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Optimasi Adsorpsi Ion Logam Cu2+ dengan Menggunakan Cangkang Telur Ayam Ras 采用自生蛋壳自生的合金升渣优化
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.115915
Nesya Febi Utami, Edi Nasra, Desy Kurniawati, Umar Kalmar Nizar
adsorption is a method of waste treatment that has the potential to remove toxic heavy metals. One of the factors that influence the occurrence of the adsorption process is the presence of a biological material called a biosorbent. The adsorption method is a method of absorbing heavy metal contamination in liquid waste that is very efficient and effective, as well as easy and cheap economically because of the use of biomaterials that are very cheap and can be regenerated. Chicken egg shell contains Calcium Carbonate (CaCO3) of 98.41% and has natural pores of 10,000 to 20,000 so it is estimated that it can absorb solutes. Based on the known mineral composition, chicken egg shells are composed of CaCO3 (98.41%), Ca3(PO4)2 (0.75%), and MgCO3 (0.84%). So it can be seen that chicken egg shells have a high calcium carbonate content, where calcium carbonate is a polar adsorbent. The optimum conditions for each variable in contacting broiler egg shells that have been activated with Cu2+ metal ions are optimum at pH 4, concentration of 250 ppm.
吸附法是一种废物处理方法,具有去除有毒重金属的潜力。影响吸附过程发生的因素之一是被称为生物吸附剂的生物材料的存在。吸附法是一种吸收废液中重金属污染的方法,效率高,效果好,而且由于使用的生物材料非常便宜,而且可以再生,所以在经济上简单便宜。鸡蛋壳含有98.41%的碳酸钙(CaCO3),天然孔隙为1万至2万个,因此估计它可以吸收溶质。根据已知矿物组成,鸡蛋壳主要由CaCO3(98.41%)、Ca3(PO4)2(0.75%)和MgCO3(0.84%)组成。由此可见,鸡蛋壳的碳酸钙含量很高,其中碳酸钙是一种极性吸附剂。Cu2+金属离子活化后的肉鸡蛋壳接触各变量的最佳条件为pH为4,浓度为250 ppm。
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引用次数: 0
Adsorpsi Anion Nitrat Menggunakan Silika Gel (SiO2) GPTMS Dimodifikasi dengan Dimetilamina 硝酸阴离子的消化道使用二氧化硅改用二恶英修饰过的二恶英
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.115920
Anisa Nahari, Budhi Oktavia, M. Khair, Ananda Putra
Silica or silicon dioxide is a chemical compound with the molecular formula SiO2 which can be obtained from the synthesis of crystals, silica minerals, and vegetables. Compounds resulting from the polymerization of silicic acid, which are composed of a tetrahedral SiO4 unit chain with the general formula SiO2. Each silica atom is surrounded by four oxygen atoms. Silica forms a polyhedral network, where the bonds between oxygen tetrahendral are one and the other. Silica will form a framework that has pores that are quite open and allow other molecules to enter and undergo adsorption on the surface of the silica. Modification of silica is done by adding heat at a certain temperature, adding reagents to the active site of silica will change the silica functional group. Silica with the addition of amine compounds reacted with GPTMS can be used as nitrate anion adsorption to see the absorption capacity of silica against nitrate anions using the batch method. The factors used to see this adsorption capacity include pH at pH 7 with an absorption of 1.931463 mg/g and the percentage of absorption is 79.5%. and contact time with a time of 90 minutes with an absorption of 0.32677 mg/g and the percentage of absorption is 67.28785%.
二氧化硅或二氧化硅是一种分子式为SiO2的化合物,可以从合成晶体、二氧化硅矿物和蔬菜中获得。由硅酸聚合而成的化合物,由四面体SiO4单元链组成,通式为SiO2。每个硅原子被四个氧原子包围。二氧化硅形成一个多面体网络,其中氧四面体之间的键是一个和另一个。二氧化硅将形成一个具有相当开放的孔隙的框架,允许其他分子进入并在二氧化硅表面进行吸附。二氧化硅的改性是通过在一定温度下加温来完成的,在二氧化硅的活性位点加入试剂会改变二氧化硅的官能团。二氧化硅与胺类化合物的加入与GPTMS反应可作为硝酸盐阴离子的吸附,用批处理法观察二氧化硅对硝酸盐阴离子的吸附能力。考察吸附量的因素包括pH值为ph7时的吸附量为1.931463 mg/g,吸附率为79.5%。接触时间为90 min,吸收率为0.32677 mg/g,吸收率为67.28785%。
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引用次数: 0
Silika Gel Termodifikasi Dimetilamin Sebagai Penyerap Anion Fosfat 修饰过的二氧化硅凝胶被甲醛吸收
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.116103
Delfitri Delfitri, Budhi Oktavia, D. Kurniawati, Umar Kalmar Nizar
— Silica gel is one type of dry silica gel which is widely used as an adsorbent. Silica has the ability to absorbsi because it has two active site groups that can be activated, namely a silanol group and a siloxane group. This modification was carried out to increase the ability of silica to absorbsi ions, one of which was phosphate anion. In waters, very high levels of phosphate anion can disrupt the marine biota ecosystem because it can cause eutrophication or decreased oxygen levels that enter the waters. The modifier compound used is dimethylamine (DMA). Silica and dimethylamine can bind to several linking compounds, namely glycidopropyltrimethoxylan (gptms). The modified silica was characterized by FTIR and the absorption results were analyzed using a UV-Vis spectrophotometer. The results of the comparison of the absorption capacity of phosphate anions after modification are greater than before modification, where the absorption capacity of silica before modification is 1,2601 mg/g with an absorption percentage of 54,46% and silica after modification is 1.9686 mg/g with an absorption percentage of 1,9686 mg/g. 85,08%.
-硅胶是一种干硅胶,广泛用作吸附剂。二氧化硅具有吸收硅的能力,是因为它有两个可以被激活的活性位基,即硅醇基和硅氧烷基。对二氧化硅进行改性是为了提高其对磷酸阴离子的吸收能力。在水中,非常高水平的磷酸盐阴离子会破坏海洋生物群生态系统,因为它会导致富营养化或降低进入水中的氧气水平。所使用的改性化合物是二甲胺(DMA)。二氧化硅和二甲胺可以结合到几种连接化合物,即甘油丙基三甲氧基胺(gptms)。用红外光谱对改性二氧化硅进行了表征,并用紫外可见分光光度计对改性二氧化硅的吸收结果进行了分析。改性后的二氧化硅对磷酸阴离子的吸收容量比改性前的大,其中改性前的二氧化硅的吸收容量为1,2601 mg/g,吸收率为54.46%;改性后的二氧化硅的吸收容量为1.9686 mg/g,吸收率为1,9686 mg/g。85年,08%。
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引用次数: 0
Pengaruh Penambahan Rempah Ketumbar (Coriandrum Sativum L.) Terhadap Cita Rasa Pada Rendang Daging Sapi Dengan Uji Hedonik 香菜香料加法(Coriandrum Sativum L)的影响。用油炸牛肉调味料进行酒精测试
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.116016
Indah Novalia Dwi Putri, Iswendi Iswendi, Iryani Iryani, Fitri Amelia
Coriander (Coriandrum sativum L.) is a spice known to have active ingredients, one of which is anti-cholesterol. Some regions use coriander as an ingredient in making beef rendang. The purpose of this study was to determine the level of preference for color, meat texture, seasoning texture, taste and aroma of beef rendang made using six variations of the addition of coriander rhizome, namely with levels: 0, 1, 2, 3, 4 and 5 grams/500 grams. beef. The organoleptic test method uses the hedonic test, namely the level of preference test with 40 panelists of UNP chemistry students 2020. The hedonic test results show that, the addition of coriander seasoning to beef rendang in general there is no significant change (p> 0.05) to the original rendang.
芫荽(Coriandrum sativum L.)是一种已知具有活性成分的香料,其中一种是抗胆固醇。有些地区用香菜作为制作牛肉辣当的原料。本研究的目的是通过6种不同的香菜根添加量,即0、1、2、3、4和5 g /500 g,来确定牛肉人当对颜色、肉质、调味质感、口感和香气的偏好程度。牛肉。感官测试方法采用享乐测试,即对40名UNP化学专业2020级学生的偏好水平测试。享乐性检验结果表明,加入香菜调味料后的牛肉任当总体上与原任当相比没有显著变化(p> 0.05)。
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引用次数: 0
Impregnasi ZnO Karbon Aktif dari Sabut Kelapa (Cocos nucifera L) Fotokatalis Untuk Degradasi Rhodamin B
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.115842
Rahayu Hardiani, M. Khair
— Research on increasing the degradation ability of AC-ZnO catalyst against Rhodamine B by impregnation on activated carbon from coconut fiber (Cocos nucifera L) has been carried out. Activated carbon is catalyzed by ZnO semiconductor catalyst by impregnation method. Impregnation was carried out by varying the addition of activated carbon (AC) 5%, 10%, 15%, 20% and 25% ZnO mass for 6 hours. The catalyst was calcined at 300 C for 105 minutes. For the results of the AC-ZnO adsorption test on Rhodamine B, the catalyst was tested on the degradation of Rhodamine B solution (10 ppm) with UV irradiation. obtained 89.76%. This shows that activated carbon from coconut fiber can support to increase the role of ZnO in the degradation of Rhodamine B. Characterization of the optimum degradation yield was carried out by FTIR. The characterization results showed that the ZnO catalyst was successfully formed.
-通过浸渍椰纤维活性炭提高AC-ZnO催化剂对罗丹明B的降解能力进行了研究。采用浸渍法制备了ZnO半导体催化剂对活性炭的催化反应。通过添加5%、10%、15%、20%和25%氧化锌的不同活性炭(AC)浸渍6小时。催化剂在300℃下煅烧105分钟。针对交流氧化锌对罗丹明B的吸附试验结果,采用紫外光照射对罗丹明B溶液(10 ppm)进行了降解试验。获得89.76%。由此可见,椰子纤维活性炭可以支持ZnO对罗丹明b的降解,并通过FTIR对最佳降解率进行表征。表征结果表明,ZnO催化剂制备成功。
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引用次数: 0
Degradasi Zat Warna Metil Violet Menggunakan Metoda Sonolisis Dengan Katalis ZnO-Ag 紫罗兰色物质的降解使用了ZnO-Ag催化剂的方法
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.116210
Abdul Rafi Jelani, Hary Sanjaya
— Methyl violet is a dye that is often used in the textile industry. Methyl violet contains aniline which is toxic, mutagenic, and carcinogenic. These compounds cause cancer and gene mutations in living tissue. In addition, methyl violet is also difficult to degrade in waste so it requires serious handling. This study aims to determine the optimum time and optimum mass of ZnO-Ag catalyst against Methyl violet degradation by the sonolysis method. The absorbance value was obtained using a UV-Vis spectrophotometer. The results stated that the Methyl violet solution had a maximum wavelength of 582 nm. The maximum time to degrade Methyl violet with ZnO catalyst was obtained at 90 minutes with %D 85.917% and the maximum mass of catalyst to degrade methyl violet with 0,15 gram ZnO-Ag 10% catalyst was obtained at 87.97% mass .
甲基紫是一种经常用于纺织工业的染料。甲基紫含有苯胺,具有毒性、致突变性和致癌性。这些化合物会在活组织中引起癌症和基因突变。此外,甲基紫在废物中也很难降解,因此需要认真处理。本研究的目的是确定声溶法降解甲基紫的最佳时间和最佳质量的ZnO-Ag催化剂。用紫外-可见分光光度计测定吸光度值。结果表明,甲基紫溶液的最大波长为582 nm。氧化锌催化剂降解甲基紫的最大时间为90 min,含锌量为85.917%;氧化锌-银含量为0.15 g,含锌量为10%的催化剂降解甲基紫的最大质量为87.97%。
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引用次数: 0
Identifikasi Senyawa Metabolit Sekunder Pada Jantung Pisang Kapas (Musa x paradisiaca L.) 香蕉棉花心脏的次级代谢化合物(摩西x范例)
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.114981
Yogi Fernanda Saputra, S. Etika, Melindra Mulia
— Musa x paradisiaca L. or cotton banana is a plant that belongs to the Musaceae family. Almost all parts of this plant can be consumed, one of which is the banana blossom. Banana blossom can be cooked as a vegetable and is useful in treating diabetes. In this study, phytochemical screening was carried out to determine secondary metabolites contained in Musa x paradisiaca L. The results of phytochemical screening showed that Musa x paradisiaca L. contained secondary metabolites of flavonoids, terpenoids, phenolics and saponins, but did not contain alkaloids and steroids.
芭蕉(Musa x paradisiaca L.)是芭蕉科的一种植物。这种植物的几乎所有部分都可以食用,其中之一就是香蕉花。香蕉花可以作为蔬菜煮熟,对治疗糖尿病很有用。本研究通过植物化学筛选确定了天堂木次生代谢物的含量。植物化学筛选结果表明,天堂木次生代谢物中含有黄酮类、萜类、酚类和皂苷,不含生物碱和类固醇。
{"title":"Identifikasi Senyawa Metabolit Sekunder Pada Jantung Pisang Kapas (Musa x paradisiaca L.)","authors":"Yogi Fernanda Saputra, S. Etika, Melindra Mulia","doi":"10.24036/p.v11i3.114981","DOIUrl":"https://doi.org/10.24036/p.v11i3.114981","url":null,"abstract":"— Musa x paradisiaca L. or cotton banana is a plant that belongs to the Musaceae family. Almost all parts of this plant can be consumed, one of which is the banana blossom. Banana blossom can be cooked as a vegetable and is useful in treating diabetes. In this study, phytochemical screening was carried out to determine secondary metabolites contained in Musa x paradisiaca L. The results of phytochemical screening showed that Musa x paradisiaca L. contained secondary metabolites of flavonoids, terpenoids, phenolics and saponins, but did not contain alkaloids and steroids.","PeriodicalId":213875,"journal":{"name":"Jurnal Periodic Jurusan Kimia UNP","volume":"25 6","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"120856928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ekstraksi Alumina (Al2O3) dari Mineral Tanah Napa Pesisir Selatan 从南海岸纳帕土壤矿物中提取铝(Al2O3)
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.115955
Arinda Frissherly, M. Mawardi
— Alumina has a wide range of industrial and technical applications and can be extracted from different locations, materials and methods. Napa soil from the Pesisir Selatan has been used as a raw material for alumina production. This alumina extraction process is the result of modifications to several methods including alkali fusion and hydrothermal methods. Napa soil is calcined at 750 0 C for 4 hours and washed with hydrochloric acid 1,5 M; 2 M; 2.5 M at 95 0 C, followed by alkali fusion by NaOH 10 M so that it is obtained Al(OH) 3 and converted to Al 2 O 3 with the calcination of 1100 0 C. The extraction results are characterized by XRF technology to understand the content of the analyzed sample. The extraction mass of alumina with different concentrations of HCl 1 M; 1,5 M; 2 M; 2.5 M is continuous 14,171 g; 41,127 g; 31,711 g; and 0 g. The result of XRF analysis of alumina extraction showed that the Al 2 O 3 content increased by 68.42%.
-氧化铝具有广泛的工业和技术应用,可以从不同的地点、材料和方法中提取。来自塞拉坦的纳帕土壤已被用作氧化铝生产的原料。这种氧化铝提取工艺是对碱熔合法和水热法等几种方法进行改进的结果。纳帕土在750℃下煅烧4小时,用1.5 M盐酸洗涤;2米;在95℃下提取2.5 M,再用10 M NaOH进行碱熔得到Al(OH) 3, 1100℃煅烧转化为Al 2o3,提取结果用XRF技术进行表征,了解分析样品的含量。不同浓度HCl 1 M对氧化铝萃取质量的影响;1、5米;2米;2.5 M连续14171 g;41127克;31711克;和0g。氧化铝萃取物的XRF分析结果表明,al2o3含量提高了68.42%。
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引用次数: 1
Adsorpsi Ion Logam Cd2+ dengan Menggunakan Cangkang Telur Ayam Ras Cd2+金属离子广告,使用自生蛋壳
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.116127
Nova Fitriani, Desy Kurniawati
— The industrial development has resulted in more and more liquid waste containing heavy metals. Therefore we need a way to reduce these heavy metals. One way is adsorption using eggshells. The purpose of this study was to determine the optimum conditions for the adsorption of Cd 2+ metal ions on the effect of variations in pH and stirring speed and to determine the adsorption capacity of eggshells for Cd 2+ metal ions. This study used the batch method with variations in pH and stirring speed. The optimum conditions obtained from each variation were at pH 4, and stirring speed at 250 rpm. The adsorption capacity at the variation of pH was 2,3875 mg/g at 42,18% and adsorption capacity at variation in stirring speed was 3,3 mg/g at 24,01%.
工业的发展导致含有重金属的废液越来越多。因此,我们需要一种方法来减少这些重金属。一种方法是用蛋壳吸附。本研究的目的是确定蛋壳吸附cd2 +金属离子的最佳条件对pH和搅拌速度变化的影响,并确定蛋壳对cd2 +金属离子的吸附能力。本研究采用不同pH值和搅拌速度的间歇式方法。从每种变化中得到的最佳条件是pH为4,搅拌速度为250 rpm。在pH为42.18%时,吸附量为2,3875 mg/g;在搅拌速度为24.01%时,吸附量为3,3 mg/g。
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引用次数: 0
Hedonic Test Method for Beef Rendang With Variations in The Addition of Cinnamomum Verum 肉桂添加量变化的牛肉任当愉悦性试验方法
Pub Date : 2022-12-12 DOI: 10.24036/p.v11i3.114883
Sherly Rahmayani, I. Iryani, I. Iswendi, Fitri Amelia
Rendang is one of the typical foods of the Minangkabaunese in West Sumatra. Many people like to consume rendang because rendang has a distinctive taste because in making rendang the type of meat, coconut milk and spices used greatly affect the aroma and taste produced. The purpose of this study was to determine the level of aroma, color, texture, and taste of beef rendang with variations in the addition of Cinnamomum verum. The hedonic test of beef rendang with variations in the addition of C. verum was carried out on 50 panelists. Panelists present 6 samples with 6 different sample numbers. Panelists were asked to rate how much preference there was for the product using a hedonic scale. The hedonic test results showed that the less C. verum added, the better the taste produced. As for the aroma and color, there is no significant difference among these products
仁当是西苏门答腊岛米南卡巴纳人的典型食物之一。许多人喜欢吃人当,因为人当有一种独特的味道,因为在制作人当时,肉的种类,椰奶和香料的使用极大地影响了香气和味道。本研究的目的是确定牛肉当的香气、颜色、质地和味道随肉桂添加量的变化而变化。以50名小组成员为研究对象,对不同添加量的牛肉串进行了享乐性试验。小组成员用6个不同的样本数呈现6个样本。小组成员被要求使用享乐量表对产品的偏好程度进行评分。享乐性测试结果表明,添加越少的verum,产生的味道越好。在香气和颜色方面,这些产品之间没有显著差异
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引用次数: 0
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Jurnal Periodic Jurusan Kimia UNP
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