Pub Date : 2025-02-06DOI: 10.1088/2058-9565/adae2d
Seyed Navid Elyasi, Matteo A C Rossi and Marco G Genoni
The possibility of extracting more work from a physical system thanks to the information obtained from measurements has been a topic of fundamental interest in the context of thermodynamics since the formulation of the Maxwell’s demon thought experiment. We here consider this problem from the perspective of an open quantum battery interacting with an environment that can be continuously measured. By modeling it via a continuously monitored collisional model, we show how to implement the corresponding dynamics as a quantum circuit, including the final conditional feedback unitary evolution that allows to enhance the amount of work extracted. By exploiting the flexibility of IBM quantum computers and by properly modelling the corresponding quantum circuit, we experimentally simulate the work extraction protocol showing how the obtained experimental values of the daemonic extracted work are close to their theoretical upper bound quantified by the so-called daemonic ergotropy. We also demonstrate how by properly modelling the noise affecting the quantum circuit, one can improve the work extraction protocol by optimizing the corresponding extraction unitary feedback operation.
{"title":"Experimental simulation of daemonic work extraction in open quantum batteries on a digital quantum computer","authors":"Seyed Navid Elyasi, Matteo A C Rossi and Marco G Genoni","doi":"10.1088/2058-9565/adae2d","DOIUrl":"https://doi.org/10.1088/2058-9565/adae2d","url":null,"abstract":"The possibility of extracting more work from a physical system thanks to the information obtained from measurements has been a topic of fundamental interest in the context of thermodynamics since the formulation of the Maxwell’s demon thought experiment. We here consider this problem from the perspective of an open quantum battery interacting with an environment that can be continuously measured. By modeling it via a continuously monitored collisional model, we show how to implement the corresponding dynamics as a quantum circuit, including the final conditional feedback unitary evolution that allows to enhance the amount of work extracted. By exploiting the flexibility of IBM quantum computers and by properly modelling the corresponding quantum circuit, we experimentally simulate the work extraction protocol showing how the obtained experimental values of the daemonic extracted work are close to their theoretical upper bound quantified by the so-called daemonic ergotropy. We also demonstrate how by properly modelling the noise affecting the quantum circuit, one can improve the work extraction protocol by optimizing the corresponding extraction unitary feedback operation.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"55 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143192588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-02-04DOI: 10.1088/2058-9565/ad9e2d
G S Grattan, A M Liguori-Schremp, D Rodriguez Perez, E Kapit, W Jones and P Graf
In this work we study the properties of dissipatively stabilized steady states of noisy quantum algorithms, exploring the extent to which they can be well approximated as thermal distributions, and proposing methods to extract the effective temperature T. We study an algorithm called the relaxational quantum eigensolver (RQE), which is one of a family of algorithms that attempt to find ground states and balance error in noisy quantum devices. In RQE, we weakly couple a second register of auxiliary ‘shadow’ qubits to the primary system in Trotterized evolution, thus engineering an approximate zero-temperature bath by periodically resetting the auxiliary qubits during the algorithm’s runtime. Balancing the infinite temperature bath of random gate error, RQE returns states with an average energy equal to a constant fraction of the ground state. We probe the steady states of this algorithm for a range of base error rates, using several methods for estimating both T and deviations from thermal behavior. In particular, we both confirm that the steady states of these systems are often well-approximated by thermal distributions, and show that the same resources used for cooling can be adopted for thermometry, yielding a fairly reliable measure of the temperature. These methods could be readily implemented in near-term quantum hardware, and for stabilizing and probing Hamiltonians where simulating approximate thermal states is hard for classical computers.
{"title":"Characterization and thermometry of dissipatively stabilized steady states","authors":"G S Grattan, A M Liguori-Schremp, D Rodriguez Perez, E Kapit, W Jones and P Graf","doi":"10.1088/2058-9565/ad9e2d","DOIUrl":"https://doi.org/10.1088/2058-9565/ad9e2d","url":null,"abstract":"In this work we study the properties of dissipatively stabilized steady states of noisy quantum algorithms, exploring the extent to which they can be well approximated as thermal distributions, and proposing methods to extract the effective temperature T. We study an algorithm called the relaxational quantum eigensolver (RQE), which is one of a family of algorithms that attempt to find ground states and balance error in noisy quantum devices. In RQE, we weakly couple a second register of auxiliary ‘shadow’ qubits to the primary system in Trotterized evolution, thus engineering an approximate zero-temperature bath by periodically resetting the auxiliary qubits during the algorithm’s runtime. Balancing the infinite temperature bath of random gate error, RQE returns states with an average energy equal to a constant fraction of the ground state. We probe the steady states of this algorithm for a range of base error rates, using several methods for estimating both T and deviations from thermal behavior. In particular, we both confirm that the steady states of these systems are often well-approximated by thermal distributions, and show that the same resources used for cooling can be adopted for thermometry, yielding a fairly reliable measure of the temperature. These methods could be readily implemented in near-term quantum hardware, and for stabilizing and probing Hamiltonians where simulating approximate thermal states is hard for classical computers.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"165 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143083902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-02-04DOI: 10.1088/2058-9565/adae2c
L Magazzù, E Paladino and M Grifoni
Heat transport in a qubit–oscillator junction described by the quantum Rabi model is investigated. Upon variation of temperature, bias on the qubit and the qubit–oscillator coupling strength, a rich variety of effects is identified. For weak coupling to bosonic heat baths, transport is essentially controlled by the qubit–oscillator coupling g which defines a Kondo-like temperature . At temperatures much lower than , coherent heat transfer via virtual processes yields a T3 behavior in the linear conductance as a function of T, modulated by a prefactor determined by the junction parameters and unravelling its multilevel nature. In particular, a coherent suppression of the conductance arises in the presence of quasi-degeneracies in the spectrum. For , sequential processes dominate heat transfer and a scaling regime is found when quantities are scaled with . The conductance as a function of the bias on the qubit undergoes a transition from a resonant behavior at weak qubit–resonator coupling to a broadened, zero-bias peak regime at ultrastrong coupling.
{"title":"Heat transport in the quantum Rabi model: universality and ultrastrong coupling effects","authors":"L Magazzù, E Paladino and M Grifoni","doi":"10.1088/2058-9565/adae2c","DOIUrl":"https://doi.org/10.1088/2058-9565/adae2c","url":null,"abstract":"Heat transport in a qubit–oscillator junction described by the quantum Rabi model is investigated. Upon variation of temperature, bias on the qubit and the qubit–oscillator coupling strength, a rich variety of effects is identified. For weak coupling to bosonic heat baths, transport is essentially controlled by the qubit–oscillator coupling g which defines a Kondo-like temperature . At temperatures much lower than , coherent heat transfer via virtual processes yields a T3 behavior in the linear conductance as a function of T, modulated by a prefactor determined by the junction parameters and unravelling its multilevel nature. In particular, a coherent suppression of the conductance arises in the presence of quasi-degeneracies in the spectrum. For , sequential processes dominate heat transfer and a scaling regime is found when quantities are scaled with . The conductance as a function of the bias on the qubit undergoes a transition from a resonant behavior at weak qubit–resonator coupling to a broadened, zero-bias peak regime at ultrastrong coupling.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"25 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143083903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-02-03DOI: 10.1088/2058-9565/adab14
Natasha Feinstein, Ivan Shalashilin, Sougato Bose and P A Warburton
In adiabatic quantum annealing, the speed with which an anneal can be run, while still achieving a high final ground state (GS) fidelity, is dictated by the size of the minimum gap that appears between the ground and first excited state in the annealing spectrum. To avoid the exponential slowdown associated with exponentially closing gaps, diabatic transitions to higher energy levels may be exploited in such a way that the system returns to the GS before the end of the anneal. In certain cases, this is facilitated by the original annealing spectrum. However, there are also examples where careful manipulation of the annealing Hamiltonian has been used to alter the spectrum to create a diabatic path to the GS. Since diabatic transitions depend on the evolution rate and the gap sizes in the spectrum, it is important to consider the sensitivity of any potential enhancement to changes in the anneal time as well as any parameters involved in the manipulation of the spectrum. We explore this sensitivity using annealing spectra containing an exponentially closing gap and an additional, tuneable, small gap created by a catalyst. We find that there is a trade-off between the precision needed in the catalyst strength and the anneal time in order to maintain the enhancement to the final GS fidelity.
{"title":"Robustness of diabatic enhancement in quantum annealing","authors":"Natasha Feinstein, Ivan Shalashilin, Sougato Bose and P A Warburton","doi":"10.1088/2058-9565/adab14","DOIUrl":"https://doi.org/10.1088/2058-9565/adab14","url":null,"abstract":"In adiabatic quantum annealing, the speed with which an anneal can be run, while still achieving a high final ground state (GS) fidelity, is dictated by the size of the minimum gap that appears between the ground and first excited state in the annealing spectrum. To avoid the exponential slowdown associated with exponentially closing gaps, diabatic transitions to higher energy levels may be exploited in such a way that the system returns to the GS before the end of the anneal. In certain cases, this is facilitated by the original annealing spectrum. However, there are also examples where careful manipulation of the annealing Hamiltonian has been used to alter the spectrum to create a diabatic path to the GS. Since diabatic transitions depend on the evolution rate and the gap sizes in the spectrum, it is important to consider the sensitivity of any potential enhancement to changes in the anneal time as well as any parameters involved in the manipulation of the spectrum. We explore this sensitivity using annealing spectra containing an exponentially closing gap and an additional, tuneable, small gap created by a catalyst. We find that there is a trade-off between the precision needed in the catalyst strength and the anneal time in order to maintain the enhancement to the final GS fidelity.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"22 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143077519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-02-03DOI: 10.1088/2058-9565/adaa12
Jasminder S Sidhu, Rocco Maggi, Saverio Pascazio and Cosmo Lupo
Quantum key distribution (QKD) promises everlasting security based on the laws of physics. Most common protocols are grouped into two distinct categories based on the degrees of freedom used to carry information, which can be either discrete or continuous, each presenting unique advantages in either performance, feasibility for near-term implementation, and compatibility with existing telecommunications architectures. Recently, hybrid QKD protocols have been introduced to leverage advantages from both categories. In this work we provide a rigorous security proof for a protocol introduced by Qi in 2021, where information is encoded in discrete variables as in the widespread Bennett Brassard 1984 protocol but decoded continuously via heterodyne detection. Security proofs for hybrid protocols inherit the same challenges associated with continuous-variable protocols due to unbounded dimensions. Here we successfully address these challenges by exploiting symmetry. Our approach enables truncation of the Hilbert space with precise control of the approximation errors and lead to a tight, semi-analytical expression for the asymptotic key rate under collective attacks. As concrete examples, we apply our theory to compute the key rates under passive attacks, linear loss, and Gaussian noise.
{"title":"Security of hybrid BB84 with heterodyne detection","authors":"Jasminder S Sidhu, Rocco Maggi, Saverio Pascazio and Cosmo Lupo","doi":"10.1088/2058-9565/adaa12","DOIUrl":"https://doi.org/10.1088/2058-9565/adaa12","url":null,"abstract":"Quantum key distribution (QKD) promises everlasting security based on the laws of physics. Most common protocols are grouped into two distinct categories based on the degrees of freedom used to carry information, which can be either discrete or continuous, each presenting unique advantages in either performance, feasibility for near-term implementation, and compatibility with existing telecommunications architectures. Recently, hybrid QKD protocols have been introduced to leverage advantages from both categories. In this work we provide a rigorous security proof for a protocol introduced by Qi in 2021, where information is encoded in discrete variables as in the widespread Bennett Brassard 1984 protocol but decoded continuously via heterodyne detection. Security proofs for hybrid protocols inherit the same challenges associated with continuous-variable protocols due to unbounded dimensions. Here we successfully address these challenges by exploiting symmetry. Our approach enables truncation of the Hilbert space with precise control of the approximation errors and lead to a tight, semi-analytical expression for the asymptotic key rate under collective attacks. As concrete examples, we apply our theory to compute the key rates under passive attacks, linear loss, and Gaussian noise.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"4 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143077518","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-31DOI: 10.1088/2058-9565/adac06
Harsh Vardhan Upadhyay, Sanket Tripathy, Ting Rei Tan, Baladitya Suri and Athreya Shankar
We propose a protocol for the preparation of generalized Greenberger–Horne–Zeilinger (GHZ) states of N atoms each with d = 3 or 4 internal levels. We generalize the celebrated one-axis twisting (OAT) Hamiltonian for N qubits to qudits by including OAT interactions of equal strengths between every pair of qudit levels, a protocol we call as balanced OAT (BOAT). Analogous to OAT for qubits, we find that starting from a product state of an arbitrary number of atoms N, dynamics under BOAT leads to the formation of GHZ states for qutrits (d = 3) and ququarts (d = 4). While BOAT could potentially be realized on several platforms where all-to-all coupling is possible, here we propose specific implementations using trapped ion systems. We show that preparing these states with fidelity above a threshold value rules out lower dimensional entanglement than that of the generalized GHZ states. For qutrits, we also propose a protocol to bound the fidelity that requires only global addressing of the ion crystal and single-shot readout of one of the levels. Our results open a path for the scalable generation and certification of high-dimensional multipartite entanglement on current atom-based quantum hardware.
{"title":"Scalable high-dimensional multipartite entanglement with trapped ions","authors":"Harsh Vardhan Upadhyay, Sanket Tripathy, Ting Rei Tan, Baladitya Suri and Athreya Shankar","doi":"10.1088/2058-9565/adac06","DOIUrl":"https://doi.org/10.1088/2058-9565/adac06","url":null,"abstract":"We propose a protocol for the preparation of generalized Greenberger–Horne–Zeilinger (GHZ) states of N atoms each with d = 3 or 4 internal levels. We generalize the celebrated one-axis twisting (OAT) Hamiltonian for N qubits to qudits by including OAT interactions of equal strengths between every pair of qudit levels, a protocol we call as balanced OAT (BOAT). Analogous to OAT for qubits, we find that starting from a product state of an arbitrary number of atoms N, dynamics under BOAT leads to the formation of GHZ states for qutrits (d = 3) and ququarts (d = 4). While BOAT could potentially be realized on several platforms where all-to-all coupling is possible, here we propose specific implementations using trapped ion systems. We show that preparing these states with fidelity above a threshold value rules out lower dimensional entanglement than that of the generalized GHZ states. For qutrits, we also propose a protocol to bound the fidelity that requires only global addressing of the ion crystal and single-shot readout of one of the levels. Our results open a path for the scalable generation and certification of high-dimensional multipartite entanglement on current atom-based quantum hardware.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"54 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143077520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-29DOI: 10.1088/2058-9565/adac05
Sebastian Deffner
Quantum thermometry refers to the study of measuring ultra-low temperatures in quantum systems. The precision of such a quantum thermometer is limited by the degree to which temperature can be estimated by quantum measurements. More precisely, the maximal precision is given by the inverse of the quantum Fisher information. In the present analysis, we show that quantum thermometers that are described by nonlinear Schrödinger equations allow for a significantly enhanced precision, that means larger quantum Fisher information. This is demonstrated for a variety of pedagogical scenarios consisting of single and two-qubits systems. The enhancement in precision is indicated by non-vanishing quantum speed limits, which originate in the fact that the thermal, Gibbs state is typically not invariant under the nonlinear equations of motion.
{"title":"Towards enhanced precision in thermometry with nonlinear qubits","authors":"Sebastian Deffner","doi":"10.1088/2058-9565/adac05","DOIUrl":"https://doi.org/10.1088/2058-9565/adac05","url":null,"abstract":"Quantum thermometry refers to the study of measuring ultra-low temperatures in quantum systems. The precision of such a quantum thermometer is limited by the degree to which temperature can be estimated by quantum measurements. More precisely, the maximal precision is given by the inverse of the quantum Fisher information. In the present analysis, we show that quantum thermometers that are described by nonlinear Schrödinger equations allow for a significantly enhanced precision, that means larger quantum Fisher information. This is demonstrated for a variety of pedagogical scenarios consisting of single and two-qubits systems. The enhancement in precision is indicated by non-vanishing quantum speed limits, which originate in the fact that the thermal, Gibbs state is typically not invariant under the nonlinear equations of motion.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"77 2 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143077522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-28DOI: 10.1088/2058-9565/ada6f8
Gabriele Agliardi and Enrico Prati
Complex quantum circuits are constituted by combinations of quantum subroutines. The computation is possible as long as the quantum data encoding is consistent throughout the circuit. Despite its fundamental importance, the formalization of quantum data encoding has never been addressed systematically so far. We formalize the concept of quantum data encoding, namely the format providing a representation of a data set through a quantum state, as a distinct abstract layer with respect to the associated data loading circuit. We survey existing encoding methods and their respective strategies for classical-to-quantum exact and approximate data loading, for the quantum-to-classical extraction of information from states, and for quantum-to-quantum encoding conversion. Next, we show how major quantum algorithms find a natural interpretation in terms of data loading. For instance, the quantum Fourier transform is described as a quantum encoding converter, while the quantum amplitude estimation as an extraction routine. The new conceptual framework is exemplified by considering its application to the simple case of the Bernstein–Vazirani algorithm, and then to quantum-based Monte Carlo simulations, thus showcasing the power of the proposed formalism for the description of complex quantum circuits. Indeed, the approach clarifies the structure of complex quantum circuits and enables their efficient design.
{"title":"Quantum data encoding as a distinct abstraction layer in the design of quantum circuits","authors":"Gabriele Agliardi and Enrico Prati","doi":"10.1088/2058-9565/ada6f8","DOIUrl":"https://doi.org/10.1088/2058-9565/ada6f8","url":null,"abstract":"Complex quantum circuits are constituted by combinations of quantum subroutines. The computation is possible as long as the quantum data encoding is consistent throughout the circuit. Despite its fundamental importance, the formalization of quantum data encoding has never been addressed systematically so far. We formalize the concept of quantum data encoding, namely the format providing a representation of a data set through a quantum state, as a distinct abstract layer with respect to the associated data loading circuit. We survey existing encoding methods and their respective strategies for classical-to-quantum exact and approximate data loading, for the quantum-to-classical extraction of information from states, and for quantum-to-quantum encoding conversion. Next, we show how major quantum algorithms find a natural interpretation in terms of data loading. For instance, the quantum Fourier transform is described as a quantum encoding converter, while the quantum amplitude estimation as an extraction routine. The new conceptual framework is exemplified by considering its application to the simple case of the Bernstein–Vazirani algorithm, and then to quantum-based Monte Carlo simulations, thus showcasing the power of the proposed formalism for the description of complex quantum circuits. Indeed, the approach clarifies the structure of complex quantum circuits and enables their efficient design.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"20 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143077535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-28DOI: 10.1088/2058-9565/ad9fa5
Samuel Warren, Yuchen Wang, Carlos L Benavides-Riveros and David A Mazziotti
Cavity-modified chemistry uses strong light-matter interactions to modify the electronic properties of molecules in order to enable new physical phenomena such as novel reaction pathways. As cavity chemistry often involves critical regions where configurations become nearly degenerate, the ability to treat multireference problems is crucial to understanding polaritonic systems. In this Letter, we show through the use of a unitary ansatz derived from the anti-Hermitian contracted Schrödinger equation that cavity-modified systems with strong correlation, such as the deformation of rectangular H4 coupled to a cavity mode, can be solved efficiently and accurately on a quantum device. In contrast, while our quantum algorithm can be made formally exact, classical-computing methods as well as other quantum-computing algorithms often yield answers that are both quantitatively and qualitatively incorrect. Additionally, we demonstrate the current feasibility of the algorithm on near intermediate-scale quantum hardware by computing the dissociation curve of H2 strongly coupled to a bosonic bath.
{"title":"Quantum algorithm for polaritonic chemistry based on an exact ansatz","authors":"Samuel Warren, Yuchen Wang, Carlos L Benavides-Riveros and David A Mazziotti","doi":"10.1088/2058-9565/ad9fa5","DOIUrl":"https://doi.org/10.1088/2058-9565/ad9fa5","url":null,"abstract":"Cavity-modified chemistry uses strong light-matter interactions to modify the electronic properties of molecules in order to enable new physical phenomena such as novel reaction pathways. As cavity chemistry often involves critical regions where configurations become nearly degenerate, the ability to treat multireference problems is crucial to understanding polaritonic systems. In this Letter, we show through the use of a unitary ansatz derived from the anti-Hermitian contracted Schrödinger equation that cavity-modified systems with strong correlation, such as the deformation of rectangular H4 coupled to a cavity mode, can be solved efficiently and accurately on a quantum device. In contrast, while our quantum algorithm can be made formally exact, classical-computing methods as well as other quantum-computing algorithms often yield answers that are both quantitatively and qualitatively incorrect. Additionally, we demonstrate the current feasibility of the algorithm on near intermediate-scale quantum hardware by computing the dissociation curve of H2 strongly coupled to a bosonic bath.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"34 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143077537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-27DOI: 10.1088/2058-9565/ada79c
Adam G Hawkins, Hannah McAleese and Mauro Paternostro
Distributing quantum correlations to each node of a network is a key aspect of quantum networking. Here, we present a robust, physically motivated protocol by which global quantum correlations, as characterized by the discord, can be distributed to quantum memories using a mixed state of information carriers which possesses only classical correlations. In addition, such distribution is done using only bilocal unitary operations and projective measurements, with the degree of discord being measurement-outcome independent. We explore the scaling of the performance of the proposed protocol with the size of the network and illustrate the structure of quantum correlations that are shared by the nodes, showing its dependence on the local operations performed. Finally, we find the counterintuitive result that even more discord can be generated when the resource state undergoes correlated dephasing noise, allowing high fidelities with mixtures of the Bell basis such as Werner states.
{"title":"Distributing quantum correlations through local operations and classical resources","authors":"Adam G Hawkins, Hannah McAleese and Mauro Paternostro","doi":"10.1088/2058-9565/ada79c","DOIUrl":"https://doi.org/10.1088/2058-9565/ada79c","url":null,"abstract":"Distributing quantum correlations to each node of a network is a key aspect of quantum networking. Here, we present a robust, physically motivated protocol by which global quantum correlations, as characterized by the discord, can be distributed to quantum memories using a mixed state of information carriers which possesses only classical correlations. In addition, such distribution is done using only bilocal unitary operations and projective measurements, with the degree of discord being measurement-outcome independent. We explore the scaling of the performance of the proposed protocol with the size of the network and illustrate the structure of quantum correlations that are shared by the nodes, showing its dependence on the local operations performed. Finally, we find the counterintuitive result that even more discord can be generated when the resource state undergoes correlated dephasing noise, allowing high fidelities with mixtures of the Bell basis such as Werner states.","PeriodicalId":20821,"journal":{"name":"Quantum Science and Technology","volume":"38 1","pages":""},"PeriodicalIF":6.7,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143077536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}