首页 > 最新文献

Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole最新文献

英文 中文
Synthesis and Reactivity of a Pentacoordinated Thiolate-Based Imido-Alkylidene W(VI) Complexes 五配位硫代酸基亚胺-烷基基W(VI)配合物的合成及反应性
Pub Date : 2016-03-01 DOI: 10.2516/OGST/2015036
F. Allouche, V. Mougel, Wolfram R. Grüning, C. Copéret
Attempt to synthesize a bis-thiolate tungsten alkylidene catalysts with bulky arenethiolates unexpectedly yielded upon activation of DME a pentacoordinated complex of general formula [W(NAr)(CHCMe3 )(SAr’)(κ 2 -O-CH2 -CH2 -OMe)], which is active towards self-metathesis of cis-4-nonene compared to the parent bis-benzenethiolate.
试图合成一种双硫代钨烷基烯催化剂,该催化剂在二甲醚的活化下意外生成了体积庞大的烯硫代酸酯(通式[W(NAr)(CHCMe3)(SAr ')(κ 2 -O-CH2 -CH2 -OMe)]的五配位配合物,与母体双苯硫代酸酯相比,它对顺式-4-壬烯的自分解具有活性)。
{"title":"Synthesis and Reactivity of a Pentacoordinated Thiolate-Based Imido-Alkylidene W(VI) Complexes","authors":"F. Allouche, V. Mougel, Wolfram R. Grüning, C. Copéret","doi":"10.2516/OGST/2015036","DOIUrl":"https://doi.org/10.2516/OGST/2015036","url":null,"abstract":"Attempt to synthesize a bis-thiolate tungsten alkylidene catalysts with bulky arenethiolates unexpectedly yielded upon activation of DME a pentacoordinated complex of general formula [W(NAr)(CHCMe3 )(SAr’)(κ 2 -O-CH2 -CH2 -OMe)], which is active towards self-metathesis of cis-4-nonene compared to the parent bis-benzenethiolate.","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77769217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Contrôle optimal d’échauffement du moteur dans les véhicules hybrides 混合动力汽车的最佳发动机热控制
Pub Date : 2016-01-01 DOI: 10.2516/OGST/2014042
van V Vital Reeven, Theo Hofman, F. Willems, Rgm Rudolf Huisman, M. Steinbuch
An Internal Combustion Engine (ICE) under cold conditions experiences increased friction losses due to a high viscosity of the lubricant. With the additional control freedom present in hybrid electric vehicles, the losses during warmup can be minimized and fuel can be saved.In this paper, firstly, a control-oriented model of the ICE, describing the warmup behavior, is developed and validated on measured vehicle data. Secondly, the two-state, non-autonomous fuel optimization, for a parallel hybrid electric vehicle with stop-start functionality, is solved using optimal control theory. The principal behavior of the Lagrange multipliers is explicitly derived, including the discontinuities (jumps) that are caused by the constraints on the lubricant temperature and the energy in the battery system. The minimization of the Hamiltonian for this two-state problem is also explicitly solved, resulting in a computationally efficient algorithm. The optimal controller shows the fuel benefit, as a function of the initial temperature, for a long-haul truck simulated on the FTP-75.
由于润滑油的高粘度,内燃机(ICE)在寒冷条件下的摩擦损失会增加。由于混合动力电动汽车具有额外的控制自由度,因此可以将预热期间的损失降至最低,并节省燃料。在本文中,首先建立了一种描述预热行为的面向控制的内燃机模型,并在实测车辆数据上进行了验证。其次,利用最优控制理论求解了具有启停功能的并联混合动力汽车的两状态非自主燃油优化问题。明确地推导了拉格朗日乘法器的主要行为,包括由电池系统中润滑剂温度和能量约束引起的不连续(跳变)。对该两态问题的最小哈密顿量也进行了显式求解,得到了计算效率高的算法。最优控制器显示了在FTP-75上模拟的长途卡车的燃油效益,作为初始温度的函数。
{"title":"Contrôle optimal d’échauffement du moteur dans les véhicules hybrides","authors":"van V Vital Reeven, Theo Hofman, F. Willems, Rgm Rudolf Huisman, M. Steinbuch","doi":"10.2516/OGST/2014042","DOIUrl":"https://doi.org/10.2516/OGST/2014042","url":null,"abstract":"An Internal Combustion Engine (ICE) under cold conditions experiences increased friction losses due to a high viscosity of the lubricant. With the additional control freedom present in hybrid electric vehicles, the losses during warmup can be minimized and fuel can be saved.In this paper, firstly, a control-oriented model of the ICE, describing the warmup behavior, is developed and validated on measured vehicle data. Secondly, the two-state, non-autonomous fuel optimization, for a parallel hybrid electric vehicle with stop-start functionality, is solved using optimal control theory. The principal behavior of the Lagrange multipliers is explicitly derived, including the discontinuities (jumps) that are caused by the constraints on the lubricant temperature and the energy in the battery system. The minimization of the Hamiltonian for this two-state problem is also explicitly solved, resulting in a computationally efficient algorithm. The optimal controller shows the fuel benefit, as a function of the initial temperature, for a long-haul truck simulated on the FTP-75.","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72924066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 30
Fast Charging and Smart Charging Tests for Electric Vehicles Batteries Using Renewable Energy 使用可再生能源的电动汽车电池快速充电和智能充电试验
Pub Date : 2016-01-01 DOI: 10.2516/OGST/2014001
Oscar Mauricio Forero Camacho, L. Mihet-Popa
Electric Vehicles (EV) technologies are still relatively new and under strong development. Although some standardized solutions are being promoted and becoming a new trend, there is an outstanding need for common platforms and sharing of knowledge and core technologies. This paper presents the development of a test platform, including three Li-ion batteries designed for EV applications, and three associated bi-directional power converters, for testing impacts on different advanced loadings of EV batteries. Different charging algorithms/profiles have been tested, including constant current and power, and forced and pulsed power. The aim of the tests has been to study the impact of smart charging and fast charging on the power system, on the battery state of health and degradation, and to find out the limitations of the batteries for a Smart Grid. The paper outlines the advantages and disadvantages of both tests in terms of regulation of the aggregated local power, power capacity and the power exchange with the grid. The smart charging tests performed have demonstrated that even with a simple control algorithm, without any forecasting, it is possible to provide the required charging and at the same time the power system services, reducing the peak power and the energy losses in the power connection line of the power exchange with the national grid.
电动汽车(EV)技术相对较新,发展势头强劲。虽然一些标准化的解决方案正在被推广并成为一种新的趋势,但对通用平台和知识和核心技术的共享的需求非常突出。本文介绍了一个测试平台的开发,包括三个为电动汽车应用而设计的锂离子电池和三个相关的双向功率转换器,用于测试电动汽车电池不同高级负载的影响。已经测试了不同的充电算法/配置文件,包括恒流和功率,以及强制和脉冲功率。测试的目的是研究智能充电和快速充电对电力系统的影响,对电池健康状态和退化状态的影响,并找出智能电网电池的局限性。本文概述了两种试验方法在调节本地总功率、调节电力容量和与电网交换电力方面的优缺点。智能充电试验表明,即使使用简单的控制算法,无需任何预测,也可以在提供所需充电的同时提供电力系统服务,减少与国家电网交换电力连接线路的峰值功率和能量损失。
{"title":"Fast Charging and Smart Charging Tests for Electric Vehicles Batteries Using Renewable Energy","authors":"Oscar Mauricio Forero Camacho, L. Mihet-Popa","doi":"10.2516/OGST/2014001","DOIUrl":"https://doi.org/10.2516/OGST/2014001","url":null,"abstract":"Electric Vehicles (EV) technologies are still relatively new and under strong development. Although some standardized solutions are being promoted and becoming a new trend, there is an outstanding need for common platforms and sharing of knowledge and core technologies. This paper presents the development of a test platform, including three Li-ion batteries designed for EV applications, and three associated bi-directional power converters, for testing impacts on different advanced loadings of EV batteries. Different charging algorithms/profiles have been tested, including constant current and power, and forced and pulsed power. The aim of the tests has been to study the impact of smart charging and fast charging on the power system, on the battery state of health and degradation, and to find out the limitations of the batteries for a Smart Grid. The paper outlines the advantages and disadvantages of both tests in terms of regulation of the aggregated local power, power capacity and the power exchange with the grid. The smart charging tests performed have demonstrated that even with a simple control algorithm, without any forecasting, it is possible to provide the required charging and at the same time the power system services, reducing the peak power and the energy losses in the power connection line of the power exchange with the national grid.","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81734413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 27
A Novel Model of Foam Flooding Considering Multi-Factors for Enhancing Oil Recovery 多因素泡沫驱提高采收率新模型
Pub Date : 2015-11-01 DOI: 10.2516/OGST/2014025
Jing Wang, Huishu Liu, H. Zhang, G. Zhang, P. Liu, K. Sepehrnoori
Foam flooding is a promising technique for achieving mobility control and diverting fluid into low-permeability strata in post-water-flooding reservoirs. However, foam flow is very complicated and is influenced by many factors which have not been studied and explored very rigorously (i.e. permeability, surfactant concentration, foam quality, reservoir temperature, oil saturation, water saturation and seepage velocity). Based on core flooding experiments of foam flowing and blocking rules using two kinds of foaming agents, a novel model of foam flooding considering the influences of the above factors is established and solved using a reservoir simulator which is formulated using the IMPES method in conjunction with a Runge-Kutta method. Then, the validation is performed by core flooding experiments in both the absence and presence of oil. Finally, the simulator is used to investigate the effects of the permeability max-min ratio, ratio of vertical to horizontal permeability, gas-liquid ratio, depositional sequence, foaming agent concentration, and reservoir temperature.
泡沫驱是一种很有前途的技术,可以在水驱后实现流动性控制和向低渗透地层转移流体。然而,泡沫流动非常复杂,受渗透率、表面活性剂浓度、泡沫质量、储层温度、含油饱和度、含水饱和度和渗流速度等诸多尚未得到严格研究和探索的因素的影响。基于两种发泡剂对岩心泡沫渗流和封堵规律的实验,建立了考虑上述因素影响的新型泡沫驱油模型,并利用IMPES方法结合龙格-库塔方法构建的储层模拟器进行求解。然后,通过无油和有油岩心驱油实验进行验证。最后,利用仿真器研究了渗透率最大最小比、纵横渗透率比、气液比、沉积顺序、发泡剂浓度、储层温度等因素对储层渗透率的影响。
{"title":"A Novel Model of Foam Flooding Considering Multi-Factors for Enhancing Oil Recovery","authors":"Jing Wang, Huishu Liu, H. Zhang, G. Zhang, P. Liu, K. Sepehrnoori","doi":"10.2516/OGST/2014025","DOIUrl":"https://doi.org/10.2516/OGST/2014025","url":null,"abstract":"Foam flooding is a promising technique for achieving mobility control and diverting fluid into low-permeability strata in post-water-flooding reservoirs. However, foam flow is very complicated and is influenced by many factors which have not been studied and explored very rigorously (i.e. permeability, surfactant concentration, foam quality, reservoir temperature, oil saturation, water saturation and seepage velocity). Based on core flooding experiments of foam flowing and blocking rules using two kinds of foaming agents, a novel model of foam flooding considering the influences of the above factors is established and solved using a reservoir simulator which is formulated using the IMPES method in conjunction with a Runge-Kutta method. Then, the validation is performed by core flooding experiments in both the absence and presence of oil. Finally, the simulator is used to investigate the effects of the permeability max-min ratio, ratio of vertical to horizontal permeability, gas-liquid ratio, depositional sequence, foaming agent concentration, and reservoir temperature.","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78538916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Coupled Hydro-Mechanical Simulations of CO2 Storage Supported by Pressure Management Demonstrate Synergy Benefits from Simultaneous Formation Fluid Extraction 压力管理支持的二氧化碳储存耦合流体力学模拟证明了同时提取地层流体的协同效益
Pub Date : 2015-04-01 DOI: 10.2516/OGST/2014029
T. Kempka, C. M. Nielsen, P. Frykman, Ji‐Quan Shi, G. Bacci, F. Dalhoff
We assessed the synergetic benefits of simultaneous formation fluid extraction during CO 2 injection for reservoir pressure management by coupled hydro-mechanical simulations at the prospective Vedsted storage site located in northern Denmark. Effectiveness of reservoir pressure management was investigated by simulation of CO 2 storage without any fluid extraction as well as with 66% and 100% equivalent volume formation fluid extraction from four wells positioned for geothermal heat recovery. Simulation results demonstrate that a total pressure reduction of up to about 1.1 MPa can be achieved at the injection well. Furthermore, the areal pressure perturbation in the storage reservoir can be significantly decreased compared to the simulation scenario without any formation fluid extraction. Following a stress regime analysis, two stress regimes were considered in the coupled hydro-mechanical simulations indicating that the maximum ground surface uplift is about 0.24 m in the absence of any reservoir pressure management. However, a ground uplift mitigation of up to 37.3% (from 0.24 m to 0.15 m) can be achieved at the injection well by 100% equivalent volume formation fluid extraction. Well-based adaptation of fluid extraction rates can support achieving zero displacements at the proposed formation fluid extraction wells located close to urban infrastructure. Since shear and tensile failure do not occur under both stress regimes for all investigated scenarios, it is concluded that a safe operation of CO 2 injection with simultaneous formation fluid extraction for geothermal heat recovery can be implemented at the Vedsted site.
在丹麦北部的Vedsted储层,通过耦合流体力学模拟,我们评估了在注入二氧化碳期间同时提取地层流体对储层压力管理的协同效益。通过模拟不抽取流体的co2储存情况,以及对4口地热采热井进行66%和100%当量体积地层流体抽取,研究了储层压力管理的有效性。模拟结果表明,注水井的总压可降低约1.1 MPa。此外,与不抽取地层流体的模拟情景相比,储层的面压扰动可以显著降低。在应力状态分析之后,在耦合的水-力学模拟中考虑了两种应力状态,表明在没有任何油藏压力管理的情况下,地表最大抬升约为0.24 m。然而,通过100%当量体积地层流体的提取,可以在注入井中实现高达37.3%的地面隆起缓解(从0.24 m到0.15 m)。在靠近城市基础设施的地层流体提取井中,基于井的流体提取速率适应性可以支持实现零排量。由于在两种应力状态下都不会发生剪切和拉伸破坏,因此可以得出结论,在Vedsted现场可以实施安全的CO 2注入操作,同时抽取地层流体进行地热回收。
{"title":"Coupled Hydro-Mechanical Simulations of CO2 Storage Supported by Pressure Management Demonstrate Synergy Benefits from Simultaneous Formation Fluid Extraction","authors":"T. Kempka, C. M. Nielsen, P. Frykman, Ji‐Quan Shi, G. Bacci, F. Dalhoff","doi":"10.2516/OGST/2014029","DOIUrl":"https://doi.org/10.2516/OGST/2014029","url":null,"abstract":"We assessed the synergetic benefits of simultaneous formation fluid extraction during CO 2 injection for reservoir pressure management by coupled hydro-mechanical simulations at the prospective Vedsted storage site located in northern Denmark. Effectiveness of reservoir pressure management was investigated by simulation of CO 2 storage without any fluid extraction as well as with 66% and 100% equivalent volume formation fluid extraction from four wells positioned for geothermal heat recovery. Simulation results demonstrate that a total pressure reduction of up to about 1.1 MPa can be achieved at the injection well. Furthermore, the areal pressure perturbation in the storage reservoir can be significantly decreased compared to the simulation scenario without any formation fluid extraction. Following a stress regime analysis, two stress regimes were considered in the coupled hydro-mechanical simulations indicating that the maximum ground surface uplift is about 0.24 m in the absence of any reservoir pressure management. However, a ground uplift mitigation of up to 37.3% (from 0.24 m to 0.15 m) can be achieved at the injection well by 100% equivalent volume formation fluid extraction. Well-based adaptation of fluid extraction rates can support achieving zero displacements at the proposed formation fluid extraction wells located close to urban infrastructure. Since shear and tensile failure do not occur under both stress regimes for all investigated scenarios, it is concluded that a safe operation of CO 2 injection with simultaneous formation fluid extraction for geothermal heat recovery can be implemented at the Vedsted site.","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91377726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 13
The Importance of Baseline Surveys of Near-Surface Gas Geochemistry for CCS Monitoring, as Shown from Onshore Case Studies in Northern and Southern Europe 北欧和南欧陆上案例研究表明,近地表气体地球化学基线调查对CCS监测的重要性
Pub Date : 2015-04-01 DOI: 10.2516/OGST/2014009
S. Beaubien, L. Ruggiero, A. Annunziatellis, S. Bigi, G. Ciotoli, P. Deiana, S. Graziani, S. Lombardi, M. C. Tartarello
The monitoring of the integrity of onshore geological carbon capture and storage projects will require an approach that integrates various methods with different spatial and temporal resolutions. One method proven to be quite effective for site assessment, leakage monitoring, and leakage verification is near-surface gas geochemistry, which includes soil gas concentration and gas flux measurements. Anomalous concentrations or fluxes, relative to the natural background values, can indicate the potential occurrence of a leak. However the natural background can be quite variable, especially for CO2 , due to biological production and accumulation in the soil that changes as a function of soil type, land use, geology, temperature, water content, and various other parameters. To better understand how these parameters influence natural, near-surface background values, and to examine the potential of different sampling strategies as a function of the survey goals, this paper reports results from two highly different case studies, one from northern Europe (Voulund, Denmark) and one from southern Europe (Sulcis, Sardinia, Italy). The small Voulund site, with its homogeneous soil, climate, and topography, was surveyed twice (in fall and in spring) within the EU-funded SiteChar project to examine the effects of different land use practices and seasons on baseline values. Forested land was found to have lower CO2 concentrations during both campaigns compared to cultivated and heath land, and higher CH4 values during the spring sampling campaign. Continuous monitoring probes showed much more detail, highlighting seasonal changes in soil gas CO2 concentrations linked primarily to temperature variations. The much larger Sulcis site, studied within an ENEA-funded project on potential CO2 -ECBM (Enhanced Coal Bed Methane) deployment, was surveyed at the regional scale and on detailed grids and transects for site assessment purposes. Despite the completely different soil and climate conditions, the statistical distribution of the Sulcis data was similar to that of Voulund. Much higher soil gas CO2 anomalies were found at this site, however, due to the less permeable sediments (i.e., better water retention and greater gas accumulation) and the warmer temperatures. Detailed surveys at this site highlighted various significant anomalies, some of which can be explained by near surface biological processes, whereas others, especially helium anomalies, were more difficult to explain. These results show the utility of baseline surveys, and highlight the need for follow-up studies to clarify any unexplained anomalies before any CO2 storage.
监测陆上地质碳捕获和封存项目的完整性需要一种将各种方法与不同的空间和时间分辨率相结合的方法。近地表气体地球化学是一种被证明对现场评估、泄漏监测和泄漏验证非常有效的方法,其中包括土壤气体浓度和气体通量测量。相对于自然背景值的异常浓度或通量可以表明可能发生泄漏。然而,由于土壤中的生物生产和积累随着土壤类型、土地利用、地质、温度、含水量和各种其他参数的变化而变化,自然背景可能是非常可变的,尤其是二氧化碳。为了更好地理解这些参数如何影响自然的近地表背景值,并检查作为调查目标函数的不同采样策略的潜力,本文报告了两个高度不同的案例研究的结果,一个来自北欧(丹麦的乌隆德),一个来自南欧(意大利撒丁岛的Sulcis)。在欧盟资助的SiteChar项目中,对沃隆德的小场地进行了两次(秋季和春季)调查,以检查不同土地利用方式和季节对基线值的影响。与耕地和荒地相比,林地在两次采样期间的CO2浓度都较低,而CH4值在春季采样期间较高。持续的监测探测器显示出更多的细节,强调了土壤气体二氧化碳浓度的季节性变化主要与温度变化有关。更大的Sulcis场址是在环境署资助的潜在二氧化碳-ECBM(强化煤层气)部署项目中研究的,该项目在区域范围内进行了详细的网格和横断面调查,以进行场址评估。尽管土壤和气候条件完全不同,但Sulcis数据的统计分布与Voulund相似。然而,由于沉积物渗透性较差(即水潴留较好,气体积聚较大)和温度较高,在该地点发现了更高的土壤气体CO2异常。在该地点进行的详细调查突出了各种重要的异常,其中一些可以用近地表生物过程来解释,而另一些,特别是氦异常,则更难解释。这些结果显示了基线调查的效用,并强调了在任何二氧化碳储存之前进行后续研究以澄清任何无法解释的异常的必要性。
{"title":"The Importance of Baseline Surveys of Near-Surface Gas Geochemistry for CCS Monitoring, as Shown from Onshore Case Studies in Northern and Southern Europe","authors":"S. Beaubien, L. Ruggiero, A. Annunziatellis, S. Bigi, G. Ciotoli, P. Deiana, S. Graziani, S. Lombardi, M. C. Tartarello","doi":"10.2516/OGST/2014009","DOIUrl":"https://doi.org/10.2516/OGST/2014009","url":null,"abstract":"The monitoring of the integrity of onshore geological carbon capture and storage projects will require an approach that integrates various methods with different spatial and temporal resolutions. One method proven to be quite effective for site assessment, leakage monitoring, and leakage verification is near-surface gas geochemistry, which includes soil gas concentration and gas flux measurements. Anomalous concentrations or fluxes, relative to the natural background values, can indicate the potential occurrence of a leak. However the natural background can be quite variable, especially for CO2 , due to biological production and accumulation in the soil that changes as a function of soil type, land use, geology, temperature, water content, and various other parameters. To better understand how these parameters influence natural, near-surface background values, and to examine the potential of different sampling strategies as a function of the survey goals, this paper reports results from two highly different case studies, one from northern Europe (Voulund, Denmark) and one from southern Europe (Sulcis, Sardinia, Italy). The small Voulund site, with its homogeneous soil, climate, and topography, was surveyed twice (in fall and in spring) within the EU-funded SiteChar project to examine the effects of different land use practices and seasons on baseline values. Forested land was found to have lower CO2 concentrations during both campaigns compared to cultivated and heath land, and higher CH4 values during the spring sampling campaign. Continuous monitoring probes showed much more detail, highlighting seasonal changes in soil gas CO2 concentrations linked primarily to temperature variations. The much larger Sulcis site, studied within an ENEA-funded project on potential CO2 -ECBM (Enhanced Coal Bed Methane) deployment, was surveyed at the regional scale and on detailed grids and transects for site assessment purposes. Despite the completely different soil and climate conditions, the statistical distribution of the Sulcis data was similar to that of Voulund. Much higher soil gas CO2 anomalies were found at this site, however, due to the less permeable sediments (i.e., better water retention and greater gas accumulation) and the warmer temperatures. Detailed surveys at this site highlighted various significant anomalies, some of which can be explained by near surface biological processes, whereas others, especially helium anomalies, were more difficult to explain. These results show the utility of baseline surveys, and highlight the need for follow-up studies to clarify any unexplained anomalies before any CO2 storage.","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85047957","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 27
Separation of Binary Mixtures of Propylene and Propane by Facilitated Transport through Silver Incorporated Poly(Ether-Block-Amide) Membranes 银掺杂聚醚-嵌段-酰胺膜促进传输分离丙烯和丙烷二元混合物
Pub Date : 2015-02-01 DOI: 10.2516/OGST/2013190
R. Murali, K. Rani, T. Sankarshana, A. Ismail, S. Sridhar
The separation of propylene and propane is a challenging task in petroleum refineries due to the similar molecular sizes and physical properties of two gases. Composite Poly(ether-block-amide) (Pebax-1657) membranes incorporated with silver tetra fluoroborate (AgBF4 ) in concentrations of 0-50% of the polymer weight were prepared by solution casting and solvent evaporation technique. The membranes were characterized by Scanning Electron Microscopy (SEM), Fourier Transform InfraRed (FTIR) and wide-angle X-ray Diffraction (XRD) to study surface and cross-sectional morphologies, effect of incorporation on intermolecular interactions and degree of crystallinity, respectively. Experimental data was measured with an indigenously built high-pressure gas separation manifold having an effective membrane area of 42 cm2 . Permeability and selectivity of membranes were determined for three different binary mixtures of propylene-propane at pressures varying in the range 2-6 bar. Selectivity of C3 H6 /C3 H8 enhanced from 2.92 to 17.22 and 2.11 to 20.38 for 50/50 and 66/34 C3 H6 +C3 H8 feed mixtures, respectively, with increasing loading of AgBF4 . Pebax membranes incorporated with AgBF4 exhibit strong potential for the separation of C3 H6 /C3 H8 mixtures in petroleum refineries.
由于丙烯和丙烷具有相似的分子大小和物理性质,因此在炼油厂分离丙烯和丙烷是一项具有挑战性的任务。采用溶液铸造和溶剂蒸发技术制备了浓度为聚合物重量0-50%的四氟硼酸银(AgBF4)掺入聚醚-嵌段酰胺(Pebax-1657)复合膜。采用扫描电镜(SEM)、傅里叶红外(FTIR)和广角x射线衍射(XRD)对膜进行了表征,分别研究了膜的表面和截面形貌、掺入对分子间相互作用的影响以及结晶度。实验数据是用国产高压气体分离歧管测量的,其有效膜面积为42 cm2。在2-6 bar的压力范围内,测定了三种不同的丙烯-丙烷二元混合物对膜的渗透性和选择性。随着AgBF4添加量的增加,C3 H6 /C3 H8的选择性分别从2.92提高到17.22和2.11提高到20.38,C3 H6 +C3 H8的选择性分别为50/50和66/34。掺入AgBF4的Pebax膜在炼油厂分离C3 H6 /C3 H8混合物方面表现出很强的潜力。
{"title":"Separation of Binary Mixtures of Propylene and Propane by Facilitated Transport through Silver Incorporated Poly(Ether-Block-Amide) Membranes","authors":"R. Murali, K. Rani, T. Sankarshana, A. Ismail, S. Sridhar","doi":"10.2516/OGST/2013190","DOIUrl":"https://doi.org/10.2516/OGST/2013190","url":null,"abstract":"The separation of propylene and propane is a challenging task in petroleum refineries due to the similar molecular sizes and physical properties of two gases. Composite Poly(ether-block-amide) (Pebax-1657) membranes incorporated with silver tetra fluoroborate (AgBF4 ) in concentrations of 0-50% of the polymer weight were prepared by solution casting and solvent evaporation technique. The membranes were characterized by Scanning Electron Microscopy (SEM), Fourier Transform InfraRed (FTIR) and wide-angle X-ray Diffraction (XRD) to study surface and cross-sectional morphologies, effect of incorporation on intermolecular interactions and degree of crystallinity, respectively. Experimental data was measured with an indigenously built high-pressure gas separation manifold having an effective membrane area of 42 cm2 . Permeability and selectivity of membranes were determined for three different binary mixtures of propylene-propane at pressures varying in the range 2-6 bar. Selectivity of C3 H6 /C3 H8 enhanced from 2.92 to 17.22 and 2.11 to 20.38 for 50/50 and 66/34 C3 H6 +C3 H8 feed mixtures, respectively, with increasing loading of AgBF4 . Pebax membranes incorporated with AgBF4 exhibit strong potential for the separation of C3 H6 /C3 H8 mixtures in petroleum refineries.","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83133180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 23
Design and Evaluation of Energy Management using Map-Based ECMS for the PHEV Benchmark 基于Map-Based ECMS的PHEV基准能源管理设计与评价
Pub Date : 2015-01-01 DOI: 10.2516/OGST/2014018
M. Sivertsson, L. Eriksson
Plug-in Hybrid Electric Vehicles (PHEV) provide a promising way of achieving the benefits of the electric vehicle without being limited by the electric range, but they increase the importance of the supervisory control to fully utilize the potential of the powertrain. The winning contribution in the PHEV Benchmark organized by IFP Energies nouvelles is described and evaluated. The control is an adaptive strategy based on a map-based Equivalent Consumption Minimization Strategy (ECMS) approach, developed and implemented in the simulator provided for the PHEV Benchmark. The implemented control strives to be as blended as possible, whilst still ensuring that all electric energy is used in the driving mission. The controller is adaptive to reduce the importance of correct initial values, but since the initial values affect the consumption, a method is developed to estimate the optimal initial value for the controller based on driving cycle information. This works well for most driving cycles with promising consumption results. The controller performs well in the benchmark; however, the driving cycles used show potential for improvement. A robustness built into the controller affects the consumption more than necessary, and in the case of altitude variations the control does not make use of all the energy available. The control is therefore extended to also make use of topography information that could be provided by a GPS which shows a potential further decrease in fuel consumption.
插电式混合动力汽车(PHEV)提供了一种很有前途的方法,可以在不受电动里程限制的情况下实现电动汽车的优点,但它们增加了监督控制的重要性,以充分利用动力系统的潜力。在由IFP energy nouvelles组织的PHEV基准测试中获胜的贡献被描述和评估。该控制是一种基于基于地图的等效消耗最小化策略(ECMS)方法的自适应策略,在为PHEV基准测试提供的模拟器中开发和实现。所实施的控制努力尽可能混合,同时仍然确保所有的电能在驾驶任务中使用。该控制器自适应降低了正确初始值的重要性,但由于初始值影响能耗,提出了一种基于行驶循环信息估计控制器最优初始值的方法。这对大多数驾驶周期都很有效,并具有良好的消费效果。该控制器在基准测试中表现良好;然而,所使用的驱动循环显示出改进的潜力。内置在控制器中的鲁棒性对消耗的影响超过了必要的程度,并且在高度变化的情况下,控制器不会利用所有可用的能量。因此,该控制也被扩展到利用GPS可以提供的地形信息,这表明燃料消耗可能进一步减少。
{"title":"Design and Evaluation of Energy Management using Map-Based ECMS for the PHEV Benchmark","authors":"M. Sivertsson, L. Eriksson","doi":"10.2516/OGST/2014018","DOIUrl":"https://doi.org/10.2516/OGST/2014018","url":null,"abstract":"Plug-in Hybrid Electric Vehicles (PHEV) provide a promising way of achieving the benefits of the electric vehicle without being limited by the electric range, but they increase the importance of the supervisory control to fully utilize the potential of the powertrain. The winning contribution in the PHEV Benchmark organized by IFP Energies nouvelles is described and evaluated. The control is an adaptive strategy based on a map-based Equivalent Consumption Minimization Strategy (ECMS) approach, developed and implemented in the simulator provided for the PHEV Benchmark. The implemented control strives to be as blended as possible, whilst still ensuring that all electric energy is used in the driving mission. The controller is adaptive to reduce the importance of correct initial values, but since the initial values affect the consumption, a method is developed to estimate the optimal initial value for the controller based on driving cycle information. This works well for most driving cycles with promising consumption results. The controller performs well in the benchmark; however, the driving cycles used show potential for improvement. A robustness built into the controller affects the consumption more than necessary, and in the case of altitude variations the control does not make use of all the energy available. The control is therefore extended to also make use of topography information that could be provided by a GPS which shows a potential further decrease in fuel consumption.","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78882697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 47
Risk Assessment-Led Characterisation of the SiteChar UK North Sea Site for the Geological Storage of CO2 以风险评估为主导的英国SiteChar北海二氧化碳地质储存地点的特征
Pub Date : 2015-01-01 DOI: 10.2516/OGST/2015013
M. Akhurst, S. Hannis, Martyn F. Quinn, Ji‐Quan Shi, M. Koenen, F. Delprat-Jannaud, J. Lecomte, D. Bossie-Codreanu, S. Nagy, ukasz Klimkowski, D. Gei, M. Pluymaekers, D. Long
Risk assessment-led characterisation of a site for the geological storage of CO 2 in the UK northern North Sea was performed for the EU SiteChar research project as one of a portfolio of sites. Implementation and testing of the SiteChar project site characterisation workflow has produced a ‘dry-run’ storage permit application that is compliant with regulatory requirements. A site suitable for commercial-scale storage was characterised, compatible with current and future industrial carbon dioxide (CO 2 ) sources in the northern UK. Pre-characterisation of the site, based on existing information acquired during hydrocarbon exploration and production, has been achieved from publicly available data. The project concept is to store captured CO 2 at a rate of 5 Mt per year for 20 years in the Blake Oil Field and surrounding Captain Sandstone saline aquifer. This commercial-scale storage of 100 Mt CO 2 can be achieved through a storage scenario combining injection of CO 2 into the oil field and concurrent water production down-dip of the field. There would be no encroachment of supercritical phase CO 2 for more than two kilometres beyond the field boundary and no adverse influence on operating hydrocarbon fields provided there is pressure management. Components of a storage permit application for the site are presented, developed as far as possible within a research project. Characterisation and technical investigations were guided by an initial assessment of perceived risks to the prospective site and a need to provide the information required for the storage permit application. The emphasis throughout was to reduce risks and uncertainty on the subsurface containment of stored CO 2 , particularly with respect to site technical performance, monitoring and regulatory issues, and effects on other resources. The results of selected risk assessment-led site characterisation investigations and the subsequent risk reassessments are described together with their implications for the understanding of the site. Additional investigations are identified that could further reduce risks and uncertainties, and enable progress toward a full storage permit application. Permit performance conditions are presented as SiteChar-recommended useful tools for discussion between the competent authority and operator. © M. Akhurst et al.
欧盟SiteChar研究项目对英国北海北部的一个二氧化碳地质储存地点进行了风险评估,并将其作为一系列地点之一。SiteChar项目现场特征描述工作流程的实施和测试产生了符合法规要求的“干式”存储许可申请。一个适合商业规模储存的地点,与英国北部当前和未来的工业二氧化碳(CO 2)来源兼容。根据油气勘探和生产过程中获得的现有信息,已经从公开的数据中实现了现场的预特征。该项目的概念是将捕获的二氧化碳以每年500万吨的速度储存在Blake油田和周围的Captain Sandstone盐水含水层中,持续20年。通过将二氧化碳注入油田并同时进行油田采水的存储方案,可以实现100万吨二氧化碳的商业规模存储。超临界相CO 2的侵入范围不会超过油田边界两公里,如果有压力管理,也不会对油气油田的运营产生不利影响。在一个研究项目中,提出了该地点存储许可申请的组成部分。对潜在地点的风险进行初步评估,并根据需要提供存储许可证申请所需的信息,指导了特征描述和技术调查。整个过程的重点是减少储存二氧化碳的地下容器的风险和不确定性,特别是在现场技术性能、监测和管理问题以及对其他资源的影响方面。本文描述了选定的以风险评估为主导的现场特征调查和随后的风险重新评估的结果,以及它们对了解现场的影响。进一步的调查可以进一步降低风险和不确定性,并使全面存储许可申请取得进展。许可证执行条件作为sitechar推荐的有用工具,供主管当局和作业者讨论。©M. Akhurst等人。
{"title":"Risk Assessment-Led Characterisation of the SiteChar UK North Sea Site for the Geological Storage of CO2","authors":"M. Akhurst, S. Hannis, Martyn F. Quinn, Ji‐Quan Shi, M. Koenen, F. Delprat-Jannaud, J. Lecomte, D. Bossie-Codreanu, S. Nagy, ukasz Klimkowski, D. Gei, M. Pluymaekers, D. Long","doi":"10.2516/OGST/2015013","DOIUrl":"https://doi.org/10.2516/OGST/2015013","url":null,"abstract":"Risk assessment-led characterisation of a site for the geological storage of CO 2 in the UK northern North Sea was performed for the EU SiteChar research project as one of a portfolio of sites. Implementation and testing of the SiteChar project site characterisation workflow has produced a ‘dry-run’ storage permit application that is compliant with regulatory requirements. A site suitable for commercial-scale storage was characterised, compatible with current and future industrial carbon dioxide (CO 2 ) sources in the northern UK. Pre-characterisation of the site, based on existing information acquired during hydrocarbon exploration and production, has been achieved from publicly available data. The project concept is to store captured CO 2 at a rate of 5 Mt per year for 20 years in the Blake Oil Field and surrounding Captain Sandstone saline aquifer. This commercial-scale storage of 100 Mt CO 2 can be achieved through a storage scenario combining injection of CO 2 into the oil field and concurrent water production down-dip of the field. There would be no encroachment of supercritical phase CO 2 for more than two kilometres beyond the field boundary and no adverse influence on operating hydrocarbon fields provided there is pressure management. Components of a storage permit application for the site are presented, developed as far as possible within a research project. Characterisation and technical investigations were guided by an initial assessment of perceived risks to the prospective site and a need to provide the information required for the storage permit application. The emphasis throughout was to reduce risks and uncertainty on the subsurface containment of stored CO 2 , particularly with respect to site technical performance, monitoring and regulatory issues, and effects on other resources. The results of selected risk assessment-led site characterisation investigations and the subsequent risk reassessments are described together with their implications for the understanding of the site. Additional investigations are identified that could further reduce risks and uncertainties, and enable progress toward a full storage permit application. Permit performance conditions are presented as SiteChar-recommended useful tools for discussion between the competent authority and operator. © M. Akhurst et al.","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2015-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84487770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
LES of the Exhaust Flow in a Heavy-Duty Engine 重型发动机排气流量的LES
Pub Date : 2014-01-01 DOI: 10.2516/OGST/2013117
O. Bodin, Yue Wang, M. Mihăescu, L. Fuchs
The flow in the exhaust port and the exhaust manifold of a heavy-duty Diesel engine has been studied using the Large Eddy Simulation approach. Some of the flow characteristics in these components a ...
采用大涡模拟方法研究了某重型柴油机排气口和排气歧管内的流动。这些部件的一些流动特性…
{"title":"LES of the Exhaust Flow in a Heavy-Duty Engine","authors":"O. Bodin, Yue Wang, M. Mihăescu, L. Fuchs","doi":"10.2516/OGST/2013117","DOIUrl":"https://doi.org/10.2516/OGST/2013117","url":null,"abstract":"The flow in the exhaust port and the exhaust manifold of a heavy-duty Diesel engine has been studied using the Large Eddy Simulation approach. Some of the flow characteristics in these components a ...","PeriodicalId":19444,"journal":{"name":"Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75495201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
Oil & Gas Science and Technology-revue De L Institut Francais Du Petrole
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1