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Current Perspectives and Future Prospects of Nano-Biotechnology in Wastewater Treatment 纳米生物技术在污水处理中的应用现状与展望
Pub Date : 2019-06-25 DOI: 10.1080/15422119.2019.1630430
J. Sahu, R. Karri, H. Zabed, S. Shams, Xianghui Qi
Industrialization and urbanization are contributing extensively to the production of wastewater, which mostly ends up untreated in water bodies, leading to water pollution. Treatment of wastewater could be a promising approach in mitigating the pollution. Nano-biotechnology (NBT), which is an emerging technology, has excellent potential in wastewater treatment. Nano-materials have the ability to remove pollutants and pathogens by working either as the stand-alone treatment agents or by being incorporated into biological membranes and integrated with the conventional treatment techniques. This review presents an overview of possible applications of NBT in wastewater treatment, highlighting the antimicrobial activities of various nanomaterials, and describing the production of algal membrane-based bioreactor and microbial fuel cells. Significant difficulties in NBT utilization in wastewater treatment are also discussed. Further research directions needed to provide a sustainable method of water purification are proposed.
工业化和城市化在很大程度上促成了废水的产生,这些废水大多未经处理就进入水体,导致水污染。废水处理是一种很有前途的减轻污染的方法。纳米生物技术是一门新兴的技术,在污水处理中具有良好的潜力。纳米材料具有去除污染物和病原体的能力,可以作为单独的处理剂,也可以结合到生物膜中并与传统的处理技术相结合。本文综述了NBT在废水处理中的可能应用,重点介绍了各种纳米材料的抗菌活性,并描述了藻类膜生物反应器和微生物燃料电池的生产。讨论了NBT在废水处理中应用的主要困难。提出了可持续水净化方法需要进一步研究的方向。
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引用次数: 46
Application of Si-Based Solvents to the Purification of Metallurgical Grade-Silicon 硅基溶剂在冶金级硅提纯中的应用
Pub Date : 2019-06-05 DOI: 10.1080/15422119.2019.1623253
Ya-qiong Li, Lifeng Zhang
Applying Si-based alloy solvents to Si purification is considered an emerging technology for the production of solar-grade Si (SOG-Si). This study reviews the principle of solvent refining. Alloy systems such as Si–Al, Si–Sn, and Si–Fe are reviewed along with the Si separation method. The effects of solvent refining processing parameters, such as the solvent metal, cooling rate, heating method, and processing time, on boron and phosphorus segregation behaviors and Si purification efficiency are discussed. Experimental and theoretical investigations have shown that removal efficiencies greater than 90% can be achieved for B and P from metallurgical-grade Si using a Si–Al alloy. Meanwhile, separation methods, namely, flotation, filtration, acid leaching, and directional solidification, are used to separate the refined Si from the alloy. Finally, a method for the potential industrial production of SOG-Si is proposed.
应用硅基合金溶剂来提纯硅被认为是生产太阳级硅(SOG-Si)的新兴技术。本文综述了溶剂精炼的原理。综述了Si - al、Si - sn和Si - fe等合金体系以及Si分离方法。讨论了溶剂金属、冷却速率、加热方式和处理时间等溶剂精炼工艺参数对硼磷偏析行为和硅净化效率的影响。实验和理论研究表明,使用硅铝合金对金属级硅中B和P的去除率大于90%。同时,采用浮选、过滤、酸浸、定向凝固等分离方法将精硅从合金中分离出来。最后,提出了SOG-Si工业化生产的可行方法。
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引用次数: 16
On the Performance of Free Radicals Combined Electrocoagulation Treatment Processes 自由基联合电凝处理工艺的性能研究
Pub Date : 2019-04-03 DOI: 10.1080/15422119.2018.1459700
Z. Al-Qodah, M. Al-Shannag
The electrocoagulation (EC) combined treatment processes have shown promising performances in which the removal of pollutants from industrial wastewater was greatly enhanced. The integration of a free radical producing step with EC has been considered as one of these new combinations that show synergy and improvements in the overall cleaning process performance. This review is devoted to discuss and analyze references on free radicals-assisted EC processes. Different combinations of free radical mechanisms were cited in the literature during the last two decades. They included ozone, advanced oxidation and ultrasound energy-assisted EC. It was noted that most of those studies were lab-scale processes that used synthetic wastewaters rather than real wastewaters. In addition the performances of those combined processes were improved compared to the EC process alone. This review considers the main parameters of free radical EC processes such as mechanisms, kinetic models, scale-up and cost estimation. Many concluding remarks were stated to give insights for possible future investigations. It seems from the results that the ozone-assisted EC is the most efficient combination since its removal efficiency is high in most applications. On the other hand, the combination of ultrasonic energy with EC was reported to reduce electrode passivation.
电絮凝(EC)联合处理工艺对工业废水中污染物的去除率有较好的提高。自由基产生步骤与EC的整合被认为是这些新组合之一,显示出协同作用和改善整体清洁过程性能。本文对自由基辅助EC过程的相关文献进行了综述和分析。在过去的二十年中,文献中引用了不同的自由基机制组合。它们包括臭氧、高级氧化和超声能量辅助EC。有人指出,这些研究大多是实验室规模的过程,使用的是合成废水,而不是真正的废水。此外,与单独的EC工艺相比,这些组合工艺的性能得到了改善。本文综述了自由基EC过程的主要参数,包括机理、动力学模型、放大和成本估算。许多结论性发言为今后可能的调查提供了见解。结果表明,臭氧辅助EC在大多数应用中具有较高的去除效率,是最有效的组合。另一方面,超声波能与EC相结合可减少电极钝化。
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引用次数: 38
Processes developed for the separation of europium (Eu) from various resources 开发了从各种资源中分离铕的工艺
Pub Date : 2019-04-03 DOI: 10.1080/15422119.2018.1454959
A. Kumari, M. Jha, D. Pathak, S. Chakravarty, Jae-chun Lee
Europium (Eu), one of the most significant rare earth (RE) elements, has wide applications as functional material in phosphor production, majorly used in fluorescent lamps, computer monitors, televisions etc. Eu is one of the three divalent lanthanides (along with Yb and Sm) having a reduction potential higher than −2 V. This possibility of Eu reduction is attributed to a relatively stable half-filled 4f7 electronic configuration, thus providing a high stabilization energy and selective recovery. But the Eu recuperation from natural minerals is either accompanied with other REs or Eu is recovered as a group of light REs. Selective recovery of Eu has sparked the progress for its reutilization through recycling of secondary resources. The perspectives of reclaiming Eu as a value added product from various sources using different pyro-hydro or hybrid techniques are discussed. The systematic research and salient findings on methods, viz., reduction, leaching, solvent extraction, as well as combined methods scaled-up to commercial scale to recover Eu, are also reported with recommendations. Thus, this comparative as well as summarized review hopes to help researchers to develop feasible processes for Eu recovery.
铕(Eu)是最重要的稀土元素之一,作为功能材料在荧光粉生产中有着广泛的应用,主要用于荧光灯、电脑显示器、电视机等。Eu是三种二价镧系元素之一(另外两种是Yb和Sm),还原电位高于- 2v。这种Eu还原的可能性归因于相对稳定的半填充4f7电子结构,从而提供了高稳定能量和选择性恢复。但从天然矿物中回收Eu或与其他REs一起回收,或作为一组轻REs回收。Eu的选择性回收引发了其通过二次资源循环利用的进展。讨论了利用不同的热-氢或混合技术从各种来源回收Eu作为增值产品的前景。报告了还原法、浸出法、溶剂萃取法以及扩大到商业规模的综合回收方法的系统研究和突出发现,并提出了建议。因此,这一比较和总结综述希望能帮助研究人员制定可行的欧盟回收流程。
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引用次数: 10
Recent trends in replacement of disperser solvent in dispersive liquid-liquid microextraction methods 分散液-液微萃取法中分散溶剂替代的研究进展
Pub Date : 2019-04-03 DOI: 10.1080/15422119.2018.1460851
H. Sereshti, Parisa Khorram, N. Nouri
Since its innovation in 2006, the dispersive liquid-liquid microextraction (DLLME) method has attracted the attention of analytical chemists in the field of sample preparation. This method has been successfully applied to determine trace amounts of pollutants in various matrices, but the restriction in the choice of suitable disperser and extraction solvents, and high disperser solvent consumption leading to decreased partition coefficients of the analytes between aqueous phase and extractant are its problems. To solve these drawbacks and develop environmentally friendly techniques, various alternatives for the conventional DLLME have been presented. The current review will begin with an introduction to the sample preparation, implementation of DLLME, and its advantages. Then, we focus on its drawbacks, which result mainly from the use of disperser solvent. Afterward, some of the most interesting approaches that have been employed and published until now are reviewed. Finally, an outlook on the future of these techniques will be given.
分散液液微萃取(DLLME)方法自2006年创新以来,引起了样品制备领域分析化学家的关注。该方法已成功地应用于各种基质中痕量污染物的测定,但存在分散剂和萃取溶剂选择的限制,以及分散溶剂用量大导致分析物在水相和萃取剂之间分配系数降低的问题。为了解决这些缺点和开发环保技术,人们提出了各种替代传统DLLME的方法。本综述将首先介绍DLLME的样品制备、实施及其优点。然后,我们重点讨论了它的缺点,主要是由于使用分散剂溶剂。然后,对迄今为止已经采用和发表的一些最有趣的方法进行了回顾。最后,对这些技术的发展前景进行了展望。
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引用次数: 52
Removal of Radionuclides from Fukushima Daiichi Waste Effluents 从福岛第一核电站废水中去除放射性核素
Pub Date : 2019-01-10 DOI: 10.1080/15422119.2018.1549567
J. Lehto, R. Koivula, H. Leinonen, E. Tusa, R. Harjula
This paper describes the processes used at the Fukushima Daiichi plant, Japan, to purify the waste effluents generated in the cooling of damaged reactors. These include primary cesium removal with the Kurion zeolite system and the SARRY system utilizing silicotitanate to remove radiocesium from water recirculated to reactors for cooling. Another process is the ALPS system to purify the retentates of the reverse osmosis plant to further purify the water from radionuclides after primary cesium separation. In ALPS, a major role is played by the transition metal hexacyanoferrate product CsTreat and sodium titanate SrTreat in the removal of radiocesium and radiostrontium, respectively. The performance of these four exchangers (zeolite, silicotitanate, hexacyanoferrate, and sodium titanate) is critically analyzed with respect to processing capacities and the decontamination factors obtained in the processes. Furthermore, general information on preparation, structure and ion exchange of these ion-exchanger categories is given with additional information on their use in nuclear waste effluent treatment processes. Finally, the importance of selectivity and associated factors are discussed.
本文描述了日本福岛第一核电站用于净化受损反应堆冷却过程中产生的废水的过程。其中包括使用Kurion沸石系统去除一次铯,以及使用硅钛酸盐去除反应堆冷却水中的放射性铯的SARRY系统。另一个过程是ALPS系统,用于净化反渗透装置的滞留物,以进一步净化一次铯分离后的水中的放射性核素。在ALPS中,过渡金属六氰高铁酸盐产物CsTreat和钛酸钠SrTreat分别在放射性铯和放射性锶的去除中起主要作用。这四种交换剂(沸石、硅钛酸盐、六氰高铁酸盐和钛酸钠)的性能在处理能力和过程中获得的去污因素方面进行了严格的分析。此外,还提供了关于这类离子交换剂的制备、结构和离子交换的一般资料,以及关于它们在核废料废水处理过程中的使用的补充资料。最后,讨论了选择性和相关因素的重要性。
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引用次数: 68
Recent Developments and Applications of Three-Phase Partitioning for the Recovery of Proteins 蛋白质回收三相分划的最新进展及应用
Pub Date : 2019-01-02 DOI: 10.1080/15422119.2018.1427596
K. Chew, T. Ling, P. Show
Three-phase partitioning (TPP) is rapidly developing as a novel bioseparation technique for the separation and purification of biomolecules. TPP has been applied in a wide range of applications including enzyme stability and enhancement of its catalytic activity. The partitioning into three phases is mainly dependent on the concentration of alcohol and salt used. TPP provides high enzyme recovery and can be utilized along with external techniques such as ultrasound, microwave assisted, microaffinity ligand-facilitated and also ionic-liquid based. This technique has attracted interest in the large scale recovery of proteins from crude feedstocks or fermentation broths. In this review, the basic principles, refolding of proteins using TPP, key design variables of TPP, types of TPP, applications of TPP in food industry as well as the challenge of TPP were analyzed. The work presented in this review will be beneficial for further researches in TPP or related separation techniques.
三相分离技术作为一种分离纯化生物分子的新型生物分离技术正在迅速发展。TPP在酶稳定性和增强催化活性等方面有着广泛的应用。划分为三个阶段主要取决于所用酒精和盐的浓度。TPP具有较高的酶回收率,可与超声、微波辅助、微亲和配体促进和离子液体等外部技术一起使用。该技术引起了人们对从粗原料或发酵液中大规模回收蛋白质的兴趣。本文就TPP的基本原理、TPP的蛋白质重折叠、TPP的关键设计变量、TPP的类型、TPP在食品工业中的应用以及TPP面临的挑战进行了分析。本文所做的工作将有助于进一步研究跨膜分离或相关分离技术。
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引用次数: 49
Nanoporous Materials as H2S Adsorbents for Biogas Purification: a Review 纳米多孔材料在沼气净化中作为H2S吸附剂的研究进展
Pub Date : 2019-01-02 DOI: 10.1080/15422119.2018.1476978
A. Peluso, N. Gargiulo, P. Aprea, F. Pepe, D. Caputo
Biogas is one of the most promising renewable sources of energy. However, it is also a gas mixture containing acidic gases, such as H2S, useless for energetic purposes, environmentally harmful and damaging for energy conversion devices. This review focuses on nanoporous materials as adsorbents of H2S for biogas purification processes. Cation-exchanged zeolites and impregnated activated carbons have been thoroughly studied since many years for this application, providing good results, in particular for what concerns activated carbons, despite having a limited regenerability. Amino-functionalized ordered mesoporous silicas produced very interesting results, both in terms of adsorption performances and regeneration capacity, but they are largely untested in large-scale “real-life” applications, and deserve further investigations, in particular for H2S and CO2 discrimination. On the contrary, despite reporting very good results, there are only few papers dealing with H2S adsorption on nanoporous metal organic frameworks.
沼气是最有前途的可再生能源之一。然而,它也是一种气体混合物,含有酸性气体,如H2S,对能源用途无用,对环境有害,对能量转换装置有害。本文综述了纳米多孔材料在沼气净化过程中作为H2S吸附剂的研究进展。多年来,人们对阳离子交换沸石和浸渍活性炭在这方面的应用进行了深入的研究,提供了良好的结果,特别是活性炭,尽管其可再生性有限。氨基功能化有序介孔二氧化硅在吸附性能和再生能力方面都产生了非常有趣的结果,但它们在很大程度上没有在大规模的“现实生活”应用中进行测试,值得进一步研究,特别是在H2S和CO2的区分方面。相反,尽管报道了非常好的结果,但只有少数论文涉及纳米多孔金属有机框架对H2S的吸附。
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引用次数: 64
Synthesis and Applications of Functionalized Magnetic Nanomaterials in Enantioseparation 功能化磁性纳米材料的合成及其在对映体分离中的应用
Pub Date : 2019-01-02 DOI: 10.1080/15422119.2017.1419257
Xiaojuan Deng, Wenbin Li, Guosheng Ding, T. Xue, Xiaoping Chen
Efficient enantioselective separation is a challenging task due to the identical physical and chemical properties of enantiomers. Functionalized magnetic nanomaterials modified with chiral ligands on their surface possess both magnetic property and chiral recognition ability, and have demonstrated great potential in chiral discrimination. This review summarizes the applications of magnetic nanomaterials modified with various chiral selectors (e.g., β-cyclodextrins, polymers, proteins, amino acids and cellulose) in enantioselective separation. After proper preparation and modification, these functionalized magnetic nanomaterials are effective for enantioseparation. Therefore, enantioseparations based on functionalized magnetic nanomaterials are convenient, economical and effective.
由于对映体具有相同的物理和化学性质,因此对映体的高效分离是一项具有挑战性的任务。手性配体修饰的功能化磁性纳米材料既具有磁性又具有手性识别能力,在手性识别方面具有很大的潜力。本文综述了各种手性选择剂(如β-环糊精、聚合物、蛋白质、氨基酸和纤维素)修饰的磁性纳米材料在对映选择分离中的应用。经过适当的制备和修饰,这些功能化磁性纳米材料可用于对映体分离。因此,基于功能化磁性纳米材料的对映体分离是一种方便、经济、有效的方法。
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引用次数: 21
Optimizing Geometric Parameters in Hydrocyclones for Enhanced Separations: A Review and Perspective 优化水力旋流分离器的几何参数:综述与展望
Pub Date : 2019-01-02 DOI: 10.1080/15422119.2017.1421558
Long Ni, Jinyi Tian, T. Song, Yongson Jong, Jianing Zhao
Hydrocyclones have been extensively applied for solid–liquid or liquid–liquid separations in various industries. However, the exact mechanisms underlying the enhanced separation technologies based on the optimization of geometric parameters of hydrocyclones remain unclear, and a number of research teams have performed numerous studies to enlarge the application scope of hydrocyclones by optimizing geometric parameters. This review provides a comprehensive state-of-the-art review of hydrocyclone enhanced-separation technologies. The enhanced-separation technologies are categorized into ten groups: cylindrical section, inlet, vortex finder, underflow pipe, conical section, hydrocyclone inclination angle, hydrocyclone insertion, conical-section/apex water injection, reflux device, and multi-hydrocyclone arrangement. These enhanced-separation technologies were analyzed and summarized according to the key separation-performance parameters of hydrocyclones, such as separation efficiency, cut size, split ratio, energy consumption, and capacity. It is expected that both the reviewed contents and the proposed challenges and future methodologies and technologies may provide research fellows working in this field with an improved understanding of enhanced separation technologies of hydrocyclones.
水力旋流器在各行业中广泛应用于固液或液液分离。然而,基于水力旋流器几何参数优化的强化分离技术的确切机制尚不清楚,许多研究团队进行了大量的研究,以通过优化几何参数来扩大水力旋流器的应用范围。本文综述了水力旋流器强化分离技术的最新进展。强化分离技术分为圆柱段、进气道、涡流探测器、底流管、锥形段、旋流器倾角、旋流器插入、锥形段/顶点注水、回流装置和多旋流器布置等十大类。根据水力旋流器的分离效率、切割粒度、劈裂比、能耗、容量等关键分离性能参数,对这些强化分离技术进行了分析和总结。希望本文所综述的内容、提出的挑战以及未来的方法和技术能够使从事该领域工作的研究人员更好地了解水力旋流器的强化分离技术。
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引用次数: 77
期刊
Separation & Purification Reviews
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