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Proceedings of 1994 IEEE 1st World Conference on Photovoltaic Energy Conversion - WCPEC (A Joint Conference of PVSC, PVSEC and PSEC)最新文献

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Effect of different TCO interfaces on the performances presented by hydrogenated amorphous silicon p-i-n solar cells 不同TCO界面对氢化非晶硅p-i-n太阳能电池性能的影响
E. Fortunato, C. Carvalho, A. Bicho, R. Martins
In this paper we report results concerning the effect of the TCO interface on hydrogenated amorphous silicon (a-Si:H) p-i-n homojunction solar cells. Its correlation with dark current density-voltage (J-V) characteristics and spectral response, before and after white light-soaking degradation, is analysed. From this study, we conclude that the properties and stability of these devices are not only influenced by the a-Si:H film properties, but also by the properties of the transparent conductive electrode and its interface with the a-Si:H layer.
本文报道了TCO界面对氢化非晶硅(a-Si:H) p-i-n均结太阳能电池的影响。分析了其与白光浸泡降解前后的暗电流密度电压(J-V)特性和光谱响应的相关性。通过本研究,我们得出结论,这些器件的性能和稳定性不仅受到a-Si:H薄膜性能的影响,还受到透明导电电极及其与a-Si:H层界面性能的影响。
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引用次数: 0
Precise investigation of the light-saturated defect density in amorphous silicon very thin films and solar cells 非晶硅极薄膜和太阳能电池中光饱和缺陷密度的精确研究
J. Kǒcka, M. Vaněček, P. Machácek, A. Fejfar, E. Šípek, Ho-The-Ha, I. Pelant, J. Frič, J. Rosa, Z. Remeš, A. Poruba, M. Konagai, W. Kusian
The authors present progress in the three regions important for optimization of the highest long term a-Si:H solar cells efficiency: (1) in order to achieve light saturated state rapidly and controllably a new method of the accelerated degradation by combined AM1 and pulsed ruby laser illumination is proposed; (2) diagnostic of the degraded state is then made possible by a new constant photocurrent method setup combining standard and transmission modes which gives absorption coefficient a in the absolute units and undisturbed by interferences; (3) the possibility to measure deep defect density of states directly on a-Si:H solar cells by space-charge-limited-current time-of-flight is demonstrated.
作者在优化a- si:H太阳能电池最高长期效率的三个重要领域取得了进展:(1)为了快速可控地达到光饱和状态,提出了一种AM1和脉冲红宝石激光联合照射加速降解的新方法;(2)利用一种结合标准模式和透射模式的新型恒光电流方法,可以得到吸收系数a的绝对单位,并且不受干扰;(3)论证了利用空间电荷限流飞行时间直接测量a-Si:H太阳能电池深层缺陷密度的可能性。
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引用次数: 0
Building integration of an amorphous silicon photovoltaic facade 建筑集成了一个非晶硅光伏立面
H. Ossenbrink, L. Rigolini, O. Chehab, O. van der Venne
A large photovoltaic facade was retrofitted to an industrial building complex of the Joint Research Centre. Amorphous silicon technology was chosen to cover the maximum possible area at a minimum of costs. The a-Si substrates are laminated within a double-glass facade element. Total area of the facade is 770 m/sup 2/, probably the largest PV facade in operation. Total power output fed into the grid is approximately 25 kWp after stabilisation. Emphasis was put on the architectural design and the visualisation of the function of the system to a wider public by an interactive user-display.
联合研究中心的工业建筑综合体改造了一个大型光伏立面。选择非晶硅技术是为了以最小的成本覆盖尽可能大的面积。a- si衬底层压在双层玻璃立面元素内。立面总面积为770平方米/平方英尺,可能是最大的光伏立面。稳定后,输电网的总输出功率约为25千瓦时。重点放在建筑设计上,并通过交互式用户显示向更广泛的公众展示系统的功能。
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引用次数: 11
Recombination mechanisms at window/emitter interface in InP and other III-V semiconductor based solar cells InP和其他III-V型半导体太阳能电池中窗口/发射极界面的复合机制
J. Lammasniemi, K. Tappura, K. Smekalin
The effect of various window layers for InP solar cells are studied. Window materials that have type I and type II alignments in the window/emitter interface are compared. All window materials that form a type II alignment with InP, such as Al/sub 0.20/In/sub 0.80/P, Ga/sub 0.20/In/sub 0.80/P, Al/sub 0.55/In/sub 0.45/As and Al/sub 0.60/In/sub 0.40/P, cause a high interface recombination velocity, which deteriorates the carrier collection. This recombination takes place due to the spatially indirect quantum well transition between the triangular quantum wells formed in the interface. ZnSe as a window layer material with type I alignment does not have this problem, but decreased response in the short wavelength region is observed due to misfit dislocation induced trap sites. Future prospects for the window layer development for InP are discussed. The discussion is extended also to other III-V semiconductor based solar cell materials, such as Ga/sub 0.5/In/sub 0.5/P solar cells with Al/sub x/Ga/sub 1-x/As window layers.
研究了不同窗口层对InP太阳能电池性能的影响。比较了在窗口/发射器界面中具有类型I和类型II对准的窗口材料。Al/sub 0.20/In/sub 0.80/P、Ga/sub 0.20/In/sub 0.80/P、Al/sub 0.55/In/sub 0.45/ as和Al/sub 0.60/In/sub 0.40/P等所有与InP形成II型取向的窗口材料,都会导致界面复合速度高,从而使载流子收集恶化。这种复合是由于在界面中形成的三角形量子阱之间的空间间接量子阱跃迁而发生的。ZnSe作为I型取向的窗口层材料不存在这个问题,但由于错配位错诱导的陷阱位点,在短波长区域的响应降低。展望了InP窗口层的发展前景。讨论还扩展到其他III-V型半导体太阳能电池材料,例如具有Al/sub x/Ga/sub 1-x/ as窗口层的Ga/sub 0.5/In/sub 0.5/P太阳能电池。
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引用次数: 3
Advanced automation techniques for interconnecting thin silicon solar cells 薄硅太阳能电池互连的先进自动化技术
M. Nowlan, S. Hogan, G. Darkazalli, S. Sutherland, W. Breen, J. Murach, J. Patterson
The objective of this work is to reduce the cost and improve the quality of terrestrial photovoltaic modules by developing automated high-throughput (5 MW/yr) processes for interconnecting thin silicon solar cells. New low-stress, high-throughput processes have been developed for cell loading, alignment, and inspection, interconnect ribbon handling, flux application, ribbon-to-cell soldering, cell string handling, and I-V testing of assembled cell strings. Both standard thickness (350 /spl mu/m) and thin (200 /spl mu/m) cells have been used to evaluate and refine these processes.
这项工作的目标是通过开发用于连接薄硅太阳能电池的自动化高通量(5兆瓦/年)工艺来降低成本并提高地面光伏组件的质量。新的低应力、高通量工艺已经开发出来,用于电池加载、对准和检查、互连带处理、助焊剂应用、带到电池焊接、电池串处理以及组装电池串的I-V测试。标准厚度(350 /spl mu/m)和薄厚度(200 /spl mu/m)的细胞都被用来评估和改进这些过程。
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引用次数: 10
Electrical and structural properties of the Si/C interface in poly-Si thin films on graphite substrates [for PV cells] 石墨基多晶硅薄膜中Si/C界面的电学和结构特性[用于光伏电池]
T. Reindl, W. Kruhler, M. Pauli, J. Muller
For the first time the Si/C interface in poly-Si photovoltaic thin films on graphite substrate is described. The isostatically pressed graphite is covered with a 3-5 /spl mu/m thick amorphous silicon layer which is recrystallized by the ZMR method (zone melting recrystallization by means of a line electron beam). During ZMR the molten silicon penetrates into the graphite pores, while at the interface /spl beta/-SiC particles with a size of 50-1000 nm were formed (TEM, SEM analysis). Furthermore there exists a "reaction zone" where Si, SiC and C are found by electron diffraction. As a consequence the poly-Si layer shows an excellent adhesion to the substrate. Since there is no continuous electrically insulating SiC layer formed, highly boron doped seed layers show an ohmic contact to the graphite. The investigated poly-Si thin films on graphite substrate offer a great potential for photovoltaic application after epitaxy up to 50 /spl mu/m by LPE or CVD.
首次描述了石墨衬底上多晶硅光伏薄膜的硅/碳界面。在等静压石墨表面覆盖3-5 /spl μ m厚的非晶硅层,采用ZMR法(线电子束区域熔化再结晶法)进行再结晶。在ZMR过程中,熔融硅渗透到石墨孔中,在界面处形成了50 ~ 1000 nm大小的/spl β /-SiC颗粒(TEM、SEM分析)。此外,还存在一个“反应区”,在那里通过电子衍射可以发现Si、SiC和C。因此,多晶硅层对衬底具有优异的附着力。由于没有形成连续的电绝缘SiC层,高硼掺杂的种子层显示出与石墨的欧姆接触。所研究的石墨衬底多晶硅薄膜在LPE或CVD外延达到50 /spl mu/m后,具有很大的光伏应用潜力。
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引用次数: 1
Overview of the US DOE/NREL polycrystalline thin-film photovoltaic technologies 美国DOE/NREL多晶薄膜光伏技术综述
H. Ullal, K. Zweibel, B. von Roedern, R. Noufi, P. Sheldon
Thin-film solar cells based on CdTe, CuInSe/sub 2/ (CIS) and Si-film have made rapid progress in the past 18 months. Total-area efficiencies of 16.8% for CIGS, 15.8% for CdTe, and 13.4% for Si-film on graphite cloth, verified by the National Renewable Energy Laboratory, have been achieved thus far. The performance of thin-film modules for both CdTe and CIS have also improved markedly. Stability data for these emerging technologies is encouraging. Nominal 1-kW CIS and CdTe PV arrays have been installed and are undergoing testing. A 2-MW thin-film CdTe manufacturing plant has been installed, and another 10-MW thin-film CdTe plant is expected to be completed in 1996. A new Thin Film Partnership Program has been initiated to further advance the state-of-art of thin film technologies.
基于CdTe、cinsse /sub 2/ (CIS)和si薄膜的薄膜太阳能电池在过去的18个月里取得了快速的进展。经国家可再生能源实验室验证,CIGS的总面积效率为16.8%,CdTe为15.8%,石墨布上的硅膜为13.4%。CdTe和CIS薄膜组件的性能也有了明显的提高。这些新兴技术的稳定性数据令人鼓舞。标称1千瓦CIS和CdTe光伏阵列已经安装并正在进行测试。一个2兆瓦的薄膜碲化镉制造工厂已经安装,另一个10兆瓦的薄膜碲化镉工厂预计将于1996年完工。一项新的薄膜合作计划已经启动,以进一步推进最新的薄膜技术。
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引用次数: 3
Schottky barrier enhancement on n-InP solar cell applications 肖特基势垒增强在n-InP太阳能电池中的应用
Thomas Clausen, O. Leistiko
It is demonstrated that the Schottky barrier height on n-type InP can be enhanced to values close to the energy bandgap (1.35 eV) by employing a AuZnCr metallization. The process is simple and requires only mild and fast annealing sequences with temperatures not exceeding 500/spl deg/C. Also, no critical epitaxial growth step of junctions is needed, making the process fairly cheap. Thus, prospects for an efficient and simple solar cell device structure for space application purposes based on highly radiant-resistant InP are greatly improved.
结果表明,采用AuZnCr金属化可以将n型InP上的肖特基势垒高度提高到接近能带隙(1.35 eV)的值。该工艺简单,只需要温度不超过500/spl℃的温和快速退火程序。此外,不需要关键的结外延生长步骤,使该过程相当便宜。因此,基于高抗辐射InP的高效、简单的空间应用太阳能电池器件结构的前景大大改善。
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引用次数: 0
Design and cost optimization of utility-grade off-grid power systems 公用级离网电力系统的设计与成本优化
J. Berdner, C. Whitaker, H. Wenger, C. Jennings
Electric utilities are beginning to provide off-grid electricity service to customers in lieu of extending uneconomic electric distribution lines. To a large extent, the success of an electric utility off-grid service program is dependent on the utility's ability to provide power systems with excellent reliability and power quality at competitive prices. In December 1992, Pacific Gas and Electric Company (USA) tested the provision of off-grid service by procuring a first-generation PV power system which was installed at a customer's residence in April 1993. This pilot was a technical success, demonstrating that an electric utility can provide reliable, high-quality off-grid power. The project did, however, highlight the need for large cost reductions necessary for significant market penetration. This paper presents a second generation design which attempts to address these issues.
电力公司开始向客户提供离网电力服务,以取代延长不经济的配电线路。在很大程度上,电力公司离网服务计划的成功取决于该公司能否以具有竞争力的价格为电力系统提供卓越的可靠性和电能质量。1992年12月,太平洋天然气和电力公司(美国)采购了第一代光伏发电系统,测试了离网服务的提供情况,该系统于1993年4月安装在一个客户的住所。该试点在技术上取得了成功,证明了电力公司可以提供可靠、高质量的离网电力。然而,该项目确实强调了大幅降低成本的必要性,这是市场渗透所必需的。本文提出了试图解决这些问题的第二代设计。
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引用次数: 2
Effects of concentrator chromatic aberration on multi-junction cells 聚光器色差对多结细胞的影响
L. W. James
Most practical photovoltaic concentrator optics have considerable chromatic aberration. Thus in a two-junction monolithic cell, the pattern of current generation in the high-bandgap junction is different from that in the low-bandgap junction, resulting in an attempted current flow parallel to the junction in the tunnel junction and adjacent layers. Sheet resistivity of these layers is too high to support this lateral current flow, so at each point on the cell, the current is limited to the current generated in the lowest-current junction. This results in a substantial loss in cell output unless the chromatic aberration of the optics is somehow compensated for. Using a software model, the authors have examined the losses caused by chromatic aberration, and have designed two types of concentrator optics which meet the spectral uniformity needs of multijunction solar cells. One is for space applications where weight is an overriding concern. The other is for terrestrial use where cost and a low sensitivity to construction and operating tolerances are paramount.
大多数实用的光伏聚光器光学具有相当大的色差。因此,在双结单片电池中,高带隙结中的电流产生模式与低带隙结中的电流产生模式不同,导致电流试图平行于隧道结和相邻层中的结。这些层的电阻率太高,无法支持这种横向电流流动,因此在电池上的每个点上,电流被限制在最低电流结中产生的电流。除非光学的色差以某种方式得到补偿,否则这将导致细胞输出的大量损失。利用软件模型研究了色差造成的损耗,设计了两种满足多结太阳能电池光谱均匀性要求的聚光光学器件。一个是空间应用,重量是最重要的问题。另一种是地面使用,成本和对结构和操作公差的低灵敏度是最重要的。
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引用次数: 35
期刊
Proceedings of 1994 IEEE 1st World Conference on Photovoltaic Energy Conversion - WCPEC (A Joint Conference of PVSC, PVSEC and PSEC)
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