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The influence of the plates on the effectiveness of penetrating thermoelements in the cooling regime 在冷却状态下,板对穿透热元有效性的影响
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-28 DOI: 10.15330/pcss.24.2.385-391
V. Semeshkin, R. Cherkez, A. Zhukova, V.V. Stefiuk
This paper describes the physical model of the penetrating thermoelement with the developed surface of warmth exchange for the cooling of the air’s flow. It presents the theory of the calculation and the method of the computer modeling of the temperature’s and potential’s allocation, the definition of the effectiveness of the energy’s transformation – the cooling factor and the cooling efficiency. This work researches the 3D temperature’s and materials’ allocation for the material of the branches of the thermoelement based on Bi2Te3.
本文描述了用于冷却气流的穿透式热元的物理模型,该热元具有发达的换热面。介绍了温度和电势分配的计算理论和计算机建模方法,给出了能量转换有效性、冷却系数和冷却效率的定义。本文研究了基于Bi2Te3的热电元件分支材料的三维温度分配和材料分配。
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引用次数: 0
Structural, morphological and photocatalytic properties of nanostructured TiO2/AgI photocatalyst 纳米TiO2/AgI光催化剂的结构、形态及光催化性能
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-27 DOI: 10.15330/pcss.24.2.374-384
I. Mironyuk, N. Danyliuk, L. Turovska, I. Mykytyn, V. Kotsyubynsky
Nanostructured TiO2/AgI photocatalyst under the action of ultraviolet or visible electromagnetic radiation effectively neutralizes organic pollutants in the aqueous environment. It is a nanostructure in which micro- and small mesopores of anatase TiO2 are filled with silver iodide in the superionic state. The content of the α-AgI ion-conducting phase in the volume of ТіО2 pores can be ~20 wt %. To obtain a photocatalyst, titanium dioxide is synthesized by the sol-gel method, using a titanium aquacomplex solution [Ti(OH2)6]3+•3Cl- and a Na2CО3 modifier additive as a precursor. The modifying additive during synthesis ensures the fixation of =О2СО carbonate groups on the surface of oxide material particles. The presence of these groups leads to an increase in both the pore volume and the specific surface area of ТіО2. The specific surface area of carbonized titanium dioxide is 368 m2•g-1, the pore volume is 0.28 cm3•g-1, and their size is 0.9-4.5 nm. To fill the micro- and small mesopores of TiO2 with the superionic α-AgI phase, Ag+ cations are first adsorbed from the AgNO3 solution on the titanium dioxide surface, and then the oxide material is contacted with the KI solution. Compared to the Evonik P25-TiO2 photocatalyst, the nanostructured TiO2/AgI photocatalyst demonstrates a significantly higher efficiency of photodegradation of organic dyes Congo Red and Methyl Orange in visible and ultraviolet radiation. The most active ТіО2/40AgI sample achieved complete degradation of the CR dye in 6 minutes of UV irradiation, while the efficiency of commercial Р25-TiO2 over the same time was only 42%.
纳米TiO2/AgI光催化剂在紫外或可见光电磁辐射作用下,能有效中和水中的有机污染物。它是一种纳米结构,在锐钛矿TiO2的微孔和小介孔中填充超离子状态的碘化银。α-AgI离子导电相在ТіО2孔隙体积中的含量可达~20 wt %。为获得光催化剂,采用溶胶-凝胶法合成二氧化钛,以钛水产复合溶液[Ti(OH2)6]3+•3Cl-和Na2CО3改性剂添加剂为前驱体。合成过程中添加的改性添加剂保证了=О2СО碳酸盐基团在氧化材料颗粒表面的固定。这些基团的存在导致ТіО2孔隙体积和比表面积的增加。碳化二氧化钛的比表面积为368 m2•g-1,孔体积为0.28 cm3•g-1,粒径为0.9 ~ 4.5 nm。为了用超离子α-AgI相填充TiO2的微、小介孔,首先将AgNO3溶液中的Ag+阳离子吸附在二氧化钛表面,然后将氧化材料与KI溶液接触。与赢创P25-TiO2光催化剂相比,纳米结构TiO2/AgI光催化剂在可见光和紫外辐射下对有机染料刚果红和甲基橙的光降解效率显著提高。最活跃的ТіО2/40AgI样品在6分钟的紫外照射下完全降解了CR染料,而商用Р25-TiO2样品在相同时间内的效率仅为42%。
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引用次数: 0
THE The ternary system Hf–Re–Al at 1000 °C 在1000℃下,三元体系Hf-Re-Al
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-27 DOI: 10.15330/pcss.24.2.361-366
L. Zinko, G. Nychyporuk, Oksana Matselko, R. Gladyshevskii
The interaction of the components in the Hf–Re–Al system was investigated by X-ray powder diffraction and scanning electron microscopy with energy-dispersive X-ray spectroscopy. The isothermal section of the phase diagram at 1000 °C was constructed in the full concentration range. A new ternary compound ~Hf5Re2Al2, isostructural with Ti5Ga4 (hP18, P63/mcm), and two extended solid solutions Hf(Re,Al)2 were found.
采用x射线粉末衍射和x射线能谱扫描电镜研究了Hf-Re-Al体系中各组分的相互作用。在全浓度范围内,构建了1000℃时相图的等温截面。发现了与Ti5Ga4 (hP18, P63/mcm)同构的新型三元化合物Hf5Re2Al2和两个扩展固溶体Hf(Re,Al)2。
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引用次数: 0
Low-temperature anomalies and nanosized levels formation of self-organized structures in the non-crystalline solids of As(Ge)-S(Se) systems As(Ge)-S(Se)非晶固体中低温异常和纳米级自组织结构的形成
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-27 DOI: 10.15330/pcss.24.2.367-373
M. Mar’yan, N. Yurkovych, V. Šebeň
The relationship between low-temperature anomalies of physical and chemical properties and the formation of self-organized structures in non-crystalline solids of the As(Ge)-S(Se) systems is discussed. Obtained temperature dependences for the specific heat capacity and coefficient of linear expansion in the temperature domain , detailing the linear and nonlinear contributions. The influence of the obtaining conditions of non-crystalline solids on the low-temperature behavior of physico-chemical properties and the change in the ratios of various contributions and temperature intervals is considered. The correlation and common features of the formation of self-organized structures of non-crystalline materials in the region of low temperatures and softening temperatures, manifested in the presence of nanolevels of structuring, are analyzed.
讨论了As(Ge)-S(Se)非晶固体中低温物理化学性质异常与自组织结构形成的关系。获得了温度域中比热容和线性膨胀系数的温度依赖关系,详细说明了线性和非线性贡献。考虑了非晶固体的制备条件对低温物化性能的影响,以及各组分的贡献比和温度区间的变化。分析了非晶体材料在低温和软化温度区域形成自组织结构的相关性和共同特征,表现为纳米级结构的存在。
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引用次数: 1
Structural and sorption properties of nanoporous carbon materials obtained from walnut shells 核桃壳纳米多孔碳材料的结构与吸附性能
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-25 DOI: 10.15330/pcss.24.2.348-353
S. A. Lisovska, R.V. Ilnytskyy, R. Lisovskyy, N. Ivanichok, K. Bandura, B. Rachiy
Using the method of low-temperature nitrogen adsorption/desorption, the porous structure of nanoporous carbon materials obtained by alkaline activation of light industry waste (walnut shells) with subsequent thermal modification was investigated. The optimal relationship between temperature and modification time has been established. It is shown that an increase in the modification temperature reduces the transition time of micropores into mesopores and leads to a decrease in the specific surface area and total pore volume. Thus, the material obtained at a modification temperature of 400 ºC and a holding time of 120 min is characterized by the maximum specific surface area of 940 m2/g. It has been investigated that an increase in the time of temperature modification leads to an increase in specific electrical conductivity.
采用低温氮吸附/解吸的方法,对轻工业废料(核桃壳)碱活化后进行热改性制备的纳米多孔碳材料的孔隙结构进行了研究。建立了温度与改性时间的最佳关系。结果表明,改性温度的升高缩短了微孔向中孔转变的时间,导致比表面积和总孔容的减小。因此,改性温度为400℃,保温时间为120 min时得到的材料的最大比表面积为940 m2/g。研究表明,温度改性时间的增加会导致比电导率的增加。
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引用次数: 1
The epitaxial iron-yttrium garnet films with homogeneous properties and narrow FMR line width 该外延铁钇石榴石薄膜具有均匀的性能和窄的FMR线宽
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-25 DOI: 10.15330/pcss.24.2.354-360
S. Yushchuk, S.A. Yur`ev, V. Moklyak
The growth of iron-yttrium garnet Y3Fe5O12 (YIG) films with of 1...15 μm thicknesses on single-crystal substrates of gallium-gadolinium garnet Gd3Ga5O12 (GGG) was carried out using the method of liquid phase epitaxy (LPE). The influence of the composition and mass of the charge, the temperature regimes, the rates of movement and the substrate rotation on the films parameters were studied. The layered structure caused by the heterogeneity of the chemical composition in the film thickness was determined and studied The dependence of the degree impurity of Pb2+ and Pt4+ ions in YIG films and their influence on the ferromagnetic resonance (FMR) line width ∆H on the films growth conditions was investigated. It’s shown that in order to obtain by the LPE method the series of defect-free films with low magnetic losses and reproducible parameters, it’s necessary to use melt-solutions of large mass (6...12 kg) and apply their additional mixing during the growth process.
铁钇石榴石Y3Fe5O12 (YIG)薄膜的生长采用液相外延(LPE)的方法,在镓钆石榴石Gd3Ga5O12 (GGG)单晶衬底上制备了厚度为15 μm的薄膜。研究了电荷的组成和质量、温度、运动速率和衬底旋转对薄膜参数的影响。研究了YIG薄膜中Pb2+和Pt4+离子的杂质度及其对薄膜生长条件下铁磁共振(FMR)线宽∆H的影响。结果表明,为了用LPE法获得一系列具有低磁损耗和可重复参数的无缺陷薄膜,必须使用大质量(6…12公斤),并在生长过程中进行额外的混合。
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引用次数: 1
Manufacturing of nitinol-based alloys by using modern technology: A short review 利用现代技术制造镍钛诺基合金:综述
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-25 DOI: 10.15330/pcss.24.2.341-347
Chingiz Imamalizade
The paper provides a brief review of literature data on the synthesis, processing, structure, mechanical properties, and application of nitinol and alloys based on it, which are promising functional materials found application in a number of high technologies. In addition, machine learning methods were applied to predict the temperatures of phase transformations.
本文对镍钛诺及其合金的合成、加工、结构、力学性能及应用等方面的文献资料进行了综述,介绍了镍钛诺及其合金在高新技术领域的应用前景。此外,应用机器学习方法预测相变温度。
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引用次数: 1
The influence of mercury vapor on the electrical resistance of chalcogenide amorphous films 汞蒸气对硫化物非晶薄膜电阻的影响
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-23 DOI: 10.15330/pcss.24.2.335-340
V. M. Rubish, V. Kyrylenko, M. Durkot, V. Boryk, R. Dzumedzey, I. Yurkin, M. Pop, Y. Myslo
Using the planar structures "Ni layer - chalcogenide amorphous film - Ni layer" and "graphite probe - chalcogenide amorphous film graphite probe" samples, the influence of mercury vapor on the electrical resistance of amorphous films of the Se-Te, Se-Sb and Se-As systems was investigated. It was established that exposure of samples in mercury vapor leads to a decrease in their electrical resistance by 4-7 orders of magnitude. As the temperature and mercury concentration increase, the transition time from a high-resistance state to a low-resistance state decreases. When introducing Te, Sb, and As into amorphous selenium and increasing their concentration in the composition of the films, the transition time increases, and the value of the change in resistance decreases. It was established that the change in resistance is mainly determined by the change in surface conductivity of chalcogenide films. A decrease in the electrical resistance of selenium-containing amorphous films modified with mercury is caused by the formation of HgSe crystalline inclusions in their matrix.
采用平面结构“Ni层-硫系非晶膜- Ni层”和“石墨探针-硫系非晶膜石墨探针”样品,研究了汞蒸气对Se-Te、Se-Sb和Se-As体系非晶膜电阻的影响。经证实,样品暴露在汞蒸气中会使其电阻降低4-7个数量级。随着温度和汞浓度的增加,从高阻态到低阻态的转变时间缩短。在非晶态硒中引入Te、Sb和As,并增加其在薄膜组成中的浓度,转变时间增加,电阻变化率减小。结果表明,电阻值的变化主要是由硫系薄膜表面电导率的变化决定的。用汞修饰的含硒非晶薄膜的电阻降低是由于在其基体中形成了HgSe晶体夹杂物。
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引用次数: 0
Properties of silica porous glasses with the nanoparticle ensembles of some compounds 含某些化合物纳米粒子系综的二氧化硅多孔玻璃的性能
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-20 DOI: 10.15330/pcss.24.2.323-334
Y. Lepikh, I. Doycho
Properties porous silica glasses are systemized in this review. Also the methods of formation of the nanoparticles’ ensembles of the substances, which are useful for the microelectronics, are described. Porous silica glasses are perspective due to their chemically resistance, mechanical strength and development of their inner surface. Own electrical resistance is too big for the porous glasses’ specimens with standard sizes, that’s why ones use them as matrixes for luminescence type of sensors mainly. The luminescent properties’ dependence on the molecular structure of investigate substances (such as dyes and metal oxides), as well as on the nanoparticle ensemble technological formation condition is studied. It is revealed to which certain gases dyes of the specified type are sensitive and why it occurs in such manners. It is shown due to which of the described nano-size systems’ properties sensitivity is appeared. Besides, one can embed a conductive phase into the pores of glass due to features of its structure. After such treatment one can use the porous glasses as matrix for formation of resistance type sensors.
本文系统介绍了多孔硅玻璃的性能。本文还介绍了在微电子学中有用的物质的纳米粒子系综的形成方法。多孔硅玻璃因其耐化学性、机械强度和内表面的发展而备受关注。对于标准尺寸的多孔玻璃试样来说,其自身的电阻太大,这就是为什么人们主要将其作为发光型传感器的基体。研究了发光性能对所研究物质(如染料和金属氧化物)分子结构以及纳米粒子系综工艺形成条件的依赖。它揭示了特定类型的某些气体染料是敏感的,以及为什么会以这种方式发生。结果表明,由于所描述的纳米系统的性质,出现了灵敏度。此外,由于玻璃的结构特点,可以将导电相嵌入到玻璃的孔隙中。经过这样的处理,人们可以使用多孔玻璃作为形成电阻型传感器的基质。
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引用次数: 0
Sandwiched Plate Vibration Analysis with Open and Closed Lattice Cell Core 开闭格芯夹层板振动分析
IF 0.7 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-19 DOI: 10.15330/pcss.24.2.312-322
Hussam Raad, E. Njim, M. Jweeg, M. Al-Waily
This work attempts to replace the sandwich core's traditional shape and material with a cellular pattern, where the cells have a regular shape, distribution, and size. The contribution of this paper is to design two structures, one open-celled and the other closed, and to evaluate the performance of sandwich plates with lattice cell core as it is used for many industrial applications, particularly in automobile engineering. The new theoretical formulations are constructed for two structures to find the free vibration characteristics. The results of the new design are compared with the traditional shape. Derivation of equations to predict mechanical properties based on relative density with the chosen shapes, specific vibration equation of three-layer sandwich plate, and substitution by equation using excel sheet. Results are promising, and the effectiveness of cellular pattern theoretical analysis estimation. Limitations and error rates for the mechanical properties come through the empirical equations, and their ratio to the relative density values are higher depending on the behavior of the core material. Findings reveal, with open cell decrease in modulus of elasticity by (PLA: -90.4%) and (TPU: -90.4%), increases natural frequency by (PLA: 44.5%) and (TPU: 46.4%), as for closed-cell decreases in the modulus of elasticity by (PLA: -66.9%) and (TPU: -64.4%), increases natural frequency by (PLA: 36%) and (TPU: 37.7%). Converting a solid substance or replacing a foam form with a cellular pattern is one way to better performance and save weight through the selected cell pattern in absorbing the energy of the vibration wave.
这项工作试图用细胞模式取代三明治芯的传统形状和材料,其中细胞具有规则的形状,分布和大小。本文的贡献在于设计了两种结构,一种是开孔结构,另一种是封闭结构,并对晶格芯夹层板的性能进行了评估,因为它在许多工业应用中,特别是在汽车工程中。建立了两种结构自由振动特性的新理论公式。将新设计的结果与传统形状进行了比较。推导了基于所选形状的相对密度预测力学性能的方程,推导了三层夹层板的具体振动方程,并用excel表格进行了方程代入。结果是有希望的,并证明了元胞模式理论分析估计的有效性。力学性能的限制和错误率来自经验方程,它们与相对密度值的比值取决于芯材的行为。结果表明,开孔弹性模量下降(PLA: -90.4%)和(TPU: -90.4%)时,固有频率增加(PLA: 44.5%)和(TPU: 46.4%);闭孔弹性模量下降(PLA: -66.9%)和(TPU: -64.4%)时,固有频率增加(PLA: 36%)和(TPU: 37.7%)。将固体物质转换为蜂窝图案或用蜂窝图案代替泡沫形式是通过所选的蜂窝图案吸收振动波的能量来提高性能和节省重量的一种方法。
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引用次数: 1
期刊
Physics and Chemistry of Solid State
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