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Chapter 7. Integrating Remediation and Resource Recovery of Industrial Alkaline Wastes: Case Studies of Steel and Alumina Industry Residues 第七章。工业碱性废物的综合治理与资源化利用——以钢铁和氧化铝工业废渣为例
Pub Date : 2020-05-22 DOI: 10.1039/9781788016353-00168
H. Gomes, M. Rogerson, R. Courtney, W. Mayes
With an estimated annual production of two billion tonnes globally, alkaline industrial wastes can be considered both major global waste streams, and materials that offer significant options for potential resource recovery. Alkaline wastes are usually derived from high temperature production (e.g. steel and alumina) or disposal (e.g. incineration) processes and are increasingly abundant given rising global demand for steel and alumina and the drive for waste incineration in some jurisdictions. Although relatively long-standing afteruses have been adopted for these materials providing opportunities for value recovery (e.g. steel slag use as an aggregate), they are not sufficient to consume all residues generated or completely limit potential environmental impacts. These impacts can include the generation of fugitive dusts, challenges associated with revegetation, and effects on the water environment. These wastes can produce highly alkaline leachates enriched with trace metals (e.g. As, Cr, Mo, V) and persist over decades after site closure. Vanadium, one of the most hazardous ecotoxins in leachates, is also a valuable commodity for renewable energy technologies, unifying the often divergent needs of resource recovery and remediation. Case studies are included to illustrate routes to resource recovery from wastes from two major industrial sectors: steel production and alumina production.
全球估计每年生产20亿吨碱性工业废物,可被视为全球主要的废物流,也是为潜在资源回收提供重要选择的材料。碱性废物通常来自高温生产(如钢铁和氧化铝)或处理(如焚烧)过程,由于全球对钢铁和氧化铝的需求不断上升以及一些司法管辖区对废物焚烧的推动,碱性废物越来越多。虽然这些材料采用了相对长期的后用方式,提供了价值回收的机会(例如钢渣作为骨料使用),但它们不足以消耗产生的所有残留物或完全限制潜在的环境影响。这些影响包括扬尘的产生、与植被恢复相关的挑战以及对水环境的影响。这些废物可产生富含微量金属(如砷、铬、钼、钒)的高碱性渗滤液,并在场地关闭后持续数十年。钒是渗滤液中最危险的生态毒素之一,也是可再生能源技术的宝贵商品,统一了资源回收和补救的不同需求。包括案例研究,以说明从两个主要工业部门:钢铁生产和氧化铝生产的废物中回收资源的途径。
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引用次数: 3
Chapter 8. Conclusions 第八章。结论
Pub Date : 2020-02-26 DOI: 10.1039/9781839160271-00223
J. Clark
In order to meet decarbonisation goals and implement a genuinely sustainable circular economy model, the chemical industry needs to transition from fossil to renewable sources of carbon. Current chemical production is dominated by petroleum where this largely uniform feedstock is separated using a q...
为了实现脱碳目标并实施真正可持续的循环经济模式,化工行业需要从化石燃料转向可再生碳源。目前的化工生产以石油为主导,这种基本均匀的原料是用蒸馏器分离的。
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引用次数: 0
Chapter 11. Applications of Engineered Nanomaterials in the Recovery of Metals from Wastewater 第十一章。工程纳米材料在废水金属回收中的应用
Pub Date : 2019-10-15 DOI: 10.1039/9781788016353-00266
R. Crane, D. Sapsford, A. Aderibigbe
The occurrences of certain metal and metalloid (hereafter metal) ions in municipal and industrial wastewater are major concerns due to the adverse effects such metals can have on human health and the environment at relatively low concentrations. Given the fact that all metals are attained from finite deposits, their recovery from wastewater is essential in order to prevent loss of materials from the global supply loop. An intrinsic challenge, however, is that economically valuable metal ions are often present at relatively low concentrations and in highly complex chemical matrices and thus conventional extraction methods are often not economically or practically feasible. The use of engineered nanomaterials could overcome this issue due to their unique properties, including high specific surface area, colloidal behaviour and quantum size effects. This chapter will discuss the wide potential of engineered nanomaterials for the recovery of metal ions from wastewater, including their use as suspended colloids and as fixed bed reactors. Significant technical challenges remain, however, associated with (1) their synthesis cost and (2) the ecotoxicity of ‘unbound’ engineered nanomaterials, which if overcome, could give rise to the widespread adoption of engineered nanomaterials in the recovery of metals from wastewater.
在城市和工业废水中出现某些金属和类金属离子(以下简称金属)是令人关切的主要问题,因为这些金属在相对较低的浓度下可能对人类健康和环境产生不利影响。鉴于所有金属都是从有限的沉积物中获得的,因此从废水中回收金属对于防止全球供应循环中的材料损失至关重要。然而,一个内在的挑战是,具有经济价值的金属离子往往以相对较低的浓度和高度复杂的化学基质存在,因此传统的提取方法往往不经济或实际上可行。工程纳米材料的使用可以克服这个问题,因为它们具有独特的特性,包括高比表面积、胶体行为和量子尺寸效应。本章将讨论工程纳米材料在从废水中回收金属离子方面的广泛潜力,包括它们作为悬浮胶体和固定床反应器的用途。然而,重大的技术挑战仍然存在,这与(1)它们的合成成本和(2)“非结合”工程纳米材料的生态毒性有关,如果克服这些挑战,可能会导致工程纳米材料在废水中金属回收中的广泛采用。
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引用次数: 2
Chapter 12. From Bioenergy By-products to Alternative Fertilisers: Pursuing a Circular Economy 第十二章。从生物能源副产品到替代肥料:追求循环经济
Pub Date : 2019-10-15 DOI: 10.1039/9781788016353-00287
R. Marshall, A. Lag-Brotons, E. Inam, B. Herbert, L. Hurst, K. Semple
A number of policy mechanisms have driven the development of a circular economy in organic waste management. This chapter explores the journey of organic wastes from a waste management problem to a renewable energy solution, and then looks to their future as a viable market alternative to conventional inorganic fertilisers. This transition reflects changes in the wider waste policy landscape with a shift from waste management to resource recovery—a viewpoint that is to become increasingly important as the UK and EU look to pursue circular economy strategies. Producing alternative fertilisers from bioenergy by-products provides a neat principle for returning nutrients to soils and closing the loop. However, myriad barriers make this challenging from regulatory viewpoints. Regulations are necessarily risk-conservative, yet arguably innovation-prohibitive. This chapter will explore the challenges that may arise from possible conflicts in regulations, and seeks to establish a way forward for the entry of bioenergy by-products into the circular economy.
一些政策机制推动了有机废物管理循环经济的发展。本章探讨了有机废物从废物管理问题到可再生能源解决方案的历程,然后展望了有机废物作为传统无机肥料的可行市场替代品的未来。这一转变反映了更广泛的废物政策格局的变化,从废物管理转向资源回收——随着英国和欧盟寻求推行循环经济战略,这一观点将变得越来越重要。从生物能源副产品中生产替代肥料提供了一种简洁的原理,可以将养分返还给土壤并完成循环。然而,从监管的角度来看,无数的障碍使这一目标具有挑战性。监管必然是风险保守的,但也可能是禁止创新的。本章将探讨法规中可能存在的冲突可能带来的挑战,并寻求为生物能源副产品进入循环经济建立一条前进的道路。
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引用次数: 5
Chapter 6. An Exploration of Key Concepts in Application of In Situ Processes for Recovery of Resources from High-volume Industrial and Mine Wastes 第六章。大容量工矿废弃物资源化就地工艺应用中的关键概念探讨
Pub Date : 2019-10-15 DOI: 10.1039/9781788016353-00141
D. Sapsford, R. Crane, D. Sinnett
This chapter presents a synthesis of key concepts concerning the potential application of in situ leaching processes for direct and indirect resource recovery (with emphasis on metals) from wastes. The global stocks of industrial and mining wastes (IMWs) run into the billions of tonnes and will continue to accumulate in response to unabating global economic growth and consumption. Circular economy (CE) discourse to date generally emphasises recycling of post-consumer goods rather than resource recovery from IMWs even though they comprise very large, albeit dilute, stocks of metals. Because the metal contents of many of these wastes are (by definition) lower than corresponding ore grades, greater energy (or exergy) expenditure is required to win metals from these sources. Since the majority of metal recovery processes are driven by fossil fuels, this also implies greater carbon footprints and other detrimental consequences to natural capital. Thus, the application of conventional pyrometallurgical and hydrometallurgical processes for recovering metals from wastes must be closely scrutinised with respect to sustainability. More energy efficient processes and/or those that utilise non-fossil energy are required. Herein we explore key concepts in the potential application of low-intensity in situ leaching processes.
本章综合了有关就地浸出法在废物中直接和间接回收资源(重点是金属)方面的潜在应用的关键概念。全球工业和采矿废物(IMWs)的存量达到数十亿吨,并将继续积累,以应对不减的全球经济增长和消费。迄今为止,循环经济(CE)的论述通常强调消费后商品的再循环,而不是从IMWs中回收资源,尽管它们包含非常大的金属库存,尽管它们被稀释了。由于这些废物中的许多金属含量(根据定义)低于相应的矿石等级,因此需要更多的能量(或能源)支出才能从这些来源中获得金属。由于大多数金属回收过程是由化石燃料驱动的,这也意味着更大的碳足迹和对自然资本的其他有害后果。因此,必须严格审查从废物中回收金属的传统火法冶金和湿法冶金方法的应用,以确保其可持续性。需要更节能的工艺和/或使用非化石能源的工艺。在此,我们探讨了低强度原位浸出过程潜在应用的关键概念。
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引用次数: 3
Chapter 4. Metal Recovery Using Microbial Electrochemical Technologies 第四章。利用微生物电化学技术回收金属
Pub Date : 2019-10-15 DOI: 10.1039/9781788016353-00087
B. Christgen, A. Suárez, E. Milner, H. Boghani, J. Sadhukhan, Mobolaji Shemfe, Siddharth Gadkari, R. Kimber, J. Lloyd, K. Rabaey, Y. Feng, G. Premier, T. Curtis, K. Scott, E. Yu, I. Head
The demand for mineral and energy resources is increasing. Resources are sourced from finite geological deposits. Therefore the development of more sustainable routes is paramount. Industrial, municipal and agricultural wastewaters are potential sources of metals and energy can be recovered from oxidising waste organic matter but conventional methods are not technically or economically feasible. Bioelectrochemical systems (BES) have the potential to overcome these problems. Integrated BES can combine wastewater treatment, energy generation and resource recovery. Organic waste generated annually by humans globally contains ca. 600–1200 TWh of energy. BES can harvest energy as electricity from wastewater but the coulombic yields and power outputs are uncompetitive with alternative systems for electricity production from waste. Alternative uses of energy recovered from wastewaters by BES include resource recovery from waste streams (e.g. metals), offering wastewater treatment while valorising a waste stream for valuable product recovery. This chapter focuses on electrochemical metal recovery from wastes, noting also (bio)electrochemical synthesis of high-value organic compounds on the cathode, and biological electricity production from wastewaters at the anode. We review how fundamental microbial processes can be harnessed for resource recovery and the environmental benefits, and consider scale-up, environmental and economic costs and benefits of BES technologies for resource recovery.
对矿物和能源的需求正在增加。资源来源于有限的地质矿床。因此,开发更可持续的路线是至关重要的。工业、城市和农业废水是金属和能源的潜在来源,可以从氧化废物有机物质中回收,但传统方法在技术上或经济上都不可行。生物电化学系统(BES)有潜力克服这些问题。一体化BES可集污水处理、发电和资源回收于一体。全球人类每年产生的有机废物含有约600-1200太瓦时的能量。BES可以从废水中收集电能,但库仑产量和电力输出与其他废物发电系统相比没有竞争力。BES从废水中回收能源的替代用途包括从废物流(例如金属)中回收资源,提供废水处理,同时对废物流进行估价,以回收有价值的产品。本章着重于从废物中回收金属的电化学,还注意到阴极上高价值有机化合物的(生物)电化学合成,以及阳极上废水的生物发电。我们回顾了如何利用基本微生物过程进行资源回收和环境效益,并考虑了资源回收的规模、环境和经济成本以及BES技术的效益。
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引用次数: 1
Chapter 1. A New Perspective on a Global Circular Economy 第1章。全球循环经济的新视角
Pub Date : 2019-10-15 DOI: 10.1039/9781788016353-00001
A. Velenturf, P. Purnell, L. Macaskie, W. Mayes, D. Sapsford
Natural resource exploitation is accelerating in the face of resource decline, while at the same time people are generating ever growing quantities of wastes. Population and income growth drive up the demand for energy, materials and food. Four planetary boundaries that indicate a safe operating space for humankind may well have been crossed – climate change, land system change, biogeochemical loading and biosphere integrity – all directly linked to resource overexploitation. Resource exploitation has brought welfare to many people, but it is now infringing upon basic human rights such as clean water and a safe living environment. The management of resources needs to change radically from the linear take-make-use-dispose model to a more sustainable, circular model. This chapter introduces the global challenges within which an international movement towards a circular economy has emerged. It critically revisits views on circular economy and proposes a new model that recognises the complex nature of our resource flows. The Resource Recovery from Waste programme is introduced and an overview is provided of the contents of this book.
面对资源的减少,自然资源的开发正在加速,与此同时,人们产生的废物数量也越来越多。人口和收入的增长推动了对能源、材料和食品的需求。气候变化、土地系统变化、生物地球化学负荷和生物圈完整性这四个表明人类安全活动空间的地球边界很可能已经被跨越,所有这些都与资源过度开发直接相关。资源开发给许多人带来了福利,但现在却侵犯了清洁用水和安全生活环境等基本人权。资源管理需要从线性的获取-利用-处置模式向更可持续的循环模式转变。本章介绍了国际循环经济运动所面临的全球性挑战。它批判性地重新审视了循环经济的观点,并提出了一个认识到我们的资源流动的复杂性的新模型。介绍了从废物中回收资源计划,并概述了本书的内容。
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引用次数: 22
Chapter 5. Adding Value to Ash and Digestate (AVAnD Project): Elucidating the Role and Value of Alternative Fertilisers on the Soil–Plant System 第五章。灰和消化物的增值(AVAnD项目):阐明替代肥料在土壤-植物系统中的作用和价值
Pub Date : 2019-10-15 DOI: 10.1039/9781788016353-00113
A. Lag-Brotons, R. Marshall, B. Herbert, L. Hurst, E. Inam, K. Semple
While bioenergy generation represents a step towards sustainability, residues and by-products are generated as a result of this process. In order to take the next step and ‘close the loop’ on the generated residues, resource recovery from these materials is required. In this chapter we will focus on the use of blends of biomass ash and anaerobic digestate, derived from industrial scale bioenergy production processes, as potential alternatives to conventional inorganic fertilisers. Topics will not only cover waste streams, their nature and relevance to agriculture, but also experimental assessments at different scales of the effects of these waste stream combinations on the soil–plant system and the wider environment.
虽然生物能源生产是朝着可持续发展迈出的一步,但这一过程会产生残留物和副产品。为了采取下一步并对产生的残留物进行“闭环”,需要从这些材料中回收资源。在本章中,我们将重点关注从工业规模的生物能源生产过程中获得的生物质灰和厌氧消化物的混合物的使用,作为传统无机肥料的潜在替代品。主题不仅包括废物流、它们的性质和与农业的相关性,而且还包括在不同尺度上对这些废物流组合对土壤-植物系统和更广泛环境的影响进行实验性评估。
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引用次数: 1
Chapter 2. Use of Biotechnology for Conversion of Lignocellulosic Waste into Biogas and Renewable Chemicals 第二章。利用生物技术将木质纤维素废物转化为沼气和可再生化学品
Pub Date : 2019-10-15 DOI: 10.1039/9781788016353-00023
G. Rashid, T. Bugg
The first part of this chapter will discuss the composition of lignocellulose, and the structures of the cellulose, hemicellulose and lignin components. Degradation of lignocellulose in soil and the microorganisms and enzymes responsible for degradation of these components will be overviewed. Degradation of lignin is aerobic and slow; therefore, lignin degradation is a slow step in breakdown of lignocellulosic waste. Microbial production of biogas will be overviewed along with its role in commercial anaerobic digestion for production of biogas from lignocellulosic biomass. Pathways for lignin biodegradation will be described, including delignification by addition of lignin-degrading fungi and bacteria, delignification by lignin-oxidising enzymes and enhancement of biogas formation. The use of metabolic engineering for production of renewable chemicals from lignin degradation will also be described.
本章第一部分将讨论木质纤维素的组成,以及纤维素、半纤维素和木质素组分的结构。木质纤维素在土壤中的降解以及负责降解这些成分的微生物和酶将被概述。木质素的降解是需氧且缓慢的;因此,木质素降解是木质纤维素废物分解的一个缓慢步骤。将概述微生物生产沼气及其在商业厌氧消化中用于从木质纤维素生物质生产沼气的作用。木质素生物降解的途径将被描述,包括通过添加降解木质素的真菌和细菌,通过木质素氧化酶和加强沼气形成的脱木质素。利用代谢工程从木质素降解生产可再生化学品也将被描述。
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引用次数: 0
Chapter 16. New Governance for Circular Economy: Policy, Regulation and Market Contexts for Resource Recovery from Waste 第十六章。循环经济的新治理:资源回收的政策、法规和市场背景
Pub Date : 2019-10-15 DOI: 10.1039/9781788016353-00395
P. Purnell, A. Velenturf, R. Marshall
This chapter discusses the impacts of policy and regulations on resource recovery from waste (RRfW) as part of a transition towards a circular economy (CE). It presents the motivations for achieving CE as expressed by government and commercial stakeholders, the general and specific benefits of RRfW in the economic, environmental and social domains, and the role of policy and regulation in preventing or overcoming barriers to achieving RRfW and CE. Policy needs to break through the short-term economic concerns that dominate the sector, ensure that ‘downstream’ processes shift focus to include RRfW as well as environmental protection, and encourage ‘upstream’ processes (particularly product design) to prioritise reuse or refurbishment and recovery of value (via extended producer responsibility). Conflict among regulations is a serious impediment, e.g. where materials cross national boundaries or processes combine both waste treatment and resource recovery sub-processes. Multiple actors all along the supply chain need to combine to implement RRfW. Data collection for material flows needs to be standardised and include social and technical metrics, not just metrics for environmental protection and economic cost–benefit analyses. RRfW infrastructure investment is ill-suited to achieving CE, almost exclusively focussed as it is on energy recovery from waste over processes further up the waste hierarchy. Fundamentally, the current policies, regulations and agencies charged with promoting RRfW and CE have evolved from their mission to protect public health and the environment and are not fit for purpose. Governments must establish agencies charged with resource management, stewardship and productivity if the purported benefits of CE are to be realised.
本章讨论了作为向循环经济(CE)过渡的一部分,政策和法规对废物资源回收的影响。它介绍了政府和商业利益相关者所表达的实现可持续发展的动机,可再生能源在经济、环境和社会领域的一般和具体利益,以及政策和法规在防止或克服实现可再生能源和可再生能源障碍方面的作用。政策需要突破主导该行业的短期经济问题,确保“下游”流程将重点转移到包括RRfW和环境保护,并鼓励“上游”流程(特别是产品设计)优先考虑再利用或翻新和价值回收(通过扩大生产者责任)。法规之间的冲突是一个严重的障碍,例如,当材料跨越国界或过程同时包含废物处理和资源回收子过程时。供应链中的多个参与者需要结合起来实现RRfW。物质流动的数据收集需要标准化,并包括社会和技术指标,而不仅仅是环境保护和经济成本效益分析的指标。RRfW基础设施投资不适合实现节能减排,因为它几乎完全专注于从废物中回收能源,而不是废物层级进一步上升的过程。从根本上说,目前负责促进RRfW和CE的政策、法规和机构是从其保护公众健康和环境的使命演变而来的,不符合目的。政府必须设立负责资源管理、管理和生产力的机构,才能实现所谓的行政管理的好处。
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引用次数: 9
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