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Huiles et corps gras des Pays du Sud et lipochimie 来自南方国家的油和脂肪以及脂肪化学
Pub Date : 2013-01-01 DOI: 10.1051/OCL.2012.0494
J. Lecomte, Michel Pina, Pierre Villeneuve
During the last decades the oleochemistry has gradually flooded our everyday life through a mass of products and applications. This is mainly due to the wide structural diversity and reactivity of fatty acids and the growing demand for bio-sourced goods. Today, almost one quarter of the global vegetable oil production is dedicated to nonfood applications, the contribution of animal fats being much more modest. Excepted biodiesels, the chemical applications of tropical edible oils depend on their fatty acids composition: lauric oils (coconut and palm kernel) and palm stearin will be mostly converted into surface actives ingredients while unsaturated oils rather will be subjected to double bond functionalization or cracking. Alongside of major vegetable oils only a few non-edible tropical oils are exclusively intended to oleochemistry such as Castor and Jatropha. Some other non-food oilseed crops (Cuphea, Lesquerella, Vernonia, black mustard. . .) are promising but further researches are still needed for their development in Southern Countries. In the future, the production increase of major vegetable oils and the development of new ones will face many challenges relating to environmental issues, competition between food and non-food uses and between non-food applications themselves.
在过去的几十年里,油脂化学通过大量的产品和应用逐渐淹没了我们的日常生活。这主要是由于脂肪酸广泛的结构多样性和反应性,以及对生物源产品的需求不断增长。今天,全球近四分之一的植物油生产用于非食品用途,动物脂肪的贡献要小得多。除生物柴油外,热带食用油的化学应用取决于其脂肪酸组成:月桂油(椰子和棕榈仁)和棕榈硬脂将主要转化为表面活性成分,而不饱和油则会受到双键功能化或裂解。除了主要的植物油外,只有少数不可食用的热带油专门用于油脂化学,如蓖麻和麻风树。其他一些非食用油籽作物(Cuphea、Lesquerella、Vernonia、black mustard等)也很有前景,但在南方国家的发展还需要进一步的研究。未来,主要植物油的产量增加和新植物油的开发将面临环境问题、食品和非食品用途之间的竞争以及非食品应用本身之间的竞争等诸多挑战。
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引用次数: 2
Filtration d’une huile dopée avec quatre hydrocarbures aromatiques polycycliques (HAP) sur des plaques garnies en charbon actif 在活性炭填充板上过滤掺杂四种多环芳烃(pah)的油
Pub Date : 2012-11-01 DOI: 10.1051/OCL.2012.0481
Marion Sidani, Marie-Agnès Gaud, X. Pagès, O. Morin, Morgan Gouband, Jérôme Buchoux, J. Goulet, C. Birot, V. Galan
Powdered activated carbon is used in oils and fats refining to bleach and purify vegetable oils and fish oils. Actually, this powder makes it possible to detoxify crude fish oils and to eliminate contaminants like PAH, dioxin and PCB. Nevertheless, the powdered activated carbon used is painful because it is pulverulent. Nowadays, producers advise filtration plates filled with this powder. The aim of this study is to check the efficiency of such plates in the PAH elimination and verify the respect of the new 2011 regulation (2 μg/kg for benzo(a)pyrene, 10 μg/kg for the sum of benzo(a)pyrene, benzo(b)fluoranthene, benzo (a)anthracene and chrysene).
粉末状活性炭用于油脂精炼,以漂白和净化植物油和鱼油。实际上,这种粉末可以使粗鱼油解毒,并消除多环芳烃、二恶英和多氯联苯等污染物。然而,粉状活性炭的使用是痛苦的,因为它是粉状的。如今,生产商建议用过滤板填充这种粉末。本研究的目的是检查这些板材在消除多环芳烃方面的效率,并验证2011年新法规(苯并(a)芘为2 μg/kg,苯并(a)芘、苯并(b)氟蒽、苯并(a)蒽和甲苯的总和为10 μg/kg)的遵守情况。
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引用次数: 0
La valorisation des coproduits de l’huilerie par méthanisation 通过甲烷化对炼油副产品进行定价
Pub Date : 2012-11-01 DOI: 10.1051/OCL.2012.0483
Laureen Badey, M. Torrijos, P. Sousbie, P. Pouech, F. Bosque
The productions of vegetable oil and methyl esters of vegetable oil lead to the generation of a lot of by-products. The purpose of this work was to study an alternative solution for a profitable use of vegetable oil by-products: anaerobic digestion. The potential for anaerobic digestion of 24 by-products was studied. The results show that most of oil by-products had a good capacity for anaerobic digestion. Then, the effects of the addition of oil by-products on the behavior of one reactor treating a mixture of grass, cow manure and fruit and vegetable waste and another reactor treating household waste were investigated. Most of the by-products tested improved significantly the production of methane indicating that the addition of by-products from oil production could represent a significant financial earning for the digester operators.Discussions are in progress involving oil producers and biogas plant operators to assess the opportunity of supporting the addition of by-products from oil refining in their facilities. A first evaluation of the costs and potential benefits of by-product treatment was performed. These costs should be reviewed in line with the increased development of anaerobic digestion and the expected benefits due to the digestion of by-products.
植物油和植物油甲酯的生产会产生大量的副产物。本工作的目的是研究一种可替代的解决方案,以有效利用植物油副产品:厌氧消化。对24种副产物的厌氧消化潜力进行了研究。结果表明,大部分油脂副产物具有良好的厌氧消化能力。在此基础上,研究了油脂副产物对处理草粪、牛粪和果蔬垃圾的反应器和处理生活垃圾的反应器性能的影响。测试的大多数副产品都显著提高了甲烷的产量,这表明石油生产副产品的加入可以为沼气池运营商带来可观的经济收入。石油生产商和沼气厂经营者正在进行讨论,以评估在其设施中支持增加炼油副产品的机会。对副产物处理的成本和潜在效益进行了首次评估。这些成本应根据厌氧消化的发展和副产品消化的预期效益进行审查。
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引用次数: 2
Comment valoriser dans l'alimentation animale, les graines de soja produites en France ? Comparaison de deux proc de transformation : l'aplatissage-cuisson-pression et l'extrusion-pression 法国生产的大豆如何在动物饲料中定价?两种加工工艺的比较:压扁-烹饪-压力和挤压-压力
Pub Date : 2012-11-01 DOI: 10.1051/OCL.2012.0484
A. Quinsac, Patrick Carr, Mathieu Janowski
How to develop the use for animal feeding, of soybean produced in France? Comparison of two processes: flaking-cooking-pressing and extrusion- pressing Cooking-pressing or extrusion-pressing processes applied to soybeans produce partially deoiled cake used for animal feeding. These two processes were studied and compared with a view to implementation in an industrial unit. The various factors of hydrothermal treatment for conditioning the beans were studied at different scales (batch from 2 kg to 100 kg, and continuous flow at 100 kg/h) and the results showed the need for moist cooking to effectively deactivate the antitrypsin factors (FAT) while maintaining protein solubility. The extrusion-pressing was more effective for deoiling cakes than cooking- pressing (5.4 vs. 6.7 %) but less robust for deactivation of FAT (6.5 vs. 3.8 TIU/mg). The techno-economical study was carried out to simulate the crushing costs and net margins of both processes in a plant capacity of 20 000 t / year. It showed that the costs of both methods were similar (about 33 s/t). Gross margins were evaluated between 18 and 84 s / t in three valuation assumptions based on market price of oil, the mode value of the meal and the residual oil, the level of premiums GMO traceability and transport. The cooking-pressing process can also be applied to sunflower and rapeseed and versatility is an advantage to ensure continuous operation of the crushing unit in case of supply difficulties in soybean.
如何开发法国生产的大豆用于动物饲养?剥皮-蒸煮-压榨与挤压两种工艺的比较蒸煮-压榨或挤压两种工艺在大豆部分去油饼生产中的应用。对这两种工艺进行了研究和比较,以期在工业装置上实现。在不同规模(批量为2 ~ 100 kg,连续流量为100 kg/h)的条件下,研究了水热对大豆进行调理的各种因素,结果表明,在保持蛋白质溶解度的同时,需要湿煮才能有效地灭活抗胰蛋白酶因子(FAT)。挤压法比蒸煮法对蛋糕去油更有效(5.4% vs. 6.7%),但对脂肪失活的效果较差(6.5 vs. 3.8 TIU/mg)。进行了技术经济研究,以模拟工厂产能为20,000 t /年的两种工艺的破碎成本和净利润率。结果表明,两种方法的成本相近(约为33 s/t)。毛利率在18至84 s / t之间进行了评估,基于油的市场价格、粕和残油的模式价值、转基因生物可追溯性和运输的溢价水平的三种估值假设。蒸煮压榨工艺也适用于葵花籽和油菜籽,在大豆供应困难的情况下,通用性是保证破碎装置连续运行的优势。
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引用次数: 8
Amélioration de l’autonomie énergétique et de l’impact environnemental d’une unité de trituration de tournesol par l’implantation conjointe d’un atelier de décorticage et d’une chaudière à coques 通过联合安装脱壳车间和壳锅炉,提高向日葵粉碎装置的能源自主和环境影响
Pub Date : 2012-11-01 DOI: 10.1051/OCL.2012.0485
Sylvain Tostain, Pierre Chervier, Alain Laulan, Thomas Kermorgant
Fibre rich sunflower hulls have always been regarded as having a remarkable calorific value (5 000 kWh/t DM), very close to that of wood. Rising energy costs, emergent environmental concerns, and fitness for use of sunflower derived products have led to a growing interest in the dehulling of sunflower seeds prior to crushing, and burning of hulls in biomass boilers to yield process steam on site. This was made possible by prominent technological improvements in boiler technology. The torsional chamber technology exhibits good performances in full combustion of sunflower hulls, allowing for a high efficiency, a great flexibility, and a limited emission of pollutants. Yet, fumes may still have to be post-treated to ensure compliance with stringent restrictions in dust emissions. Being a robust and versatile technology, the torsional chamber is able to cope with a feedstock quality varying to a certain extent. The general design of a crushing plant fitted with a dehulling unit is impacted dramatically and becomes very sensitive to variations in hullability of the incoming seeds. Hull content and size of the seeds are correlated positively to hullability; moisture, density and oil content being correlated negatively. Hullability is affected mostly by environmental effects, cultivars being responsible for it to a lesser extent. Thus, hullability is impacted by upstream practices in plant breeding, field, and grain elevator management. Success in an efficient hulling strategy not only depends on the use of relevant technologies on processing plants, but also relies on knowledge of the seed and meal customer needs, as well as on concerted actions at various levels along the sunflower chain.
富含纤维的葵花籽壳一直被认为具有显著的热值(5 000千瓦时/吨日干),非常接近木材。不断上升的能源成本,紧急出现的环境问题,以及使用向日葵衍生产品的适应性,导致人们对粉碎前的葵花籽脱壳,以及在生物质锅炉中燃烧壳以产生现场工艺蒸汽的兴趣越来越大。这是由于锅炉技术的显著技术改进而成为可能的。扭转室技术在葵花籽壳的充分燃烧中表现出良好的性能,具有效率高、灵活性强、污染物排放少的特点。然而,废气可能仍然需要进行后处理,以确保符合严格的粉尘排放限制。作为一种强大的和通用的技术,扭转室能够应付原料质量在一定程度上的变化。装有脱壳装置的破碎装置的总体设计受到巨大的影响,并且对进入的种子的壳性变化非常敏感。种子的壳含量和大小与壳性呈正相关;水分、密度和含油量呈负相关。稻壳性主要受环境影响,品种对稻壳性的影响较小。因此,植物育种、田间和粮食升降机管理的上游实践影响着稻壳性。有效剥壳策略的成功不仅取决于加工厂相关技术的使用,还取决于对种子和豆粕客户需求的了解,以及向日葵链上各个层面的协调行动。
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引用次数: 3
Process et qualité 过程和质量评估
Pub Date : 2012-11-01 DOI: 10.1051/OCL.2012.0488
X. Pagès
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引用次数: 0
Le projet français P.I.V.E.R.T. 我们的项目是P.I.V.E.R.T.
Pub Date : 2012-11-01 DOI: 10.1051/OCL.2012.0432
Jean-François Rous
P.I.V.E.R.T. is an ambitious project of development of the 3rd generation biorefinery by 2020. Conceived around a technological complex with strict environmental criteria (aiming at obtaining a label HQE), P.I.V.E.R.T. federates all the national and main roads lifeblood, of the sector (some international partnerships are also under development). The major objectives of the P.I.V.E.R.T. project are: a valorization of oilseeds, proteins and lignocellulosic plant in its entirety (approach ‘‘entire plants’’) ; an operation in closed circuit on the level of water and energy exchanges, the platform providing for its own needs, in a logic of industrial ecology ; collection and valorization of a significant part of the CO2 produced by the activities of the refinery. Two strategies will be developed jointly: on one hand the development of ‘‘platform’’ molecules entering the traditional circuits of chemistry, on the current markets with the renewable character, in addition, the development of new molecules having new properties, thus giving access to new markets. Thanks to the research and development realized by researchers dedicated to P.I.V.E.R.T., the industrial partners will have access to a capable structure to develop, and to test demonstrators preceding future industrial production units. Certain technological bricks could be tested in a large scale industrial platform dedicated to operational integration of innovations. The development of programming technologies of refineries will give to P.I.V.E.R.T. the means to develop new innovative processes and will give to the industrials the possibility of modeling their future production units.
P.I.V.E.R.T.是一个雄心勃勃的项目,到2020年开发第三代生物炼制。P.I.V.E.R.T.围绕着一个具有严格环境标准的技术综合体(旨在获得HQE标签),将该行业所有国家和主要道路的生命线联合起来(一些国际合作伙伴关系也在发展中)。P.I.V.E.R.T.项目的主要目标是:油籽、蛋白质和木质纤维素植物的整体价值(接近“整个植物”);一个在水和能源交换层面的闭环操作,平台提供自己的需求,在工业生态的逻辑;炼油厂生产活动产生的大部分二氧化碳的收集和增值。两种策略将共同开发:一方面开发进入传统化学电路的“平台”分子,在当前具有可再生特性的市场上,另外,开发具有新性质的新分子,从而进入新市场。由于研究人员致力于P.I.V.E.R.T的研究和开发,工业合作伙伴将有机会获得一个有能力的结构来开发,并在未来的工业生产单元之前测试演示。某些技术模块可以在专门致力于创新运营集成的大型工业平台上进行测试。精炼厂程序设计技术的发展将给P.I.V.E.R.T.提供开发新的创新工艺的手段,并将给工业提供对其未来生产装置进行建模的可能性。
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引用次数: 2
Impact du décorticage du tournesol sur la valeur nutritionnelle et l’intérêt économique des tourteaux en fabrication d’aliments composés 向日葵脱壳对复合饲料生产中油饼营养价值和经济效益的影响
Pub Date : 2012-11-01 DOI: 10.1051/OCL.2012.0486
C. Peyronnet, F. Pressenda, A. Quinsac, P. Carré
Sunflower meal is an alternative source of proteins for feedstuff but its high fiber content reduces the nutritional value. Different dehulling processes can improve the protein content and the nutritional value of meal. Partially dehulled sunflower meals with 32% and 36% of proteins produced in different crushing plants in France had been compared to non-dehulled sunflower meal (29% of proteins). The total French feedstuff production was simulated with a model including prices of raw materials observed during 2010-2011 campaign. The interest prices of the different qualities of sunflower meal compared to soybean meal varied from 0.43, 0.50 to 0.70 for 29, 32 and 36% of proteins content respectively. The 36% protein sunflower meal seems very well adapted to laying hens and ducks diets where 29% type should be more adapted to meat cows, sows and rabbits who need less concentrated diets. The new market for the 36 % protein sunflower meal type could notably help to provide local sources of proteins for high quality poultry production.
葵花籽粉是饲料蛋白质的另一种来源,但其高纤维含量降低了营养价值。不同的脱壳工艺可提高粗粉的蛋白质含量和营养价值。部分去皮的向日葵粕含有32%和36%的蛋白质,这些蛋白质来自法国不同的压榨厂,与未去皮的向日葵粕(29%的蛋白质)进行了比较。用一个模型模拟了法国饲料总产量,其中包括2010-2011年期间观察到的原材料价格。不同品质的葵花籽粕与豆粕相比,蛋白质含量分别为29、32和36%,利息价格分别为0.43、0.50 ~ 0.70。36%的蛋白质向日葵粉似乎非常适合蛋鸡和鸭的日粮,而29%的蛋白质向日葵粉应该更适合需要较少浓缩日粮的肉牛、母猪和兔子。蛋白质含量为36%的向日葵粕的新市场将显著有助于为高品质家禽生产提供本地蛋白质来源。
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引用次数: 7
Recovery of low temperature heat in oil mills 油厂低温热的回收
Pub Date : 2012-11-01 DOI: 10.1051/OCL.2012.0482
P. Carré
Energy consumption in oil mills is a major item of costs and a sensitive point in the production of biofuels. To improve their performance, industrials can recover lowtemperature heat thanks to a new technology of heat exchangers suitable for treating granular solid materials. Information about the energy requirements of the rapeseed crushing being not readily available, the article gives a detailed assessment of consumption items (per ton of seed: 263 MJ for preparation operations and 284 MJ for solvent extraction). These exchangers used as pre-conditioners saves about 55 MJ.t−1 of heat by use of steam condensates. We could go further in use of these devices on the one hand to recover heat from press cake and meal, and secondly to use recovered energy to dry and warm up the seeds before pre-pressing. In this configuration, the energy savings could reach 38% of current needs.
在生产生物燃料的过程中,炼油厂的能源消耗是成本的一个主要项目,也是一个敏感点。为了提高它们的性能,工业可以回收低温热量,这要归功于一种适用于处理颗粒状固体材料的热交换器新技术。关于油菜籽粉碎的能量需求信息并不容易获得,文章给出了详细的消耗项目评估(每吨种子:制备操作263兆焦耳和溶剂萃取284兆焦耳)。这些换热器用作预调节器可节省约55兆焦耳。利用蒸汽冷凝物产生的热量的T−1。我们可以进一步利用这些设备,一方面从压榨饼和粕中回收热量,其次在预压榨前利用回收的能量干燥和加热种子。在这种配置下,节省的能源可以达到当前需求的38%。
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引用次数: 6
Compte rendu de la 18e Conférence Internationale sur le Tournesol : Mar del Plata & Balcarce (Argentine), 2012 第18届国际向日葵会议纪要:马德普拉塔和巴尔卡塞(阿根廷),2012年
Pub Date : 2012-11-01 DOI: 10.1051/OCL.2012.0478
É. Pilorgé, L. Champolivier, Sylvie Dauguet, P. Jouffret, Françoise Labalette, N. Landé, A. Merrien, E. Mestries, A. Penaud, F. Salvi, C. Vogrincic
The 18th International Sunflower Conference took place in Mar del Plata, Argentina, in February, 2012. The key-points and evolutions of sunflower research were presented, in the fields of agronomy, physiology, genetics and genomics, crop protection, quality and markets. Major evolutions can be observed concerning the sequencing of sunflower genome, announced to be complete by the end of 2012, but also concerning the use of models and the progress in the studies on the interactions between varieties genetic pattern, environment and crop management practices. In crop protection aspects, the evolutions of the major pathogens, downy mildew and Orobanche cumana, have been discussed, as well as the breeding efforts for genetic resistances, or the advances concerning the herbicides tolerant varieties. Evolutions in oil quality aspects have been exposed too, such as varieties enriched in stearic acid, or tocopherols, or with low contents in saturated fatty acids.
第18届国际向日葵大会于2012年2月在阿根廷的马德普拉塔举行。介绍了向日葵在农学、生理学、遗传学和基因组学、作物保护、品质和市场等方面的研究重点和进展。在向日葵基因组测序(预计于2012年底完成)、模型的使用以及品种遗传模式、环境和作物管理措施之间相互作用的研究进展等方面都取得了重大进展。在作物保护方面,讨论了主要病原菌霜霉病和褐霉病的演变,以及遗传抗性的育种工作和耐除草剂品种的进展。油脂质量方面的演变也被揭示出来,例如富含硬脂酸或生育酚的品种,或饱和脂肪酸含量低的品种。
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引用次数: 1
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Oléagineux, Corps gras, Lipides
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