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Criteria for laves-phase formation in refractory high-entropy alloys 难熔高熵合金中laves相形成的准则
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-11-11 DOI: 10.1080/09500839.2021.1998692
H. Yao, Dongxu Qiao, Junwei Miao, Jun Wang, E. Guo, Yiping Lu
ABSTRACT The refractory high-entropy alloys (RHEAs) have been the subject of considerable research in recent years. Since the Laves phase usually leads to a dramatic decrease in the malleability of RHEAs at ambient temperatures, it is critical to identifying the Laves-phase formation. Here, a facile and effective criterion is proposed to predict the phase stability based on the empirical parameters of reported RHEAs. The results indicate that the small atomic size difference is a sufficient condition for determining the stability of solid solution but not a necessary one. In general, the Laves-phase precipitates can be inhibited by decreasing the atomic-size difference, the enthalpy of mixing, and the valence electron concentration. These criteria can be easily adapted to design new RHEAs with the desired phase structure.
难熔高熵合金(RHEAs)是近年来研究的热点。由于Laves相通常会导致RHEA在环境温度下的延展性显著降低,因此识别Laves相的形成至关重要。在此,基于已报道的RHEA的经验参数,提出了一个简单有效的相稳定性预测准则。结果表明,小的原子尺寸差是确定固溶体稳定性的充分条件,但不是必要条件。通常,可以通过降低原子尺寸差、混合焓和价电子浓度来抑制Laves相沉淀。这些标准可以很容易地适用于设计具有所需相结构的新RHEA。
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引用次数: 3
Correlation between bulk and precipitate composition in Al-Zn-Mg-Cu alloys Al-Zn-Mg-Cu合金中体积和沉淀成分的相关性
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-11-11 DOI: 10.1080/09500839.2021.1998690
Y. Zou, Xiaodong Wu, Songbai Tang, Qianqian Zhu, Hui Song, M. Guo, Ling-fei Cao
ABSTRACT The composition of precipitates in peak-aged Al-Zn-Mg-Cu alloys with various Zn/Mg ratios has been investigated by atom probe tomography (APT). The results show that the η′ and the T′ phases have different compositions with a similar Zn/Mg ratio in the same alloy. The Zn/Mg ratio within precipitates was shown to be positively correlated with the Zn/Mg ratio in the alloy. Moreover, the size dependency of composition for ageing precipitates in Al-Zn-Mg-Cu alloys has been determined. This study enriches the understanding of precipitate composition relative to that of the bulk in Al-Zn-Mg-Cu alloys.
摘要用原子探针层析成像(APT)研究了不同Zn/Mg比的峰值时效Al-Zn-Mg-Cu合金中沉淀物的组成。结果表明,在同一合金中,η′和T′相的组成不同,Zn/Mg比例相近。沉淀物中的Zn/Mg比率与合金中的Zn-Mg比率呈正相关。此外,还测定了Al-Zn-Mg-Cu合金中时效析出物成分的尺寸依赖性。这一研究丰富了对Al-Zn-Mg-Cu合金中沉淀成分相对于本体成分的理解。
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引用次数: 5
Preparation and study of cerium lanthanum zirconate fibres 锆酸铈镧纤维的制备与研究
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-11-03 DOI: 10.1080/09500839.2021.1984603
Jianing Wang, Chaohui Wang, Qingke Li, Guang‐Ming Li, Chunqi Wang, You Wang, Meiling Dong
ABSTRACT LZ7C3 fibres with nanostructures have been synthesised by the sol–gel method combined with electrostatic spinning technology and a high-temperature-resistant LZ7C3 ceramic material prepared by high-temperature calcination. The formation process of the ceramic fibre was studied and its properties characterized by differential thermal analysis, X-ray diffraction and infrared spectroscopy. The microstructure of the fibre was analysed by scanning electron microscopy and transmission electron microscopy, and the properties of the fibre were determined. The results showed that many conditions, such as calcination temperature and silica-sol content, have a pivotal influence on the crystal phase composition and morphology. By comparing the effects of these conditions, ceramic materials with exceptional properties have been prepared.
采用溶胶-凝胶法结合静电纺丝技术合成了具有纳米结构的LZ7C3纤维,并通过高温煅烧制备了耐高温LZ7C3陶瓷材料。研究了陶瓷纤维的形成过程,并用差热分析、x射线衍射和红外光谱对其性能进行了表征。采用扫描电镜和透射电镜对纤维的微观结构进行了分析,并对纤维的性能进行了测定。结果表明,煅烧温度和硅溶胶含量等条件对晶体相组成和形貌有重要影响。通过比较这些条件的影响,制备出了性能优异的陶瓷材料。
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引用次数: 0
Criticism of the paper titled ‘Solidification thermal parameters, microstructural evolution and dendritic growth in an AlCuNi alloy’ by Correa et al. 对Correa等人发表的题为“AlCuNi合金的凝固热参数、显微组织演变和枝晶生长”的论文的批评。
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-10-29 DOI: 10.1080/09500839.2021.1994160
M. Tiryakioğlu, Güven Kurtuldu
Recently, Correa et al. [1] conducted experiments on the relationship between solidification parameters, including solidification time ts and secondary dendrite arm spacing λ2, for an Al-3wt.%Cu-3wt.%Ni alloy. Their data for the ts λ2 relationship are presented in Figure 1. Note that there are two regions with very different slopes (i.e. the exponent of ts). The fit to the data by Correa et al. is presented in the figure. Note that the slope in the trend of the data, i.e. the exponent of solidification time, is 0.076 below ts = 70 s – a value significantly less than 1/3. At longer solidification times, the exponent of the solidification time is 0.251, a value approaching 1/3, which is consistent with coarsening. The reason for the existence of two distinct regions is unknown. Correa et al. applied the Rappaz-Boettinger [2] and Tiryakioğlu [3] models for the ts λ2 relationship to their dataset and reported that both models overestimated λ2 significantly. We note that Correa et al. used a surface tension value of 1.29 N/ m, rather than the solid–liquid interfacial energy, in their calculations. This is consistent with their previous studies [4]. We contend that the approach taken by Correa et al. is erroneous on account of the following reasons:
最近,Correa等人对al -3wt.%Cu-3wt进行了凝固参数(凝固时间ts与二次枝晶臂间距λ2)关系的实验。%镍合金。他们的ts λ2关系数据如图1所示。注意,有两个区域具有非常不同的斜率(即ts的指数)。Correa等人对数据的拟合结果如图所示。注意,数据趋势的斜率,即凝固时间指数,在ts = 70 s以下为0.076,这个值明显小于1/3。在较长凝固时间下,凝固时间的指数为0.251,接近1/3,与粗化一致。两个不同地区存在的原因尚不清楚。Correa等人将Rappaz-Boettinger[2]和Tiryakioğlu[3]模型用于其数据集的ts - λ2关系,并报道这两个模型都显著高估了λ2。我们注意到,Correa等人在计算中使用了1.29 N/ m的表面张力值,而不是固液界面能。这与他们之前的研究结果一致。我们认为Correa等人采用的方法是错误的,原因如下:
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引用次数: 0
In situ change of fractal structure in coal with coking capability during high-temperature carbonisation 具有炼焦能力的煤在高温炭化过程中分形结构的原位变化
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-10-29 DOI: 10.1080/09500839.2021.1995634
Yuexiang Wang, Zhihong Li, Jiao Kong, L. Chang, Yixin Zhao, Lili Dong, Baoliang Lv
ABSTRACT Coal is an important energy and chemical raw material. Carbonization is an effective way for comprehensive utilization of coal, especially for coal with coking capability. The complex pore structure of raw coal and its carbonization solid products can be well characterized by a fractal description. Owing to a lack of in situ studies, the change in the fractal structure of coal with coking capability during carbonization remains unclear. Here we report briefly on an in situ study on high-temperature (1000°C) carbonization of four kinds of Chinese typical bituminous coal with coking capability, namely gas coal, fat coal, coking coal and lean coal, by synchrotron radiation small-angle X-ray scattering (SAXS). The change of fractal structure of the coal is analyzed in terms of corresponding mechanisms.
摘要煤是一种重要的能源和化工原料。炭化是煤炭综合利用的有效途径,特别是对具有炼焦能力的煤炭。分形描述可以很好地表征原煤及其炭化固体产物的复杂孔隙结构。由于缺乏现场研究,具有炼焦能力的煤在炭化过程中分形结构的变化尚不清楚。本文简要报道了用同步辐射小角度X射线散射(SAXS)对四种具有炼焦性能的中国典型烟煤,即气煤、肥煤、焦煤和贫煤进行高温(1000°C)炭化的原位研究。从相应的机理分析了煤的分形结构的变化。
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引用次数: 2
Correlation between tensile strength and microstructural properties of LM6 semi-solid cast alloy ball-milled with Si-rich/Al powder 富硅/铝球磨LM6半固态铸造合金抗拉强度与显微组织性能的关系
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-10-11 DOI: 10.1080/09500839.2021.1986644
M. Agarwal, R. Srivastava
ABSTRACT This experimental study deals with the effect of modifying an Si-rich LM6 cast alloy by ball milling with Si/Al powder particulates in which alloying was conducted via semi-solid liquid processing. The cast alloys were analyzed via their tensile properties with a microstructural evaluation of their fractured surfaces. The tensile results reveal the influence of ball-milled Si-rich powdery chips on the cast materials and demonstrate an improvement in tensile properties for 10% (R = 0.1) and 25% (R = 0.25) addition of reinforcement particulates. The combined effect of processing and the presence of Si-rich particulates is identified on the fractured surfaces. The results also show that higher values of tensile stress and Young’s modulus are obtained for the R = 0.1 samples but that the strain was higher for the R = 0.25 samples. A mechanism and model for the tensile fracture, and particle and interface cracking are proposed according to microstructure and EDX observations.
摘要:本实验研究了采用半固液合金化工艺,用Si/Al粉末颗粒球磨改性富硅LM6铸造合金的效果。通过对合金的拉伸性能和断口表面的显微组织进行分析。拉伸实验结果表明,添加10% (R = 0.1)和25% (R = 0.25)的增强颗粒能改善铸态材料的拉伸性能。在断口表面发现了加工和富硅颗粒的共同作用。结果还表明,当R = 0.1时试样的拉应力和杨氏模量较高,而当R = 0.25时试样的应变较高。根据显微组织和EDX观察,提出了拉伸断裂、颗粒断裂和界面断裂的机理和模型。
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引用次数: 1
Microstructure refinement and high-temperature tensile properties of Mg–12Gd–3Y–0.5Zr alloy after equal channel angular pressing Mg–12Gd–3Y–0.5Zr合金等通道角挤压后的组织细化和高温拉伸性能
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-10-06 DOI: 10.1080/09500839.2021.1985733
N. Zhang, Hang Yang, X. Shao
ABSTRACT Grain refinement is significant for the mechanical properties of engineering alloys. We achieved a bi-ultrafine microstructure in an Mg–12Gd–3Y–0.5Zr alloy through equal channel angular pressing (ECAP) at 300°C. The ECAP not only refined the matrix grains but also broke the large intermetallic particles into fine secondary particles and then rearranged them at the grain boundaries. These fine particles can suppress the growth of the recrystallised grains, as well as promote nucleation for recrystallisation. After four passes of ECAP, a uniform microstructure with both the matrix grain (∼500 nm) and the particle size (∼300 nm) in the ultrafine range was obtained. This unique microstructure resulted in a good combination of strength (>300MPa) and elongation to failure (>35%) at 200°C, which sheds new light on refining microstructure to obtain good mechanical performance at elevated temperatures for Mg alloys.
晶粒细化对工程合金的力学性能具有重要意义。我们在300°C下通过等通道角挤压(ECAP)在Mg–12Gd–3Y–0.5Zr合金中获得了双超细组织。ECAP不仅细化了基体晶粒,而且将较大的金属间颗粒破碎成细小的二次颗粒,然后在晶界处重新排列。这些细颗粒可以抑制再结晶晶粒的生长,并促进再结晶的成核。经过四次ECAP后,获得了基体晶粒(~500nm)和粒度(~300nm)均在超细范围内的均匀微观结构。这种独特的微观结构使镁合金在200°C下具有良好的强度(>300MPa)和断裂伸长率(>35%),这为细化微观结构以在高温下获得良好的机械性能提供了新的线索。
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引用次数: 2
Nano-scale superelastic response of laser-welded NiTi shape-memory alloys 激光焊接NiTi形状记忆合金的纳米超弹性响应
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-10-03 DOI: 10.1080/09500839.2021.1972177
H. Vashishtha, D. Kumar, S. Neelakantan, J. Jain
ABSTRACT In this work, Ni-Ti shape-memory alloy (SMA) plates were laser welded using different laser powers. A systematic trend of decreasing deterioration in nanomechanical properties – including superelastic recovery – from the weld centre, through the interface region and the heat-affected zone to the base–metal regimes has been observed. The extent of the deterioration increases with increasing laser power. The observations are explained in terms of a decreasing cooling rate and increasing austenite finish temperature (Af ) with an increase in laser power.
本文采用不同的激光功率对镍钛形状记忆合金(SMA)板进行了激光焊接。已经观察到从焊接中心、通过界面区域和热影响区到基底金属状态,纳米机械性能(包括超弹性恢复)的退化呈系统趋势。退化的程度随着激光功率的增加而增加。观察结果是根据冷却速率的降低和奥氏体终饰温度(Af)随激光功率的增加而增加来解释的。
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引用次数: 1
Microstructural evolution and grain-growth kinetics of Al0.2CoCrFeNi high-entropy alloy Al0.2CoCrFeNi高熵合金的组织演变和晶粒生长动力学
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-09-29 DOI: 10.1080/09500839.2021.1975056
Srinivas Dudala, Chenna Krishna S, Rajesh Korla
ABSTRACT Grain-growth kinetics of high-entropy, single-phase, face-centred cubic (FCC) Al0.2CoCrFeNi alloy was studied by isothermal annealing over a wide temperature range for different time intervals. Both optical and EBSD studies show a significant amount of annealing twins. Data were analysed using classical grain-growth models and the activation energy was estimated using the Arrhenius type equation. The grain-growth exponent was found to be n = 3 and the measured activation energy for grain growth was 190 ± 15 kJ mol−1. Significant resistance to grain growth was observed at 1100°C. Microstructural characterisation tools like EBSD, along with nanoindentation, was used to understand the observed behaviour.
摘要采用宽温度范围、不同时间间隔的等温退火方法,研究了高熵单相面心立方(FCC)Al0.2CoCrFeNi合金的晶粒生长动力学。光学和EBSD研究都显示了大量的退火孪晶。使用经典的晶粒生长模型分析数据,并使用Arrhenius型方程估计活化能。发现晶粒生长指数为n = 3,测得的晶粒生长活化能为190 ± 15 kJ mol−1。在1100°C时观察到对谷物生长的显著抗性。使用EBSD等微观结构表征工具以及纳米压痕来了解观察到的行为。
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引用次数: 1
Study of desirable precipitate-strengthening effects on friction-stir welded joints of third-generation Al–Cu–Li alloys 第三代Al-Cu-Li合金搅拌摩擦焊接接头理想析出强化效果的研究
IF 1.2 4区 材料科学 Q3 Physics and Astronomy Pub Date : 2021-09-29 DOI: 10.1080/09500839.2021.1980833
Dongyao Wang, L. Zhan, Quan-qing Zeng, D. He, Kefu Gan
ABSTRACT A friction-stir welded Al–Cu–Li alloy plate with desirable mechanical performance has been obtained using specific parameters. The microstructures of the nugget zone were systematically characterised and nano-sized phases, including , and were found in its matrix. These phases enhance the strength of the joint to a level comparable with the base metal. The results provide the means of obtaining a reliable and low-cost friction-stir weld (FSW) joint for T3-tempered Al–Cu–Li alloy plates without any post-welding heat treatments. This study shows that, by using appropriate parameters of FSW, the microstructures and mechanical precipitates of the nugget zone can be controlled to enhance the weld quality.
采用特定的工艺参数,获得了力学性能良好的搅拌摩擦焊接铝铜锂合金板。对熔核区微观结构进行了系统表征,并在基体中发现了纳米相。这些相将接头的强度提高到与母材相当的水平。研究结果为在不进行焊后热处理的情况下获得可靠的低成本搅拌摩擦焊接接头提供了手段。研究表明,采用适当的摩擦焊参数可以控制熔核区的组织和力学相,从而提高焊接质量。
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引用次数: 3
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Philosophical Magazine Letters
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