofouling: enhanced biofouling control with quorum sensing inhibitor-functionalized membranes","authors":"Chao Chen, Yu Yang, Kwang-Ho Choo, How Yong Ng, Satoshi Takizawa, Li-an Hou","doi":"10.1038/s41545-024-00305-w","DOIUrl":"10.1038/s41545-024-00305-w","url":null,"abstract":"Membrane biofouling poses an ongoing challenge in seawater reverse osmosis (SWRO) desalination. Here we delved into the impact of seasonal variations in microbial communities on membrane biofouling and innovatively fabricated quorum sensing inhibitors (acylase (AC) and methyl anthranilate (MA))-modified membranes to combat it. Results indicated that Proteobacteria dominated in seawater and membrane biofilm across all seasons, while other phyla varied seasonally. At the class level, the two leading bacteria on the membrane were Gamma- and Alphaproteobacteria, constituting 14–48% and 4–27%, respectively. Genera like Arcobacter, Vibrio, and Rhodobacteraceae were identified as keystone species that exhibited a significant positive correlation with extracellular polymeric substance (EPS) and biofilm formation, leading to a substantive reduction in membrane flux by 70 to 77%. The introduction of AC and MA inhibitors on the membrane suppressed keystone bacteria Rhodobacteraceae and Arcobacter and affected their metabolism, thereby significantly reducing EPS by 65–69% and 55–59%, respectively, and alleviating membrane flux decline by 30–32% and 18–22%, respectively, compared to the pristine membrane. These findings shed new light on the seasonal patterns of membrane biofouling and provide valuable insights into anti-biofouling strategies based on QS inhibition for collaborative biofilm formation.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00305-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139937481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-15DOI: 10.1038/s41545-024-00301-0
Ahmed Fuwad, Hyunil Ryu, Eui Don Han, Jun-Hee Lee, Noah Malmstadt, Young-Rok Kim, Young Ho Seo, Sun Min Kim, Tae-Joon Jeon
Aquaporin (AQP) biomimetic membranes are a coming-of-age technology for water purification. Although several studies have reported aquaporin biomimetic membrane fabrication to date, these membranes show low water flux mainly due to the low porosity and inherently dense structure of the polymeric substrate materials. Herein, we report a ceramic-based aquaporin biomimetic membrane based on anodic aluminum oxide (AAO) as a substrate, which has a uniform porous structure with a high aspect ratio and pore density compared to conventional polymer substrates and exhibits a high water flux of 27.6 ± 3.6 LMH (L m−2 h−1) and superior membrane selectivity of 0.11 g L−1. Briefly, the AAO substrate was functionalized with amino-silane followed by polydopamine coating, then the AQP vesicles were immobilized on the functionalized AAO substrate surface using an electrokinetic method, and the water rejection performance of the membrane was analyzed in a forward osmosis system. Furthermore, a simple cryodesiccation method is introduced to improve the storage stability and easy transportation of aquaporin membranes, which does not require special environmental conditions to transport or store them.
{"title":"Highly permeable and shelf-stable aquaporin biomimetic membrane based on an anodic aluminum oxide substrate","authors":"Ahmed Fuwad, Hyunil Ryu, Eui Don Han, Jun-Hee Lee, Noah Malmstadt, Young-Rok Kim, Young Ho Seo, Sun Min Kim, Tae-Joon Jeon","doi":"10.1038/s41545-024-00301-0","DOIUrl":"10.1038/s41545-024-00301-0","url":null,"abstract":"Aquaporin (AQP) biomimetic membranes are a coming-of-age technology for water purification. Although several studies have reported aquaporin biomimetic membrane fabrication to date, these membranes show low water flux mainly due to the low porosity and inherently dense structure of the polymeric substrate materials. Herein, we report a ceramic-based aquaporin biomimetic membrane based on anodic aluminum oxide (AAO) as a substrate, which has a uniform porous structure with a high aspect ratio and pore density compared to conventional polymer substrates and exhibits a high water flux of 27.6 ± 3.6 LMH (L m−2 h−1) and superior membrane selectivity of 0.11 g L−1. Briefly, the AAO substrate was functionalized with amino-silane followed by polydopamine coating, then the AQP vesicles were immobilized on the functionalized AAO substrate surface using an electrokinetic method, and the water rejection performance of the membrane was analyzed in a forward osmosis system. Furthermore, a simple cryodesiccation method is introduced to improve the storage stability and easy transportation of aquaporin membranes, which does not require special environmental conditions to transport or store them.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00301-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139739301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-15DOI: 10.1038/s41545-024-00303-y
Hanaa M. Hegab, Ahmed Elmekawy, Cyril Aubry, Parashuram Kallem, Vijay S. Wadi, Fawzi Banat, Shadi W. Hasan
The aqueous system is being polluted by the untreated direct discharge of industrial oily wastewater into the ecosystem. Due to its low cost, energy economy, and sustainability, the advanced membrane filtration method is regarded as one of the best methods for treating oily wastewater. Its exceptional atomic thickness and superior amphiphilic properties of graphene oxide (GO) nanosheet make it one of the finest 2D constituents for creating membranes with high permeability. Nevertheless, the interlayer d-spacing of multi-stacked GO membranes is crucial since it is responsible for the permeability/selectivity trade-off. To efficiently separate oil-in-water emulsion using an in-situ polymerization technique, we developed an aquaporin-like 3D hierarchical multi-functionalized nanoporous graphene (NPG) membrane with tripartite nanochannels. The extraordinary, prepared membrane displayed both ultra-water-permeability of 2490 L m−2 h−1.bar along with superior selectivity. Consequently, the permeance of the aquaporin-like 3D hierarchical multi-functionalized NPG membrane achieves a higher flux than the GO membrane, while the oil rejection reaches ~97%.
未经处理的工业含油废水直接排入生态系统，污染了水系统。先进的膜过滤方法因其成本低、节能和可持续性而被视为处理含油废水的最佳方法之一。氧化石墨烯（GO）纳米片具有超强的原子厚度和卓越的两亲特性，是制造高渗透性膜的最佳二维成分之一。然而，多层 GO 膜的层间 d 距至关重要，因为它决定了渗透性/选择性的权衡。为了利用原位聚合技术高效分离水包油型乳液，我们开发了一种具有三方纳米通道的类似水汽素的三维分层多功能纳米多孔石墨烯（NPG）膜。所制备的膜非同一般，不仅具有 2490 L m-2 h-1.bar 的超强透水性，还具有卓越的选择性。因此，类似于水生蛋白的三维分层多功能 NPG 膜的渗透率比 GO 膜更高，而油排斥率则达到了约 97%。
{"title":"3D hierarchical aquaporin-like nanoporous graphene membrane with engineered tripartite nanochannels for efficient oil/water separation","authors":"Hanaa M. Hegab, Ahmed Elmekawy, Cyril Aubry, Parashuram Kallem, Vijay S. Wadi, Fawzi Banat, Shadi W. Hasan","doi":"10.1038/s41545-024-00303-y","DOIUrl":"10.1038/s41545-024-00303-y","url":null,"abstract":"The aqueous system is being polluted by the untreated direct discharge of industrial oily wastewater into the ecosystem. Due to its low cost, energy economy, and sustainability, the advanced membrane filtration method is regarded as one of the best methods for treating oily wastewater. Its exceptional atomic thickness and superior amphiphilic properties of graphene oxide (GO) nanosheet make it one of the finest 2D constituents for creating membranes with high permeability. Nevertheless, the interlayer d-spacing of multi-stacked GO membranes is crucial since it is responsible for the permeability/selectivity trade-off. To efficiently separate oil-in-water emulsion using an in-situ polymerization technique, we developed an aquaporin-like 3D hierarchical multi-functionalized nanoporous graphene (NPG) membrane with tripartite nanochannels. The extraordinary, prepared membrane displayed both ultra-water-permeability of 2490 L m−2 h−1.bar along with superior selectivity. Consequently, the permeance of the aquaporin-like 3D hierarchical multi-functionalized NPG membrane achieves a higher flux than the GO membrane, while the oil rejection reaches ~97%.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00303-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139739290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-14DOI: 10.1038/s41545-024-00304-x
Billel Salhi, Nadeem Baig, Ismail Abdulazeez
Designing a high-performance capacitive deionization setup is limited due to the slow salt removal and charge storage capacities. Efforts are being made to replace traditional electrodes with advanced 2D materials. We introduce a simple method for synthesizing two-dimensional titanium dioxide graphene-like nanosheets via a unique air-gap-assisted solvothermal method. Crystalline 2D graphene-like anatase-TiO2 sheets of unprecedented quality were obtained by tuning the air gap in the solvothermal reactor. The 2D TiO2 synthesized by air-gap-assisted solvothermal process has shown an exceptionally high surface area of 934.5 m2/g compared to the pristine TiO2 (249.5 m2/g). The sheets were used as Faradaic electrodes in ion-electrosorption and their capacitive deionization capabilities were evaluated. The electrochemical conductivity was examined via an in situ investigation of Na+-ion migration and storage. The adsorption capacity of 2D TiO2 sheets increased with higher applied potential while keeping the adsorption time constant at 15 min. At adsorption potentials of –0.8 V, –1.0 V, and –1.2 V, desalting rates of 2.09, 2.18, and 2.20 mg g−1 min−1 resulted in adsorption capacities of 31.33, 32.73, and 33.023 mg g–1, respectively. The 2D TiO2 electrode demonstrated high electron-transfer rates, a large desalination capacity, and a rapid average desalting rate. The specific capacity of the 2D-layered TiO2 electrode was found to be about 45.68 F g−1. These results can be attributed to the large specific surface area, short ionic diffusion paths, numerous active adsorption sites, surface defects, and pseudocapacitance. This air-gap-assisted solvothermal method is expected to open new avenues for the synthesis of high-quality 2D materials.
{"title":"Air-gap-assisted solvothermal process to synthesize unprecedented graphene-like two-dimensional TiO2 nanosheets for Na+ electrosorption/desalination","authors":"Billel Salhi, Nadeem Baig, Ismail Abdulazeez","doi":"10.1038/s41545-024-00304-x","DOIUrl":"10.1038/s41545-024-00304-x","url":null,"abstract":"Designing a high-performance capacitive deionization setup is limited due to the slow salt removal and charge storage capacities. Efforts are being made to replace traditional electrodes with advanced 2D materials. We introduce a simple method for synthesizing two-dimensional titanium dioxide graphene-like nanosheets via a unique air-gap-assisted solvothermal method. Crystalline 2D graphene-like anatase-TiO2 sheets of unprecedented quality were obtained by tuning the air gap in the solvothermal reactor. The 2D TiO2 synthesized by air-gap-assisted solvothermal process has shown an exceptionally high surface area of 934.5 m2/g compared to the pristine TiO2 (249.5 m2/g). The sheets were used as Faradaic electrodes in ion-electrosorption and their capacitive deionization capabilities were evaluated. The electrochemical conductivity was examined via an in situ investigation of Na+-ion migration and storage. The adsorption capacity of 2D TiO2 sheets increased with higher applied potential while keeping the adsorption time constant at 15 min. At adsorption potentials of –0.8 V, –1.0 V, and –1.2 V, desalting rates of 2.09, 2.18, and 2.20 mg g−1 min−1 resulted in adsorption capacities of 31.33, 32.73, and 33.023 mg g–1, respectively. The 2D TiO2 electrode demonstrated high electron-transfer rates, a large desalination capacity, and a rapid average desalting rate. The specific capacity of the 2D-layered TiO2 electrode was found to be about 45.68 F g−1. These results can be attributed to the large specific surface area, short ionic diffusion paths, numerous active adsorption sites, surface defects, and pseudocapacitance. This air-gap-assisted solvothermal method is expected to open new avenues for the synthesis of high-quality 2D materials.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00304-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139739307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-12DOI: 10.1038/s41545-024-00298-6
Zonghan Li, Chunyan Wang, Yi Liu, Jiangshan Wang
Estimating household water consumption can facilitate infrastructure management and municipal planning. The relatively low explanatory power of household water consumption, although it has been extensively explored based on various techniques and assumptions regarding influencing features, has the potential to be enhanced based on the water-energy nexus concept. This study attempts to explain household water consumption by establishing estimation models, incorporating energy-related features as inputs and providing strong evidence of the need to consider the water-energy nexus to explain water consumption. Traditional statistical (OLS) and machine learning techniques (random forest and XGBoost) are employed using a sample of 1320 households in Beijing, China. The results demonstrate that the inclusion of energy-related features increases the coefficient of determination (R2) by 34.0% on average. XGBoost performs the best among the three techniques. Energy-related features exhibit higher explanatory power and importance than water-related features. These findings provide a feasible modelling basis and can help better understand the household water-energy nexus.
{"title":"Enhancing the explanation of household water consumption through the water-energy nexus concept","authors":"Zonghan Li, Chunyan Wang, Yi Liu, Jiangshan Wang","doi":"10.1038/s41545-024-00298-6","DOIUrl":"10.1038/s41545-024-00298-6","url":null,"abstract":"Estimating household water consumption can facilitate infrastructure management and municipal planning. The relatively low explanatory power of household water consumption, although it has been extensively explored based on various techniques and assumptions regarding influencing features, has the potential to be enhanced based on the water-energy nexus concept. This study attempts to explain household water consumption by establishing estimation models, incorporating energy-related features as inputs and providing strong evidence of the need to consider the water-energy nexus to explain water consumption. Traditional statistical (OLS) and machine learning techniques (random forest and XGBoost) are employed using a sample of 1320 households in Beijing, China. The results demonstrate that the inclusion of energy-related features increases the coefficient of determination (R2) by 34.0% on average. XGBoost performs the best among the three techniques. Energy-related features exhibit higher explanatory power and importance than water-related features. These findings provide a feasible modelling basis and can help better understand the household water-energy nexus.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00298-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139720196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-08DOI: 10.1038/s41545-024-00302-z
Dana Kadadou, Thanigaivelan Arumugham, Lina Tizani, Shadi W. Hasan
The need for antifouling membranes is substantial due to fouling’s negative impact on the effectiveness and durability of ultrafiltration membranes. In recent times, Metal-Organic Frameworks (MOFs) have emerged as effective additives for crafting ultrafiltration (UF) membranes. However, to harness their benefits and mitigate their drawbacks, a well-considered approach is imperative. In this work, polyethersulfone (PES) UF membranes were tailored with polydopamine (PDA)-modified cerium (Ce)-MOF (PDA@Ce-MOF) to achieve satisfactory antifouling properties and to remove biological macromolecules such as bovine serum albumin (BSA) and humic acid (HA) from wastewater. The non-solvent induced phase separation (NIPS) method was used to simultaneously fabricate the membrane and modify it with different PDA@Ce-MOF concentrations ranging from 0.05 to 0.50 wt.%. Results showed significant improvements on the membrane’s morphology, hydrophilicity, porosity and pore size at 0.10 wt.% loading of PDA@Ce-MOF. The synergistic effect of the PDA and Ce-MOF on the membrane improved the pure water flux (337 L m−2 h−1) and filtration performance in the filtration of Bovine serum albumin (BSA) and humic acid (HA) reporting 145 L m−2 h−1 and 98% rejection, and 164 L m−2 h−1 and 88% rejection; respectively. Further, water-attracting functional moieties of PDA@Ce-MOF hindered the deposition of BSA protein on the membrane surface, resulting in an excellent flux recovery ratio (FRR) of ~87%, alongside mitigated irreversible fouling.
{"title":"Enhanced antifouling and separation capabilities of polydopamine@Ce-MOF functionalized PES ultrafiltration membrane","authors":"Dana Kadadou, Thanigaivelan Arumugham, Lina Tizani, Shadi W. Hasan","doi":"10.1038/s41545-024-00302-z","DOIUrl":"10.1038/s41545-024-00302-z","url":null,"abstract":"The need for antifouling membranes is substantial due to fouling’s negative impact on the effectiveness and durability of ultrafiltration membranes. In recent times, Metal-Organic Frameworks (MOFs) have emerged as effective additives for crafting ultrafiltration (UF) membranes. However, to harness their benefits and mitigate their drawbacks, a well-considered approach is imperative. In this work, polyethersulfone (PES) UF membranes were tailored with polydopamine (PDA)-modified cerium (Ce)-MOF (PDA@Ce-MOF) to achieve satisfactory antifouling properties and to remove biological macromolecules such as bovine serum albumin (BSA) and humic acid (HA) from wastewater. The non-solvent induced phase separation (NIPS) method was used to simultaneously fabricate the membrane and modify it with different PDA@Ce-MOF concentrations ranging from 0.05 to 0.50 wt.%. Results showed significant improvements on the membrane’s morphology, hydrophilicity, porosity and pore size at 0.10 wt.% loading of PDA@Ce-MOF. The synergistic effect of the PDA and Ce-MOF on the membrane improved the pure water flux (337 L m−2 h−1) and filtration performance in the filtration of Bovine serum albumin (BSA) and humic acid (HA) reporting 145 L m−2 h−1 and 98% rejection, and 164 L m−2 h−1 and 88% rejection; respectively. Further, water-attracting functional moieties of PDA@Ce-MOF hindered the deposition of BSA protein on the membrane surface, resulting in an excellent flux recovery ratio (FRR) of ~87%, alongside mitigated irreversible fouling.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00302-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139710631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
To address the problems of low efficacy and low microbial activity in low-temperature municipal wastewater treatment, this study utilized an air-lift micro-pressure internal circulation integrated reactor (AMICIR). Through controlling the amount of aeration and dissolved oxygen (DO) in the reactor, AMICIR creates alternating aerobic and anaerobic environments, explores the enrichment conditions of aerobic denitrifying bacteria, examines the changes in pollutant removal efficiency and the characteristics of bacterial colony structure during the process of enrichment of aerobic denitrifying bacteria in the system, and reveals the mechanism of nitrogen removal by aerobic denitrifying bacteria cooperating with anaerobic denitrifying bacteria in the low-temperature municipal wastewater treatment system. Experimental results showed average removal rates of NH4+-N, chemical oxygen demand (COD), total phosphorus (TP), and total nitrogen (TN) reaching 93.85%, 89.30%, 92.75%, and 75.4%, respectively. The microorganisms secreted large amounts of proteins and polysaccharides, forming zoogloea and anaerobic microenvironments conducive to traditional denitrification reactions. IlluminaMiSeq sequencing analysis revealed the presence of anaerobic phyla. The system was enriched with a large number of microorganisms, and aerobic denitrifying bacteria (Flavobacterium, Rhodoferax, and Pseudomonas) were successfully cultured. Flavobacterium emerged as the dominant species, with relative abundance ranging from 18.56% to 22.60%. Functional gene prediction indicated high abundance of aerobic denitrification genes, such as napA. Aerobic denitrifying bacteria were successfully enriched in the system to improve nitrogen removal from municipal wastewater at low temperatures.
{"title":"Synergistic denitrification mechanism of domesticated aerobic denitrifying bacteria in low-temperature municipal wastewater treatment","authors":"Fan Wang, Qin Cui, Wenai Liu, Weiqing Jiang, Shengshu Ai, Wanqi Liu, Dejun Bian","doi":"10.1038/s41545-024-00299-5","DOIUrl":"10.1038/s41545-024-00299-5","url":null,"abstract":"To address the problems of low efficacy and low microbial activity in low-temperature municipal wastewater treatment, this study utilized an air-lift micro-pressure internal circulation integrated reactor (AMICIR). Through controlling the amount of aeration and dissolved oxygen (DO) in the reactor, AMICIR creates alternating aerobic and anaerobic environments, explores the enrichment conditions of aerobic denitrifying bacteria, examines the changes in pollutant removal efficiency and the characteristics of bacterial colony structure during the process of enrichment of aerobic denitrifying bacteria in the system, and reveals the mechanism of nitrogen removal by aerobic denitrifying bacteria cooperating with anaerobic denitrifying bacteria in the low-temperature municipal wastewater treatment system. Experimental results showed average removal rates of NH4+-N, chemical oxygen demand (COD), total phosphorus (TP), and total nitrogen (TN) reaching 93.85%, 89.30%, 92.75%, and 75.4%, respectively. The microorganisms secreted large amounts of proteins and polysaccharides, forming zoogloea and anaerobic microenvironments conducive to traditional denitrification reactions. IlluminaMiSeq sequencing analysis revealed the presence of anaerobic phyla. The system was enriched with a large number of microorganisms, and aerobic denitrifying bacteria (Flavobacterium, Rhodoferax, and Pseudomonas) were successfully cultured. Flavobacterium emerged as the dominant species, with relative abundance ranging from 18.56% to 22.60%. Functional gene prediction indicated high abundance of aerobic denitrification genes, such as napA. Aerobic denitrifying bacteria were successfully enriched in the system to improve nitrogen removal from municipal wastewater at low temperatures.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00299-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139695536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-01DOI: 10.1038/s41545-024-00300-1
Shuai-Wen Huang, Hong-Lian Zhou, Rui Zeng, Ying Yao
This study aimed to investigate the relationship between the utilization of household water treatment devices (UHWTD) and both overall and cause-specific mortality, addressing the lack of comprehensive prospective research in this area. The study was a population-based prospective cohort study using data from the US National Health and Nutrition Examination Survey (NHANES 1999–2010). Among the 30,322 participants included in the study, the group without UHWTD (No UHWTD) was younger but reported worse baseline health compared to the UHWTD group. During an average follow-up period of 14.3 years, 6811 participants died. After adjusting for age, sex, and other covariates, No UHWTD was significantly associated with a higher risk of overall (adjusted hazard ratio [aHR]: 1.221, 95% Confidence Interval [CI]: 1.147–1.300), heart (aHR: 1.405, 95% CI: 1.241–1.589), cancer (aHR: 1.176, 95% CI: 1.003–1.379), Alzheimer’s disease (aHR: 1.404, 95% CI: 1.027–1.919), and nephrosis (aHR: 1.613, 95% CI: 1.026–2.537) mortality compared to UHWTD. Moreover, those main association almost remained after further adjustment for water source. Additionally, we observed a lower detection rate of bromoform, chloroform, bromodichloromethane, and dibromochloromethane in tap water when household water treatment devices was used compared to No UHWTD. The utilization of household water treatment devices in this prospective cohort was associated with modest reductions in the risk of overall, heart, cancer, Alzheimer’s disease, and nephrosis mortality. These findings suggest that the use of household water treatment devices may have the potential to influence health outcomes and extend life expectancy.
{"title":"Associations of the utilization of household water treatment devices with mortality","authors":"Shuai-Wen Huang, Hong-Lian Zhou, Rui Zeng, Ying Yao","doi":"10.1038/s41545-024-00300-1","DOIUrl":"10.1038/s41545-024-00300-1","url":null,"abstract":"This study aimed to investigate the relationship between the utilization of household water treatment devices (UHWTD) and both overall and cause-specific mortality, addressing the lack of comprehensive prospective research in this area. The study was a population-based prospective cohort study using data from the US National Health and Nutrition Examination Survey (NHANES 1999–2010). Among the 30,322 participants included in the study, the group without UHWTD (No UHWTD) was younger but reported worse baseline health compared to the UHWTD group. During an average follow-up period of 14.3 years, 6811 participants died. After adjusting for age, sex, and other covariates, No UHWTD was significantly associated with a higher risk of overall (adjusted hazard ratio [aHR]: 1.221, 95% Confidence Interval [CI]: 1.147–1.300), heart (aHR: 1.405, 95% CI: 1.241–1.589), cancer (aHR: 1.176, 95% CI: 1.003–1.379), Alzheimer’s disease (aHR: 1.404, 95% CI: 1.027–1.919), and nephrosis (aHR: 1.613, 95% CI: 1.026–2.537) mortality compared to UHWTD. Moreover, those main association almost remained after further adjustment for water source. Additionally, we observed a lower detection rate of bromoform, chloroform, bromodichloromethane, and dibromochloromethane in tap water when household water treatment devices was used compared to No UHWTD. The utilization of household water treatment devices in this prospective cohort was associated with modest reductions in the risk of overall, heart, cancer, Alzheimer’s disease, and nephrosis mortality. These findings suggest that the use of household water treatment devices may have the potential to influence health outcomes and extend life expectancy.","PeriodicalId":19375,"journal":{"name":"npj Clean Water","volume":null,"pages":null},"PeriodicalIF":11.4,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41545-024-00300-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139659860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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