首页 > 最新文献

Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving最新文献

英文 中文
Indirect determination of the melting temperature in aluminum scrap furnaces 废铝炉熔化温度的间接测定
Ye.N. Panov, M. Bozhenko, M. Korzhyk
Based on the analysis of literary sources, it is shown that the production of secondary non-ferrous metals, and aluminum in particular, is very efficient since the costs of raw materials and materials for their production are much lower than for the production of primary metals. For the production of 1 ton of secondary aluminum, of which about 100,000 tons are produced in Ukraine, about 2,000 kWh of electrical energy is consumed, which is 7-9 times less than for the production of aluminum by the electrolytic method. At the same time, emissions of hydrogen fluoride and resinous substances into the atmosphere, which occur during the production of primary aluminum, are virtually eliminated. Furnaces heated by the burning of gaseous or liquid fuel, as well as furnaces with electric heating, are used for melting aluminum scrap, curing and processing the obtained aluminum. Previous authors’ research concerned the study of temperature and thermal conditions of operation of a stationary furnace for remelting aluminum scrap with electric and gas heating. The working space of the furnace is made in the form of a lined rectangular chamber with a floor, side and end walls, and a vault. The chamber has two zones: the lower one, where the aluminum is located after melting the loaded scrap, and the upper one (without melt). According to the technology, aluminum scrap is first loaded into the furnace through open prechambers, then external heating devices are turned on and the solid material is heated and melted, and then the molten metal is brought to the required temperature, after which steel and other impurities are removed from the working space through prechambers and perform casting of products. After the aluminum casting is complete, the cycle is repeated. Measurement of the melt temperature is usually carried out by thermocouples placed in stainless steel covers or ceramic covers, which, after melting the aluminum, are inserted into the working space of the furnace through holes in the vault. It is noted that the service life of such thermocouples is quite limited due to the destruction of the stainless steel covers upon contact with the melt, and the ceramic covers are quite fragile. That's why a method of an indirect determining the temperature of the melt, which will allow constant control of this temperature and save money on the manufacture of thermocouples in covers, was developed. The results of calculation studies on the determination of the heat flux density and the temperature of the outer surfaces of the side and end walls of the furnace for remelting aluminum scrap in the melt temperature range of 670-750 ºС that were performed using the software developed by the authors, are given. The results of calculations for all options with the relevant specified materials and thicknesses of individual layers of fences, heat transfer surface area and melt temperature tm included the heat flow density q, W / m2; wall temperature of the outer surface of
根据文献资料的分析,它表明,生产次生有色金属,特别是铝,是非常有效的,因为原材料和生产材料的成本远远低于生产原生金属。生产1吨二次铝,其中乌克兰生产约10万吨,消耗约2000千瓦时的电能,比用电解法生产铝少7-9倍。与此同时,在原铝生产过程中产生的氟化氢和树脂物质排放到大气中的现象实际上已被消除。通过燃烧气体或液体燃料加热的炉,以及电热炉,用于熔化铝废料,固化和加工得到的铝。先前作者的研究涉及使用电加热和燃气加热的固定炉重熔铝废料的温度和热条件的研究。该炉的工作空间以有衬里的矩形室的形式制成,具有地板、侧墙和端墙以及拱顶。该腔室有两个区域:下部区域,铝位于熔化后的装载废料,和上部区域(未熔化)。根据该技术,首先通过开放式预室将铝废料装入炉内,然后打开外部加热装置,对固体材料进行加热熔化,然后将熔融金属带到所需温度,然后通过预室将钢和其他杂质从工作空间中去除,进行产品铸造。铝铸件完成后,循环往复。熔体温度的测量通常是通过放置在不锈钢盖或陶瓷盖上的热电偶来进行的,这些热电偶在铝熔化后,通过拱顶上的孔插入炉子的工作空间。值得注意的是,这种热电偶的使用寿命是相当有限的,因为不锈钢盖在接触熔体时被破坏,陶瓷盖非常脆弱。这就是为什么一种间接确定熔体温度的方法被开发出来的原因,这种方法可以恒定地控制温度,并节省盖内热电偶的制造成本。本文给出了用自己开发的软件对废铝重熔炉在熔体温度670 ~ 750ºС范围内的热流密度和侧壁、端壁外表面温度进行计算研究的结果。根据相关规定的材料和栅栏各层厚度、传热表面积和熔体温度tm,计算所有选项的结果包括热流密度q, W / m2;箱体外表面壁温tw,ºС;温差Δ tw = tm - tw,ºС;铝熔体到箱体外表面的换热系数km = (q / Δ tw), W / (m2∙K)。在计算数据的基础上,得到了一个近似的相关性q = f (tw),其最大偏差不超过4.6%。建立了箱体外表面壁面温度对换热系数的依赖关系,建立了km = f (tw)的依赖关系,计算数据的最大偏差不超过5.6%。本文提供了一些实用的建议,关于在熔化铝废料的循环中对炉内熔体温度的操作测定,根据这些建议,在铝熔化后,有必要测量炉壁外表面twºС的两个或三个点的温度,例如,为此目的使用铬铝热电偶。今后还需要根据热流密度q、W/m2和换热系数km、W/ (m2∙K)的图形或它们之间的近似依赖关系来确定。炉内熔体的温度ºС由公式tm = tw + (q / km)确定。在从炉中浇注铝熔体之前,可以用盖上的标准热电偶短时间测量其温度。
{"title":"Indirect determination of the melting temperature in aluminum scrap furnaces","authors":"Ye.N. Panov, M. Bozhenko, M. Korzhyk","doi":"10.20535/2617-9741.2.2023.283520","DOIUrl":"https://doi.org/10.20535/2617-9741.2.2023.283520","url":null,"abstract":"Based on the analysis of literary sources, it is shown that the production of secondary non-ferrous metals, and aluminum in particular, is very efficient since the costs of raw materials and materials for their production are much lower than for the production of primary metals. For the production of 1 ton of secondary aluminum, of which about 100,000 tons are produced in Ukraine, about 2,000 kWh of electrical energy is consumed, which is 7-9 times less than for the production of aluminum by the electrolytic method. At the same time, emissions of hydrogen fluoride and resinous substances into the atmosphere, which occur during the production of primary aluminum, are virtually eliminated. Furnaces heated by the burning of gaseous or liquid fuel, as well as furnaces with electric heating, are used for melting aluminum scrap, curing and processing the obtained aluminum. Previous authors’ research concerned the study of temperature and thermal conditions of operation of a stationary furnace for remelting aluminum scrap with electric and gas heating. The working space of the furnace is made in the form of a lined rectangular chamber with a floor, side and end walls, and a vault. The chamber has two zones: the lower one, where the aluminum is located after melting the loaded scrap, and the upper one (without melt). According to the technology, aluminum scrap is first loaded into the furnace through open prechambers, then external heating devices are turned on and the solid material is heated and melted, and then the molten metal is brought to the required temperature, after which steel and other impurities are removed from the working space through prechambers and perform casting of products. After the aluminum casting is complete, the cycle is repeated. Measurement of the melt temperature is usually carried out by thermocouples placed in stainless steel covers or ceramic covers, which, after melting the aluminum, are inserted into the working space of the furnace through holes in the vault. It is noted that the service life of such thermocouples is quite limited due to the destruction of the stainless steel covers upon contact with the melt, and the ceramic covers are quite fragile. That's why a method of an indirect determining the temperature of the melt, which will allow constant control of this temperature and save money on the manufacture of thermocouples in covers, was developed. The results of calculation studies on the determination of the heat flux density and the temperature of the outer surfaces of the side and end walls of the furnace for remelting aluminum scrap in the melt temperature range of 670-750 ºС that were performed using the software developed by the authors, are given. The results of calculations for all options with the relevant specified materials and thicknesses of individual layers of fences, heat transfer surface area and melt temperature tm included the heat flow density q, W / m2; wall temperature of the outer surface of","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76764916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flange connections of chemical technology equipment and pipelines 化工设备和管道的法兰连接
Іgor Mikulionok, A. Karvatskii, O. Ivanenko, S. Leleka
The subject of the research is the most common type of detachable joints in chemical, petrochemical, oil refining, food and energy machine and apparatus construction, namely flanged joints of technological and auxiliary equipment, as well as pipelines. The study of the state of the issue and trends in the development of structural and technological design of flanged joints is based on a critical analysis of scientific and technical sources of information and, above all, patent information of the leading countries of the world, since it is in the patent documentation that information is given about innovative developments in the relevant field of engineering and technology. With the help of methods of analysis and synthesis, flange connections that affect the efficiency of operation of equipment and pipelines in the chemical and related fields of technology have been systematized. A thorough classification has been developed for each type of device, based on which the most interesting designs proposed by scientists, designers and inventors of the world's leading countries have been examined in detail. A critical assessment of most of the above constructions is provided, their advantages and disadvantages are discussed. Preference is given to sources of information from the end of the second and beginning of the third millennium. The constructions of flanged joints were analyzed depending on the degree of assembly, the degree of mobility of their structural elements, the possibility of removing the flanges without dismantling the entire joint, the mechanism of compression of the sealing gasket, the presence of additional functions, as well as the material of the flanges. It is shown that, despite the considerable variety of developed designs of flanged connections, the most demanded by the industry are flat welded and butt-welded flanges, as well as free flanges on a welded ring. However, thanks to the advances in materials science and computer modelling, the search for new flange connection designs continues. The developed detailed classification of flange connections can be useful to the developers of new equipment for the creation of highly efficient technological equipment of various industries.
本课题的研究对象是化工、石化、炼油、食品、能源等机电设备建设中最常见的可拆卸接头类型,即工艺、辅助设备及管道的法兰接头。对法兰连接结构和技术设计发展的现状和趋势的研究是基于对科学和技术信息来源的批判性分析,尤其是世界主要国家的专利信息,因为在专利文件中提供了有关工程和技术相关领域创新发展的信息。通过分析和综合的方法,对化工及相关技术领域中影响设备和管道运行效率的法兰连接进行了系统化研究。每种类型的设备都进行了彻底的分类,并在此基础上对世界主要国家的科学家、设计师和发明家提出的最有趣的设计进行了详细的审查。对上述大多数结构进行了批判性评估,并讨论了它们的优点和缺点。优先考虑来自第二个千年结束和第三个千年开始的资料来源。对法兰连接的结构进行了分析,这取决于装配程度、其结构元件的可移动性程度、在不拆卸整个连接的情况下拆卸法兰的可能性、密封垫片的压缩机制、附加功能的存在以及法兰的材料。结果表明,尽管有各种各样的法兰连接设计,但工业上需求量最大的是平焊和对焊法兰,以及焊接环上的自由法兰。然而,由于材料科学和计算机建模的进步,对新的法兰连接设计的探索仍在继续。所开发的法兰连接的详细分类对新设备的开发人员非常有用,可以用于创建各种行业的高效技术设备。
{"title":"Flange connections of chemical technology equipment and pipelines","authors":"Іgor Mikulionok, A. Karvatskii, O. Ivanenko, S. Leleka","doi":"10.20535/2617-9741.2.2023.283516","DOIUrl":"https://doi.org/10.20535/2617-9741.2.2023.283516","url":null,"abstract":"The subject of the research is the most common type of detachable joints in chemical, petrochemical, oil refining, food and energy machine and apparatus construction, namely flanged joints of technological and auxiliary equipment, as well as pipelines. \u0000The study of the state of the issue and trends in the development of structural and technological design of flanged joints is based on a critical analysis of scientific and technical sources of information and, above all, patent information of the leading countries of the world, since it is in the patent documentation that information is given about innovative developments in the relevant field of engineering and technology. \u0000With the help of methods of analysis and synthesis, flange connections that affect the efficiency of operation of equipment and pipelines in the chemical and related fields of technology have been systematized. A thorough classification has been developed for each type of device, based on which the most interesting designs proposed by scientists, designers and inventors of the world's leading countries have been examined in detail. A critical assessment of most of the above constructions is provided, their advantages and disadvantages are discussed. Preference is given to sources of information from the end of the second and beginning of the third millennium. \u0000The constructions of flanged joints were analyzed depending on the degree of assembly, the degree of mobility of their structural elements, the possibility of removing the flanges without dismantling the entire joint, the mechanism of compression of the sealing gasket, the presence of additional functions, as well as the material of the flanges. \u0000It is shown that, despite the considerable variety of developed designs of flanged connections, the most demanded by the industry are flat welded and butt-welded flanges, as well as free flanges on a welded ring. However, thanks to the advances in materials science and computer modelling, the search for new flange connection designs continues. \u0000The developed detailed classification of flange connections can be useful to the developers of new equipment for the creation of highly efficient technological equipment of various industries.","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85559022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modelling of high performance electrocoalescer based on experimental data 基于实验数据的高性能电聚结器建模
Redrikh Putiatin, V. Tsapar
Modern approaches to automatic control of crude oil dewatering and desalting are predominantly model-free, and described model-based systems lack precise mathematical description. Not a single research provides a dynamic input-output model for electric dehydrator, suitable for control system development. As far as electric dehydrator, which is the main plant to control in the process, is a non-linear system with distributed parameters, a need for linearization arises. The aim of present study is to compare different methods for obtaining approximate transfer function of an electric dehydrator from graphical experimental data.
现代原油脱水脱盐自动控制方法主要是无模型的,基于模型的系统缺乏精确的数学描述。目前还没有一项研究提供适合于控制系统开发的电动脱水机动态输入输出模型。作为过程控制的主要装置,电脱水机是一个参数分布的非线性系统,需要对其进行线性化处理。本研究的目的是比较用图形化实验数据求得电脱水机近似传递函数的不同方法。
{"title":"Modelling of high performance electrocoalescer based on experimental data","authors":"Redrikh Putiatin, V. Tsapar","doi":"10.20535/2617-9741.2.2023.283523","DOIUrl":"https://doi.org/10.20535/2617-9741.2.2023.283523","url":null,"abstract":"Modern approaches to automatic control of crude oil dewatering and desalting are predominantly model-free, and described model-based systems lack precise mathematical description. Not a single research provides a dynamic input-output model for electric dehydrator, suitable for control system development. As far as electric dehydrator, which is the main plant to control in the process, is a non-linear system with distributed parameters, a need for linearization arises. The aim of present study is to compare different methods for obtaining approximate transfer function of an electric dehydrator from graphical experimental data.","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77721954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Іnfluence of finishing on the material performances Іnfluence整理对材料性能的影响
Anatolyi Danylkovych, O. Sanginova
The complex of polyacrylic and polyurethane films physical and mechanical properties and the operational properties of leather decorated with them has been studied. The polyacrylate and polyurethane protective coatings formation is performed on the grain face of the semi-finished leather. 150–200 µm thick films are formed from the polymer solutions and aqueous dispersions. Acrylic films are obtained from a dispersion of methylbutylacrylate and a dispersion modified by acrylic lcarboxyethanolamine of kerosene-gas-oil fraction natural naphthenic acids. Polyurethane films are formed by the method of condensation structure formation in the presence of water vapor based on 4,4’-diphenylmethanediisocyanate, polyethylene glycol and polyester. Polyacrylurethane films are obtained from an aqueous dispersion of polyurethane and acrylate Lepton SPC. The coating is applied to the semi-finished leather by watering and spraying the polymer composition. The complex of physical-mechanical and sorption-diffusion properties of polymer films has been studied. It was found that the films obtained from the polyacrylurethane composition outperform polyurethane and polyacrylic by 1.9 and 6.7 times, respectively. Modification of the polyurethane composition with a polyacrylic polymer makes it possible to obtain films with higher sorption-diffusion properties. Polyurethane coated leather is superior to polyacrylic in the complex of physical and mechanical parameters, in particular in terms of adhesive strength in 3.4-4.4 times, and polyacrylurethane coated leather - in 5 times. Such leather has the highest sorbino-diffusion capacity, which is 1.4 times higher in vapor permeability compared to skins with polyacrylic coating. The acrylurethane polymer-based composition is promising formation of eco-coatings based on them in the technology of manufacturing leather materials. The studied polymeric film formers can be used for the formation of various kind protective coatings on a wide range of semi-finished leather products.
研究了聚丙烯酸与聚氨酯复合薄膜的物理力学性能及其装饰皮革的使用性能。将聚丙烯酸酯和聚氨酯保护涂层形成在半成品皮革的颗粒表面上。150-200µm厚的薄膜由聚合物溶液和水分散体形成。丙烯酸薄膜是由甲基丙烯酸丁酯分散体和由煤油-气-油馏分天然环烷酸改性的丙烯酸-羧基乙醇胺分散体制备的。聚氨酯薄膜是以4,4 ' -二苯基甲烷二异氰酸酯、聚乙二醇和聚酯为基料,在水蒸气存在下通过缩合结构形成的方法形成的。聚丙烯酸酯薄膜是由聚氨酯和丙烯酸酯的水分散体得到的。通过对聚合物组合物进行浇水和喷涂,将涂层涂在半成品皮革上。研究了聚合物薄膜的物理-机械和吸附-扩散复合性能。结果表明,该复合材料制备的薄膜性能分别是聚氨酯和聚丙烯酸的1.9倍和6.7倍。用聚丙烯酸聚合物对聚氨酯组合物进行改性,可以获得具有更高吸附扩散性能的薄膜。聚氨酯涂布革在复合物理力学参数上优于聚丙烯酸,特别是粘接强度是聚丙烯酸的3.4-4.4倍,是聚丙烯酸涂布革的5倍。这种皮革具有最高的sorbino扩散能力,其透气性比涂有聚丙烯酸涂层的皮革高1.4倍。在皮革材料制造技术中,以丙烯酸酯聚合物为基础形成的生态涂料是很有前途的。所研究的聚合物成膜剂可用于各种皮革半成品的防护涂层。
{"title":"Іnfluence of finishing on the material performances","authors":"Anatolyi Danylkovych, O. Sanginova","doi":"10.20535/2617-9741.2.2023.283526","DOIUrl":"https://doi.org/10.20535/2617-9741.2.2023.283526","url":null,"abstract":"The complex of polyacrylic and polyurethane films physical and mechanical properties and the operational properties of leather decorated with them has been studied. The polyacrylate and polyurethane protective coatings formation is performed on the grain face of the semi-finished leather. \u0000150–200 µm thick films are formed from the polymer solutions and aqueous dispersions. Acrylic films are obtained from a dispersion of methylbutylacrylate and a dispersion modified by acrylic lcarboxyethanolamine of kerosene-gas-oil fraction natural naphthenic acids. Polyurethane films are formed by the method of condensation structure formation in the presence of water vapor based on 4,4’-diphenylmethanediisocyanate, polyethylene glycol and polyester. Polyacrylurethane films are obtained from an aqueous dispersion of polyurethane and acrylate Lepton SPC. \u0000The coating is applied to the semi-finished leather by watering and spraying the polymer composition. The complex of physical-mechanical and sorption-diffusion properties of polymer films has been studied. It was found that the films obtained from the polyacrylurethane composition outperform polyurethane and polyacrylic by 1.9 and 6.7 times, respectively. Modification of the polyurethane composition with a polyacrylic polymer makes it possible to obtain films with higher sorption-diffusion properties. \u0000Polyurethane coated leather is superior to polyacrylic in the complex of physical and mechanical parameters, in particular in terms of adhesive strength in 3.4-4.4 times, and polyacrylurethane coated leather - in 5 times. Such leather has the highest sorbino-diffusion capacity, which is 1.4 times higher in vapor permeability compared to skins with polyacrylic coating. The acrylurethane polymer-based composition is promising formation of eco-coatings based on them in the technology of manufacturing leather materials. The studied polymeric film formers can be used for the formation of various kind protective coatings on a wide range of semi-finished leather products.","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79055561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research of phosphate removal from water on reverse osmotic filters 反渗透过滤器去除水中磷酸盐的研究
M. Gomelya, I. Trus, A. Vakulenko, A. Taranenko
Eutrophication of natural water bodies caused by an excess of biogenic substances is one of the global environmental problems of modern times. Usually, phosphorus is a limiting biogenic element, the concentration of which determines the intensity of eutrophication processes in water bodies. Therefore, it is important to develop methods aimed at preventing excessive amounts of phosphates from entering the environment. To remove phosphates from water, typically used biological degradation technologies, which usually proceed very slowly and depend on the conditions under which the process takes place. Also, Biogenic elements can be removed by using ion exchange, reverse osmosis, and chemical methods. However, the disposal of concentrated solutions becomes an issue with these methods. Baromembrane purification methods, particularly reverse osmosis, are becoming increasingly important in the field of water treatment and purification and are essential in creating efficient and low-waste complex technologies for water purification from biogenic compounds. The study investigated the processes of removing orthophosphates from distilled and artesian water using a low-pressure reverse osmosis membrane Filmtec TW30-1812-50. The dependence of membrane productivity and selectivity on the concentration of phosphates and the degree of permeate rejection was determined. Was found that residual concentrations of phosphates in the permeate increase with the increase in the degree of permeate rejection. The lowest residual concentrations of phosphates were observed at the initial concentration of up to 10 mg/dm3. The highest residual phosphate concentrations were observed at initial concentrations above 900 mg/dm3. At the same time, the membrane productivity constantly decreased with increasing feed concentration and degree of permeate recovery due to the increased osmotic pressure on the membrane. The selectivity of the membrane was highest at an initial concentration of up to 10 mg/dm3 and slightly decreased at a rejection rate of 20-50% for initial phosphate concentrations of 100-900 mg/dm3. At the maximum degree of permeate rejection (90%), the selectivity of the membrane reached 97-99 % and decreased with an increase in phosphate concentrations, which is due to a change in the pH of the medium, hydrolysis of phosphates, hydration of ions, and concentration polarization. The membrane selectivity for phosphates in solutions in artesian water was slightly lower (95-99 %), which was due to the competing influence of chlorides, sulfates, and bicarbonates, as well as a decrease in the pH of the solution to 7.52-7.67, which promotes the hydrolysis of o-phosphates.
由生物物质过量引起的水体富营养化是现代全球性环境问题之一。通常,磷是一种限制性生物元素,其浓度决定了水体富营养化过程的强度。因此,制定旨在防止过量磷酸盐进入环境的方法是很重要的。为了从水中去除磷酸盐,通常使用生物降解技术,这通常进行得非常缓慢,并且取决于过程发生的条件。此外,生物源元素可以通过离子交换、反渗透和化学方法去除。然而,浓缩溶液的处理成为这些方法的一个问题。气压膜净化方法,特别是反渗透,在水处理和净化领域正变得越来越重要,并且对于创造从生物化合物中净化水的高效和低废物复杂技术至关重要。研究了使用低压反渗透膜Filmtec TW30-1812-50从蒸馏水和自流水中去除正磷酸盐的过程。测定了膜的产率和选择性与磷酸盐浓度和渗透排斥程度的关系。发现渗透液中磷酸盐残留浓度随渗透液排斥程度的增加而增加。在初始浓度高达10 mg/dm3时,观察到磷酸盐残留浓度最低。在初始浓度高于900 mg/dm3时,观察到最高残留磷酸盐浓度。同时,随着进料浓度和渗透恢复程度的增加,膜的产率不断降低,这是由于膜上渗透压的增加。当初始磷酸盐浓度为10 mg/dm3时,膜的选择性最高,当初始磷酸盐浓度为100-900 mg/dm3时,膜的拒绝率略有下降,为20-50%。在最大阻渗度(90%)时,膜的选择性达到97- 99%,并随着磷酸盐浓度的增加而降低,这是由于介质pH的变化、磷酸盐的水解、离子的水合作用和浓度极化。在自流水中溶液中,磷酸盐的膜选择性略低(95- 99%),这是由于氯化物、硫酸盐和碳酸氢盐的竞争影响,以及溶液pH降至7.52-7.67,促进了邻磷酸盐的水解。
{"title":"Research of phosphate removal from water on reverse osmotic filters","authors":"M. Gomelya, I. Trus, A. Vakulenko, A. Taranenko","doi":"10.20535/2617-9741.2.2023.283525","DOIUrl":"https://doi.org/10.20535/2617-9741.2.2023.283525","url":null,"abstract":"Eutrophication of natural water bodies caused by an excess of biogenic substances is one of the global environmental problems of modern times. Usually, phosphorus is a limiting biogenic element, the concentration of which determines the intensity of eutrophication processes in water bodies. Therefore, it is important to develop methods aimed at preventing excessive amounts of phosphates from entering the environment. To remove phosphates from water, typically used biological degradation technologies, which usually proceed very slowly and depend on the conditions under which the process takes place. Also, Biogenic elements can be removed by using ion exchange, reverse osmosis, and chemical methods. However, the disposal of concentrated solutions becomes an issue with these methods. Baromembrane purification methods, particularly reverse osmosis, are becoming increasingly important in the field of water treatment and purification and are essential in creating efficient and low-waste complex technologies for water purification from biogenic compounds. The study investigated the processes of removing orthophosphates from distilled and artesian water using a low-pressure reverse osmosis membrane Filmtec TW30-1812-50. The dependence of membrane productivity and selectivity on the concentration of phosphates and the degree of permeate rejection was determined. Was found that residual concentrations of phosphates in the permeate increase with the increase in the degree of permeate rejection. The lowest residual concentrations of phosphates were observed at the initial concentration of up to 10 mg/dm3. The highest residual phosphate concentrations were observed at initial concentrations above 900 mg/dm3. At the same time, the membrane productivity constantly decreased with increasing feed concentration and degree of permeate recovery due to the increased osmotic pressure on the membrane. The selectivity of the membrane was highest at an initial concentration of up to 10 mg/dm3 and slightly decreased at a rejection rate of 20-50% for initial phosphate concentrations of 100-900 mg/dm3. At the maximum degree of permeate rejection (90%), the selectivity of the membrane reached 97-99 % and decreased with an increase in phosphate concentrations, which is due to a change in the pH of the medium, hydrolysis of phosphates, hydration of ions, and concentration polarization. The membrane selectivity for phosphates in solutions in artesian water was slightly lower (95-99 %), which was due to the competing influence of chlorides, sulfates, and bicarbonates, as well as a decrease in the pH of the solution to 7.52-7.67, which promotes the hydrolysis of o-phosphates.","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79814257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical analysis of the adhesion strength between layers of composite polymeric materials 复合高分子材料层间粘接强度的数值分析
V. Makovskyi, Andrii Chemerys
In today's world, structural elements made of composite polymeric materials (CPMs) are widely used in various engineering fields. One of the innovative directions of using CPMs is the creation of composite membranes based on a different set of polymers and fabrics. Based on the results of the literature analysis, the direction of studying the adhesion strength of banner fabric layers was chosen. The purpose of this work is to build a computational model and numerically analyze the adhesion strength of the layers of the banner fabric, which may lead to the development of new materials with improved mechanical and physical properties. This will ensure their wider application in various industries, science, and technology. The developed methods make it possible to accurately assess the adhesion strength between the layers of the CPM and can be used both in the production of CPM and in the creation of new structures based on composite polymeric materials.
在当今世界,由复合聚合物材料(cpm)制成的结构元件广泛应用于各个工程领域。使用cpm的创新方向之一是基于一组不同的聚合物和织物来制造复合膜。在文献分析的基础上,确定了banner织物层间粘接强度的研究方向。本工作的目的是建立计算模型并对旗帜织物各层的粘附强度进行数值分析,这可能会导致开发具有改善机械和物理性能的新材料。这将确保它们在各个工业和科技领域得到更广泛的应用。所开发的方法可以准确地评估CPM层之间的粘附强度,并且可以用于CPM的生产和基于复合聚合物材料的新结构的创建。
{"title":"Numerical analysis of the adhesion strength between layers of composite polymeric materials","authors":"V. Makovskyi, Andrii Chemerys","doi":"10.20535/2617-9741.1.2023.276445","DOIUrl":"https://doi.org/10.20535/2617-9741.1.2023.276445","url":null,"abstract":"In today's world, structural elements made of composite polymeric materials (CPMs) are widely used in various engineering fields. One of the innovative directions of using CPMs is the creation of composite membranes based on a different set of polymers and fabrics. Based on the results of the literature analysis, the direction of studying the adhesion strength of banner fabric layers was chosen. \u0000The purpose of this work is to build a computational model and numerically analyze the adhesion strength of the layers of the banner fabric, which may lead to the development of new materials with improved mechanical and physical properties. This will ensure their wider application in various industries, science, and technology. \u0000The developed methods make it possible to accurately assess the adhesion strength between the layers of the CPM and can be used both in the production of CPM and in the creation of new structures based on composite polymeric materials.","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86842752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Technological features of production high-quality packaging material with metallized paper for the food industry 食品工业用金属化纸生产高品质包装材料的工艺特点
V. Ploskonos, V. Halysh
Introduction The barrier properties of paper-based packaging may not be sufficient for long-term storage to ensure the quality and taste of packaged food products. All this requires researching the technological features and developing a combined packaging material in which the base paper is combined with polymer materials or a metallized coating is applied to its surface. Results and discussion Food products are very sensitive to the influence of external factors, so the barrier properties of paper-based packaging become insufficient for long-term storage to ensure the quality of food products and their taste properties. All this requires the development and mastery of the production of modern barrier combined packaging materials and conducting research on the development of requirements for base paper in order to obtain combined, namely: metallized packaging materials. As research results have shown, base paper should be characterized by high resistance to mechanical influences in the process of processing, as well as exploitation of the finished material. It should have a surface that provides optimal interaction with the foil, have high barrier and protective properties. In the process of carrying out research on the creation of a new combined package, the requirements for the metallized material and the quality of the base paper were determined. The index of smoothness of the surface of the base paper should not be lower than 150 s, and its moisture content should not exceed 4%, because its higher values, as experiments have shown, do not allow creating the necessary rarefaction in the chamber for metallization and ensuring the uniformity of metal application. In the case of spraying aluminum with increased residual humidity of the paper, intensive oxidation processes take place, which negatively affect the quality of the coating, its protective properties and the strength of adhesion (adhesion) to the surface of the substrate. As a result of the research, graphical dependences of the electrical resistance and opacity of the metallized material on the thickness of the coating were also obtained, which plays an important role in improving the protective, barrier and other properties of the packaging. Experimental data were also obtained that illustrate the influence of the speed of rewinding and the smoothness of the surface of the base paper in the process of metallization in a vacuum on the indicator of electrical resistance, which is an indirect characteristic of the thickness of the metallized coating of the material. The conducted studies of the new combined metallized packaging material also showed that the coating contributes to the improvement of the protective properties of the material and the tightness of the packaging, namely: reducing gas permeability, weakening the effect of optical radiation on products, increasing the opacity and smoothness of the surface. Conclusions New packaging materials created in the course of resea
纸质包装的阻隔性能可能不足以长期储存以保证包装食品的质量和味道。所有这一切都需要研究技术特点,并开发一种复合包装材料,其中原纸与高分子材料结合或在其表面应用金属化涂层。结果与讨论食品对外界因素的影响非常敏感,纸包装的阻隔性不足以保证长期储存食品的质量和口感。这就要求开发和掌握现代阻隔复合包装材料的生产,并对原纸的开发要求进行研究,以获得复合的,即:金属化的包装材料。研究结果表明,原纸在加工过程和成品材料的开发过程中应具有高的抗机械影响的特性。它应该有一个表面,提供最佳的相互作用与箔,具有高的屏障和保护性能。在进行新型组合包装的研究过程中,确定了对金属化材料和原纸质量的要求。原纸表面的光洁度指数不应低于150 s,其含水量不应超过4%,因为实验表明,其较高的数值不允许在金属化室中产生必要的稀薄,也不能保证金属应用的均匀性。在纸张残留湿度增加的情况下喷涂铝,会发生强烈的氧化过程,这对涂层的质量、保护性能和与基材表面的附着力(附着力)产生负面影响。研究结果还得出了金属化材料的电阻和不透明度随涂层厚度的图形依赖关系,这对提高包装的保护、阻隔等性能起着重要作用。实验数据也说明了真空金属化过程中复卷速度和原纸表面平整度对电阻指标的影响,而电阻是材料金属化涂层厚度的间接表征。对新型组合金属化包装材料的研究也表明,该涂层有助于提高材料的防护性能和包装的密闭性,即:降低透气性,减弱光辐射对产品的影响,增加表面的不透明度和光洁度。结论本研究创造的新型包装材料——金属涂层纸可用于包装工艺。
{"title":"Technological features of production high-quality packaging material with metallized paper for the food industry","authors":"V. Ploskonos, V. Halysh","doi":"10.20535/2617-9741.1.2023.276448","DOIUrl":"https://doi.org/10.20535/2617-9741.1.2023.276448","url":null,"abstract":"Introduction The barrier properties of paper-based packaging may not be sufficient for long-term storage to ensure the quality and taste of packaged food products. All this requires researching the technological features and developing a combined packaging material in which the base paper is combined with polymer materials or a metallized coating is applied to its surface. \u0000Results and discussion Food products are very sensitive to the influence of external factors, so the barrier properties of paper-based packaging become insufficient for long-term storage to ensure the quality of food products and their taste properties. All this requires the development and mastery of the production of modern barrier combined packaging materials and conducting research on the development of requirements for base paper in order to obtain combined, namely: metallized packaging materials. As research results have shown, base paper should be characterized by high resistance to mechanical influences in the process of processing, as well as exploitation of the finished material. It should have a surface that provides optimal interaction with the foil, have high barrier and protective properties. \u0000In the process of carrying out research on the creation of a new combined package, the requirements for the metallized material and the quality of the base paper were determined. The index of smoothness of the surface of the base paper should not be lower than 150 s, and its moisture content should not exceed 4%, because its higher values, as experiments have shown, do not allow creating the necessary rarefaction in the chamber for metallization and ensuring the uniformity of metal application. In the case of spraying aluminum with increased residual humidity of the paper, intensive oxidation processes take place, which negatively affect the quality of the coating, its protective properties and the strength of adhesion (adhesion) to the surface of the substrate. \u0000As a result of the research, graphical dependences of the electrical resistance and opacity of the metallized material on the thickness of the coating were also obtained, which plays an important role in improving the protective, barrier and other properties of the packaging. Experimental data were also obtained that illustrate the influence of the speed of rewinding and the smoothness of the surface of the base paper in the process of metallization in a vacuum on the indicator of electrical resistance, which is an indirect characteristic of the thickness of the metallized coating of the material. \u0000The conducted studies of the new combined metallized packaging material also showed that the coating contributes to the improvement of the protective properties of the material and the tightness of the packaging, namely: reducing gas permeability, weakening the effect of optical radiation on products, increasing the opacity and smoothness of the surface. \u0000Conclusions New packaging materials created in the course of resea","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86987380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Theoretical and experimental studies of the electrical properties of electrical contact gasket for the graphitizing of electrode preparations in direct heating furnaces 直接加热炉电极制备石墨化用电接触垫片电学性能的理论与实验研究
A. Karvatskii, Іgor Mikulionok, S. Leleka, V. Vytvytskyi
The article presents the results of theoretical and experimental studies of specific contact electrical resistance (SCER) and specific electrical resistance (SER) of electrical contact gaskets (ECG) made of thermally expanded graphite (TEG) and intended for their placement on the ends of electrode blanks before their graphitization in direct heating furnaces – furnaces Castner's. The obtained data of SCER “graphite–gasket–graphite” and SER (or electrical conductivity) of the ECG material are needed to minimize the energy consumption of the graphitization process using numerical modeling of the thermoelectric state of Castner's furnaces in order to develop energy-efficient regulations for their operation. The method of two samples was used for the experimental determination of the SCER, and the theoretical-experimental approach was used for the study of the SER, which makes it possible to exclude the influence of the contact resistance between the experimental sample and the electrodes for supplying the electric current on the value of the measured quantity and is based on the solution of the inverse coefficient problem of electrical conductivity (ICPE) using experimental data obtained during the SCER study. A mathematical formulation of the ICPE was formulated, a numerical method and an algorithm for its solution were developed, and a study of the SER of the TEG at different values of temperature and pressure was carried out. Determination of SCER and SER was carried out for ECG material with an initial density of 1000 kg/m3 in the temperature range up to 250 °С under different pressures in the range of up to 1.75 MPa. The results of these studies are presented in the form of two-parameter dependences on pressure and temperature with extrapolation up to 3000 °C. The measurement error of SCER and SER by the specified methods is estimated to be within 4–5% in the intervals of temperature change up to 250 °С and pressure up to 1.75 MPa. The obtained SCER and SER dependences for the ECG material are needed to perform a numerical analysis of the thermoelectric state of Castner's furnaces in order to develop rational graphitization regulations.
本文介绍了由热膨胀石墨(TEG)制成的电接触衬垫(ECG)的比接触电阻(SCER)和比接触电阻(SER)的理论和实验研究结果,这些衬垫在直接加热炉- Castner的炉中石墨化之前放置在电极坯的末端。利用Castner炉热电状态的数值模拟,需要获得SCER(石墨-衬垫-石墨)和SER(或电导率)的数据,以最大限度地减少石墨化过程的能量消耗,从而制定其运行的节能法规。SCER的实验测定采用两样品法,SER的研究采用理论-实验方法。它可以排除实验样品和提供电流的电极之间的接触电阻对测量量值的影响,并且是基于利用在SCER研究中获得的实验数据解决电导率反系数问题(ICPE)。建立了ICPE的数学表达式,提出了求解ICPE的数值方法和算法,研究了不同温度和压力下TEG的SER。测定初始密度为1000 kg/m3,温度范围为250°С,不同压力范围为1.75 MPa的ECG材料的SCER和SER。这些研究的结果以压力和温度的双参数依赖形式呈现,外推至3000°C。在温度变化至250°С和压力至1.75 MPa的范围内,用规定的方法测量SCER和SER的误差估计在4-5%以内。获得的ECG材料的SCER和SER依赖关系需要对Castner炉的热电状态进行数值分析,以便制定合理的石墨化规则。
{"title":"Theoretical and experimental studies of the electrical properties of electrical contact gasket for the graphitizing of electrode preparations in direct heating furnaces","authors":"A. Karvatskii, Іgor Mikulionok, S. Leleka, V. Vytvytskyi","doi":"10.20535/2617-9741.1.2023.276444","DOIUrl":"https://doi.org/10.20535/2617-9741.1.2023.276444","url":null,"abstract":"The article presents the results of theoretical and experimental studies of specific contact electrical resistance (SCER) and specific electrical resistance (SER) of electrical contact gaskets (ECG) made of thermally expanded graphite (TEG) and intended for their placement on the ends of electrode blanks before their graphitization in direct heating furnaces – furnaces Castner's. The obtained data of SCER “graphite–gasket–graphite” and SER (or electrical conductivity) of the ECG material are needed to minimize the energy consumption of the graphitization process using numerical modeling of the thermoelectric state of Castner's furnaces in order to develop energy-efficient regulations for their operation. \u0000The method of two samples was used for the experimental determination of the SCER, and the theoretical-experimental approach was used for the study of the SER, which makes it possible to exclude the influence of the contact resistance between the experimental sample and the electrodes for supplying the electric current on the value of the measured quantity and is based on the solution of the inverse coefficient problem of electrical conductivity (ICPE) using experimental data obtained during the SCER study. \u0000A mathematical formulation of the ICPE was formulated, a numerical method and an algorithm for its solution were developed, and a study of the SER of the TEG at different values of temperature and pressure was carried out. \u0000Determination of SCER and SER was carried out for ECG material with an initial density of 1000 kg/m3 in the temperature range up to 250 °С under different pressures in the range of up to 1.75 MPa. The results of these studies are presented in the form of two-parameter dependences on pressure and temperature with extrapolation up to 3000 °C. The measurement error of SCER and SER by the specified methods is estimated to be within 4–5% in the intervals of temperature change up to 250 °С and pressure up to 1.75 MPa. \u0000The obtained SCER and SER dependences for the ECG material are needed to perform a numerical analysis of the thermoelectric state of Castner's furnaces in order to develop rational graphitization regulations.","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87680325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficiency of water purification from oil with aluminum coagulants 铝混凝剂对油品水净化效果的研究
M. Vozniuk, T. Shabliy
In this work, the processes of reagent purification of aqueous emulsions from oil using aluminum coagulants, such as: aluminum sulfate, aluminum hydroxide, and aluminum hydroxochloride, were investigated. In emulsion cleaning processes, coagulants were used separately, as well as in the presence of sorbents: bentonite or activated carbon. The results of the conducted studies demonstrate that aluminum sulfate, aluminum hydroxide, and aluminum hydroxochloride in doses of 2–50 mg/dm3 provide a high degree of oil extraction from emulsions. The degree of water purification reaches 97–99 %. It was established that the efficiency of oil extraction from water with the help of aluminum coagulants depends significantly on the chemical composition of the coagulant and the original mineralization of the water. Aluminum hydroxide has the greatest efficiency in removing oil from water, which ensures the maximum reduction of oil concentration in both fresh and mineralized water. The combined use of aluminum coagulants and sorbents such as bentonite and activated carbon is characterized by fluctuating efficiency, which depends on the type of coagulant and sorbent, their concentrations, and the mineralization of the source water. To a large extent, the ambiguity of the presented results can be explained by the heterogeneity of the emulsions. However, it can be unequivocally stated that the use of aluminum coagulants in the processes of removing oil from water of different mineralization is expedient and effective.
研究了用硫酸铝、氢氧化铝、氯化铝等铝质混凝剂提纯油中含水乳剂的工艺。在乳液清洗过程中,混凝剂可以单独使用,也可以在吸附剂:膨润土或活性炭的存在下使用。所进行的研究结果表明,剂量为2-50 mg/dm3的硫酸铝、氢氧化铝和氯化铝可从乳剂中提取出高程度的油。水的净净度达到97 - 99%。研究结果表明,铝絮凝剂对水中采油效果的影响很大程度上取决于絮凝剂的化学成分和水的原始矿化程度。氢氧化铝具有最大的除油效率,从而确保最大限度地降低淡水和矿化水中的油浓度。铝混凝剂和吸附剂(如膨润土和活性炭)的联合使用的特点是效率波动,这取决于混凝剂和吸附剂的类型、浓度和源水的矿化程度。在很大程度上,所提出的结果的模糊性可以用乳剂的非均质性来解释。但是,可以明确地说,在不同矿化度的水中使用铝絮凝剂脱油是方便和有效的。
{"title":"Efficiency of water purification from oil with aluminum coagulants","authors":"M. Vozniuk, T. Shabliy","doi":"10.20535/2617-9741.1.2023.276446","DOIUrl":"https://doi.org/10.20535/2617-9741.1.2023.276446","url":null,"abstract":"In this work, the processes of reagent purification of aqueous emulsions from oil using aluminum coagulants, such as: aluminum sulfate, aluminum hydroxide, and aluminum hydroxochloride, were investigated. In emulsion cleaning processes, coagulants were used separately, as well as in the presence of sorbents: bentonite or activated carbon. \u0000The results of the conducted studies demonstrate that aluminum sulfate, aluminum hydroxide, and aluminum hydroxochloride in doses of 2–50 mg/dm3 provide a high degree of oil extraction from emulsions. The degree of water purification reaches 97–99 %. \u0000It was established that the efficiency of oil extraction from water with the help of aluminum coagulants depends significantly on the chemical composition of the coagulant and the original mineralization of the water. Aluminum hydroxide has the greatest efficiency in removing oil from water, which ensures the maximum reduction of oil concentration in both fresh and mineralized water. \u0000The combined use of aluminum coagulants and sorbents such as bentonite and activated carbon is characterized by fluctuating efficiency, which depends on the type of coagulant and sorbent, their concentrations, and the mineralization of the source water. \u0000To a large extent, the ambiguity of the presented results can be explained by the heterogeneity of the emulsions. However, it can be unequivocally stated that the use of aluminum coagulants in the processes of removing oil from water of different mineralization is expedient and effective.","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74784106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Review of fluorine removal methods from aqueous solutions 水溶液中除氟方法综述
Viktor Kurylenko, N. Tolstopalova, O. Sanginova, T. Obushenko
Introduction. The high-quality water conditioning problem does not disappear from the agenda of chemists, biologists, and ecologists. Fluoride content is an important water quality indicator, as fluoride can have both positive and negative effects on the human body. The purpose of this work is a critical review of methods for removing fluorine compounds from natural surface and underground waters, and from wastewater. An analysis of 77 modern scientific articles was performed, the advantages and disadvantages of such methods as precipitation and co-precipitation, methods using semipermeable membranes, dialysis and electrocoagulation, ion exchange and sorption methods were determined. Results and discussion. It was determined that the precipitation and co-precipitation methods use of chemical reagents, so they are quite expensive, and the sediments formed in the defluoridation process are subject to disposal. Membrane methods do not require the chemicals addition, are highly efficient and easy to control, but at the same time, defluoridation removes other ions that are present in water and are important indicators of the drinking water quality. A significant disadvantage of membrane methods is that a major amount of brine is formed during the treatment process, which also creates a disposal problem. Dialysis and electrocoagulation methods have the advantages and disadvantages of electrochemical methods: they provide high quality water, but this is accompanied by increased electricity consumption, the use of limited service life electrodes. Along with the high degree of water defluoridation, ion exchange methods are characterized by high cost, as well as significant water consumption for such technological processes as loosening, regeneration and washing of ion-exchange resins. An additional problem is the flushing and rinsing wastewater disposal. Sorptive fluoride removal is the most promising and widely used method. The main advantages include the method simplicity, non-deficiency and availability of sorbents. Effective sorbents are natural minerals, foremost, clinoptilolite, nepheline, low-quality phosphorites and apatites, glauconite, basalt tuffs, which are abundant in the subsoil of Ukraine. Unlike other methods, the spent materials are easily disposed of, or can be used as additives in the production of silicate materials, for example, bricks. Conclusions. Promising fluoride removal methods are sorption methods using natural mineral and modified sorbents.
介绍。高质量的水调理问题并没有从化学家、生物学家和生态学家的议程上消失。氟化物含量是一项重要的水质指标,因为氟化物对人体既有积极的影响,也有消极的影响。这项工作的目的是对从天然地表水和地下水以及废水中去除氟化合物的方法进行评述。对77篇现代科学文献进行了分析,比较了沉淀法和共沉淀法、半透膜法、透析法和电凝法、离子交换法和吸附法等方法的优缺点。结果和讨论。经测定,沉淀法和共沉淀法使用化学试剂,费用较高,除氟过程中形成的沉淀物需要处理。膜法不需要添加化学物质,效率高,易于控制,但同时除氟去除水中存在的其他离子,这些离子是饮用水质量的重要指标。膜法的一个显著缺点是在处理过程中形成了大量的盐水,这也造成了处置问题。透析和电凝方法具有电化学方法的优点和缺点:它们提供高质量的水,但这伴随着电力消耗的增加,使用寿命有限的电极。除氟程度高的同时,离子交换法成本高,离子交换树脂的松动、再生、洗涤等工艺过程耗水量大。另一个问题是冲洗和漂洗废水的处理。吸附除氟是目前应用最广泛、最有前途的方法。该方法的主要优点是方法简单,无缺陷,吸附剂可用。有效的吸附剂是天然矿物,最重要的是斜沸石、霞石、低质量磷矿和磷灰石、海绿石、玄武岩凝灰岩,它们在乌克兰的底土中含量丰富。与其他方法不同,废材料很容易处理,或者可以用作生产硅酸盐材料(例如砖)的添加剂。结论。利用天然矿物和改性吸附剂的吸附法是很有前途的除氟方法。
{"title":"Review of fluorine removal methods from aqueous solutions","authors":"Viktor Kurylenko, N. Tolstopalova, O. Sanginova, T. Obushenko","doi":"10.20535/2617-9741.1.2023.276447","DOIUrl":"https://doi.org/10.20535/2617-9741.1.2023.276447","url":null,"abstract":"Introduction. The high-quality water conditioning problem does not disappear from the agenda of chemists, biologists, and ecologists. Fluoride content is an important water quality indicator, as fluoride can have both positive and negative effects on the human body. The purpose of this work is a critical review of methods for removing fluorine compounds from natural surface and underground waters, and from wastewater. An analysis of 77 modern scientific articles was performed, the advantages and disadvantages of such methods as precipitation and co-precipitation, methods using semipermeable membranes, dialysis and electrocoagulation, ion exchange and sorption methods were determined. \u0000Results and discussion. It was determined that the precipitation and co-precipitation methods use of chemical reagents, so they are quite expensive, and the sediments formed in the defluoridation process are subject to disposal. Membrane methods do not require the chemicals addition, are highly efficient and easy to control, but at the same time, defluoridation removes other ions that are present in water and are important indicators of the drinking water quality. A significant disadvantage of membrane methods is that a major amount of brine is formed during the treatment process, which also creates a disposal problem. Dialysis and electrocoagulation methods have the advantages and disadvantages of electrochemical methods: they provide high quality water, but this is accompanied by increased electricity consumption, the use of limited service life electrodes. Along with the high degree of water defluoridation, ion exchange methods are characterized by high cost, as well as significant water consumption for such technological processes as loosening, regeneration and washing of ion-exchange resins. An additional problem is the flushing and rinsing wastewater disposal. Sorptive fluoride removal is the most promising and widely used method. The main advantages include the method simplicity, non-deficiency and availability of sorbents. Effective sorbents are natural minerals, foremost, clinoptilolite, nepheline, low-quality phosphorites and apatites, glauconite, basalt tuffs, which are abundant in the subsoil of Ukraine. Unlike other methods, the spent materials are easily disposed of, or can be used as additives in the production of silicate materials, for example, bricks. \u0000Conclusions. Promising fluoride removal methods are sorption methods using natural mineral and modified sorbents.","PeriodicalId":20682,"journal":{"name":"Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88332656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Proceedings of the NTUU “Igor Sikorsky KPI”. Series: Chemical engineering, ecology and resource saving
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1