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Features of obtaining a vacuum-dense weakly conductive ceramics based on barium aluminate 获得基于铝酸钡的真空致密弱导电陶瓷的特点
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-8-14-20
A. A. Zhdanok, L. Berdnikova, Z. A. Korotaeva, B. P. Tolochko, V. Bulgakov, M. A. Mikhaylenko
Ceramics based on barium aluminate with additives of iron (III) oxide and lithium hydroxide were obtained by solid-phase synthesis. It has been established that high-temperature treatment in an oxidizing medium contributes to the production of vacuum-dense samples that meet the «absolutely impermeable» tightness criterion, with a density of 3,75 g/cm3 , with a compressive strength limit of 597,1 MPa and a specific electrical conductivity in the range of 1,50·10‒7‒1,05·10‒4 Cm/ cm (at 90‒300 °C).
通过固相合成法获得了以铝酸钡为基础、添加氧化铁(III)和氢氧化锂的陶瓷。已证实在氧化介质中进行高温处理有助于生产出符合 "绝对不渗透 "密封标准的真空致密样品,其密度为 3.75 g/cm3,抗压强度极限为 597.1 MPa,比电导率范围为 1.50-10-7-1.05-10-4 Cm/cm(90-300 °C)。
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引用次数: 0
Effect of plasma spraying technological modes on the formation of protective and functional coatings 等离子喷涂技术模式对形成保护性和功能性涂层的影响
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-7-33-37
I. N. Kravchenko, S. Y. Zhachkin, E. P. Timashov, G. Trifonov, S. Kartsev, S. N. Kuznetsov
The improvement of the technology of plasma deposition of wear-resistant coatings is shown. At the same time, special attention is paid to one of the most important parameters ― the thickness of the functional layer, since when using plasma deposition methods, it has a significant impact on the quality of coatings, as well as the functionality and productivity of the process. Based on the planning of the experiment, mathematical models have been developed that make it possible to establish the relationship between the coating thickness and the given technological parameters of the plasma spraying process. The results of the analysis of the dependences obtained showed that the thickness of the coating is most affected by the strength of the arc current of the plasma torch.
展示了耐磨涂层等离子沉积技术的改进。同时,对最重要的参数之一--功能层的厚度给予了特别关注,因为在使用等离子沉积方法时,它对涂层的质量以及工艺的功能性和生产率都有重大影响。根据实验计划,我们建立了数学模型,以确定涂层厚度与等离子喷涂工艺给定技术参数之间的关系。对所获得的关系进行分析的结果表明,涂层厚度受等离子喷枪电弧电流强度的影响最大。
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引用次数: 0
Refined express method for evaluation of porous structure ceramic materials 用于评估多孔结构陶瓷材料的改进表达法
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-9-16-19
Y. Kryuchkov
The express method for evaluating the porous structure of ceramic materials has been refined by replacing a smooth change in gas pressure with a stepwise one with pressure holding at each stage. After determining the average radius, the maximum pressure drop is determined until only one chain of gas bubbles remains. The average coordination number for the solid phase and the coefficient of capillary tortuosity were calculated. The experimental and calculated mean radii are in good agreement with the data, while the tortuosity coefficients differ.
评估陶瓷材料多孔结构的明示方法已得到改进,将气体压力的平滑变化改为在每个阶段保持压力的阶梯式变化。在确定平均半径后,确定最大压降,直到只剩下一条气泡链。固相的平均配位数和毛细管迂回系数都已计算出来。实验得出的平均半径和计算得出的平均半径与数据十分吻合,而毛细管迂回系数则有所不同。
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引用次数: 0
Evaluation of performance of advanced refractory materials intended for the arch of the electric furnace for HLW vitrification 评估用于高浓缩铀玻璃化电炉拱顶的先进耐火材料的性能
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-7-8-11
I. I. Dement’eva, P. V. Kozlov, E. V. Polyakov, M. B. Remizov, A. A. Mal’tsev, P. I. Sikhinin
The paper presents the results of the studies of refractory materials produced by the company Keralit, JSC Borovichi Refractories Plant and STC Bakor and intended for the arch of the electric furnace EP-6 for HLW vitrification. The studies have determined strength properties and acid resistance of the materials when exposed to vapors of nitric acid and nitric acid solution. It has been concluded as a result of the studies that optimum materials for construction of the furnace arch are MKRTU-50 and MKV-65 materials produced by JSC Borovichi Refractories Plant and STC Bakor, respectively.
本文介绍了对凯拉利特(Keralit)公司、博罗维奇耐火材料厂股份公司(JSC Borovichi Refractories Plant)和巴科尔(STC Bakor)公司生产的耐火材料进行研究的结果,这些耐火材料将用于玻璃化高浓缩铀电炉EP-6的拱形结构。研究确定了这些材料在接触硝酸蒸汽和硝酸溶液时的强度特性和耐酸性。研究得出的结论是,建造炉拱的最佳材料是分别由 JSC Borovichi 耐火材料厂和 STC Bakor 生产的 MKRTU-50 和 MKV-65 材料。
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引用次数: 0
Features of manufacturing high-heat-resistant ceramics using aluminum hafnium binder 使用铝铪粘结剂制造高耐热陶瓷的特点
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-10-22-26
M. S. Varfolomeev, A. Pokhorenko, G. Shcherbakova
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引用次数: 0
Electrodeposition of nickel-based composite electrochemical coatings using bulk-reinforced Al‒TiB2 powders 使用批量强化的 Al-TiB2 粉末电沉积镍基复合电化学涂层
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-8-54-59
F. V. Krasikov, M. Markov, M. V. Staritsyn, M. L. Fedoseev, D. A. Tkachev, A. Bykova
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引用次数: 0
Refractory materials for high-temperature pulse installations 用于高温脉冲装置的耐火材料
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-9-39-46
A. V. Fedotov, A. V. Belyakov, I. Kashcheev
The results of studies of materials of high and higher refractoriness for the cowper heater of high-temperature pulsed installations are presented. It is shown that long-term operation of corundum refractories (up to one and a half years) at temperatures of 1750‒1800 °C slightly changes the thermophysical properties of the material. Тhe materials and designs of the elements of the packing and lining of the cowper heater for different layers and temperatures are selected. The velocity of the gas flow, which ensures the fixed position of the ball nozzle, is determined. Efficient packing design improves heat transfer and reduces the size of the cowper column by a factor of 3,75.
本文介绍了用于高温脉冲装置罩式加热器的高耐火度和更高耐火度材料的研究结果。结果表明,刚玉耐火材料在 1750-1800 °C的温度下长期运行(最长可达一年半)会略微改变材料的热物理性质。选择了不同层数和温度下的罩式加热器填料和内衬元件的材料和设计。确定确保球形喷嘴固定位置的气流速度。高效的填料设计可改善传热效果,并将牛尾管柱的尺寸缩小 3.75 倍。
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引用次数: 0
Preparation of nanoceramic material based on bismuth titanate Bi2Ti4O11 制备基于钛酸铋 Bi2Ti4O11 的纳米陶瓷材料
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-9-24-27
N. Lomanova
The functional characteristics of materials based on bismuth titanate Bi2Ti4O11 largely depend on the synthesis conditions. The preparation of nanocrystals of this compound is topical in connection with the problem of miniaturization of electronic components. The features of phase formation and the optimal conditions for the formation of a nanoceramic material based on Bi2Ti4O11 via coprecipitation from salt solutions are studied in the present work. The morphological features, temperature of formation and activation of sintering of the material were established.
基于钛酸铋 Bi2Ti4O11 的材料的功能特性在很大程度上取决于合成条件。该化合物纳米晶体的制备与电子元件微型化问题有关。本研究对基于 Bi2Ti4O11,通过盐溶液共沉淀形成纳米陶瓷材料的相形成特征和最佳条件进行了研究。研究确定了该材料的形态特征、形成温度和烧结活化。
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引用次数: 0
Features of the effect of coke oxidation kinetics on the performance of the mineral wool 焦炭氧化动力学对矿棉性能影响的特点
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-10-3-8
V. I. Matyukhin, A. V. Matyukhina, S. E. Punenkov
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引用次数: 0
Research and modeling of the ecological efficiency of drying refractory and building materials in vertical shaft furnaces 竖炉干燥耐火材料和建筑材料的生态效率研究与建模
Pub Date : 2023-11-30 DOI: 10.17073/1683-4518-2023-7-52-59
V. N. Makarov, R. G. Akhmetov, S. Davydov, N. Makarov
Based on the hypothesis of the dominant effect on the environmental efficiency of drying materials in shaft furnaces of the concentration, median diameter, dispersion, temperature and humidity of dust particles at the outlet of the dryer, a device for thermal aeration separation of dust is proposed. The analysis of mathematical modeling of aerothermodynamic processes in a two-phase medium asbestos dust ‒ gas flow confirmed the conclusions of industrial studies on the influence of aerothermodynamic parameters of direct flow on the temperature and humidity of asbestos dust in the pneumatic dryer. Based on the principle of additive classification, a mathematical model of aeration separation of dust particles directly in the dryer of the shaft furnace is constructed, depending on the parameters of the heat carrier and the proposed device.
根据灰尘颗粒在干燥器出口处的浓度、中值直径、分散度、温度和湿度对竖炉中干燥材料的环境效率的主要影响这一假设,提出了一种灰尘热曝气分离装置。通过对石棉粉尘-气流两相介质中空气热力学过程的数学建模分析,证实了关于直接流空气热力学参数对气动干燥器中石棉粉尘温度和湿度影响的工业研究结论。根据添加剂分类原理,根据热载体和拟议装置的参数,构建了直接在竖炉干燥器中进行粉尘颗粒曝气分离的数学模型。
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引用次数: 0
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