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Facile approach for novel TFC-NF membranes preparation using water soluble poly(vinyl alcohol-co-styrenesulfonic acid) and their characterizations 水溶性聚乙烯醇-co-苯乙烯磺酸制备新型TFC-NF膜的简易方法及其表征
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-25 DOI: 10.1080/01496395.2023.2240500
Rikarani R Choudhury, J. Gohil, H. Raval
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引用次数: 0
Separation of fluoride in the presence of large amounts of organic acids by ion chromatography 离子色谱法在存在大量有机酸的情况下分离氟化物
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-25 DOI: 10.1080/01496395.2023.2240494
C. Arul Suganthi, V. Raut, N. K. Bharti, U. K. Thakur, P. Sri Renganathan, S. Jeyakumar, M. K. Saxena
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引用次数: 0
Acid gas preparation for enhanced oil recovery: techno-economic analysis of different dehydration processes 提高采收率的酸气制备:不同脱水工艺的技术经济分析
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-24 DOI: 10.1080/01496395.2023.2219379
H. Nikkhah, A. Nikkhah, Y. Ghalavand
ABSTRACT The natural gas treatment plant is one source of CO2 emissions into the atmosphere. To tackle this issue, it is probable to inject CO2 into the wells and it can be used for enhanced oil recovery (EOR) application. However, the main setback is the high content of water in acid gas that could be converted to hydrate at high pressure in the pipelines. In this article, two different processes (solvent extraction, stripping gas) with two different solvents mono ethylene glycol (MEG), Tri ethylene glycol (TEG), are simulated in Aspen HYSYS. The stripping gas method is more efficient in terms of energy consumption, consuming 31.8% and 56.8% less energy than solvent extraction method for MEG and TEG solvents, respectively. Hydrate formation analyses showed that applying MEG as a solvent in the stripping gas method leads to a safer operation region. Economic evaluation depicts that the stripping gas method saves the total annual cost by 22.2% compared to solvent extraction. GRAPHICAL ABSTRACT
天然气处理厂是向大气中排放二氧化碳的一个来源。为了解决这个问题,可能会向井中注入二氧化碳,并将其用于提高石油采收率(EOR)。然而,主要的问题是酸性气体中的水含量高,在管道中的高压下可以转化为水合物。本文在Aspen HYSYS中模拟了用两种不同溶剂(单乙二醇(MEG)、三乙二醇(TEG))进行的两种不同工艺(溶剂萃取、汽提)。气提法能耗更高,对于MEG和TEG溶剂,气提法能耗分别比溶剂萃取法低31.8%和56.8%。水合物形成分析表明,在汽提气法中采用MEG作为溶剂可使作业区域更加安全。经济评价表明,气提法与溶剂萃取法相比,年总成本节约22.2%。图形抽象
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引用次数: 3
The improvement in whiteness index of calcite tailings using attrition-scrubbing process 磨洗法提高方解石尾矿白度指标
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-24 DOI: 10.1080/01496395.2023.2219380
Bancha Wongkaewphothong, Chinawich Kertbundit, Palot Srichonphaisan, Pongsiri Julapong, P. Homchuen, O. Juntarasakul, K. Maneeintr, C. Tabelin, A. Numprasanthai, S. Saisinchai, T. Phengsaart
ABSTRACT Calcium carbonate (CaCO3) is an essential mineral critical for various applications in many industries like plastic, rubber, paint, and paper manufacturing. However, salable CaCO3 products need to meet specific requirements. For the paint and paper manufacturing industries, the whiteness index (WI) of CaCO3 is an important property because it strongly influences the final color of paper and paint products. In this study, the effects of retention time and pulp density on the WI after attrition-scrubbing of calcite tailings were investigated. To increase the whiteness index, an attrition scrubber was used to remove impurities on the CaCO3 surface with different pulp densities—40, 45, 50, 55, 60, and 70% solids—and retention time—10, 15, 20, and 25 min—as process variables. The results of laboratory-scale experiments found that the attrition-scrubbing process improved the whiteness index of CaCO3 tailings and reduced its iron content. The optimum condition was at the pulp density of 55% solids, which was used in the pilot-scale experiments. The results of the pilot-scale tests were consistent with the laboratory-scale, indicating that the attrition-scrubbing process can be used to improve the quality of CaCO3 tailings.
碳酸钙(CaCO3)是一种重要的矿物,在塑料、橡胶、油漆和造纸等许多行业中都有重要的应用。然而,可销售的CaCO3产品需要满足特定的要求。对于涂料和造纸行业来说,碳酸钙的白度指数(WI)是一项重要的性能,因为它强烈影响纸张和涂料产品的最终颜色。研究了方解石尾矿磨洗后保留时间和矿浆密度对WI的影响。为了提高白度指数,使用摩擦洗涤器去除不同矿浆密度(40、45、50、55、60和70%固相)下CaCO3表面的杂质,并将保留时间(10、15、20和25 min)作为过程变量。室内试验结果表明,磨洗工艺提高了CaCO3尾矿的白度指数,降低了其含铁量。最佳工艺条件为固含量为55%,并进行了中试试验。中试结果与实验室试验结果基本一致,表明磨擦-洗涤工艺可以改善CaCO3尾矿的质量。
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引用次数: 0
Exploring the effect of aeration intensity on a modified PVDF-PEG membrane incorporated with nano-MgO: antifouling and AnT-POME treatment 探讨曝气强度对纳米氧化镁改性PVDF-PEG膜的防污和抗聚甲醛处理的影响
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-16 DOI: 10.1080/01496395.2023.2237181
H. Man, Mohammed Abdulsalam, Fikri Ahmad Abdullahi, Murni Marlina Abd-Karim, Khairul Faezah Yunos, M. Aida Isma
ABSTRACT Aeration effects on membrane filtration of wastewater remain partially explored, as lesser or excessive application often aggravates the fouling. Furthermore, most polymeric membranes are hydrophobic, which facilitates the deposition of foulants and layer formation. There is a need for further investigation on the use of aeration and membrane modifications with a better antifouling property. This study focused on investigating the influence of aeration intensity on the antifouling performance of a modified co-polymerized polyvinylidene-fluoride (PVDF-PEG) fiber using a hydrophilic nano-MgO to treat anaerobically digested palm oil mill effluent (AnT-POME). The aeration intensity was varied to three levels (3,4,5Lmin-1). Both neat and modified membranes obtained their best AnT-POME permeate flux at 4Lmin-1 with a relatively stable value of 28.67 and 89.85 Lm-2 h-1 after 5 h filtration, respectively. The irreversible fouling percentage (IFP) for the neat and modified membrane at 4Lmin-1 aeration intensity, was 66.67% and 12.42%, respectively. This indicates that the neat membrane is more susceptible to fouling. To investigate the changes in the membranes, the fouled membranes were characterized using SEM, FTIR and porosity, then compared with that of the pristine samples. Cake-scaly layers were noticed on the neat membrane. Additionally, both membranes successfully reduced the COD, TDS, TSS, and TN above 60%. GRAPHICAL ABSTRACT
曝气对废水膜过滤的影响尚不完全清楚,因为较少或过多的曝气往往会加重污染。此外,大多数聚合物膜是疏水的,这有利于污染物的沉积和层的形成。有必要进一步研究使用具有较好防污性能的曝气和膜改性。研究了曝气强度对改性聚偏氟乙烯-聚偏氟乙烯(PVDF-PEG)纤维处理棕榈油厂厌氧消化废水(AnT-POME)防污性能的影响。曝气强度分为3、4、5min -1 3个等级。净膜和改性膜在4lm -1时均获得最佳的AnT-POME渗透通量,过滤5 h后相对稳定的值分别为28.67和89.85 Lm-2 h-1。在4min -1曝气强度下,净膜和改性膜的不可逆污染率(IFP)分别为66.67%和12.42%。这说明整洁的膜更容易受到污染。为了研究膜的变化,利用扫描电镜(SEM)、红外光谱(FTIR)和孔隙率对污染膜进行了表征,并与原始样品进行了比较。整齐的膜上可见饼状鳞状层。此外,两种膜都能成功地将COD、TDS、TSS和TN降低60%以上。图形抽象
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引用次数: 0
Highly selective separation of plutonium using a mono-amide-based supported liquid membrane 利用单酰胺基支撑液膜对钚进行高选择性分离
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-16 DOI: 10.1080/01496395.2023.2232536
Sumana Paul, B. G. Vats, Preeti G. Goswami, K. Sasi Bhushan
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引用次数: 0
Simplified solvent extraction process for high-purity Ni/Co mixed solution for lithium–ion batteries 锂离子电池用高纯镍钴混合溶液的简化溶剂萃取工艺
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-16 DOI: 10.1080/01496395.2023.2232094
Gogwon Choe, Y. Lim, Younghyun Kim, Go-Gi Lee, Yong‐Tae Kim
ABSTRACT The demands for Ni-based raw materials increase as Ni–Co–Mn ternary cathode materials become the main axis of the battery industry. Conventional hydrometallurgical process to produce raw materials from Ni ore for battery application is as follows: (i) leaching of metal ions by acid, (ii) solvent extraction process to extract target metals, and (iii) crystallization process to produce final single-metal compound as powder products. The conventional solvent extraction process is a three-circuit process comprising impurity removal, Co extraction, and Ni extraction circuits. Unlike conventional process, in this work, we suggest a simplified two-circuit process to simultaneously extract Ni and Co to produce Ni/Co mixed solution for cathode material precursor production. Accordingly, the efficiency of site utilization can be maximized by reducing the investment cost for the manufacturing process and downsizing mixer-settler facilities. Further, eco-friendly effects such as reducing the consumption of titrants and cutting down the process costs and wastewater discharge can be realized.
随着Ni-Co-Mn三元正极材料成为电池工业的主轴,对镍基原材料的需求不断增加。从镍矿石中生产电池用原料的常规湿法冶金工艺是:(1)用酸浸出金属离子,(2)用溶剂萃取法提取目标金属,(3)用结晶法生产最终的单一金属化合物作为粉末产品。传统的溶剂萃取过程是一个三回路过程,包括杂质去除、Co萃取和Ni萃取回路。与传统工艺不同,本文提出了一种简化的双回路工艺,同时提取Ni和Co,制备Ni/Co混合溶液,用于正极材料前驱体的生产。因此,通过减少制造过程的投资成本和缩小混合-沉淀设施的规模,可以最大限度地提高场地利用效率。此外,还可以实现诸如减少滴定剂消耗、降低工艺成本和废水排放等环保效果。
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引用次数: 0
Selective extraction of molybdenum (VI) with novel ionic liquid from nitric acid solution 新型离子液体从硝酸溶液中选择性萃取钼(VI)
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-11 DOI: 10.1080/01496395.2023.2232099
Sherien Emam, E. M. A. Elgoud, A. Abd-Elhamid, H. Aly
ABSTRACT The novel ionic liquid [Aliq–336]+[HCit]− is produced by the reaction of tricaprylylmethyl ammonium chloride, Aliq–336, and tri-sodium citrate. In this investigation, the extraction of Mo(VI) from the nitric acid solution using ([Aliq-336]+[HCit]−) ionic liquid in toluene as a diluent was studied. The effects of various parameters on the extraction process such as shaking time, nitric acid concentration, ionic liquid concentration, hydrogen ion, nitrate ion, Mo(VI) concentration as well as temperature were evaluated. The loading capacity of the prepared ionic liquid was 0.078 mole of Mo(VI) per mole [Aliq-336]+[HCit]−. On the basis of IR spectra and the slope analysis method, the installation of the expected extracted metal species in the organic phase was found to be . As well, the average conditional extraction constant (KCex) for Mo(VI) extraction was 45.96 ± 3.5. The stripping percent of Mo(VI) reached the maximum value (exceeding 99.0%) with 0.5 mol/L sodium acetate as well as 1.0 mol/L of different mineral acids. Based on the obtained results, the prepared ionic liquid in toluene could be used for the effective extraction of molybdenum (VI) from a synthetic mixture of different metal ions found in fission products.
摘要:新型离子液体[Aliq-336]+[HCit]−由三丙基甲基氯化铵、Aliq-336和柠檬酸三钠反应生成。本文研究了以甲苯为稀释剂,用([Aliq-336]+[HCit]−)离子液体从硝酸溶液中萃取Mo(VI)。考察了振荡时间、硝酸浓度、离子液体浓度、氢离子、硝酸盐离子、Mo(VI)浓度、温度等参数对提取过程的影响。离子液体的负载量为0.078 mol / mol [Aliq-336]+[HCit]−。根据红外光谱和斜率分析方法,发现期望提取的金属在有机相中的安装位置为。Mo(VI)提取的平均条件提取常数(KCex)为45.96±3.5。在0.5 mol/L乙酸钠和1.0 mol/L不同无机酸的条件下,Mo(VI)的溶出率达到最大值(99.0%以上)。根据所得结果,所制备的甲苯离子液体可用于从裂变产物中不同金属离子的合成混合物中有效提取钼(VI)。
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引用次数: 0
Liquid-liquid equilibria of ternary mixtures containing Aniline + Toluene + water at elevated temperatures: measurements and correlation 苯胺+甲苯+水三元混合物在高温下的液-液平衡:测量和相关性
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-09 DOI: 10.1080/01496395.2023.2232104
S. Gaikwad, Abhishek A. Pathak, D. Mote, P. Gogate, Shivani Singh, Bharat Modhera
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引用次数: 0
Improving xanthate flotation of fine pyrite using SPAM and the mechanism SPAM改进黄原药浮选细粒黄铁矿及其机理
IF 2.8 4区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2023-07-09 DOI: 10.1080/01496395.2023.2232942
Yunlou Qian, Dan Zou, Renfan Chen, Xiaolong Huang, Zhen Wang
ABSTRACT This paper focuses on the promotion mechanism of sulfonated polyacrylamide (SPAM) on SBX flotation performance on fine pyrite, and verifies the positive effect for a gold ore with pyrite as the main Au-bearing mineral. Micro flotation showed that fine pyrite (−26 + 15 μm) floated poorly compared with coarser ones (−74 + 38 μm), and this cannot be completely filled through increasing the SBX dosage; however, by adding moderate SPAM into the pulp after SBX the flotation of fine pyrite was obviously improved. The real ore flotation revealed that SPAM decreased total reagent dosage and improvement on the concentrate indexes. SBX/SPAM system enabled faster settlement of fine pyrite compared with only SBX or SPAM system, indicating that larger particle size was obtained through hydrophobic and bridging flocculation. Zeta potential results showed that the pre-adsorbed SBX had little effect on the further adsorption of SPAM. Contact angle measurements suggested that the addition of moderate SPAM (50 μg/L) had almost no effect on pyrite surface hydrophobicity, illustrating that SPAM just bridged different fine particles adsorbed SBX rather that covered them. FTIR results showed that the amount of SPAM participating in bridging action was few.
摘要研究了磺化聚丙烯酰胺(SPAM)对细粒黄铁矿SBX浮选性能的促进机理,并对某以黄铁矿为主含金矿石的SBX浮选效果进行了验证。细粒黄铁矿(−26 + 15 μm)与粗粒黄铁矿(−74 + 38 μm)相比,微细粒黄铁矿(−26 + 15 μm)的浮选效果较差,不能通过增加SBX的掺量来完全充填;在SBX后矿浆中加入适量SPAM,可明显改善细粒黄铁矿的浮选效果。实际浮选结果表明,SPAM降低了药剂总用量,改善了精矿各项指标。与单独的SBX或SPAM体系相比,SBX/SPAM体系对细粒黄铁矿的沉降速度更快,说明通过疏水和桥接絮凝获得了更大的粒径。Zeta电位结果表明,预吸附的SBX对SPAM的进一步吸附影响不大。接触角测量结果表明,适量SPAM (50 μg/L)的加入对黄铁矿表面疏水性几乎没有影响,说明SPAM只是桥接了不同细颗粒对SBX的吸附而不是覆盖。FTIR结果表明,参与桥接作用的SPAM数量很少。
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引用次数: 0
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Separation Science and Technology
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