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Design of highly conductive iongel soft solid electrolytes for Li-O2 batteries 锂氧电池用高导电性离子凝胶软固体电解质的设计
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2022.59
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引用次数: 2
Recent advances in photocatalytic renewable energy production 光催化可再生能源生产的最新进展
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2021.24
Xiaolang Chen, Jingjing Zhao, Guisheng Li, Dieqing Zhang, Hexing Li
The development of green and renewable energy is becoming increasingly more important in reducing environmental pollution and controlling CO2 discharge. Photocatalysis can be utilized to directly convert solar energy into chemical energy to achieve both the conversion and storage of solar energy. On this basis, photocatalysis is considered to be a prospective technology to resolve the current issues of energy supply and environmental pollution. Recently, several significant achievements in semiconductor-based photocatalytic renewable energy production have been reported. This review presents the recent advances in photocatalytic renewable energy production over the last three years by summarizing the typical and significant semiconductorbased and semiconductor-like photocatalysts for H2 production, CO2 conversion and H2O2 production. These reactions demonstrate how the basic principles of photocatalysis can be exploited for renewable energy production. Finally, we conclude our review of photocatalytic renewable energy production and provide an outlook for future related research. Page 2 of Chen et al. Energy Mater 2022;2:200001 https://dx.doi.org/10.20517/energymater.2021.24 36
发展绿色能源和可再生能源在减少环境污染和控制二氧化碳排放方面变得越来越重要。利用光催化可以直接将太阳能转化为化学能,实现太阳能的转换和储存。在此基础上,光催化被认为是解决当前能源供应和环境污染问题的一种有前景的技术。最近,在半导体光催化可再生能源生产方面取得了一些重大成就。本文综述了近三年来光催化可再生能源生产的最新进展,总结了用于H2生产、CO2转化和H2O2生产的典型和重要的半导体光催化剂和半导体样光催化剂。这些反应展示了如何利用光催化的基本原理来生产可再生能源。最后,对光催化可再生能源的研究进展进行了综述,并对今后的研究进行了展望。Chen等人的第2页。能源材料2022;2:200001 https://dx.doi.org/10.20517/energymater.2021.24
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引用次数: 24
A cigarette filter-derived nitrogen-doped carbon nanoparticle coating layer for stable Zn-ion battery anodes 一种用于稳定锌离子电池阳极的香烟过滤器衍生的氮掺杂碳纳米颗粒涂层
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2022.45
Yi Guo, Cheng Liu, Lei Xu, Kaixin Huang, Hao Wu, Wenlong Cai, Yun Zhang
Despite the low cost, safety and high theoretical capacity of metallic zinc, zinc anodes face chronic problems, including zinc dendrites, corrosion and side reactions in aqueous zinc-ion batteries (ZIBs). Herein, a nitrogen-doped carbon nanoparticle coating layer derived from discarded cigarette filters is constructed to suppress parasitic side reactions and zinc dendrite growth. The dense coating layer isolates water from the zinc anode, effectively inhibiting side reactions. Furthermore, the special micro-mesoporous structure and sufficient zincophilic groups guarantee uniform Zn stripping/plating. Consequently, durable cycle stability (2400 cycles at a current density of 1 mA cm-2) with a stable polarization potential is achieved for symmetrical cells. The coating layer derived in this study therefore has the potential to improve the electrochemical performance of ZIBs.
尽管金属锌具有成本低、安全、理论容量高等优点,但锌阳极在水锌离子电池(zbs)中存在锌枝晶、腐蚀和副反应等长期问题。本文构建了一种源自废弃香烟过滤嘴的氮掺杂碳纳米颗粒涂层,以抑制寄生副反应和锌枝晶的生长。致密的涂层层隔绝了锌阳极的水分,有效地抑制了副反应。此外,特殊的微介孔结构和充足的亲锌基团保证了锌剥离/镀的均匀性。因此,持久的循环稳定性(2400次,电流密度为1毫安厘米-2)与稳定的极化电位实现对称电池。因此,本研究中得到的涂层具有改善ZIBs电化学性能的潜力。
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引用次数: 11
Atomistic Engineering of Ag/Pt nanoclusters for remarkably boosted mass electrocatalytic activity 银/铂纳米团簇的原子工程技术显著提高了质量电催化活性
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2022.03
Liangzhen Liu, Qiangyu Zhu, Junwei Li, Junxiang Chen, Junheng Huang, Qingfu Sun, Z. Wen
It is of vital importance to boost the intrinsic activity and augment the active sites of expensive and scarce platinum-based catalysts for advancing a variety of electrochemical energy applications. We herein report a mild electrochemical bottom-up approach to deposit ultrafine, but stable, Pt8Ag4 alloy clusters on carbon nanotubes (CNTs) by elaborately designing bimetallic organic cluster precursors with four silver and eight platinum atoms coordinated with µ,σ-bridged ethynylpyridine ligands, i.e., [Ag4(C24H16N4Pt)8(BF4)4]. The Pt8Ag4 cluster/CNT hybrids present impressively high platinum mass activity that is threefold that of commercial Pt/C toward the hydrogen evolution reaction, as a result of the cooperative contributions from the Ag atoms that enhance the intrinsic activity and the CNT supports that increase the activity sites. The present work affords an attractive avenue for engineering and stabilizing Pt-based nanoclusters at the atomic level and represents a promising strategy for the development of high-efficiency and durable electrocatalysts.
提高昂贵而稀缺的铂基催化剂的本征活性和增加活性位点对于推进各种电化学能源的应用至关重要。本文报道了一种温和的电化学自下而上的方法,通过精心设计双金属有机团簇前驱体,由4个银原子和8个铂原子配以μ,σ-桥接乙基吡啶配体,即[Ag4(C24H16N4Pt)8(BF4)4],在碳纳米管(CNTs)上沉积超细但稳定的Pt8Ag4合金团簇。Pt8Ag4簇/碳纳米管杂化物对析氢反应表现出令人印象深刻的高铂质量活性,是商业Pt/C的三倍,这是由于Ag原子的协同贡献,增强了固有活性,而碳纳米管支持增加了活性位点。目前的工作为在原子水平上工程和稳定基于pt的纳米团簇提供了一条有吸引力的途径,并代表了开发高效耐用电催化剂的有前途的策略。
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引用次数: 4
Recent advances and perspectives of microsized alloying-type porous anode materials in high-performance Li- and Na-ion batteries 高性能锂、钠离子电池微尺寸合金型多孔负极材料的研究进展与展望
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2022.24
Gaojie Li, Siguang Guo, Ben Xiang, Shixiong Mei, Yang Zheng, Xuming Zhang, B. Gao, Paul K. Chu, K. Huo
Alloying materials (e.g., Si, Ge, Sn, Sb, and so on) are promising anode materials for next-generation lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) due to their high capacity, suitable working voltage, earth abundance, environmental friendliness, and non-toxicity. Although some important breakthroughs have been reported recently for these materials, their dramatic volume change during alloying/dealloying causes severe pulverization, leading to poor cycling stability and safety risks. Although the nanoengineering of alloys can mitigate the volumetric expansion to some extent, there remain other drawbacks, such as low initial Columbic efficiency and volumetric energy density. Porous microscale alloys comprised of nanoparticles and nanopores inherit micro- and nanoproperties, so that volume expansion during lithiation/sodiation can be better accommodated by the porous structure to consequently release stress and improve the cycling stability. Herein, the recent progress of porous microscale alloying-type anode materials for LIBs and SIBs is reviewed by summarizing the Li and Na storage mechanisms, the challenges associated with different materials, common fabrication methods, and the relationship between the structure and electrochemical properties in LIBs and SIBs. Finally, the prospects of porous microscale alloys are discussed to provide guidance for future research and the commercial development of anode materials for LIBs and SIBs.
合金材料(如Si、Ge、Sn、Sb等)具有容量大、工作电压适宜、接地丰度高、环境友好、无毒等优点,是下一代锂离子电池和钠离子电池极具发展前景的负极材料。尽管这些材料最近取得了一些重要的突破,但它们在合金化/脱合金过程中的巨大体积变化导致严重的粉化,导致循环稳定性差和安全风险。虽然纳米工程技术可以在一定程度上缓解合金的体积膨胀,但仍存在初始哥伦比亚效率低、体积能量密度低等缺点。由纳米颗粒和纳米孔组成的多孔微尺度合金继承了微纳米特性,因此多孔结构可以更好地适应锂化/钠化过程中的体积膨胀,从而释放应力,提高循环稳定性。本文综述了近年来多孔微尺度合金型锂离子电池和sib负极材料的研究进展,综述了锂离子电池和sib负极材料的Li和Na存储机理、不同材料面临的挑战、常见的制备方法以及锂离子电池和sib负极材料结构与电化学性能之间的关系。最后,对多孔微尺度合金的发展前景进行了展望,为今后锂离子电池和硅离子电池阳极材料的研究和商业化开发提供指导。
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引用次数: 25
Design of Zn anode protection materials for mild aqueous Zn-ion batteries 温和水性锌离子电池用锌阳极保护材料的设计
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2022.08
Yuejuan Zhang, S. Bi, Zhiqiang Niu, Weiya Zhou, S. Xie
Rechargeable aqueous Zn-ion batteries (AZIBs) are considered alternative stationary storage systems for large-scale applications due to their high safety, low cost, and high power density. However, Zn anode issues including dendrite formation and side reactions greatly hinder the practical application of AZIBs. To solve the Zn anode issues, various strategies based on material designs have been developed. It is necessary to analyze and classify these strategies according to different materials, because different properties of materials determine the underlying mechanisms. In this review, we briefly introduce the fundamental issues in Zn anodes. Furthermore, this review highlights the material designs for the protection of Zn anodes in mild AZIBs. Finally, we also offer insight into potential directions in the material designs to promote the development of AZIBs in the future.
由于其高安全性、低成本和高功率密度,可充电水性锌离子电池(azib)被认为是大规模应用的替代固定存储系统。然而,锌阳极的枝晶形成和副反应等问题极大地阻碍了azib的实际应用。为了解决锌阳极的问题,基于材料设计的各种策略已经被开发出来。有必要根据不同的材料对这些策略进行分析和分类,因为材料的不同性质决定了其潜在的机制。在这篇综述中,我们简要介绍了锌阳极的基本问题。此外,本文还重点介绍了在轻度azib中保护Zn阳极的材料设计。最后,我们还提出了材料设计的潜在方向,以促进azib在未来的发展。
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引用次数: 21
Two-dimensional nanofluidics for blue energy harvesting 蓝色能量收集的二维纳米流体
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2022.04
L. Xie, Jiadong Tang, Runan Qin, Jingbing Liu, Qianqian Zhang, Yuhong Jin, Hao Wang
Blue energy harvesting based on the ion flow obtained from seas and rivers provides a clean, stable and continuous electric output that is highly dependent on ion-selective membranes (ISMs) that conduct single ions. In recent years, ISMs constructed based on two-dimensional (2D) nanofluidics have demonstrated promising application prospects in blue energy harvesting due to their facile fabrication, excellent ion selectivity and high ion flux. In this review, the principles of 2D nanofluidics in regulating ionic transport are firstly proposed and discussed, including ion selectivity and ultrafast ion transmission, which are considered as two critical factors for achieving highly efficient blue energy harvesting. The advantages of 2D nanofluidics towards blue energy harvesting are analyzed to reveal the necessity of this review. The construction of 2D nanofluidic membranes based on several typical materials and their recent research advances in salinity gradient- and pressure-driven blue energy harvesting are also summarized in detail. Finally, the existing challenges of 2D nanofluidic membranes regarding blue energy harvesting applications are discussed to provide new insights for the development of high-performance blue energy harvesting systems based on 2D nanofluidics.
基于从海洋和河流中获得的离子流的蓝色能量收集提供了清洁、稳定和连续的电力输出,这高度依赖于传导单离子的离子选择膜(ISMs)。近年来,基于二维(2D)纳米流体构建的ISMs由于其易于制作、优异的离子选择性和高的离子通量,在蓝色能量收集方面显示出广阔的应用前景。本文首先提出并讨论了二维纳米流体调节离子传输的原理,包括离子选择性和超快离子传输,这是实现高效蓝色能量收集的两个关键因素。分析了二维纳米流体在蓝色能量收集方面的优势,揭示了本文的必要性。综述了基于几种典型材料的二维纳米流体膜的构建及其在盐度梯度和压力驱动蓝色能量收集方面的最新研究进展。最后,讨论了二维纳米流体膜在蓝色能量收集应用方面存在的挑战,为基于二维纳米流体的高性能蓝色能量收集系统的开发提供了新的见解。
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引用次数: 6
Design of manganese dioxide for supercapacitors and zinc-ion batteries: similarities and differences 超级电容器和锌离子电池用二氧化锰的设计:异同
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2022.56
Henghan Dai, Ruicong Zhou, Zhao Zhang, Jinyuan Zhou, Gengzhi Sun
Energy storage devices, e.g., supercapacitors (SCs) and zinc-ion batteries (ZIBs), based on aqueous electrolytes, have the advantages of rapid ion diffusion, environmental benignness, high safety and low cost. Generally, SCs provide excellent power density with the capability of fast charge/discharge, while ZIBs offer high energy density by storing more charge per unit weight/volume. Although the charge storage mechanisms are considered different, manganese dioxide (MnO2) has proven to be an appropriate electrode material for both SCs and ZIBs because of its unique characteristics, including polymorphic forms, tunable structures and designable morphologies. Herein, the design of MnO2-based materials for SCs and ZIBs is comprehensively reviewed. In particular, we compare the similarities and differences in utilizing MnO2-based materials as active materials for SCs and ZIBs by highlighting their corresponding charge storage mechanisms. We then introduce a few commonly adopted strategies for tuning the physicochemical properties of MnO2 and their specific merits. Finally, we discuss the future perspectives of MnO2 for SC and ZIB applications regarding the investigation of charge storage mechanisms, materials design and the enhancement of electrochemical performance.
超级电容器(SCs)、锌离子电池(zib)等基于水溶液的储能装置具有离子扩散快、环保、安全性高、成本低等优点。一般来说,sc具有快速充放电的能力,提供了出色的功率密度,而zib通过单位重量/体积存储更多的电荷来提供高能量密度。尽管电荷存储机制被认为是不同的,但二氧化锰(MnO2)已被证明是SCs和ZIBs的合适电极材料,因为它具有独特的特性,包括多态形式、可调结构和可设计的形态。本文对二氧化锰基材料的设计进行了综述。特别地,我们通过强调其相应的电荷存储机制,比较了二氧化锰基材料作为sc和ZIBs活性材料的异同。然后,我们介绍了几种常用的调整二氧化锰物理化学性质的策略及其具体优点。最后,我们讨论了二氧化锰在SC和ZIB中的应用前景,包括电荷存储机制的研究、材料设计和电化学性能的提高。
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引用次数: 20
Research progress on the surface/interface modification of high-voltage lithium oxide cathode materials 高压氧化锂正极材料表面/界面改性研究进展
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2022.18
Yong-Li Heng, Zhenyi Gu, Jin-Zhi Guo, Xiaotong Yang, Xin‐Xin Zhao, Xing Wu
Lithium oxides are the most promising cathode candidates for high-performance lithium-ion batteries (LIBs), owing to their high theoretical capacity and average working voltage, which are conducive to achieving the ultimate goal of upgrading energy density. By raising the upper limit of the cutoff voltage, we may be able to further improve both the practical capacity and average voltage of lithium oxide cathodes. Unfortunately, the high-voltage operation of these cathodes results in significant challenges, namely, reduced surface structural stability and interfacial stability with electrolytes, thus degrading the electrochemical performance. Accordingly, surface/interface modification strategies, including surface coating, electrolyte regulation, binder design, and special surface treatments, are systematically summarized and comprehensively analyzed for high-voltage lithium oxide cathode materials in this review. Furthermore, the corresponding modification mechanisms are discussed in detail to better grasp the internal mechanisms for the enhanced electrochemical performance. Based on recent progress, we further propose predictable development directions for high-performance LIBs in future practical applications. This review provides new insights into various high-voltage lithium oxide cathodes and their universal surface/interface modification strategies towards advanced next-generation LIBs with high energy and power density and long cycle life.
锂氧化物具有较高的理论容量和平均工作电压,有利于实现能量密度提升的最终目标,是高性能锂离子电池(LIBs)最有前途的正极候选者。通过提高截止电压的上限,可以进一步提高氧化锂阴极的实用容量和平均电压。不幸的是,这些阴极的高压工作带来了重大挑战,即降低了表面结构稳定性和与电解质的界面稳定性,从而降低了电化学性能。因此,本文系统总结和全面分析了高压氧化锂正极材料的表面/界面改性策略,包括表面涂层、电解质调节、粘结剂设计和特殊表面处理。此外,还详细讨论了相应的改性机理,以便更好地掌握电化学性能增强的内在机理。基于最近的研究进展,我们进一步提出了高性能lib在未来实际应用中可预测的发展方向。本文综述了各种高压氧化锂阴极及其通用表面/界面改性策略,为实现高能量和功率密度、长循环寿命的先进下一代锂离子电池提供了新的见解。
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引用次数: 8
Advances in lithium-ion battery materials for ceramic fuel cells 陶瓷燃料电池用锂离子电池材料研究进展
Pub Date : 2022-01-01 DOI: 10.20517/energymater.2022.76
Xiaomi Zhou, Jingjing Yang, Ruoming Wang, Wei Zhang, Sining Yun, Baoyuan Wang
Lithium-ion batteries (LIBs) and ceramic fuel cells (CFCs) are important for energy storage and conversion technologies and their materials are central to developing advanced applications. Although there are many crosslinking research activities, e.g., through materials and some common scientific fundamentals employed for both LIB and CFCs, crosslinking scientific aspects to achieve a comprehensive understanding are missing. There is a lack of such a review to promote and guide further research and development in the crosslinking of LIBs and CFCs. Herein, we review the existing application of LIB materials in CFCs to discover the scientific advances of lithium-ion and proton transport cooperation and identify the new directions of Li-CFCs in the future. This review is the first to propose CFC advances, especially at low temperatures (300-600 °C) by applying LIB materials to practical devices and highlight the material properties and new device functions with enhanced performance, as well as the scientific mechanisms and principles. Furthermore, we seek to deepen the scientific understanding of materials science, ion transport mechanisms and semiconductor electrochemistry to benefit both the battery and fuel cell fields.
锂离子电池(LIBs)和陶瓷燃料电池(cfc)对于能量存储和转换技术非常重要,它们的材料是开发先进应用的核心。虽然有许多交联研究活动,例如通过材料和一些常见的科学基础来研究LIB和CFCs,但缺乏交联科学方面的全面认识。缺乏这样的综述来促进和指导lib与CFCs交联的进一步研究和开发。本文综述了锂离子材料在氟氯化碳中的应用现状,揭示了锂离子与质子输运合作的科学进展,并确定了未来锂氟氯化碳的新方向。本文首次提出了低温(300-600°C)下CFC材料应用于实际器件的研究进展,重点介绍了材料性能和性能增强的新器件功能,以及科学的机理和原理。此外,我们寻求加深对材料科学,离子传输机制和半导体电化学的科学理解,以使电池和燃料电池领域受益。
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引用次数: 12
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Solar Energy Materials
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