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Evaluation of the Potential of Ethyl Esterification Reaction Catalyzed by Enzyme to Improve the Quality of Bio-Oil 酶催化乙基酯化反应提高生物油品质的潜力评价
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.254
Candida Luiza Simonato, A. Gonçalves, Bruno Eduardo Piske, Luana Marcele Chiarello, V. Botton, Laércio Endre, Vinicyus Rodolfo Wiggers
Biomass has been investigated in recent years as an alternative source for fuel production. The use of triglyceride biomass is highlighted and, from the thermal cracking process, solid, liquid and gaseous products with energetic potential are generated. The liquid product, called bio-oil, has characteristics similar those of fossil fuels. Its composition is mainly based on hydrocarbons and carboxylic acids, and the second group generates a limiting characteristic in its processing, refining and use as fuel, increasing the acidity of bio-oil. In this work, bio-oil produced from commercial soybean oil was used in a thermal cracking process at 525ºC. The objective was to carry out ethyl esterification reactions via enzymatic catalysis in order to reduce the acidity index of the crude bio-oil. All reactions were carried out at 40ºC to avoid enzyme deactivation and different conditions of type and amount of catalyst, alcohol mass ratio and reaction time were evaluated. The best result was obtained after 6 hours of reaction with 60% acidity reduction, using Novozym 435 lipase as a catalyst at a concentration of 5% in relation to the substrate mass and 1:3 mass ratio.
近年来,生物质作为燃料生产的一种替代来源得到了研究。强调了甘油三酯生物质的使用,并从热裂解过程中产生具有能量潜力的固体、液体和气体产品。这种液体产品被称为生物油,具有与化石燃料相似的特性。其成分主要以碳氢化合物和羧酸为主,而第二类在其加工、提炼和用作燃料时产生限制特性,增加了生物油的酸度。以商品大豆油为原料制备生物油,在525℃条件下进行热裂解。目的是通过酶催化进行乙基酯化反应,以降低生物原油的酸度指数。为避免酶失活,所有反应均在40℃下进行,并对不同条件下催化剂种类、用量、乙醇质量比和反应时间进行了评价。以Novozym 435脂肪酶为催化剂,与底物质量比为5%,质量比为1:3,酸度降低60%,反应6小时后得到最佳效果。
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引用次数: 0
Modelling Wind Turbine Power Curves based on Frank’s copula 基于弗兰克公式的风力发电机功率曲线建模
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.378
M.A. Garcia-Vaca, J. Sierra-García, M. Santos, Ravi Kumar Pandit
In the study of wind turbines, one of the most relevant and useful indicators is the power curve. It has been shown to be of paramount importance in evaluating turbine performance and therefore reducing operation and maintenance (O&M) costs. Various techniques can be applied to model and obtain the shape of this curve, which relates the electrical power generated by a turbine to the wind speed. Statistical copulas are used in this paper, a tool used in other fields such as econometrics, and whose potential lies in its ability to capture the complex dependency between the variables involved. In particular, the Frank copula is applied to obtain a probabilistic model of the power curve of a wind turbine. This model is compared with the Gaussian Mixture Model, a technique widely used to obtain parametric probabilistic models. As a result of this comparison, it is observed that the Frank copula model fits the power curve of the wind turbine with greater precision and reliability, which would allow its use for prediction and fault detection.
在风力涡轮机的研究中,功率曲线是最相关和最有用的指标之一。它已被证明是最重要的评估涡轮机性能,从而降低运行和维护(O&M)成本。可以应用各种技术来建模并获得这条曲线的形状,这条曲线将涡轮机产生的电力与风速联系起来。统计公式在本文中使用,这是一种在其他领域如计量经济学中使用的工具,其潜力在于它能够捕捉所涉及变量之间的复杂依赖关系。特别地,应用Frank联结公式得到了风力机功率曲线的概率模型。该模型与高斯混合模型进行了比较,高斯混合模型是一种广泛用于获取参数概率模型的技术。通过比较可以看出,Frank copula模型对风力机功率曲线的拟合精度和可靠性更高,可用于预测和故障检测。
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引用次数: 0
Technical-economic feasibility analysis of a large-scale parabolic trough collectors solar power plant in Brazil 巴西大型抛物面槽集热器太阳能电站技术经济可行性分析
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.316
M. Lopes, G. Acevedo, B. Menezes, O.H.F. Rabelo, L. B. Brito, A. B. Dias, A. Filho, E. G. Domingues
This study aims to present the results of the application of a computational tool developed to perform a technical-economic feasibility analysis of large-scale Parabolic Trough Collectors (PTC) solar power plants in Brazil. The gross revenue from cash flow is obtained through an energy trading model for the Regulated Contracting Environment of the Brazilian Electricity Market. The economic viability analysis uses the Net Present Value, Modified Internal Rate of Return, Discounted Payback, and Levelized Cost of Energy indicators. The parametric structural optimization method is used to optimize the technical parameters of the plant. A case study was conducted to analyse the feasibility of implementing a 100 MW PTC in the five regions of Brazil. The results indicated that the best region in Brazil to receive this technology is the northeastern region. However, the project is economically unfeasible in all cities analysed. Therefore, a sensitivity analysis of the main parameters that affect the project's net present value is carried out to evaluate the impact of the economic parameters on the economic viability of an optimized PTC plant located in the city with the best technical performance. An optimistic scenario was evaluated considering the system's response to the parameters investigated in the sensitivity analysis. For this scenario, the results pointed to the project's economic viability.
本研究旨在展示巴西大型抛物槽集热器(PTC)太阳能发电厂的技术经济可行性分析所开发的计算工具的应用结果。现金流的总收入是通过巴西电力市场受管制承包环境的能源交易模型获得的。经济可行性分析使用净现值、修正内部收益率、贴现回收期和能源平准化成本指标。采用参数结构优化方法对装置的技术参数进行优化。进行了一个案例研究,以分析在巴西五个地区实施100兆瓦PTC的可行性。结果表明,巴西东北地区最适合采用该技术。然而,该项目在所有分析的城市中都是经济上不可行的。因此,对影响项目净现值的主要参数进行敏感性分析,以评估经济参数对优化后技术性能最佳的城市PTC工厂经济可行性的影响。考虑到系统对灵敏度分析中所研究的参数的响应,评估了一个乐观的情景。在这种情况下,结果表明了该项目的经济可行性。
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引用次数: 0
Utility-scale renewable hydrogen generation by wind turbines 利用风力涡轮机生产公用事业规模的可再生氢
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.208
R. Dufo-López, J. Lujano-Rojas, J. Bernal-Agustín, J. S. Artal-Sevil, Á. Bayod-Rújula, Tomás Cortés-Arcos, Javier Carroquino Oñate, Cristina Escriche Martínez
In this paper, we use MHOGA software for the evaluation of a hydrogen generation system powered by wind turbines. We study the state of the art of the electrolyzers, obtaining the most important characteristics and costs of PEM electrolyzers. The optimization of a Wind-H2 system is performed, obtaining the best combination of components (wind turbines and electrolyzer) and control strategy for the hydrogen production. We will compare to the Wind-only system (wind farm which injects all the electricity produced to the gird). Two cases have been evaluated regarding the electricity price: Spanish SPOT price of 2019 and of 2021, with an expected increase of 1% annual. The Wind-H2 system can be competitive to the Wind-only system if the hydrogen sale price is 4.8 €/kg for the case of 2019 SPOT prices and 6.7 €/kg for the case of 2021 SPOT prices, considering 1% annual increase in the SPOT prices and 2% for the hydrogen price.
在本文中,我们使用MHOGA软件对风力发电系统进行了评估。研究了PEM电解槽的发展现状,得到了PEM电解槽最重要的特性和成本。对wind - h2系统进行了优化,获得了最佳的组件组合(风力涡轮机和电解槽)和制氢控制策略。我们将比较风力发电系统(风电场将所有产生的电力注入电网)。对电价进行了两种情况的评估:2019年和2021年的西班牙现货价格,预计每年增长1%。如果氢的销售价格在2019年现货价格为4.8欧元/公斤,在2021年现货价格为6.7欧元/公斤的情况下,考虑到现货价格每年上涨1%,氢价格每年上涨2%,那么Wind-H2系统可以与纯风能系统竞争。
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引用次数: 0
Inverter Control Design for the optimal management of electrical Microgrids 微电网优化管理的逆变器控制设计
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.310
J. R. Vazquez, N. Magro, R. S. Herrera, A. Martin
Nowadays, the promotion of renewable energy sources is a necessity. Technically, the increase of the renewable penetration in the power system (PS) is a challenge. One solution for this problem is the use of self-controlled microgrids (smartgrid, SG). In this work, the design of an algorithm to optimal manage the SG energy through the power inverter control in the SG is presented. In general, a SG consists of renewable energy sources, electrical loads and storage systems. In an isolated SG (no connected to the power system), a DC/AC (direct current / alternating current) converter (power inverter, PInv) is necessary to provide an alternating voltage to supply the loads. If the SG is connected to the PS, the PInv is used to inject the active power from the renewable energy sources.
如今,推广可再生能源是必要的。从技术上讲,提高可再生能源在电力系统中的渗透率是一个挑战。这个问题的一个解决方案是使用自控微电网(智能电网,SG)。本文提出了一种通过SG中的逆变器控制实现SG能量优化管理的算法。一般来说,SG由可再生能源、电力负荷和存储系统组成。在隔离的SG(未连接到电源系统)中,必须使用DC/AC(直流/交流)转换器(电源逆变器,PInv)来提供交流电压以供电负载。如果SG与PS连接,则PInv用于注入可再生能源的有功功率。
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引用次数: 0
Performance of an OVT inverter reliant on the switching frequency of the filtering inverter OVT逆变器的性能依赖于滤波逆变器的开关频率
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.450
A. Muc, J. Iwaszkiewicz
The paper presents an inverter based on the orthogonal space vectors theory (OVT inverter) and its performance. The OVT inverter consists of two constituent twolevel 3-phase inverters: the main inverter (MI) and the auxiliary one (AI). The MI is controlled in a simple way to generate the stepped output voltage and the AI works as an active filter limiting the higher harmonics in the OVT output voltage. The filtering process is formed by the use of the orthogonal space vector theory. The output voltage of the OVT inverter takes the shape of a stepped voltage comparable to the voltage generated by multilevel inverters. The AI operates as a very effective active power filter (APF) of the OVT inverter output voltage. The AI power is significantly lower in comparison to the MI power nevertheless its switching frequency affects the OVT performance. The article describes studies in which the impact of changes in the switching frequency filter inverter on the operation of the orthogonal inverter and the output voltage THD. Increasing the filter inverter switching frequency improved performance and reduced the transformer size, which acts as a summing node.
介绍了一种基于正交空间矢量理论的逆变器(OVT逆变器)及其性能。OVT逆变器由两个组成的两电平三相逆变器组成:主逆变器(MI)和辅助逆变器(AI)。MI以一种简单的方式控制以产生阶跃输出电压,AI作为有源滤波器限制OVT输出电压中的高谐波。利用正交空间矢量理论形成滤波过程。OVT逆变器的输出电压采用与多电平逆变器产生的电压相当的阶跃电压的形状。人工智能作为OVT逆变器输出电压的一个非常有效的有源电源滤波器(APF)。与MI功率相比,AI功率明显较低,但其开关频率影响OVT性能。本文研究了逆变器开关频率滤波器的变化对正交逆变器的工作和输出电压THD的影响。提高滤波器逆变器的开关频率,可以提高逆变器的性能,减小变压器的尺寸,起到求和节点的作用。
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引用次数: 0
Alternative Uses of Hydroelectric Power Plants in a Decarbonized Energy Scenario 脱碳能源情景下水力发电厂的替代用途
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.368
M. Remiro-Cinca, L. Elorza-Uriarte, G. Fernández, L. Luengo-Baranguan, D. Martinez, N. Galán Hernández
Drastic reduction of greenhouse gases emissions depends, among other factors, on a quick and efficient integration of renewable sources in the energy generation pool. In this context, hydropower nowadays represents the biggest share of the world renewable energy generation. However, in the case of European Union, many hydropower plants are about to reach their end-of-life stage and environmental regulations on the recovery of natural water flows require these plants to be dismantled. In the controversial scenario where the need to recover natural waterflows and the loss of a key source of green energy clash with each other, the objective of this work is to provide an exhaustive review of the different auxiliary services that hydropower plants can provide in the current and especially future decarbonized electricity paradigm. To this end, services such as participation in secondary and tertiary regulation markets, power purchase agreements, local energy communities, reduction of curtailments, renewable energy storage or contribution to physical inertia to the grid are analyzed and final conclusions are drawn.
除其他因素外,大幅度减少温室气体排放取决于迅速有效地将可再生能源纳入能源生产池。在这种情况下,水力发电目前占世界可再生能源发电的最大份额。然而,就欧盟而言,许多水电站即将达到其生命周期的最后阶段,有关自然水流恢复的环境法规要求这些电站被拆除。在有争议的情况下,恢复自然水流的需要和绿色能源的关键来源的损失相互冲突,本工作的目的是对水电站在当前和特别是未来脱碳电力范例中可以提供的不同辅助服务进行详尽的审查。为此,分析了参与二级和三级监管市场、电力购买协议、当地能源社区、减少弃电、可再生能源存储或对电网的物理惯性做出贡献等服务,并得出了最终结论。
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引用次数: 0
Dynamic energy prices for residential users based on Deep Learning prediction models of consumption and renewable generation 基于消费和可再生能源发电深度学习预测模型的住宅用户动态能源价格
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.226
J. Cano-Martínez, E. Peñalvo-López, V. León-Martínez, I. Valencia-Salazar
New demand-side management models have emerged as a result of rising energy prices, the development of artificial intelligence, and the rise of prosumers. The purpose of this research is to use deep learning techniques to predict the energy production and demand of a prosumer network to determine dynamic prices for the local market. Gated Recurrent Units (GRU) and Long Short-Term Memory (LSTM) were two methods that were taken into consideration for forecasting consumer demand and wind and solar energy generation. Root Mean Square Error (RMSE), Mean Absolute Error (MAE), and Mean Absolute Percentage Error (MAPE) were used to compare the various approaches. The results demonstrated that GRU, with 0.0273, 0.0158, and 49.8 in RMSE, MAE, and MAPE respectively, is the best method for predicting energy generation and consumption in our datasets. Demand management system dynamic prices were calculated on an hourly basis using input from energy generation and demand forecasts. Finally, an optimization method was developed for establishing the energy planning.
由于能源价格上涨、人工智能发展和产消者崛起,新的需求侧管理模式应运而生。本研究的目的是使用深度学习技术来预测产消网络的能源生产和需求,以确定当地市场的动态价格。门控循环单元(GRU)和长短期记忆(LSTM)是用于预测消费者需求和风能和太阳能发电的两种方法。使用均方根误差(RMSE)、平均绝对误差(MAE)和平均绝对百分比误差(MAPE)来比较各种方法。结果表明,GRU在RMSE、MAE和MAPE上分别为0.0273、0.0158和49.8,是预测能源产生和消耗的最佳方法。需求管理系统动态价格按小时计算,使用能源发电和需求预测的输入。最后,提出了一种制定能源规划的优化方法。
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引用次数: 0
Reducing Fossil Fuel Consumption by Incorporating Renewable Energy Sources in Wastewater Treatment Processes 通过在废水处理过程中使用可再生能源来减少化石燃料的消耗
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.360
H. Friman
Various types of aqueous solutions are disposed of in residential, institutional, commercial, and industrial buildings. The wastewater must be treated to remove pathogens (bacteria, viruses), nutrients (nitrogen, phosphorus), and other compounds in order to maintain public health and the environment. Accumulation of untreated sewage can result in a wide range of nuisances. Most of Israel's wastewater is purified and used for irrigation every year, which amounts to 530 million cubic meters. Approximately 80 percent of wastewater recovered in Israel is recycled. By treating wastewater appropriately, agriculture, tourism, gardening, and industry can benefit. The presence of raw sewage in settlements with no sewage collection or transportation networks continues to pose a great threat even today. There is a significant energy consumption associated with wastewater treatment processes. In this study, solar energy was attempted to be integrated as a renewable energy source. With Renewable Energy Sources integrated into the process, costs will be reduced, and it will also be possible to establish decentralized facilities in areas without proper infrastructure for traditional treatment methods.
在住宅、机构、商业和工业建筑中处理各种类型的水溶液。必须对废水进行处理,以去除病原体(细菌、病毒)、营养物质(氮、磷)和其他化合物,以维护公众健康和环境。未经处理的污水积聚会造成各种滋扰。以色列每年的大部分废水经过净化后用于灌溉,总量达5.3亿立方米。在以色列,大约80%的废水被循环利用。通过适当处理废水,农业、旅游业、园艺和工业都能受益。即使在今天,在没有污水收集或运输网络的住区中,未经处理的污水仍然构成巨大威胁。与废水处理过程相关的能源消耗很大。在本研究中,试图将太阳能作为一种可再生能源加以整合。在将可再生能源纳入这一过程后,成本将会降低,而且在没有传统处理方法的适当基础设施的地区,也将有可能建立分散的设施。
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引用次数: 0
Protection of MVDC grids for the production of green hydrogen 保护MVDC电网生产绿色氢
Q4 Energy Pub Date : 2023-07-01 DOI: 10.24084/repqj21.260
D. M. Larruskain, P. Eguía, A. Iturregi, E. Torres, V. Valverde, A. Blázquez
Green hydrogen production from renewable energy sources has a big potential to reduce energy dependence on fossil fuel, contributing to the global goal set by the international community of net zero emissions by 2050. Electrolyzers are connected to grid with power stages that can be designed as active devices with high control capability and a remarkably fast operation. Nevertheless, in the present, they must overcome some challenges in order to ensure a reliable operation. This paper addresses the concept of protection of DC grids with electrolyzers fed from renewable energy sources. The topologies of the grid are discussed as well as protection features and fault clearing strategies. A new dynamic model for multi megawatt PEM electrolyzer is introduced. Finally, a case study with a PEM electrolyzer in a MVDC system is included.
利用可再生能源生产绿色氢具有很大的潜力,可以减少对化石燃料的能源依赖,有助于实现国际社会制定的到2050年实现净零排放的全球目标。电解槽连接到电网的功率级,可以设计为具有高控制能力和运行速度非常快的有源设备。然而,在目前,他们必须克服一些挑战,以确保可靠的行动。本文讨论了用可再生能源供电的电解槽保护直流电网的概念。讨论了电网的拓扑结构、保护特性和故障清除策略。介绍了一种新的多兆瓦PEM电解槽动态模型。最后,给出了MVDC系统中PEM电解槽的实例研究。
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引用次数: 0
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Renewable Energy and Power Quality Journal
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