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Damage mitigation method studies through simulation modeling of chemical accidents 通过化学事故模拟模型研究损害缓解方法
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-10 DOI: 10.1002/prs.12563
Sehyeon Oh, Junseo Lee, Byungchol Ma
In the chemical industry, when a fire occurs, a significant amount of energy is generated due to combustion, impacting other facilities within the plant and potentially leading to severe consequences through a domino effect. For decades, thermal radiation caused by flames has been calculated and predicted through simplified fire modeling. However, with advancements in computing technology, numerical model-based calculations have greatly improved, allowing for a more realistic implementation that considers actual phenomena. In this study, accident data and 3D modeling information were utilized to conduct fire modeling and simulation based on actual incidents in chemical plants. Through the analysis of simulation results, the initial emergency evacuation distance was provided to minimize the damage caused by thermal radiation, and the final evacuation distance was presented using the probit function. In addition, the study evaluated the impact of generated thermal radiation and overpressure on structures and equipment, providing evidence regarding the potential for secondary incidents. Moreover, the research revealed that the impact of thermal radiation and overpressure decreases due to obstacles, offering insights into the selection of emergency evacuation routes. This study can contribute to supporting effective emergency evacuation strategies in chemical facilities.
在化学工业中,一旦发生火灾,燃烧会产生大量能量,影响工厂内的其他设施,并可能通过多米诺骨牌效应导致严重后果。几十年来,火焰引起的热辐射一直是通过简化的火灾模型来计算和预测的。然而,随着计算技术的进步,基于数值模型的计算方法也有了很大的改进,从而可以更真实地考虑实际现象。本研究利用事故数据和三维建模信息,根据化工厂的实际事故进行火灾建模和模拟。通过对模拟结果的分析,提供了初始紧急疏散距离,以最大限度地减少热辐射造成的损害,并利用 probit 函数提出了最终疏散距离。此外,研究还评估了产生的热辐射和超压对结构和设备的影响,为可能发生的二次事故提供了证据。此外,研究还发现,热辐射和超压的影响会因障碍物的存在而减小,这为选择紧急疏散路线提供了启示。这项研究有助于支持化工设施的有效紧急疏散战略。
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引用次数: 0
In memory of Joseph F. Louvar, 1935–2023, former Editor-in-Chief of Process Safety Progress 纪念《过程安全进展》前主编约瑟夫-F-卢瓦尔(Joseph F. Louvar),1935-2023 年
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-09 DOI: 10.1002/prs.12581
Daniel A. Crowl, John Murphy, Roy Sanders, Ronald J. Willey
<h2>1 REMEMBRANCE BY DANIEL A. CROWL, FORMER EDITOR-IN-CHIEF, OF <i>PROCESS SAFETY PROGRESS</i></h2><p>Joseph F. Louvar passed away on December 11, 2023, at the age of 88.</p><p>Louvar was best known as an outstanding advocate for process safety and undergraduate chemical engineering instruction in process safety.</p><p>Louvar was born on September 27, 1935, in south Chicago, IL. He was the son of a Chicago fireman.</p><p>He received his BS degree in 1957 from the Missouri School of Mines and Technology (currently Missouri University of Science and Technology), his MS degree from Carnegie Mellon in 1961, and his PhD from Wayne State University in 1983, all in chemical engineering.</p><p>Louvar was in ROTC during his undergraduate years and graduated with the rank of second Lieutenant.</p><p>In 1960, Louvar joined Corn Products as a process engineer.</p><p>In 1961, Louvar married Berenice “Diane” Wassil who was working on her chemistry degree at Carnegie Mellon. They were married for 62 years until her passing in June of 2023. They have four children and eight grandchildren.</p><p>In 1962, Louvar and his wife were hired by the Catholic Extension Society to manage St. Joseph's Orphanage in Bethany, Oklahoma. They directed a staff of 12 and cared for up to 70 children.</p><p>In 1965, Louvar joined Wyandotte Chemicals (now BASF) in Wyandotte, MI as a development engineer. He held many positions at BASF, including Director of Inorganic R&D and Director of Chemical Engineering. His job functions included systems engineering, process design, R&D management, and small-scale production of chemicals. He retired from BASF in 2000.</p><p>In 1983, Louvar received his PhD degree from Wayne State University in Detroit. His Ph.D. advisor was Dr. Daniel A. Crowl.</p><p>In the summer of 1985, Louvar convinced Crowl to spend a summer working at BASF in Wyandotte, MI. Through this experience, Crowl recognized the importance of process safety to industrial operations and the necessity for undergraduate instruction in process safety. Louvar and Crowl form an inseparable team for process safety education.</p><p>In 1987, Louvar became chair of the CCPS Undergraduate Education Committee, which would be renamed SACHE: Safety and Chemical Engineering Education in 1993. Louvar would also serve as chair of the AIChE 11a committee, Chair of the Loss Prevention Symposium, and Chair of the Safety and Health Division.</p><p>In 1987, Louvar and Crowl decided that a textbook on process safety for undergraduate chemical engineers is essential. Their first edition was published in 1990. It is currently in the fourth edition.</p><p>In 2000, Louvar was appointed Research Professor at Wayne State, a position he held until 2010.</p><p>Louvar authored or coauthored 35 publications, 10 patents, and 2 books.</p><p>In 1986, Louvar was recognized as the Chemical Engineer of the Year by the AIChE Detroit Local Section. In 1996, he became a Fellow of AIChE. In 1997, he
1 PROCESS SAFETY PROGRESS 前主编 DANIEL A. CROWL 的悼念Joseph F. Louvar 于 2023 年 12 月 11 日逝世,享年 88 岁。他于 1957 年获得密苏里矿业技术学院(现密苏里科技大学)理学学士学位,1961 年获得卡内基梅隆大学理学硕士学位,1983 年获得韦恩州立大学化学工程博士学位。1960 年,卢瓦尔加入玉米产品公司,担任工艺工程师。1961 年,卢瓦尔与正在卡内基梅隆大学攻读化学学位的 Berenice "Diane" Wassil 结婚。他们结婚 62 年,直到她于 2023 年 6 月去世。1962 年,卢瓦尔和妻子受雇于天主教推广协会,管理俄克拉荷马州伯大尼的圣约瑟夫孤儿院。1965 年,卢瓦尔加入密歇根州怀恩多特的怀恩多特化工公司(现为巴斯夫公司),担任开发工程师。他在巴斯夫担任过许多职位,包括无机研发总监和化学工程总监。他的工作职能包括系统工程、工艺设计、研发管理和化学品的小规模生产。1983 年,卢瓦尔从底特律韦恩州立大学获得博士学位。1985 年夏天,卢瓦尔说服克劳尔在密歇根州怀安多特的巴斯夫工作了一个夏天。通过这段经历,克劳尔认识到了工艺安全对工业运营的重要性,以及本科生工艺安全教学的必要性。1987 年,Louvar 成为 CCPS 本科教育委员会主席,该委员会于 1993 年更名为 SACHE:安全与化学工程教育。Louvar 还担任了 AIChE 11a 委员会主席、损失预防研讨会主席以及安全与健康分会主席。1987 年,Louvar 和 Crowl 决定,为本科生化学工程师编写一本工艺安全教科书至关重要。第一版于 1990 年出版。2000 年,卢瓦尔被任命为韦恩州立大学的研究教授,他一直担任这一职务直到 2010 年。1986 年,卢瓦尔被美国化学工程师学会底特律地方分会评为年度化学工程师。1996 年,他成为 AIChE 会员。1997 年,他荣获韦恩州立大学杰出成就奖。1998 年,他入选密歇根理工大学杰出化学工程学院。2000 年,他入选密苏里州 S&T 化学工程师学会。2001 年,他获得了诺顿-沃尔顿/拉塞尔-米勒安全/损失预防奖(Norton H. Walton/Russell L. Miller Award in Safety/Loss Prevention),这是美国化学工程师学会安全与健康分会(现为工艺安全分会)颁发的最高奖项。那一天,我的生活和世界都发生了翻天覆地的变化!
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引用次数: 0
Status of the Process Safety Division newsletter 工艺安全司通讯的现状
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-09 DOI: 10.1002/prs.12578
Lisa A. Long
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引用次数: 0
Omission of important concepts in two articles on laboratory safety in PSP, Vol. 42, No. 4 December 2023 PSP》中两篇关于实验室安全的文章遗漏了重要概念,第 42 卷第 4 期 2023 年 12 月
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-09 DOI: 10.1002/prs.12583
R. Prugh
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引用次数: 0
Kinetics for the sulfuric acid-catalyzed reactions of ethylene oxide with water and ethylene glycols 硫酸催化环氧乙烷与水和乙二醇的反应动力学
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-08 DOI: 10.1002/prs.12557
Marc E. Levin, Justin Mitschke, Sheehan Smith, Peter I. Chipman, S. K. Singh, Robert Lenahan, Timothy S. Frederick, Bill Gulledge
Adiabatic calorimeter experiments have quantified the sulfuric acid-catalyzed reaction of ethylene oxide (EO) with water to form ethylene glycol (EG) and higher glycols. Conditions were selected relevant to industrial safety, such as a scenario of reverse flow of acid from a scrubber to an EO tank. Concentrations of 25–95 wt% EO with acidified water of pH 3.0 down to pH –0.7 were examined. In some experiments, EG was also added to the mix. The best fit apparent reaction rate expression exhibits a 1.5 order in EO concentration, third order in water concentration, nearly first order in acid concentration, and an activation energy of 76,500 kJ/kmol. The reaction model provides an adequate fit of adiabatic self-heat rate versus temperature, pressure rate versus temperature, pressure versus time, and temperature versus time data for a large number of APTAC (Automatic Pressure Tracking Adiabatic Calorimeter) experiments. The model builds on one previously developed for the neutral reactions of EO with water and EGs. A case study involving a sulfuric acid-contaminated EO railcar is presented. The reaction model can help quantify the behavior of EO contaminated with sulfuric acid solution below about 120°C. Above this temperature, other reaction pathways not characterized in this study become more prominent.
绝热量热计实验对硫酸催化环氧乙烷(EO)与水反应生成乙二醇(EG)和高乙二醇的过程进行了量化。实验选择了与工业安全相关的条件,例如酸从洗涤器逆向流向环氧乙烷罐的情景。实验考察了浓度为 25-95 wt% 的环氧乙烷与 pH 值为 3.0 至 pH 值为 -0.7 的酸化水的混合情况。在某些实验中,还在混合液中加入了 EG。最佳拟合表观反应速率表达式显示,环氧乙烷浓度为 1.5 阶,水浓度为三阶,酸浓度接近一阶,活化能为 76,500 kJ/kmol。该反应模型充分拟合了大量 APTAC(自动压力跟踪绝热量热仪)实验的绝热自热速率与温度、压力速率与温度、压力与时间以及温度与时间的关系数据。该模型建立在之前为环氧乙烷与水和 EGs 的中性反应开发的模型基础之上。介绍了一个涉及硫酸污染环氧乙烷轨道车的案例研究。该反应模型有助于量化被硫酸溶液污染的环氧乙烷在 120°C 以下的行为。在这一温度以上,本研究中未描述的其他反应途径变得更加突出。
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引用次数: 0
Consequences analysis of a natural gas pipeline: The case of the trans-Anatolian natural gas pipeline 天然气管道的后果分析:跨安纳托利亚天然气管道案例
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-08 DOI: 10.1002/prs.12574
Saliha Cetinyokus, Duran Dinc, Sila Ata
Industrial accidents include fire, explosion, and toxic substance spread involving hazardous substances. They threaten the health of many people, cause permanent or long-term pollution of the natural environment, cause a high degree of property damage, and require a large-scale emergency response. Pipelines that transfer hazardous chemicals over a large area are risky for industrial accidents. In this study, we aimed to analyze the consequences of a possible industrial accident at the Edirne Ipsala compressor station in the trans-Anatolian natural gas pipeline (TANAP). Analyses were carried out with the ALOHA software on two hypothetical scenarios: In Scenario 1, the chemical escapes from the pipe without the gas burning; and in Scenario 2, the chemical escapes from the pipe with the gas burning (jet fire). In the analysis of overpressure effects, TNT EM and TNO MEM were used besides the software. The largest effect distance (≈5000 m) was determined in the flammable area as a result of Scenario 1, and the prominent hazard property of the chemical was supported. The overpressure effects obtained with TNO MEM and the software were compatible with each other, but the values obtained with TNT EM were less severe and quite different. In the analysis of overpressure effects, it is shown that the ALOHA software provided more conservative results and that buildings would collapse and lethal effects might occur at a distance of 1000 m from the source. ALOHA produced outputs integrated with GIS by providing thermal radiation and toxic effect threat zones as well as overpressure effects. ALOHA turns out to be a more convenient and practical tool for risk assessment studies and emergency plans.
工业事故包括火灾、爆炸和涉及有害物质的有毒物质扩散。它们会威胁许多人的健康,对自然环境造成永久或长期的污染,造成严重的财产损失,并需要采取大规模的应急措施。大面积输送危险化学品的管道具有工业事故风险。在本研究中,我们旨在分析跨安纳托利亚天然气管道 (TANAP) 埃迪尔内 Ipsala 压缩站可能发生的工业事故的后果。我们使用 ALOHA 软件对两种假设情况进行了分析:在方案 1 中,化学品从管道中逸出,气体没有燃烧;在方案 2 中,化学品从管道中逸出,气体燃烧(喷射火)。在分析超压效应时,除软件外,还使用了 TNT EM 和 TNO MEM。根据方案 1 的结果,确定了易燃区的最大影响距离(≈5000 米),并证明了该化学品的突出危险特性。使用 TNO MEM 和软件得出的超压效应相互兼容,但使用 TNT EM 得出的数值不太严重,且差异较大。在分析超压效应时,结果表明 ALOHA 软件提供的结果更为保守,在距离辐射源 1000 米的地方,建筑物就会倒塌,并可能产生致命影响。ALOHA 的输出结果与 GIS 相结合,提供了热辐射和毒性效应威胁区以及超压效应。在风险评估研究和应急计划方面,ALOHA 被证明是一种更方便、更实用的工具。
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引用次数: 0
Grid-based assessment of hydrogen leakages for an offshore process to improve the design and human performance 基于网格的近海工艺氢泄漏评估,以改进设计和人的表现
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-08 DOI: 10.1002/prs.12567
Asher Ahmed Malik, Risza Rusli, Salman Nazir, Rizal Harris Wong, Ushtar Arshad
Hydrogen is gaining global recognition as a sustainable energy source, but its combustible nature raises concerns, especially in congested offshore settings. Steam methane reforming (SMR) remains the predominant hydrogen production method; however, offshore SMR facilities exposed to harsh weather could potentially compromise safety because of leakages. This study uses the fire dynamics simulator (FDS) to carry out the first-of-its-kind CFD modeling of hydrogen leakage and its wind-influenced dispersion on an offshore SMR platform. It also provides the spatial risk that accounts for the probabilities of human errors and wind speeds. The study uses a grid-based approach with 120 monitor points (MPs) to measure locally dispersed gas concentration. At 2 m/s wind speed, only nine grids contain explosive concentrations while the rest remain safe. At 5 m/s, the flammable zones increase by 133%, affecting 21 grids. Extreme wind speeds of 12.5 m/s have limited impact, but SMR1 exhibits higher stoichiometric concentrations. MPs 43–48 record flammable concentrations at all wind speeds; however, at 12.5 m/s the explosion risk is well below the threshold of 1 × 10−4 due to the low wind occurrence probability. Overall, this research contributes to addressing the safety concerns associated with hydrogen in offshore settings and provides a foundation for future risk assessments.
氢作为一种可持续能源正得到全球的认可,但其可燃性引起了人们的担忧,尤其是在拥挤的近海环境中。蒸汽甲烷重整(SMR)仍然是最主要的制氢方法;然而,暴露在恶劣天气下的近海 SMR 设施可能会因泄漏而危及安全。本研究使用火灾动力学模拟器(FDS)对海上 SMR 平台的氢气泄漏及其受风影响的扩散进行了首次 CFD 建模。它还提供了考虑到人为失误概率和风速的空间风险。该研究采用基于网格的方法,通过 120 个监测点 (MP) 来测量局部扩散的气体浓度。风速为 2 米/秒时,只有 9 个网格含有爆炸浓度,其余网格仍然安全。风速为 5 米/秒时,易燃区增加了 133%,影响到 21 个网格。12.5 米/秒的极端风速影响有限,但 SMR1 显示出更高的化学计量浓度。第 43-48 号重大计划在所有风速下都记录了可燃浓度;然而,在 12.5 米/秒时,由于风速发生概率较低,爆炸风险远低于 1 × 10-4 的阈值。总之,这项研究有助于解决近海环境中与氢有关的安全问题,并为未来的风险评估奠定基础。
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引用次数: 0
Digital twin technology and ergonomics for comprehensive improvement of safety in the petrochemical industry 数字孪生技术和人体工程学全面提升石化行业的安全性
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-08 DOI: 10.1002/prs.12575
Jinyang Jia, Xuetao Wang, Yang Xu, Zehua Song, Zimeng Zhang, Jiaqi Wu, Ziyu Liu
In order to improve the safety performance of the complete industrial chain, the petrochemical industry is in urgent need of digitalization and modernization. Considering two types of safety issues, namely safety hazards originating from non-human and human sources, this paper proposes two solutions. Digital twin technology provides an effective way for the integration of the physical and information worlds through bidirectional real mapping and real-time interaction between physical and virtual production lines, which can meet the high requirements of safety, stability, and continuity in the production process. On the other hand, micro-ergonomics improves human–machine interaction, enhances comfort and work efficiency, and reduces negative emotions and the prevalence of musculoskeletal disorders; macro-ergonomics and health, safety, environment, and ergonomics (HSEE) concepts take into account the human factor to maximize work efficiency and reduce the rate of injuries, morbidity, and accidents at work.
为了提高完整产业链的安全性能,石化行业迫切需要实现数字化和现代化。考虑到两类安全问题,即源于非人为和人为的安全隐患,本文提出了两种解决方案。数字孪生技术通过物理生产线与虚拟生产线之间的双向真实映射和实时交互,为物理世界与信息世界的融合提供了有效途径,可满足生产过程对安全性、稳定性和连续性的高要求。另一方面,微观工效学改善了人机交互,提高了舒适度和工作效率,减少了负面情绪和肌肉骨骼疾病的发生率;宏观工效学和健康、安全、环境与工效学(HSEE)理念考虑了人的因素,最大限度地提高了工作效率,降低了工伤率、发病率和事故率。
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引用次数: 0
Analysis of the progress of chemical process safety management in China 中国化工工艺安全管理进展分析
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-05 DOI: 10.1002/prs.12580
Jiling Zhou, Xin Wang
Process safety management (PSM) is a proven and effective management approach that has been validated through practical experience. In recent years, China has been actively exploring advanced PSM methods and has implemented several regulations and standards related to chemical PSM. This article begins with a review of chemical PSM development in China and the United States. It then conducts a comparative analysis of the quantity and content of elements in the PSM systems of both countries. Based on the analysis results, suggestions for improving PSM in China are presented.
工艺安全管理(PSM)是一种经过实践验证的行之有效的管理方法。近年来,中国一直在积极探索先进的 PSM 方法,并实施了多项与化工 PSM 相关的法规和标准。本文首先回顾了中美两国化学品 PSM 的发展历程。然后对两国 PSM 体系中元素的数量和含量进行了对比分析。根据分析结果,提出了改进中国 PSM 的建议。
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引用次数: 0
Adaptive thresholds-based leak detection using real-time transient modeling of two-phase flows 利用两相流实时瞬态建模进行基于阈值的自适应泄漏检测
IF 1 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2024-01-03 DOI: 10.1002/prs.12572
Seshu Kumar Vandrangi, Tamiru Alemu Lemma, Syed Muhammad Mujtaba
Pipelines are widely regarded as the most cost-effective mode of transportation for oil and gas, particularly when it comes to covering long distances. Regrettably, pipelines are not impervious to accidents, which can result in colossal material damage and fatalities. As the demand for oil and gas rises, so does the need for pipelines. Therefore, issues in pipeline malfunctions cannot be overlooked. Leakage and blockage are the two main faults in pipelines that lead to pipeline incidents if not addressed timely. Detecting pipeline leaks is a major hurdle for industry, and various techniques have been developed to tackle this. This article focuses on the modeling of leakage detection in pipelines in two-phase transient flows. Initially, OLGA, a multiphase software, is used for simulating the transient flows in a black oil case study. A leak was induced after 30 min of the simulation and leak cases were designed with varying parameters. Using the simulated data of mass flow rate, and pressure at the inlets and outlets, the model will be identified. The adaptive thresholds-based model was able to predict the leaks accurately. The performance of the leak detection model was analyzed. The model was able to detect leaks of 2%–10% sizes successfully.
管道被广泛认为是最具成本效益的石油和天然气运输方式,尤其是在长距离运输方面。遗憾的是,管道并非不会发生事故,这些事故可能会造成巨大的物质损失和人员伤亡。随着石油和天然气需求的增加,对管道的需求也在增加。因此,管道故障问题不容忽视。管道泄漏和堵塞是管道的两大主要故障,如果不及时处理,就会导致管道事故。检测管道泄漏是工业领域的一大难点,目前已开发出多种技术来解决这一问题。本文重点介绍两相瞬态流中管道泄漏检测建模。首先,在黑油案例研究中使用多相软件 OLGA 模拟瞬态流。模拟 30 分钟后诱发泄漏,并设计了不同参数的泄漏案例。利用质量流量、入口和出口压力的模拟数据,确定模型。基于自适应阈值的模型能够准确预测泄漏。对泄漏检测模型的性能进行了分析。该模型能够成功检测出 2%-10% 尺寸的泄漏。
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引用次数: 0
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Process Safety Progress
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