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Comparative Characteristics of the Layering of Mafic–Ultramafic Intrusions of the Oulanka Group, Northern Karelia 北卡累利阿奥兰卡群镁铁质-超镁铁质岩体层状对比特征
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-15 DOI: 10.1134/S0869591122060091
A. R. Tskhovrebova, E. V. Koptev-Dvornikov, D. A. Bychkov

The Oulanka group is a compact group of three peridotite–gabbronorite intrusions that is convenient for testing various petrogenetic concepts. The three intrusions are similar in age and occur not far from one another but differ in the composition of their original magmas, are characterized by different sets of cumulus mineral assemblages, and are different in inner structure and rhythmic layering. We applied cluster analysis of the contents of major elements to reproduce the cumulus mineral assemblages of the isochemically altered rocks of the Tsipringa and Lukkulaisvaara massifs. Although the parental magmas of the Kivakka and Tsipringa massifs were of different composition and their crystallization sequences were also different, the vertical sections of these massifs can be clearly subdivided into zones according to their cumulus mineral assemblages, with the limited development of rhythmic interbedding (with individual rhythms ranging from a few to a few dozen meters in thickness). Conversely, the Lukkulaisvaara intrusion does not possess any clearly distinguishable cumulus zones, and large-scale rhythmic layering is traceable throughout the entire thickness of the massif (with rhythms ranging from a few dozen to a few hundred meters in thickness). The different character of the rhythmic layering of the three intrusions may provide an insight into the different scenarios of magma convection in the chambers.

奥兰卡群是由3个橄榄岩-辉长岩侵入体组成的致密群,便于检验各种岩石成因概念。三次侵入岩年龄相近,发生地点相距不远,但原始岩浆组成不同,具有不同套积云矿物组合特征,内部构造和韵律分层也不同。利用主元素含量的聚类分析,重现了齐普林加和卢卡库莱斯瓦拉地块等化学蚀变岩的积云矿物组合。Kivakka和Tsipringa地块的母岩浆虽然成分不同,结晶序列也不同,但根据它们的积云矿物组合,在垂向剖面上可以清晰地划分成带,韵律互层发育有限(单个韵律厚度从几米到几十米不等)。相反,Lukkulaisvaara岩体没有任何明显可区分的积云带,在整个地块厚度上都可以追踪到大规模的有节奏分层(厚度从几十米到几百米不等)。三次侵入岩的韵律层理特征不同,可为岩浆在岩浆室中对流的不同情况提供线索。
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引用次数: 0
The Effect of CO2 Reduction in Low-Water Melts at Low Hydrogen Fugacity: Experiment at 500 MPa and Thermodynamic Model 低氢逸度低水熔体中CO2还原的影响:500 MPa实验和热力学模型
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-15 DOI: 10.1134/S0869591122060078
A. G. Simakin, V. N. Devyatova, G. V. Bondarenko

Formation of graphite was observed in experiments on synthesis of dry carbon-bearing albite glasses in platinum capsules in an Internally Heated Pressure Vessel at 500 MPa and Т = 1200–1250°С. A thermodynamic model is proposed that explains the achievement of low oxygen fugacity near QFM-2 in the melt at low fugacity of hydrogen formed due to the decomposition of trace amounts of water in a compression medium (Ar gas). The unexpectedly low fugacity of oxygen is explained by the shift of equilibrium between the gases dissolved in the melt CO2 + H2 = H2O + CO to the right due to the low activity of molecular water at a low total content of H2O ~ 0.1–0.5 wt %. The high local СО concentrations in the melt lead to the platinum dissolution in form of carbonyl, corrosion of capsule walls, and redeposition of the metal at the contact with melt. With increase of water concentration in the melt (>1 wt %), the effect of reduction disappears.

在内热压力容器中,在500 MPa和Т = 1200 ~ 1250°С条件下,用铂胶囊合成干含碳钠长石玻璃,观察了石墨的形成。提出了一个热力学模型,解释了熔体在QFM-2附近低氧逸度的实现,这是由于在压缩介质(Ar气体)中分解微量水而形成的氢的低逸度。氧的逸度之所以如此之低,是由于在H2O总含量(0.1-0.5 wt %)低的情况下,水分子的活度较低,导致熔体中溶解的气体CO2 + H2 = H2O + CO的平衡向右移动。熔体中较高的СО局部浓度导致铂以羰基形式溶解,胶囊壁腐蚀,金属在与熔体接触处再沉积。随着熔体中水浓度的增加(1 wt %),还原效果消失。
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引用次数: 0
Eastern Margin of the Neoarchean Tunguska Superterrane: Data from Boreholes in the Central Part of the Siberian Platform 新太古代通古斯超级地体的东缘:西伯利亚地台中部钻孔资料
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-15 DOI: 10.1134/S0869591122050058
A. V. Samsonov, K. G. Erofeeva, Yu. O. Larionova, A. N. Larionov, N. B. Kuznetsov, T. V. Romanyuk, N. V. Solovyova, O. M. Zhilicheva, A. S. Dubenskiy, V. S. Sheshukov

The paper presents data on granites and gneisses recovered by Kulindinskaya-1 hole drilled in the central part of the Siberian Craton. The biotite granites retain a porphyritic texture, correspond to I-type according to their compositional features, are enriched in LREE and moderately depleted in HREE, and have negative Eu, Sr, and Nb and positive Zr anomalies. The U−Pb zircon age of the granites is Neoarchean (2525 ± 10 Ma), with single cores of zircon grains dated at about 2.6 Ga, which likely suggests a crustal source of the granitic magmas. The model age TNd(DM) = 2.77 Ga of the granite shows that the crust from which the initial melts were derived had been formed shortly before the melting episode. In terms of age and all characteristics, the granites are close to those of the Yurubchen massif, which was drilled through in the western part of the Tunguska superterrane. The biotite gneiss was apparently derived from sedimentary rocks and was heavily reworked when the granites were emplaced. The enrichment of the gneiss in Cr and Ni is probably inherited from the sedimentary protolith, whereas the REE, HFSE, and LILE concentrations and distribution in the gneiss are similar to those of the granite. The concordant (D < 1%) U−Pb zircon ages (according to LA-ICP-MS data) broadly vary from 3284 to 2620 Ma, with two major peaks at 2717 and 2678 Ma. The model age of the gneiss TNd(DM) = 2.91 Ga confirms a contribution of the ancient crustal component to the sedimentary protolith of the rock. The minimum age of the detrital zircon, 2.62 Ga, determines the maximum age limit for sedimentation, and the minimum age limit is set by the age of the granite intrusions at 2.53 Ga. According to our data, the Archean gneisses and granites recovered by the Kulindinskaya-1 drillhole probably compose the eastern part of the Neoarchean Tunguska superterrane. Ereminskaya-101 drillhole, which was drilled 20 km northeast of Kulindinskaya-1, recovered gneisses with model ages TNd(DM) from 2.30 to 2.37 Ga, which belong to the adjacent Taimyr−Baikal suture zone with widespread Paleoproterozoic rocks. The contrasting crustal history of the adjacent complexes provides grounds to suggest that they were tectonically combined, which is an additional reason to consider the Taimyr−Baikal suture zone as a Paleoproterozoic collisional orogen.

本文介绍了在西伯利亚克拉通中部钻取的Kulindinskaya-1孔所恢复的花岗岩和片麻岩资料。黑云母花岗岩呈斑岩状,组成特征为i型,重稀土富集,重稀土中度亏缺,Eu、Sr、Nb呈负异常,Zr呈正异常。花岗岩的U - Pb锆石年龄为新太古代(2525±10 Ma),单核锆石颗粒年龄约为2.6 Ga,可能为地壳岩浆来源。花岗岩的模型年龄TNd(DM) = 2.77 Ga,表明产生初始熔体的地壳是在熔化期前不久形成的。花岗岩的年龄和各项特征与通古斯超地体西部钻穿的于鲁沁地块接近。黑云母片麻岩明显来源于沉积岩,并在花岗岩就位时被大量改造。片麻岩中Cr和Ni的富集可能继承自沉积原岩,而片麻岩中的REE、HFSE和LILE的浓度和分布与花岗岩相似。协和(D <U−Pb锆石年龄(根据LA-ICP-MS数据)在3284 ~ 2620 Ma之间变化较大,其中两个主要峰位于2717和2678 Ma。片麻岩的模式年龄TNd(DM) = 2.91 Ga,证实了古地壳成分对岩石沉积原岩的贡献。碎屑锆石的最小年龄为2.62 Ga,决定了沉积的最大年龄限制;花岗岩侵入物的最小年龄为2.53 Ga。根据我们的资料,Kulindinskaya-1钻孔恢复的太古代片麻岩和花岗岩可能构成了新太古代通古斯超级地体的东部。在Kulindinskaya-1东北方向20km处的Ereminskaya-101钻孔,发现片麻岩模式年龄TNd(DM)为2.30 ~ 2.37 Ga,属于邻近的Taimyr - Baikal缝合带,古元古代岩石分布广泛。相邻杂岩体的对比地壳历史提供了它们是构造组合的依据,这是将泰米尔-贝加尔湖缝合带视为古元古代碰撞造山带的另一个理由。
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引用次数: 1
Tantalite Solubility in Granitoid Melts and Evaluation of the Ta and Nb Diffusion Coefficients 花岗岩熔体中钽的溶解度及Ta、Nb扩散系数的评定
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-15 DOI: 10.1134/S0869591122060030
V. Yu. Chevychelov

The paper presents experimental data on tantalite solubility in water-saturated granitoid melts with various alumina and alkaline elements concentrations at T = 650–850°C and P = 100 MPa. The maximum Ta concentration (effective solubility) in melt is shown to be always higher than the Nb concentration. As the melt composition is changed from alkaline to Al2O3-enriched, the Ta and Nb concentrations decrease by one to two orders of magnitude, and the Nb/Ta ratio simultaneously decreases (from ~0.8–0.7 to ~0.4–0.1) because the Nb concentration decreases notably more rapidly than that of Ta. This effect is enhanced at decreasing temperature. The effective Ta solubility in melt is demonstrated to be practically independent of the composition of the dissolving mineral of the columbite-tantalite series. The Ta, Nb, Mn, and Fe diffusion coefficients in granitoid melts are estimated. The Ta and Nb diffusion coefficients at T = 750°C and P = 100 MPa are ~10–10 cm2/s, and those of Fe and Mn are ~10–8.5 cm2/s. With an increase in temperature from 740 to 980°C, all of the diffusion coefficients increase by approximately 1.5 orders of magnitude. The configurations of the diffusion profiles of Ta concentration in melts change differently depending on change in the composition of the melt, temperature, or pressure.

本文介绍了在T = 650 ~ 850℃,P = 100 MPa条件下,不同氧化铝和碱性元素浓度的水饱和花岗岩熔体中钽铁矿溶解度的实验数据。熔体中Ta的最大浓度(有效溶解度)总是高于Nb的浓度。随着熔体成分由碱性向al2o3富集转变,Ta和Nb浓度下降了1 ~ 2个数量级,Nb/Ta比值同时下降(从~0.8 ~ 0.7降至~0.4 ~ 0.1),因为Nb浓度的下降速度明显快于Ta。这种效应在温度降低时增强。熔体中Ta的有效溶解度实际上与钶钽铁矿系列溶解矿物的组成无关。估算了花岗岩熔体中Ta、Nb、Mn和Fe的扩散系数。T = 750℃,P = 100 MPa时,Ta和Nb的扩散系数为~10 ~10 cm2/s, Fe和Mn的扩散系数为~10 ~ 8.5 cm2/s。当温度从740℃升高到980℃时,所有的扩散系数都增加了大约1.5个数量级。熔体中Ta浓度扩散曲线的形态随熔体成分、温度或压力的变化而发生不同的变化。
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引用次数: 0
Re-Os Isotope and HSE Abundance Systematics of the 2.9 Ga Komatiites and Basalts from the Sumozero-Kenozero Greenstone Belt, SE Fennoscandian Shield: Implications for the Mixing Rates of the Mantle Fennoscandian Shield东南sumo0 - kenozero绿岩带2.9 Ga科马提岩和玄武岩Re-Os同位素和HSE丰度系统:地幔混合速率的意义
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-15 DOI: 10.1134/S0869591122060054
Igor S. Puchtel

Rhenium-Os isotope and highly siderophile element (HSE, including Re, Os, Ir, Ru, Pt, and Pd) abundance systematics of Archean komatiites can be used to estimate the stirring rates of the mantle for the HSE and the timing of homogenization of late accreted materials within the mantle. In this study, we report Re-Os isotope and HSE abundance data for ~2.9 Ga komatiites and basalts from the Sumozero-Kenozero greenstone belt in the SE Fennoscandian Shield. The lavas are characterized by excellent preservation of the primary textural, chemical, and Re-Os isotope characteristics. The Re-Os isotopic data for spinifex-textured and cumulate komatiite and massive basalt samples from the lowermost sequences define a precise 10-point isochron (MSWD = 2.6) with an age of 2904 ± 18 Ma and an initial 187Os/188Os = 0.10758 ± 18 (γ187Os(2904) = +0.45 ± 0.17). This is the first direct age determination for the Sumozero-Kenozero lower komatiite-basalt sequences. Our modeling indicates that the mantle source of the komatiites and basalts evolved with a time-integrated 187Re/188Os = 0.418 ± 6. This ratio is well within the uncertainty of the bulk chondritic average 187Re/188Os = 0.410 ± 51 (2SD), also consistent with the chondritic evolution of the majority of komatiite mantle sources observed globally. The mantle source of the Sumozero-Kenozero komatiites has been calculated to contain the total HSE abundances of 58 ± 7% of those in the estimates for modern Bulk Silicate Earth (BSE). This estimate is in the middle of the range for other late Archean and Proterozoic komatiite systems. Using the estimated HSE abundances in the sources of komatiite systems as a function of their ages and ISOPLOT regression analysis, we calculated the average time in the past by which late accreted materials have been completely homogenized within the mantle to be 2.48 ± 0.23 Ga. These data require that the residence times of the late accreted planetesimals within the mantle, before complete homogenization, were on average 1.92 ± 0.23 Ga. This estimate represents a constraint on the average mixing rates of the mantle in terms of the HSE abundances in the Hadean and the Archean.

太古宙科马长岩的铼-Os同位素和高亲铁元素(HSE,包括Re、Os、Ir、Ru、Pt和Pd)丰度系统可用于估算地幔对HSE的搅拌速率和地幔内晚期吸积物质的均匀化时间。本文报道了芬诺斯坎德地盾东南部sumo0 - kenozero绿岩带~2.9 Ga花岗岩和玄武岩的Re-Os同位素和HSE丰度数据。火山岩的主要特征是原始结构、化学和Re-Os同位素特征保存完好。从最下层的层序中得到的尖晶石纹理和堆积的科马铁矿和块状玄武岩样品的Re-Os同位素数据定义了一个精确的10点等时线(MSWD = 2.6),年龄为2904±18 Ma,初始187Os/188Os = 0.10758±18 (γ187Os(2904) = +0.45±0.17)。这是首次对sumo0 - kenozero下科马铁矿-玄武岩层序进行直接年龄测定。模拟结果表明,科马长岩和玄武岩的地幔源演化时间积分为187Re/188Os = 0.418±6。该比值完全符合总体球粒陨石平均值187Re/188Os = 0.410±51 (2SD)的不确定度,也与全球观测到的大多数科马地岩地幔源球粒陨石演化一致。经计算,sumo0 - kenozero科马岩源幔源中HSE总丰度为现代块状硅酸盐土(BSE)估算值的58±7%。对其他晚太古宙和元古宙的科马岩系的估算值处于中等范围。利用估算的科马地岩源中HSE丰度与年龄的函数关系和ISOPLOT回归分析,我们计算出过去晚期吸积物质在地幔内完全均匀化的平均时间为2.48±0.23 Ga。这些数据表明,在完全均匀化之前,晚期吸积星子在地幔内的停留时间平均为1.92±0.23 Ga。根据冥古宙和太古宙的HSE丰度,这一估计代表了对地幔平均混合率的限制。
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引用次数: 2
The Kulikovs: A Family of Geologists. Vyacheslav Stepanovich Kulikov, Viktoria Vladimirovna Kulikova, and Yana Vyacheslavovna Bychkova (Kulikova) 库利科夫家族:地质学家家族。Vyacheslav Stepanovich Kulikov、Viktoria Vladimirovna Kulikova和Yana Vyachesravovna Bychkova
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-15 DOI: 10.1134/S0869591122060108
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引用次数: 0
Mineralogical, Geochemical, and Nd-Sr Isotope Characteristics of Amphibolites from the Alag-Khadny High-Pressure Complex (SW Mongolia): Intracontinental Rifting as a Precursor of Continental-Margin Subduction 来自 Alag-Khadny 高压复合体(蒙古西南部)的闪长岩的矿物学、地球化学和钕-锶同位素特征:大陆内部断裂是大陆边缘俯冲的前兆
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-09-06 DOI: 10.1134/S0869591122040051
S. Yu. Skuzovatov, M. A. Gornova, A. A. Karimov
<div><p>Within subduction-accretion complexes, high-pressure rocks (blueschists, eclogites) are commonly juxtaposed with lower-grade rocks, which represent their retrograded counterparts or were involved into accretionary event at later stages, and thus characterize distinct stages of evolution of accretionary belts. In SW Mongolia, the Central Asian Orogenic Belt includes Neoproterozoic–Early Paleozoic paleosubduction complexes represented by eclogites and associated rocks of the Alag-Khadny accretionary complex. This paper reports the results of mineralogical, geochemical and isotopic studies of amphibolites from this complex, the geochemical nature and relationships of which with eclogites have been yet uncertain. The texture of the studied rocks varies from fine- and medium-grained granoblastic and nematoblastic amphibole–plagioclase–epidote rocks to medium-grained nematoblastic amphibole–epidote–albite–titanite amphibolites, which experienced intense recrystallization as a response to late deformations. Primary assemblages include pargasite and Mg-hornblende (<sup>[B]</sup>Na = 0.07–0.16, <sup>IV</sup>Al = 0.79–1.69, <sup>[A]</sup>(Na + K + 2Ca) = 0.14–0.64, <sup>[C]</sup>(Al+ Ti + Fe<sup>3+</sup>) = 0.58–1.29, Fe<sup>2+</sup>/(Fe<sup>2+</sup> + Mg) = 0.18–0.46 at Fe<sup>3+</sup>/(Fe<sup>3+</sup>+Al) = 0.18–0.77), low-to-medium-Ca plagioclase (<i>An</i><sub>24–36</sub>), and epidote–clinozoisite (0.08 < <span>({{X}_{{{text{F}}{{{text{e}}}^{{{text{3 + }}}}}}}})</span> < 0.16), whereas the retrograde assemblage is represented by albite and Mg-hornblende. Calculations using amphibole composition and amphibole/amphibole–plagioclase thermobarometry revealed peak <i>P-T</i> conditions up to 570–630°С and 7–9 kbar ascribed to the high-<i>T</i> epidote-amphibolite facies with subsequent greenschist-facies retrogression. The major-element composition of the amphibolites corresponds to low-alkali moderate-Ti tholeiites, although their trace-element composition varies significantly from N-MORB to E-MORB-type basalts, which are variably enriched in LREE, Nb, Ta, Th, U, and show negative Eu and Ti anomalies due to fractionation of parental melts for precursor rocks. Isotopic composition of Nd (ε<sub>Nd</sub>(550) from +5.1 to –9.1) and Sr ((<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>550</sub> = 0.7057–0.7097) indicates distinct mainly moderately-depleted nature of mantle sources for the mafic rocks, but also highlights the involvement of “anomalous” mantle domains with unradiogenic Nd composition. The data supports that the precursor rocks of the amphibolites were formed during intracontinental extension of a continental margin, which was likely linked to opening of a limited Neoproterozoic oceanic basin with a subsequent Late Vendian–Early Cambrian convergence. The medium- to high-pressure metamorphism of amphibolites had similar <i>P-T</i> conditions to that of retrograde metamorphism of eclogites and associated metasediments and was directly related t
在俯冲-增生复合体中,高压岩(蓝闪长岩、斜长岩)通常与低品位岩并置,后者代表其逆退的对应岩,或在后期卷入增生事件,因此是增生带演化的不同阶段的特征。在蒙古西南部,中亚造山带包括新元古代-早古生代的古俯冲复合体,其代表是闪长岩和阿拉格-哈德尼增生复合体的伴生岩。本文报告了对这一复合体中的闪长岩进行矿物学、地球化学和同位素研究的结果。所研究岩石的质地各不相同,有细粒和中粒粒状和线粒状闪石-斜长石-橄榄石岩石,也有中粒状线粒状闪石-橄榄石-赤铁矿-钛铁矿闪长岩,这些岩石在晚期变形过程中经历了强烈的再结晶。原生组合包括辉石和镁角闪石([B]Na = 0.07-0.16, IVAl = 0.79-1.69, [A](Na + K + 2Ca) = 0.14-0.64, [C](Al+ Ti + Fe3+) = 0.58-1.29, Fe2+/(Fe2+ + Mg) = 0.18-0.46 at Fe3+/(Fe3++Al) = 0.18-0.77.77)、低到中等Ca的斜长石(An24-36)和闪石-闪长岩(0.08 < ({{X}_{text{F}}{{text{e}}}^{{text{3 + }}}}}}}}) < 0.16),而逆行集合体则以白云石和镁角闪石为代表。利用闪石成分和闪石/闪石-斜长石热压仪进行的计算显示,峰值P-T条件可达570-630°С和7-9千巴,归因于高T的闪石-斜长石面,随后出现绿辉石派逆变。闪长岩的主要元素组成与低碱中钛透辉岩一致,但其痕量元素组成从N-MORB到E-MORB型玄武岩差异很大,LREE、Nb、Ta、Th、U元素不同程度富集,Eu和Ti元素呈现负异常,这是由于前驱岩的母熔体分馏造成的。钕(εNd(550)从+5.1到-9.1)和锶((87Sr/86Sr)550 = 0.7057-0.7097)的同位素组成表明,岩浆岩的地幔源主要具有明显的中度贫化性质,但也突出了具有非辐射钕组成的 "异常 "地幔域的参与。这些数据支持了闪长岩的前身岩石是在大陆边缘的大陆内延伸过程中形成的,这很可能与一个有限的新元古代大洋盆地的开辟以及随后的晚文武世-早寒武世的汇聚有关。闪长岩的中高压变质作用与斜长岩及相关基岩的逆行变质作用具有相似的P-T条件,与早古生代的俯冲-充填变质作用(约550-540Ma)直接相关,或者是湖泊带与Dzabkhan地层之间的构造混杂带(约515-490Ma或更年轻)形成过程中最终增生的结果。
{"title":"Mineralogical, Geochemical, and Nd-Sr Isotope Characteristics of Amphibolites from the Alag-Khadny High-Pressure Complex (SW Mongolia): Intracontinental Rifting as a Precursor of Continental-Margin Subduction","authors":"S. Yu. Skuzovatov,&nbsp;M. A. Gornova,&nbsp;A. A. Karimov","doi":"10.1134/S0869591122040051","DOIUrl":"10.1134/S0869591122040051","url":null,"abstract":"&lt;div&gt;&lt;p&gt;Within subduction-accretion complexes, high-pressure rocks (blueschists, eclogites) are commonly juxtaposed with lower-grade rocks, which represent their retrograded counterparts or were involved into accretionary event at later stages, and thus characterize distinct stages of evolution of accretionary belts. In SW Mongolia, the Central Asian Orogenic Belt includes Neoproterozoic–Early Paleozoic paleosubduction complexes represented by eclogites and associated rocks of the Alag-Khadny accretionary complex. This paper reports the results of mineralogical, geochemical and isotopic studies of amphibolites from this complex, the geochemical nature and relationships of which with eclogites have been yet uncertain. The texture of the studied rocks varies from fine- and medium-grained granoblastic and nematoblastic amphibole–plagioclase–epidote rocks to medium-grained nematoblastic amphibole–epidote–albite–titanite amphibolites, which experienced intense recrystallization as a response to late deformations. Primary assemblages include pargasite and Mg-hornblende (&lt;sup&gt;[B]&lt;/sup&gt;Na = 0.07–0.16, &lt;sup&gt;IV&lt;/sup&gt;Al = 0.79–1.69, &lt;sup&gt;[A]&lt;/sup&gt;(Na + K + 2Ca) = 0.14–0.64, &lt;sup&gt;[C]&lt;/sup&gt;(Al+ Ti + Fe&lt;sup&gt;3+&lt;/sup&gt;) = 0.58–1.29, Fe&lt;sup&gt;2+&lt;/sup&gt;/(Fe&lt;sup&gt;2+&lt;/sup&gt; + Mg) = 0.18–0.46 at Fe&lt;sup&gt;3+&lt;/sup&gt;/(Fe&lt;sup&gt;3+&lt;/sup&gt;+Al) = 0.18–0.77), low-to-medium-Ca plagioclase (&lt;i&gt;An&lt;/i&gt;&lt;sub&gt;24–36&lt;/sub&gt;), and epidote–clinozoisite (0.08 &lt; &lt;span&gt;({{X}_{{{text{F}}{{{text{e}}}^{{{text{3 + }}}}}}}})&lt;/span&gt; &lt; 0.16), whereas the retrograde assemblage is represented by albite and Mg-hornblende. Calculations using amphibole composition and amphibole/amphibole–plagioclase thermobarometry revealed peak &lt;i&gt;P-T&lt;/i&gt; conditions up to 570–630°С and 7–9 kbar ascribed to the high-&lt;i&gt;T&lt;/i&gt; epidote-amphibolite facies with subsequent greenschist-facies retrogression. The major-element composition of the amphibolites corresponds to low-alkali moderate-Ti tholeiites, although their trace-element composition varies significantly from N-MORB to E-MORB-type basalts, which are variably enriched in LREE, Nb, Ta, Th, U, and show negative Eu and Ti anomalies due to fractionation of parental melts for precursor rocks. Isotopic composition of Nd (ε&lt;sub&gt;Nd&lt;/sub&gt;(550) from +5.1 to –9.1) and Sr ((&lt;sup&gt;87&lt;/sup&gt;Sr/&lt;sup&gt;86&lt;/sup&gt;Sr)&lt;sub&gt;550&lt;/sub&gt; = 0.7057–0.7097) indicates distinct mainly moderately-depleted nature of mantle sources for the mafic rocks, but also highlights the involvement of “anomalous” mantle domains with unradiogenic Nd composition. The data supports that the precursor rocks of the amphibolites were formed during intracontinental extension of a continental margin, which was likely linked to opening of a limited Neoproterozoic oceanic basin with a subsequent Late Vendian–Early Cambrian convergence. The medium- to high-pressure metamorphism of amphibolites had similar &lt;i&gt;P-T&lt;/i&gt; conditions to that of retrograde metamorphism of eclogites and associated metasediments and was directly related t","PeriodicalId":20026,"journal":{"name":"Petrology","volume":"30 5","pages":"523 - 544"},"PeriodicalIF":1.5,"publicationDate":"2022-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4279408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metasomatized Xenoliths of Mantle Eclogites and Garnet Pyroxenites from the V. Grib Kimberlite, Arkhangelsk Province 阿尔汉格尔斯克省V. Grib金伯利岩中地幔榴辉岩和石榴石辉石岩的交代捕虏体
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-09-06 DOI: 10.1134/S0869591122050046
N. M. Lebedeva, A. A. Nosova, L. V. Sazonova, Y. O. Larionova

We investigated mantle eclogite and garnet pyroxenite xenoliths from the V. Grib kimberlite located in the Arkhangelsk diamond province. The eclogites in the lithospheric mantle beneath the Arkhangelsk province were strongly modified by metasomatic processes, which totally obliterated the primary features of protolith. Detailed studies of the xenoliths allowed us to distinguish the following metasomatic events: (1) early mantle metasomatism and (2) interaction with kimberlite melt. During the multiple early mantle metasomatism, primary clinopyroxene and garnet were replaced by metasomatic clinopyroxene, garnet, amphibole, calcite, and phlogopite under the influence of carbonated ultramafic melts. The impact of kimberlite melt caused the dissolution and recrystallisation of solid-phase inclusions and formation of melt pockets consisting of serpentine, chlorite, carbonate, spinel, perovskite, amphibole, recrystallized garnet, and clinopyroxene. En route to the surface in kimberlite melt, the xenoliths were disintegrated and primary garnet and clinopyroxene were metasomatized with increasing Ti and Cr contents, up to formation of high-Cr megacrysts. The garnet pyroxenites are represented by high-Ca, low-Mg and low-Ca, high-Mg types. It is shown that the high-Ca, low-Mg garnet pyroxenites can be the final products of the eclogite xenolith metasomatism by carbonated ultramafic melts. The low-Ca, high-Mg pyroxenites were derived through the interaction of a partial eclogite melt with depleted peridotites.

研究了位于阿尔汉格尔斯克钻石省V. Grib金伯利岩的地幔榴辉岩和石榴石辉石岩包体。阿尔汉格尔斯克省岩石圈地幔中的榴辉岩受到交代作用的强烈改造,完全湮没了原岩的基本特征。对包体的详细研究使我们能够区分以下交代事件:(1)早期地幔交代作用和(2)与金伯利岩熔体的相互作用。在早期地幔的多次交代作用中,受碳酸盐超镁铁质熔体的影响,原生斜辉石和石榴石被交代斜辉石、石榴石、角闪石、方解石和辉云母所取代。金伯利岩熔体的影响导致固相包裹体的溶解和再结晶,形成由蛇纹石、绿泥石、碳酸盐、尖晶石、钙钛矿、角闪孔、再结晶石榴石和斜辉石组成的熔体袋。在金伯利岩熔体走向地表的过程中,捕虏体破碎,原生石榴石和斜辉石随着Ti和Cr含量的增加而交代,最终形成高Cr巨晶。石榴石辉石岩分为高钙低镁型和低钙高镁型。结果表明,高钙、低镁石榴石辉石岩可能是超镁质碳酸盐熔体对榴辉岩捕虏体交代作用的最终产物。低钙、高镁辉石岩是部分榴辉岩熔体与贫橄榄岩相互作用形成的。
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引用次数: 1
Composition and Isotope Parameters of Metabasalts and Gabbroids of the Onot Granite–Greenstone Block, Southwestern Siberian Platform, as Indicators of Lithospheric Mantle Evolution from the Archean to Paleoproterozoic 西伯利亚地台西南部奥诺特花岗岩-绿岩块的元基岩和辉长岩的成分和同位素参数,作为岩石圈地幔从奥陶纪到古近纪演化的指标
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-09-06 DOI: 10.1134/S0869591122040063
O. M. Turkina, A. E. Izokh, A. V. Lavrenchuk, Ya. Yu. Shelepov

The paper summarizes major and trace-element compositions and Sm–Nd isotope data on metabasites (amphibolites) and gabbroids of the Onot granite–greenstone block in the Sharyzhalgai basement uplift, southwestern Siberian craton. The Onot block consists of tectonically combined nappes of the Paleoarchean tonalite–trondhjemite–granodiorite (TTG) complex and the metasedimentary-volcanic complex of the greenstone belt (GB). The Mezoarchean (∼2.88 Ga) metabasalts of the greenstone belt and Paleoproterozoic (∼1.86 Ga) gabbronorites and vein gabbros were formed at rifting and postcollisional extension, respectively. The Archean metabasites of the greenstone belt and enclaves in the TTG complex compositionally correspond to low-Ti tholeiitic basalts and basaltic andesites. The basaltic rocks are characterized by flat REE patterns [(La/Sm)n = 0.9–1.9], depletion in Nb relative to Th and La (Nb/Nb* = 0.4–1.1), and a wide range of mostly positive εNd(T) values (from +5.2 to –1.0). The enrichment of the basaltic andesite in incompatible elements, its Eu minimum, and negative εNd(T) values resulted from contamination by Paleoarchean TTG gneisses, that form the basement of GB. The Paleoproterozoic gabbronorites have high Mg# and extremely low concentrations of Ti and incompatible elements. The rocks are characterized by low (Nb/Y) (0.8–1.0), negative εNd(T) values (from 0 to –1.4), and weak enrichment in Th and LREE relative to Nb. The vein gabbros have low (La/Sm)n, positive εNd(T) values of +2.8 and +0.3, and a negative Nb anomaly (Nb/Nb* = 0.3–0.4). The trace element-composition of the amphibolites, gabbronorites, and gabbros and the results of geochemical modeling indicate that the parental melts were derived mainly from weakly depleted mantle sources. The Nd isotope composition of the Paleoproterozoic gabbroids resulted from the evolution of the heterogeneous Archean lithospheric mantle. Variations in the isotope and trace-element composition of the amphibolites reflect the initially depleted nature of the Mezoarchean mantle and its metasomatic alteration by fluids/melts, which occurred before its melting at ∼2.88 Ga. The geochemical and Nd isotopic characteristics of gabbronorites and gabbros indicate that the lithospheric mantle had become progressively more heterogeneous by the Paleoproterozoic due to preceding Archean processes. The variable depletion of both the Archean and the Paleoproterozoic mafic rocks in Nb relative to Th and La may be explained by mantle metasomatism and does not reflect the geodynamic settings of the mafic magmatism.

本文概述了西伯利亚环形山西南部 Sharyzhalgai 基底隆起区 Onot 花岗岩-绿岩地块的主要元素和痕量元素组成以及 Sm-Nd 同位素数据。奥诺特区块由古新世的碳酸盐岩-特朗杰米岩-花岗闪长岩(TTG)复合体和绿岩带(GB)的变质岩-火山岩复合体的构造组合页岩组成。绿岩带的美宙(2.88 Ga ∼2.88Ga)变玄武岩和古近纪的(1.86 Ga ∼1.86Ga)榴辉岩和脉辉长岩分别形成于断裂和碰撞后延伸时期。TTG复合体中绿岩带和飞地的阿新世代谢岩在成分上与低钛托勒密玄武岩和玄武安山岩相对应。玄武岩的特征是REE形态平坦[(La/Sm)n = 0.9-1.9],相对于Th和La,Nb贫化(Nb/Nb* = 0.4-1.1),εNd(T)值范围宽广,大部分为正值(从+5.2到-1.0)。玄武安山岩中不相容元素的富集、Eu的最小值以及εNd(T)的负值都是由古新世TTG片麻岩污染造成的,而古新世TTG片麻岩构成了GB的基底。古新生代榴辉岩具有高Mg#和极低的Ti及不相容元素浓度。岩石的特征是低(Nb/Y)PМ(0.8-1.0)、负εNd(T)值(从0到-1.4),以及相对于Nb的弱Th和LREE富集。脉辉长岩的(La/Sm)n较低,εNd(T)值为+2.8和+0.3,Nb异常为负值(Nb/Nb* = 0.3-0.4)。闪长岩、榴辉岩和辉长岩的微量元素组成以及地球化学建模结果表明,母体熔体主要来自弱贫化地幔源。古近纪辉长岩的钕同位素组成是由异质的阿新世岩石圈地幔演化形成的。闪长岩的同位素和痕量元素组成的变化反映了梅索阿尔奇岩地幔最初的贫化性质及其在2.88 Ga∼熔融之前发生的流体/熔体的元气蚀变。榴辉岩和辉长岩的地球化学特征和钕同位素特征表明,岩石圈地幔在古近纪时由于之前的阿契安过程而逐渐变得更加异质。相对于Th和La而言,阿新世和古近古生代岩浆岩的Nb贫化程度不同,这可能是地幔变质作用造成的,并不反映岩浆岩形成的地球动力学环境。
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引用次数: 2
Pauzhetka Caldera (South Kamchatka): Еxploring Temporal Evolution and Origin of Voluminous Silicic Magmatism 南堪察加保哲特卡火山口:Еxploring大体积硅质岩浆作用的时间演化与成因
IF 1.5 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-09-06 DOI: 10.1134/S0869591122050022
V. O. Davydova, I. N. Bindeman, M. D. Shchekleina, S. N. Rychagov

The Pauzhetka Caldera (27 × 18 km) was formed in the South Kamchatka during the Golygin Ignimbrite eruption (420–440 ka), the largest known eruption in the region in the past 1 Myr. The eruption was preceded by the 3 Ma-old mafic and intermediate volcanism. After the caldera-forming eruption, a variety of products, from basalt to rhyolite, were ejected within the caldera. For understanding the origin of voluminous silicic magmatism in thin mafic South Kamchatka crust, we used geochemical and isotope data. Our research has characterized the major and trace element composition of Golygin ignimbrite, intra-caldera hydrothermally altered deposits, pre-caldera (Mt. Orlinoe Krylo, Mt. Klyuchevskaya) and post-caldera (Kambalny Ridge, Chernye Skaly) eruptive centers. The Sr–Nd isotope composition of the Golygin ignimbrite and some eruptive post-caldera products was investigated. The isotope variations indicate that parental magmas for all rocks of the Pauzhetka area were obtained from a weakly evolved source derived through fluid-assisted melting of a subducted slab. Geochemical data support that the formation of most magmas of the Pauzhetka caldera was mainly controlled by fractional crystallization in the lower to middle crust. MELTS-modelling agrees with geochemical data. The fractional crystallization of Kambalny basalt with 2 wt % H2O at 6 kbar provides the best fit to the observed composition of the Golygin dacite.

保哲特卡火山口(27 × 18公里)是在南堪察加半岛的Golygin Ignimbrite火山喷发(420-440 ka)期间形成的,这是该地区过去1世纪以来已知的最大火山喷发。喷发前为3 Ma-old的基性和中期火山作用。形成破火山口后,从玄武岩到流纹岩等各种产物在破火山口内喷射出来。为了了解南堪察加薄基性地壳中大量硅质岩浆活动的成因,我们利用地球化学和同位素资料进行了研究。我们研究了Golygin火成岩、破火山口内热液蚀变矿床、破火山口前(Mt. Orlinoe Krylo, Mt. Klyuchevskaya)和破火山口后(Mt. Kambalny Ridge, Chernye Skaly)喷发中心的主量和微量元素组成特征。研究了戈利金火成岩和部分火山口后喷发产物的Sr-Nd同位素组成。同位素变化表明,Pauzhetka地区所有岩石的母岩浆均来自一个弱演化源,该源是由俯冲板块的流体辅助熔融形成的。地球化学资料支持保哲特卡火山口大部分岩浆的形成主要受中下地壳分异结晶控制。melts模型与地球化学数据一致。在6 kbar条件下,用2 wt % H2O对Kambalny玄武岩进行分馏结晶,与观察到的Golygin英安岩组成最吻合。
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引用次数: 2
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Petrology
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