Reaktor最新文献

{"title":"Recovery of Cu (II) and Cr (VI) Metals from Electroplating Liquid Waste Using Polymer Inclusion Membrane (PIM)","authors":"M. C. Djunaidi, Nor Basid Adiwibawa Prasetya, N. Setyowati, Khabibi Khabibi, Khoirun Nita Ulfia","doi":"10.14710/REAKTOR.18.2.102-109","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.2.102-109","url":null,"abstract":"Research on recovery of Cu (II) and Cr (VI) from electroplating liquid waste has been carried out using a Polymer Inclusion Membrane (PIM). PIM has a high stability to overcome the weakness of liquid membrane instability. The PIM membrane was placed between two phases namely the feed phase as a metal source of Cu (II) from electroplating waste with pH 3 and the receiving phase which is HNO3 solution with pH 1 and pH 4.4 in the feed phase and pH 6.3 in the receiving phase with NaCl 2 N for metal Cr (VI). Recovery efficiency is known by determining the concentration of Cu (II) and Cr (VI) in the feed and receiving phases using AAS, while the membrane characterization were carried out using FTIR, SEM and UV-vis spectroscopy. The resulting PIM membrane has properties of thin, clear and flexible. AAS data showed that the percentage of PIM transport with stirring for 24 hours performed the highest percentage of Cu (II) metal transport from feed phase of 83.41% and transport in the receiving phase of 72.56%. While the percentage of optimum Cr (VI) transport was 97.8% in the feed phase and 76.5% in the receiving phase. The results of membrane characterization using FTIR and UV spectroscopy showed that the PIM membrane was quite stable. While the results of SEM show that there were no pores in the membrane so that the transport occurs by diffusion through the intermediate of the carrier compound. Keywords: electroplating waste; liquid membrane; PIM","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78866522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Performance of Various Organic Solvents as Reaction Media in Plant Oil Lipolysis with Plant Lipase","authors":"A. N. Istyami, T. Soerawidjaja, T. Prakoso, Tri Ari Penia Kresnowati","doi":"10.14710/REAKTOR.18.2.71-75","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.2.71-75","url":null,"abstract":"Fatty acids are intermediate substances in synthesis of oleochemical products. Enzymatic technology of fatty acids production (also known as lipolysis) is now developing as potential substitution for the conventional production of fatty acid, i.e. thermal hydrolysis of triglyceride. It offers more economical process condition, low energy consumption, and minimal product degradation compared to the conventional process. This research aims to evaluate performance of various organic solvents as reaction media in lipolysis with plant latex lipase. Organic solvents observed were chloroform, n-hexane, diethyl ether, benzene, acetone, ethanol, methanol, n-heptane, and isooctane. Analysis of each organic solvent effect on lipolysis was described based on solvents properties. Conversion of lipolysis with organic solvents is 0,10-1,25 times fold compared to conversion of non-solvent lipolysis. We suggest that dielectric constant and viscosity are the two main organic solvent properties affecting lipase performance in lipolysis. Overall, n-hexane, n-heptane, and isooctane are recommended to be used as reaction media in lipolysis with plant lipase because their effects to degree of lipolysis are positive.  Keywords: lipolysis; lipase; organic solvent; frangipani","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86408453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recovery Logam Cu (II) dan Cr(VI) dari Limbah Cair Elektroplating Menggunakan Polymer Inclusion Membrane (PIM)","authors":"M. Djunaidi","doi":"10.14710/reaktor.18.2.113-116","DOIUrl":"https://doi.org/10.14710/reaktor.18.2.113-116","url":null,"abstract":"Telah dilakukan penelitian tentang recovery logam Cu(II) dan Cr(VI) dari limbah cair elektroplating menggunakan Polymer Inclusion Membrane (PIM). [NA1] PIM memiliki kestabilan yang tinggi untuk mengatasi kelemahan ketidakstabilan membran cair. Membran PIM diletakkan diantara dua fasa yaitu fasa umpan sebagai sumber logam Cu (II) dari limbah elektroplating dengan pH 3 dan fasa penerima adalah larutan HNO3 denganpH 1 dan pH 4,4 di fasa umpan serta pH 6,3 di fasa penerima dengan NaCl 2 N untuk logam  Cr(VI). Efisiensi recovery diketahui dengan menentukan kadar Cu (II) dan Cr(VI) dalam fasa umpan dan penerima menggunakan AAS, sedangkan karakterisasi membran menggunakan FTIR, SEM dan spektroskopi UV. Membran PIM yang dihasilkan memiliki sifat: tipis, bening, jernih dan lentur. Dari hasil AAS diperoleh persentase transpor PIM yang dilakukan dengan pengadukan selama 24 jam menunjukkan bahwa persentase transpor logam Cu (II) yang paling tinggi dari fasa umpan sebesar 83,41% dan transpor pada fasa penerima sebesar 72,56%. Sementara prsentase transpor Cr(VI) optimal yaitu 97,8% dari fasa umpan serta 76,5 % di fasa penerima. Hasil karakterisasi membran menggunakan spektroskopi FTIR dan UV menunjukkan bahwa membran PIM cukup stabil. Sedangkan hasil SEM menunjukkan tidak terdapat pori dalam membran sehingga transpor yang terjadi secara difusi melalui perantara senyawa pembawa  Research on Cu (II) and Cr(VI) metal recovery from electroplating wastewater using a Polymer Membrane Inclusion (PIM was conduct. PIM has a high stability to overcome the distability of liquid membrane. PIM membrane was placed between two phases, namely phase feed as a source of Cu(II) from electroplating wastewater with pH 3 and receiver phase was HNO3 solution with a pH of 1 while a system with pH 4,4 in feed phase and 6.3 in receiver phase (2N NaCl) was used for recoveried Cr(VI) from electroplating. The efficiency of recovery was known by determine the concentration  of Cu (II) and Cr(VI) in feed phase and receiver using AAS, whereas the membrane was characterized using FTIR, SEM and UV spectroscopy. The resulting PIM membrane had properties: a thin, transparent, clear and supple. From the results was obtained that the percentage of transport of Cu (II) at the highest performance from the feed phase was 83.41% and transport at the receiving phase was 72.56%. While the highest transport of Cr(VI) from feed phase by 97,8 %  and in receiving phase was 76,5 %. Results membrane characterization using FTIR and UV spectroscopy showed that the PIM membrane was quite stable. While the results of SEM showed that no pores in the membrane so that the diffusion transport occurs through intermediary carrier compound.","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73516798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ultra-capacitor based Hybrid Electric Vehicle (Medium) for Developing Countries","authors":"Md.Zahid Hasan, Md. Rubaiat Adnan, Sabhasachi Saha, Souvik Roy","doi":"10.14710/REAKTOR.18.2.92-101","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.2.92-101","url":null,"abstract":"This research is directed to the hybridization of battery and ultra-capacitor for a better effectiveness. This portrays the benefits of introducing an ultra-capacitor into a battery pack of an urban electric vehicle drive train. Matlab Simulations are done taking two basic scenarios into consideration: fresh cells and half-used battery cells. The simulations show that the lower the temperature (25-28 OC) higher the hybrid system efficiency (25-30%). Data from real world and previous studies are considered to conduct this study. Previous studies showed efficiency raise upto 7%, whereas this system showed around 14% efficiency raise. Simulations are done considering modified Bangladeshi drive cycle for low weight vehicles. Several issues like volumetric, gravimetric and cost issues of hybridization are present in this paper. By this system the power loss of the system can be reduced by up to 5% to 10% regarding to conventional system. Finally hybridization not only increases the efficiency of the energy storage system also increases the power train efficiency and battery lifespan. This paper would help researchers for further development of this topic.","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80360603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The effects of biofilm and selective mixed culture on the electricity outputs and wastewater quality of tempe liquid waste based microbial fuel cell","authors":"T. S. Utami, R. Arbianti, M. Mariana, Nathania Dwi Karina, Vifki Leondo","doi":"10.14710/REAKTOR.18.2.84-91","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.2.84-91","url":null,"abstract":"Microbial Fuel Cell (MFC) technology is highly prospective to be developed because it could be utilized as the alternative electricity sources and simultaneously as the wastewater treatment unit using microorganism as catalyst. Industrial Tempe wastewater has the potential to be used as MFC substrate since it still contains high nutrition for microbe and could pollute the environment if it disposed before being processed first. This study focused on investigating the effect of selective mixed culture addition and biofilm formation on the electricity production and the wastewater treatment aspects with tubular single chamber membranless reactor and industrial Tempe wastewater substrate. The result showed that, with the addition of selective mixed culture, the optimum electricity production obtained with addition of 1 ml gram-negative bacteria with increase in electricity production up to 92.14% and average voltage of 17.91 mV, while the optimum decreased levels of COD and BOD obtained with addition of 5 ml gram-negative bacteria which are 29.32% and 51.32%. On the biofilm formation experiment, optimum electricity production obtained from biofilm formation time for 14 days with increase in electricity production up to 10-folds and average voltage of 30.52 mV, while the optimum decreased levels of COD and BOD obtained from biofilm formation time for 7 days which are 18.2% and 35.9%.Keywords : biofilm, Microbial Fuel Cell, selective mixed culture, Tempe wastewater, tubular reactor","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82141006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Kinetic Study of limonene and glucose adsorption on immobilization and coimmobilization beads","authors":"A. Damayanti, S. Sarto, W. B. Sediawan","doi":"10.14710/REAKTOR.18.2.57-62","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.2.57-62","url":null,"abstract":"Rotten oranges contain glucose and limonene, in which limonene is an inhibitor of microorganisms. Immobilization of mixed culture used the entrapment method is the easiest method of protecting the mixed culture from inhibitors. Entrapment method with extrusion drip is an efficient and effective technique to produce beads. This study aims to determine the adsorption rate of adsorbate (glucose and limonene) on the adsorbent surface (beads). Materials used in this study were glucose, DL-limonene, mixed culture, and beads. Three types of beads consisted of alginate - no mixed culture (A), alginate and activated carbon - no mixed culture (CA), alginate and activated carbon - free mixed culture (CB). Adsorption column consist of 30 ml nutrient, 15 mL substrate, and 5 mL beads. If the beads do not contain mixed culture, nutrients and substrate were replaced by aquadest. The reactor was done in a batch system at 37oC. The lowest order of beads ability to adsorb glucose were AG followed by CAG and finally CBG, whereas to limonene solution were AL followed by CBL and finally CAL. Lagergren model was used to determined kinetic bioadsorption on limonene and glucose. The adsorption rate value in the pseudo-second order (k2,ad) for the glucose solution was ranged between 0.025 to 0.087 min-1, while the D-limonene was in the range between 2.084 to 5.233 min-1. Adsorption of glucose and limonene on the surface of the three types of adsorbents was reached steady state at the 60th minute.Keywords: orange, limonene, immobilization, adsorption, Lagergren model.","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86451141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hazard Assessment of LNG Loading-Unloading Process in Cirebon Port","authors":"H. Devianto, M. Eviani, P. Widiatmoko, I. Nurdin","doi":"10.14710/REAKTOR.18.2.117-121","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.2.117-121","url":null,"abstract":"Cirebon Port has spacious work and water area that provides opportunities to be developed in industrial sectors, particularly the petrochemical industries such as ethylene and Liquefied Natural Gas (LNG). In atmospheric condition, they are classified as volatile gas. Either in processing or transporting, they are stored in closed system. However, they still have a probability to be released to the environment and may lead to a fire or explosion. This probability is increased in the existence of coal stockpile in the port area which can evoke a fire. Therefore, a safety study is needed to identify the risk of the loading-unloading activities. The problem was solved by following steps. First, the data such as physical properties, layout area, and geographical condition around the port were collected. Then, the hazardous nodes were identified qualitatively, and then the quantitative analysis was done using As Low As Reasonably Practicable (ALARP) analysis. From the safety study, a suitable handling and safety system is provided to ensure safety viability in the ethylene and LNG loading-unloading process at the Cirebon port.Keywords: ethylene; hazard assessment; LNG; loading-unloading process; Quantitative Risk Assessment (QRA)","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82478991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Extraction Time on Unreacted Oil Removal in Biodiesel Purification Using Deep Eutectic Solvent","authors":"H. Niawanti, S. Zullaikah","doi":"10.14710/REAKTOR.18.2.122-127","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.2.122-127","url":null,"abstract":"Rice bran oil (RBO) based biodiesel contains unreacted oil such as monoglyceride (MG), diglyceride (DG) and triglyceride (TG) to be purified. The liquid-liquid extraction (LLE) method was used for purification using Deep Eutectic Solvent (DES). The objective of this work was to study the effect of extraction time on unreacted oil removal. RBO containing 16.49% oil with free fatty acids (FFA) content of 44.75%. Acid catalyzed methanolysis was used for biodiesel production under operating conditions: T = 60°C, t = 8 hours, molar ratio of oil/methanol  was 1/10, H2SO4 1% w/w of RBO. Crude biodiesel containing 89.05% fatty acid methyl ester (FAME), 0.05% FFA, TG 4.03%, DG 4.01%  and MG 0.30%. DES was made from choline chloride and ethylene glycol with 1/2 molar ratio, while molar ratio of biodiesel/DES was 1/2. The extraction time was varied from 15 to 240 minutes at 30°C. The highest TG, DG and MG removal were obtained at 240 minutes, they were 3.01%, 0.22% and 0.03%, respectively. FAME and FFA content were 96.55% and 0.03%. Keywords: biodiesel; DES; extraction; unreacted oil; purification","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82358394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Shelf Life Prediction of Chocomix Instant Chocolate Beverage Powder Using Accelerated Shelf Life Testing (ASLT) based on Critical Moisture Content Approach","authors":"R. Nurhayati, R. Pratiwi, Baskara Katri Anandito, Ervika Rahayu Novita, M. Angwar","doi":"10.14710/reaktor.18.2.63-70","DOIUrl":"https://doi.org/10.14710/reaktor.18.2.63-70","url":null,"abstract":"Chocomix chocolate beverage powder is one of the increased value-added cocoa products by Griya Cokelat Nglanggeran. The aimed of this study to estimate the shelf life using Accelerated Shelf Life Testing (ASLT) based on critical moisture content. Results showed that critical moisture content of Chocomix was 4.01 % (db). Moisture sorption isotherm (MSI) curve of Chocomix at 28oC was type II isothermic sigmoidal with 2 curves at the ranged of water activity between 0.24 and 0.68; and the equation was  y = 86.584X3 – 91.893X2 + 28.818X – 0.470. The calculation showed that estimated shelf life of Chocomix stored in 51.89 µm thick package at 28oC was 16.4 months.Keywords: chocolate powder, critical moisture content, moisture sorption isotherm, shelf life","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87491513","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of Matrix Si-K-HAs Gel from Geothermal Sludge and Peat","authors":"Srie Muljani, B. Wahyudi, S. Suprihatin, K. Sumada","doi":"10.14710/REAKTOR.18.2.76-83","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.2.76-83","url":null,"abstract":"The synthesis of matrix silica-potassium-humic acid gel (Si-K-HAs) has been performed successfully by gradual extraction and acidification method. The extraction was carried out in two stages: 1) extraction of humic substances from peat prepared by potassium hydroxide to produce potassium humate (K-HAS) solution, 2) extraction silica from geothermal sludge using K-HAs solution to produce Si-K-HAs solution. Acidification of Si-K-HAs solution prepared by citric acid (1-3N) to produce matrix gel of Si-K-HAs. The Si-K-HAs matrix gel products are characterized by Fourier Transform InfraRed (FTIR), X-ray fluroscence (XRF), and Brunauer–Emmett–Teller (BET) analysis. The acidification process was carried out in neutral to acid (pH 3-7) conditions and the results showed that at neutral pH no Si-K-HAs gel formed. IR spectra confirmed the presence of humic acid in the gel product, whereas XRF analysis confirmed the presence of potassium (K) and silica (SiO2) in the gel product. The molar ratio of SiO2:K2O in the product is 0.9 - 0.3 in the pH range of 3-5. Si-K-HAs powder can be used as soil fertilizer especially for soils that lack silica, humic, and potassium nutrients or for future application development. Keywords: gradual extraction; geothermal sludge; matrix gel; humic substance","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82780345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}