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Synthesis and Characterization of Novel Water-Soluble Tetra-Substituted Zn(II) Phthalocyanine Containing Triazole and Galactose Moieties 新型水溶性含三唑半乳糖四取代酞菁锌的合成与表征
Pub Date : 2023-08-25 DOI: 10.16984/saufenbilder.1266799
Yasemin BAYĞU
In this study, new water-soluble non-peripheral tetra-substituted zinc complex of phthalocyanine which is contain galactose moieties was synthesized. ZnPc-I was prepared from the galactose substituted dicyano compound by the cyclotetramerization reaction. This dicyano compound was synthesized by Click reaction between 3-(pent-4-yn-1-yloxy)phthalonitrile and 6-azido-6-deoxy1,2:3,4-di-O-isopropylidene-α-D-galactopyranose. ZnPc-II was obtained by hydrolysis of the protected isopropylidene groups in ZnPc-I in TFA and water mixture. The galactose linked Zn(II) phthalocyanine was achieved to dissolve in common polar solvents and water. All of the new compounds were characterized by elemental analysis, 1H NMR, 13C NMR, IR, UV–vis and MS spectral data.
本文合成了一种新的含半乳糖部分的酞菁非外周四取代锌水溶性配合物。以半乳糖取代双氰基化合物为原料,采用环四聚反应制备了锌氯化锌。以3-(戊-4-炔-1-氧基)邻苯二腈和6-叠氮-6-脱氧1,2:3,4-二- o-异丙基-α- d -半乳糖为原料,通过Click反应合成了该双氰化合物。ZnPc-II是由ZnPc-I中的保护异丙基在TFA和水混合物中水解得到的。实现了半乳糖连接锌(II)酞菁在一般极性溶剂和水中的溶解。所有新化合物都通过元素分析、1H NMR、13C NMR、IR、UV-vis和MS数据进行了表征。
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引用次数: 0
Transforming Sketches into Realistic Images: Leveraging Machine Learning and Image Processing for Enhanced Architectural Visualization 将草图转换为逼真的图像:利用机器学习和图像处理增强建筑可视化
Pub Date : 2023-08-07 DOI: 10.16984/saufenbilder.1319166
I. Karadag
This article presents a novel approach for transforming architectural sketches into realistic images through the utilization of machine learning and image processing techniques. The proposed method leverages the Stable Diffusion model, a deep learning framework specifically designed for text-to-image generation. By integrating image processing algorithms into the workflow, the model gains a better understanding of the input sketches, resulting in visually coherent and meaningful output images. The study explores the application of the Stable Diffusion model in the context of architectural design, showcasing its potential to enhance the visualization process and support designers in generating accurate and compelling representations. The efficacy of the method is evaluated through qualitative and quantitative assessments, demonstrating its effectiveness in bridging the gap between initial sketches and photorealistic renderings. This research contributes to the growing body of knowledge on the integration of machine learning and image processing in architecture, providing insights and practical implications for design professionals and researchers in the field.
本文提出了一种利用机器学习和图像处理技术将建筑草图转换为逼真图像的新方法。该方法利用了稳定扩散模型,这是一种专门为文本到图像生成而设计的深度学习框架。通过将图像处理算法集成到工作流中,该模型可以更好地理解输入的草图,从而产生视觉上连贯且有意义的输出图像。该研究探讨了稳定扩散模型在建筑设计中的应用,展示了它在增强可视化过程和支持设计师生成准确和引人注目的表现方面的潜力。该方法的有效性通过定性和定量评估来评估,证明其在弥合初始草图和逼真渲染之间的差距方面的有效性。这项研究有助于在建筑中集成机器学习和图像处理的知识体系的发展,为该领域的设计专业人员和研究人员提供见解和实际意义。
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引用次数: 0
Short-Term Electrical Load Forecasting in Power Systems Using Deep Learning Techniques 基于深度学习技术的电力系统短期负荷预测
Pub Date : 2023-08-03 DOI: 10.16984/saufenbilder.1256743
Nihat PAMUK
The use of big data in deep neural networks has recently surpassed traditional machine learning techniques in many application areas. The main reasons for the use of deep neural networks are the increase in computational power made possible by graphics processing units and tensor processing units, and the new algorithms created by recurrent neural networks and CNNs. In addition to traditional machine learning methods, deep neural networks have applications in anticipating electricity load. Using a real dataset for one-step forecasting, this article compares three deep learning algorithms for short-term power load forecasting: LSTM, GRUs, and CNN. The statistics come from the Turkish city of Zonguldak and include hourly electricity usage loads and temperatures over a period of three years, commencing in 2019 and ending in 2021. The mean absolute percentage error is used to compare the performances of the techniques. Forecasts are made for twelve representative months from each season. The main reason for the significant deviations in the forecasts for January, May, September, and December is the presence of religious and national holidays in these months. This was solved by adding the information obtained from religious and national holidays to the modeling. This is not to say that CNNs are not good at capturing long-term dependencies and modeling sequential data. In all experiments, LSTM, GRUs and encoder-decoder LSTM outperformed simple CNN designs. In the future, these new architectural methods can be applied to long- or short-term electric charge predictions and their results can be compared to LSTM, GRUs and their variations.
最近,深度神经网络中大数据的使用在许多应用领域超过了传统的机器学习技术。使用深度神经网络的主要原因是图形处理单元和张量处理单元带来的计算能力的提高,以及由循环神经网络和cnn创建的新算法。除了传统的机器学习方法外,深度神经网络在预测电力负荷方面也有应用。本文使用真实数据集进行一步预测,比较了三种用于短期电力负荷预测的深度学习算法:LSTM、GRUs和CNN。这些统计数据来自土耳其的宗古尔达克市,包括从2019年开始到2021年结束的三年内每小时的用电负荷和温度。使用平均绝对百分比误差来比较这些技术的性能。从每个季节开始的12个有代表性的月份进行预测。1月、5月、9月和12月的预测出现显著偏差的主要原因是这些月份存在宗教和法定假日。这是通过将从宗教和国家节日获得的信息添加到建模中来解决的。这并不是说cnn不擅长捕获长期依赖关系和对顺序数据建模。在所有实验中,LSTM、gru和编码器-解码器LSTM都优于简单的CNN设计。在未来,这些新的体系结构方法可以应用于长期或短期电荷预测,其结果可以与LSTM, gru及其变化进行比较。
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引用次数: 0
Sturm-Liouville Problems with Polynomially Eigenparameter Dependent Boundary Conditions 具有多项式特征参数相关边界条件的 Sturm-Liouville 问题
Pub Date : 2023-07-31 DOI: 10.16984/saufenbilder.1304365
A. Kabataş
Eigenfunctions for Sturm-Liouville problems associated with polynomially eigenparameter dependent boundary conditions are obtained. The Weyl m-functions of the related problems are investigated.
获得了与多项式特征参数相关边界条件有关的 Sturm-Liouville 问题的特征函数。研究了相关问题的 Weyl m 函数。
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引用次数: 0
One-step and Cost-effective Conversion of Polyimide to Graphene by Utilizing a Desktop Laser 利用台式激光器一步高效地将聚酰亚胺转化为石墨烯
Pub Date : 2023-07-30 DOI: 10.16984/saufenbilder.1201851
Nihan AYDEMİR
Herein a one-step, cost-effective, chemical-free, and versatile graphene fabrication by employing a CO2 laser is presented. A cost-effective desktop laser, compared to expensive and bulky lasers reported in the literature, is utilized for the conversion of polyimide films to graphene. Optimization of the fabrication is enabled by the examination of laser parameters such as laser power and scanning speed. Also, various 2D pattern drawings and in-situ fabrication were realized by the Laser Draw software. Furthermore, characterization experiments such as Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD), Raman Spectroscopy, and X-Ray Photon Spectroscopy (XPS) were performed to prove the successive graphene fabrication.
本文提出了一种采用CO2激光一步、低成本、无化学物质、通用的石墨烯制造方法。与文献中报道的昂贵且笨重的激光器相比,一种具有成本效益的台式激光器用于将聚酰亚胺薄膜转化为石墨烯。通过检查激光功率和扫描速度等激光参数,实现了制造的优化。利用激光绘制软件实现了各种二维图形的绘制和现场制作。此外,通过扫描电子显微镜(SEM)、x射线衍射(XRD)、拉曼光谱(Raman Spectroscopy)和x射线光子光谱(XPS)等表征实验证明了石墨烯的连续制备。
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引用次数: 0
An endemic vascular plant species for Turkey, Ferulago humilis Boiss., and its potential distribution areas 土耳其特有维管束植物物种 Ferulago humilis Boiss 及其潜在分布区
Pub Date : 2023-07-30 DOI: 10.16984/saufenbilder.1302376
Ece Gökçe ÇAKIR-DİNDAR, Behlül Güler
Turkey is expected to be affected considerably in future adverse climatic conditions. Plant species are one of the most vulnerable to these climatic changes. In this study, we aimed to investigate current and future potential distribution areas of Ferulago humilis Boiss., which is an endemic vascular plant species for Turkey, using CMIP5 projected to year 2070. For this purpose, we obtained occurence data (presence-only) from Global Biodiversity Information Facility (GBIF). Regarding bioclimatic data we used WorldClim dataset with 10 km2 resolution. Using both plant occurrence and bioclimatic data, we performed species distribution modelling analysis. We used two methods namely Boosted Regression Trees (BRT) and Random Forest (RF). Additionally, we used bootstrapping method as partitioning resampling for all analysis. Our analysis has showed that potential distribution areas of the species has slightly changed for the future projection. The species movement is towards slightly upwards as higher latitudes. We believe that our study shows the importance and relevance of the endemic species in the scope of species distribution models for plant conservation topics.
在未来不利的气候条件下,土耳其预计将受到相当大的影响。植物物种是最容易受到气候变化影响的物种之一。在本研究中,我们旨在利用 CMIP5 预测到 2070 年的数据,调查土耳其特有维管束植物 Ferulago humilis Boiss.目前和未来的潜在分布区域。为此,我们从全球生物多样性信息基金(GBIF)获得了出现数据(仅存在)。在生物气候数据方面,我们使用了分辨率为 10 平方公里的 WorldClim 数据集。利用植物出现数据和生物气候数据,我们进行了物种分布建模分析。我们使用了两种方法,即提升回归树(BRT)和随机森林(RF)。此外,我们还在所有分析中使用了引导法作为分区重采样。我们的分析表明,物种的潜在分布区域在未来预测中略有变化。随着纬度的升高,物种的移动方向略微向上。我们相信,我们的研究表明了特有物种在植物保护主题的物种分布模型中的重要性和相关性。
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引用次数: 0
Analysis and Control of Chaos in Permanent Magnet Synchronous Motor 永磁同步电机中的混沌分析与控制
Pub Date : 2023-07-27 DOI: 10.16984/saufenbilder.1286774
Abdallah MOUSSA YAYA, Y. Uyaroğlu
In this paper, the chaotic behavior of permanent magnet synchronous motor is investigated by analyzing Lyapunov exponents and equilibrium points. Then, the control of the permanent magnet synchronous motor, which presents a chaotic behavior under certain parameters, was studied using a simple controller. The resolution method adopted is that of the single-state feedback controller. The resulting control law makes it possible to stabilize the state of the system around a reference state in the presence of uncertainties on the parameters and without the system exhibiting chaotic behavior. Numerical simulations were made in MATLAB to demonstrate the application of the proposed method.
本文通过分析 Lyapunov 指数和平衡点,研究了永磁同步电机的混沌行为。然后,使用一个简单的控制器研究了永磁同步电机在某些参数下呈现混沌行为的控制问题。采用的解析方法是单态反馈控制器。由此产生的控制法则可以在参数存在不确定性的情况下,使系统状态稳定在参考状态附近,而不会出现混乱行为。我们在 MATLAB 中进行了数值模拟,以演示所提方法的应用。
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引用次数: 0
Common Solutions to Stein Inequalities 斯坦因不等式的常见解法
Pub Date : 2023-07-25 DOI: 10.16984/saufenbilder.1260438
Şerife Yilmaz, Birgül Aksoy
In this paper for linear discrete time switched systems, the problem of existence of a common solution to Stein inequalities is considered. A sufficient condition for robust Schur stability of a matrix polyope by using Schur complement lemma and a necessary and sufficient condition for the existence of a common solution of Stein equation are given. As in the case of continuous time systems, the problem of existence of a common solution is reduced to a convex optimization one. An efficient solution algorithm which requires solving a linear minimax problem at each step is suggested. The algorithm is supported with a number of examples from the literature and observed that the method desired results fastly.
本文针对线性离散时间开关系统,考虑了 Stein 不等式共解的存在性问题。本文给出了利用舒尔补足定理实现矩阵多面体稳健舒尔稳定性的充分条件,以及斯坦因方程公共解存在的必要条件和充分条件。与连续时间系统的情况一样,共同解的存在问题被简化为凸优化问题。提出了一种高效的求解算法,该算法每一步都需要求解一个线性最小问题。该算法得到了大量文献实例的支持,并观察到该方法能快速得到所需的结果。
{"title":"Common Solutions to Stein Inequalities","authors":"Şerife Yilmaz, Birgül Aksoy","doi":"10.16984/saufenbilder.1260438","DOIUrl":"https://doi.org/10.16984/saufenbilder.1260438","url":null,"abstract":"In this paper for linear discrete time switched systems, the problem of existence of a common solution to Stein inequalities is considered. A sufficient condition for robust Schur stability of a matrix polyope by using Schur complement lemma and a necessary and sufficient condition for the existence of a common solution of Stein equation are given. As in the case of continuous time systems, the problem of existence of a common solution is reduced to a convex optimization one. An efficient solution algorithm which requires solving a linear minimax problem at each step is suggested. The algorithm is supported with a number of examples from the literature and observed that the method desired results fastly.","PeriodicalId":21468,"journal":{"name":"Sakarya University Journal of Science","volume":"27 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139355455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the Usage Properties of Steel Slag as Pigment in Low-Temperature Glaze 钢渣作为颜料在低温釉中的使用性能研究
Pub Date : 2023-07-22 DOI: 10.16984/saufenbilder.1264392
Muhterem Koç, E. Taşçi
The evaluation of industrial wastes in the ceramics industry has been the subject of research studies in recent years. This study investigated the use of steel slag as a colouring pigment in ceramic glazes. The colour effects of 45 compositions created with a triple-phase diagram with steel slag, CoO, and Cr2O3 on low-temperature glaze composition were determined. The microstructural evaluation of the selected colours by SEM and EDX analysis were carried out.The prepared glaze compositions were applied by pouring on the high silica ceramic body. Glazed tiles were sintered in a muffle furnace at 950 ℃ and then L*a*b colour and gloss brightness values were measured. By using steel slags instead of Fe2O3, black glazes were obtained in the triple diagram.
近年来,对陶瓷工业中的工业废料进行评估一直是研究的主题。本研究调查了钢渣作为着色颜料在陶瓷釉料中的应用。研究确定了 45 种由钢渣、CoO 和 Cr2O3 三相图组成的成分对低温釉成分的着色效果。通过 SEM 和 EDX 分析对所选颜色进行了微观结构评估。釉面砖在马弗炉中于 950 ℃ 下烧结,然后测量 L*a*b 颜色和光泽亮度值。通过使用钢渣代替 Fe2O3,在三重图中得到了黑色釉。
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引用次数: 0
Estimating Human Poses Using Deep Learning Models 使用深度学习模型估计人体姿势
Pub Date : 2023-07-17 DOI: 10.16984/saufenbilder.1311198
Fırgat Muradli, Serap Cakar, Feyza Cerezci, Guluzar Cit
Over the past decade, extensive research has focused on the extraction of 3D human poses from images. The existing datasets must effectively address common challenges related to pose estimation. These datasets serve as valuable resources for evaluating, informing, and comparing different models. Deep learning models have gained widespread adoption and have demonstrated impressive performance across various domains of research and engineering. In this study, we employ these models, leveraging the open-source libraries OpenCV and Keras. To enhance the diversity and complexity of the training and testing process, we utilize the MPII Human Pose dataset. Specifically, we train and test the ResNet50 and VGG16 models using this dataset, resulting in significant improvements. The model's performance is evaluated based on the validation rate of the dataset and the accuracy of our model was 88.8 percent for VGG16 and 67 percent for ResNet50.
在过去的十年里,大量的研究集中在从图像中提取3D人体姿势上。现有的数据集必须有效地解决与姿态估计相关的共同挑战。这些数据集是评估、告知和比较不同模型的宝贵资源。深度学习模型已经被广泛采用,并在各个研究和工程领域展示了令人印象深刻的性能。在本研究中,我们利用这些模型,利用开源库OpenCV和Keras。为了增强训练和测试过程的多样性和复杂性,我们使用了MPII人体姿态数据集。具体来说,我们使用该数据集训练和测试了ResNet50和VGG16模型,得到了显著的改进。模型的性能是基于数据集的验证率来评估的,我们的模型在VGG16上的准确率为88.8%,在ResNet50上的准确率为67%。
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引用次数: 0
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Sakarya University Journal of Science
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