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Structural Change of Carbon Anode in a Lithium-ion Battery Product Associated with Charging Process Observed by Neutron Transmission Bragg-edge Imaging 锂离子电池产品碳负极结构随充电过程的变化
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.06.003
Takashi Kamiyama , Yuki Narita , Hirotaka Sato , Masato Ohnuma , Yoshiaki Kiyanagi

Spectroscopic neutron Bragg-edge imaging was performed to study a lithium-ion battery (LIB) product. This non-destructive neutron imaging method is suitable for the evaluation of industrial products, but presents some difficulties for application to multicomponent products. The LIB includes a strong neutron scatterer and an absorber, and is thus a suitable test case for the use of neutron imaging in actual product measurement. In this study, we analyzed the variation of the graphite anode structure with changes in the battery charge level. The experiments were carried out using the compact neutron source at the Hokkaido University neutron source facility (HUNS). To eliminate the effect of scattered neutron contamination, we first determined the distance between the sample and detector required to reduce this effect to under 1%. Using this separation, the charge level dependence of the anode structure was measured. The graphite {002} Bragg-edge could be recognized on the neutron transmission spectra. The Bragg-edge was shifted and broadened with increasing battery charge. The edge was consistent with the existence of multiple graphite structural stages. The layer spacing distribution images for different charge levels showed the inhomogeneous fluctuation on the LIB lattice plane. Based on the images the fraction of the graphite structural stages were analyzed. The ratio of each stage varied with the charge level, and the ideal intercalation structure, in which the graphite layers are stuffed with Li-ions, was found to be minor in the final charging state.

利用中子布拉格边缘成像技术对锂离子电池产品进行了研究。这种无损中子成像方法适用于工业产品的评价,但应用于多组分产品存在一定的困难。LIB包括一个强中子散射体和一个吸收体,因此是在实际产品测量中使用中子成像的合适测试案例。在本研究中,我们分析了石墨阳极结构随电池充电水平变化的变化。实验是在北海道大学中子源设施(HUNS)使用紧凑型中子源进行的。为了消除散射中子污染的影响,我们首先确定了将这种影响降低到1%以下所需的样品和探测器之间的距离。利用这种分离,测量了阳极结构对电荷水平的依赖性。在中子透射谱上可以识别出石墨{002}布拉格边缘。随着电池电量的增加,布拉格边发生了位移和变宽。边缘与多个石墨结构阶段的存在相一致。不同电荷水平的层间距分布图像显示了LIB晶格平面上的不均匀波动。在此基础上,分析了石墨结构阶段的比例。各阶段的比例随充电水平而变化,在最终充电状态下,石墨层填充锂离子的理想嵌入结构较少。
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引用次数: 15
The Signal Chain - how the Removal of an Image Intensifier at the AERE Reactor in Bangladesh Improves Neutron Imaging 信号链——孟加拉国AERE反应堆去除图像增强器如何改善中子成像
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.06.034
Burkhard Schillinger , Sudipta Saha

Most neutron imaging systems use a neutron sensitive scintillation screen and camera. Due to the highly exothermic nature of the detection reaction, many thousand photons are produced for one detected neutron. If an additional image intensifier is used, the signal generated by very few neutrons may saturate the camera without delivering sufficient neutron statistics to examine a neutron radiography sample. This article takes a look at the signal chain for neutron radiography and tries to give some help for estimating required statistics and exposure times.

大多数中子成像系统使用中子敏感闪烁屏和照相机。由于探测反应的高度放热性质,一个被探测到的中子产生数千个光子。如果使用额外的图像增强器,由极少数中子产生的信号可能会使相机饱和,而无法提供足够的中子统计数据来检查中子射线照相样品。本文介绍了中子射线照相的信号链,并试图为估计所需的统计数据和曝光时间提供一些帮助。
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引用次数: 4
Illinois Accelerator Research Center 伊利诺斯加速器研究中心
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.09.030
Thomas K. Kroc, Charlie A. Cooper

The Illinois Accelerator Research Center (IARC) hosts a new accelerator development program at Fermi National Accelerator Laboratory. IARC provides access to Fermi's state-of-the-art facilities and technologies for research, development and industrialization of particle accelerator technology. In addition to facilitating access to available existing Fermi infrastructure, the IARC Campus has a dedicated 36,000 ft2 Heavy Assembly Building (HAB) with all the infrastructure needed to develop, commission and operate new accelerators. Connected to the HAB is a 47,000 ft2 Office, Technology and Engineering (OTE) building, paid for by the state, that has office, meeting, and light technical space. The OTE building, which contains the Accelerator Physics Center, and nearby Accelerator and Technical divisions provide IARC collaborators with unique access to world class expertise in a wide array of accelerator technologies. At IARC scientists and engineers from Fermilab and academia work side by side with industrial partners to develop breakthroughs in accelerator science and translate them into applications for the nation's health, wealth and security.

伊利诺斯加速器研究中心(IARC)在费米国家加速器实验室主持了一个新的加速器开发项目。IARC为粒子加速器技术的研究、开发和产业化提供了使用费米最先进的设备和技术的途径。除了方便使用现有的费米基础设施外,IARC园区还有一个专门的36000平方英尺的重型装配大楼(HAB),里面有开发、调试和运行新加速器所需的所有基础设施。与HAB相连的是一个47,000平方英尺的办公、技术和工程(OTE)建筑,由国家支付,具有办公、会议和轻型技术空间。OTE大楼包含加速器物理中心,以及附近的加速器和技术部门,为IARC的合作者提供了独特的途径,可以获得世界一流的加速器技术。在IARC,来自费米实验室和学术界的科学家和工程师与工业合作伙伴并肩工作,在加速器科学方面取得突破,并将其转化为国家健康、财富和安全的应用。
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引用次数: 3
Historic binnacle of 14C/12C concentration in Mexico City 墨西哥城14C/12C浓度的历史坐标
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.09.007
J.A. Flores , C. Solís , A. Huerta , M.E. Ortiz , M.G. Rodríguez-Ceja , J. Villanueva , E. Chávez

The radiocarbon concentration is reduced in urban areas, generally due to high CO2 emissions derived from fossil fuels. In this paper, new Δ14C measurements in cellulose extracted from the growth rings of two trees over a 43-year period are presented. The first is in a zone with clean air (El Nayar, Durango, Mexico) and the second is from the Greater Mexico City area (Chapultepec). Data from El Nayar is consistent with that reported for Zone 2 of the Northern Hemisphere while that from the urban area shows a significant decrease in Δ14C. Our results are compared with data from other cities (Nagoya, Japan and Valladolid, Spain).

城市地区的放射性碳浓度降低,通常是由于化石燃料产生的大量二氧化碳排放。在本文中,新的Δ14C测量从两棵树的生长年轮中提取的纤维素在43年期间提出。第一个是在空气清新的地区(墨西哥杜兰戈的El Nayar),第二个是在大墨西哥城地区(查普尔特佩克)。来自El Nayar的数据与北半球第2区报告的数据一致,而来自城市地区的数据显示Δ14C显著减少。我们的结果与其他城市(日本名古屋和西班牙巴利亚多利德)的数据进行了比较。
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引用次数: 6
Computational Analysis Supporting the Design of a New Beamline for the Mines Neutron Radiography Facility 支持矿山中子射线照相设备新型光束线设计的计算分析
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.06.045
C. Wilson, J. King

The Colorado School of Mines installed a neutron radiography system at the United States Geological Survey TRIGA reactor in 2012. An upgraded beamline could dramatically improve the imaging capabilities of this system. This project performed computational analyses to support the design of a new beamline, with the major goals of minimizing beam divergence and maximizing beam intensity. The new beamline will consist of a square aluminum tube with an 11.43 cm (4.5 in) inner side length and 0.635 cm (0.25 in) thick walls. It is the same length as the original beam tube (8.53 m) and is composed of 1.22 m (4 ft) and 1.52 m (5 ft) flanged sections which bolt together. The bottom 1.22 m of the beamline is a cylindrical aluminum pre-collimator which is 0.635 cm (0.25 in) thick, with an inner diameter of 5.08 cm (2 in). Based on Monte Carlo model results, when a pre-collimator is present, the use of a neutron absorbing liner on the inside surface of the beam tube has almost no effect on the angular distribution of the neutron current at the collimator exit. The use of a pre-collimator may result in a non-uniform flux profile at the image plane; however, as long as the collimator is at least three times longer than the pre-collimator, the flux distortion is acceptably low.

2012年,科罗拉多矿业学院在美国地质调查局(United States Geological Survey)的TRIGA反应堆上安装了中子射线照相系统。升级后的光束线可以显著提高该系统的成像能力。该项目进行了计算分析,以支持新光束线的设计,其主要目标是最小化光束发散和最大化光束强度。新的光束线将由一个方形铝管组成,内径为11.43厘米(4.5英寸),壁厚为0.635厘米(0.25英寸)。它与原来的梁管(8.53米)长度相同,由1.22米(4英尺)和1.52米(5英尺)的法兰部分螺栓连接在一起。光束线的底部1.22米是一个圆柱形的铝预准直器,厚度为0.635厘米(0.25英寸),内径为5.08厘米(2英寸)。基于蒙特卡罗模型的结果表明,当存在预准直器时,在束流管内表面使用中子吸收衬垫对准直器出口处中子电流的角分布几乎没有影响。预准直器的使用可能导致像面上的通量分布不均匀;然而,只要准直器至少比预准直器长三倍,磁通畸变是可接受的低。
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引用次数: 0
Experimental Evaluation of Neutron Absorption Grating Fabricated by Oblique Evaporation of Gadolinium for Phase Imaging 钆斜蒸发中子吸收光栅相位成像的实验评价
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.06.030
Yoshichika Seki , Takenao Shinohara , Wakana Ueno , Joseph D. Parker , Tetsuo Samoto , Wataru Yashiro , Atsushi Momose

For the neutron phase imaging with a Talbot-Lau interferometer, we have fabricated neutron absorption gratings with a pitch of 9 μm by oblique evaporation of gadolinium. The performances of these gratings for the phase measurement were experimentally evaluated at RADEN in J-PARC, by observing the neutron transmission and the visibility of moiré fringe in the interferometer. A new analysis method using the wavelength-resolved neutron transmission was also attempted to estimate the characteristics of gratings.

为了在塔尔伯特-劳干涉仪上进行中子相位成像,我们采用钆斜蒸发法制备了9 μm的中子吸收光栅。在J-PARC的RADEN上,通过观察中子透射率和干涉条纹的可见性,对这些光栅的相位测量性能进行了实验评价。本文还尝试了一种利用波长分辨中子透射率分析光栅特性的新方法。
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引用次数: 14
Influence of Formation Conditions on the Level of Arrays Ordering of Anodic Titanium Oxide Nanotubes 形成条件对阳极氧化钛纳米管阵列有序水平的影响
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.01.015
N.B. Kondrikov, P.L. Titov, S.A. Schegoleva, M.A. Khorin

Nanotubular titanium oxide coatings with different morphology and dimensional parameters are formed by anodic oxidation under different voltage and time modes in fluorine aqueous-nonaqueous electrolytes containing glycerin as well as several surface-active agents (SAA). Their morphological peculiarities are examined and qualitative and quantitative analysis of obtained types of ordering is carried out, geometric configuration entropy are calculated on the base of analysis SEM images and theory of self-organization.

在含氟的水-非水电解质(含甘油)和几种表面活性剂(SAA)中,通过不同电压和时间模式的阳极氧化,形成了具有不同形貌和尺寸参数的纳米管氧化钛涂层。考察了它们的形态特征,对得到的有序类型进行了定性和定量分析,并根据分析SEM图像和自组织理论计算了几何构型熵。
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引用次数: 3
Local Density of States in One-dimensional Photonic Crystals and Sinusoidal Superlattices 一维光子晶体和正弦超晶格的局域态密度
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.01.030
V.A. Ignatchenko, D.S. Tsikalov

We have calculated the local density of states (LDOS) for four Brillouin zones of a superlattice for a plane source depending on its location relative to the change in the profile of dielectricpermeability ɛ(z) of the superlattice. It is shown that the LDOS for the cases of sinusoidal and rectangular profiles of ɛ(z) are close to each other in the first and second Brillouin zones, and sharp differences between them appear beginning with the third zone. Radical changes in the LDOS occur in a rectangular superlattice with different thicknesses of adjacent layers. In this case, the function LDOS has a sharp jump at the edges of the allowed bands in the transition from one layer to another. The effects studied theoretically in this paper, can be detected and studied experimentally by the intensively developing currently methods of nanooptics.

我们计算了平面源超晶格四个布里渊带的局域态密度(LDOS),这取决于其相对于超晶格介电导率曲线的变化。结果表明,正弦曲线和矩形曲线的LDOS在第一和第二布里渊区非常接近,而从第三布里渊区开始,它们之间出现了明显的差异。LDOS的剧烈变化发生在相邻层厚度不同的矩形超晶格中。在这种情况下,函数LDOS在从一层到另一层的过渡中,在允许带的边缘有一个急剧的跳跃。本文理论研究的效应,可以通过目前正在蓬勃发展的纳米光学方法进行检测和实验研究。
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引用次数: 3
Monitoring of Varying Joint Gap Width During Laser Beam Welding by a Dual Vision and Spectroscopic Sensing System 激光焊接过程中接头间隙宽度变化的双视觉和光谱传感系统监测
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.08.014
Morgan Nilsen , Fredrik Sikström , Anna-Karin Christiansson , Antonio Ancona

A vision and spectroscopic system for estimation of the joint gap width in autogenous laser beam butt welding is presented. Variations in joint gap width can introduce imperfections in the butt joint seam, which in turn influence fatigue life and structural integrity. The aim of the monitoring approach explored here is to acquire sufficiently robust process data to be used to guide post inspection activities and/or to enable feedback control for a decreased process variability. The dual-sensing approach includes a calibrated CMOS camera and a miniature spectrometer integrated with a laser beam tool. The camera system includes LED illumination and matching optical filters and captures images of the area in front of the melt pool in order to estimate the joint gap width from the information in the image. The intensity of different spectral lines acquired by the spectrometer has been investigated and the correlation between the intensity of representative lines and the joint gap width has been studied. Welding experiments have been conducted using a 6 kW fiber laser. Results from both systems are promising, the camera system is able to give good estimations of the joint gap width, and good correlations between the signal from the spectrometer and the joint gap width have been found. However, developments of the camera setup and vision algorithm can further improve the joint gap estimations and more experimental work is needed in order to evaluate the robustness of the systems.

提出了一种用于自激光束对接焊接接头间隙宽度估计的视觉光谱系统。接头间隙宽度的变化会在对接缝中引入缺陷,进而影响疲劳寿命和结构完整性。这里探讨的监控方法的目的是获得足够可靠的过程数据,用于指导后期检查活动和/或对减少的过程可变性进行反馈控制。双传感方法包括一个校准的CMOS相机和一个集成了激光束工具的微型光谱仪。该摄像系统包括LED照明和匹配的光学滤光片,并捕获熔池前方区域的图像,以便从图像中的信息估计接合间隙宽度。研究了不同谱线的强度,并研究了代表性谱线强度与接头间隙宽度的相关性。利用6kw光纤激光器进行了焊接实验。两种系统的结果都很有希望,相机系统能够很好地估计节理间隙宽度,并且发现了光谱仪信号与节理间隙宽度之间的良好相关性。然而,摄像机设置和视觉算法的发展可以进一步改善关节间隙估计,并且需要更多的实验工作来评估系统的鲁棒性。
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引用次数: 7
Detection System of the First Rapidly Relocatable Tagged Neutron Inspection System (RRTNIS), Developed in the Framework of the European H2020 C-BORD Project 在欧洲H2020 C-BORD项目框架下开发的首个快速可重新定位标记中子检测系统(RRTNIS)的检测系统☆
Pub Date : 2017-01-01 DOI: 10.1016/j.phpro.2017.09.010
Cristiano Lino Fontana , Alberto Carnera , Marcello Lunardon , Felix Pino , Cinzia Sada , Francesca Soramel , Luca Stevanato , Giancarlo Nebbia , Cédric Carasco , Bertrand Perot , Alix Sardet , Guillaume Sannie , Alessandro Iovene , Carlo Tintori , Krystian Grodzicki , Marek Moszyński , Paweł Sibczyński , Lukasz Swiderski , Sandra Moretto

The European project entitled “effective Container inspection at BORDer control points” (C-BORD) focuses on the development and in-situ tests of a comprehensive cost-effective solution for the generalized Non-Intrusive Inspection (NII) of containers and large-volume freight at the European Union (EU) border. It copes with a large range of targets, including explosives, chemical warfare agents, illicit drugs, tobacco and Special Nuclear Materials. Within the C-BORD project, a new generation of Tagged Neutron Inspection System (TNIS) for cargo containers is foreseen. Unlike its predecessors, this system would be the first Rapidly Relocatable TNIS (RRTNIS). It will be a second-line defense system, to be used on sealed containers in order to detect explosives, illicit drugs and chemical agents in a suspect voxel (elementary volume unit).

We report on the status of the RRTNIS system, in particular the overall design, the characterization of the large-volume NaI(Tl) gamma detectors, the digital analysis of the time measurements and the Data Acquisition System (DAQ).

题为"边境控制点有效集装箱检查" (C-BORD)的欧洲项目侧重于开发和现场测试一种具有成本效益的综合解决方案,用于在欧洲联盟(欧盟)边境对集装箱和大批量货物进行普遍非侵入性检查。它能对付各种各样的目标,包括炸药、化学战剂、非法药物、烟草和特殊核材料。在C-BORD项目中,新一代的标签中子检测系统(TNIS)将用于货物集装箱。与之前的系统不同,该系统将是第一个快速可重新定位的TNIS (RRTNIS)。这将是第二线防御系统,用于密封容器,以便在可疑体素(基本体积单位)中探测爆炸物、非法药物和化学剂。我们报告了RRTNIS系统的现状,特别是总体设计,大体积NaI(Tl)伽马探测器的特性,时间测量的数字分析和数据采集系统(DAQ)。
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引用次数: 17
期刊
Physics Procedia
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