Pub Date : 2023-01-01DOI: 10.20517/energymater.2022.55
{"title":"Organic-inorganic hybrid quasi-2D perovskites incorporated with fluorinated additives for efficient and stable four-terminal tandem solar cells","authors":"","doi":"10.20517/energymater.2022.55","DOIUrl":"https://doi.org/10.20517/energymater.2022.55","url":null,"abstract":"","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"3 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75615733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.20517/energymater.2022.60
{"title":"Lithium metal stabilization for next-generation lithium-based batteries: from fundamental chemistry to advanced characterization and effective protection","authors":"","doi":"10.20517/energymater.2022.60","DOIUrl":"https://doi.org/10.20517/energymater.2022.60","url":null,"abstract":"","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"30 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80022621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.20517/energymater.2023.03
Lucia Mazzapioda, A. Tsurumaki, Graziano Di Donato, Henry Adenusi, M. Navarra, S. Passerini
Solid-state batteries (SSBs) based on inorganic solid electrolytes (ISEs) are considered promising candidates for enhancing the energy density and the safety of next-generation rechargeable lithium batteries. However, their practical application is frequently hampered by the high resistance arising at the Li metal anode/ISE interface. Herein, a review of the conventional solid-state electrolytes (SSEs) the recent research on quasi-solid-state battery (QSSB) approaches to overcome the issues of the state-of-the-art SSBs is reported. The feasibility of ionic liquid (IL)-based interlayers to improve ISE/Li metal wetting and enhance charge transfer at solid electrolyte interfaces with both positive and lithium metal electrodes is presented together with a novel generation of IL-containing quasi-solid-state-electrolytes (QSSEs), offering favourable features. The opportunities and challenges of QSSE for the development of high energy and high safety quasi-solid-state lithium metal batteries (QSSLMBs) are also discussed.
{"title":"Quasi-solid-state electrolytes - strategy towards stabilising Li|inorganic solid electrolyte interfaces in solid-state Li metal batteries","authors":"Lucia Mazzapioda, A. Tsurumaki, Graziano Di Donato, Henry Adenusi, M. Navarra, S. Passerini","doi":"10.20517/energymater.2023.03","DOIUrl":"https://doi.org/10.20517/energymater.2023.03","url":null,"abstract":"Solid-state batteries (SSBs) based on inorganic solid electrolytes (ISEs) are considered promising candidates for enhancing the energy density and the safety of next-generation rechargeable lithium batteries. However, their practical application is frequently hampered by the high resistance arising at the Li metal anode/ISE interface. Herein, a review of the conventional solid-state electrolytes (SSEs) the recent research on quasi-solid-state battery (QSSB) approaches to overcome the issues of the state-of-the-art SSBs is reported. The feasibility of ionic liquid (IL)-based interlayers to improve ISE/Li metal wetting and enhance charge transfer at solid electrolyte interfaces with both positive and lithium metal electrodes is presented together with a novel generation of IL-containing quasi-solid-state-electrolytes (QSSEs), offering favourable features. The opportunities and challenges of QSSE for the development of high energy and high safety quasi-solid-state lithium metal batteries (QSSLMBs) are also discussed.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83068560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.20517/energymater.2022.84
{"title":"Zn-based batteries for energy storage","authors":"","doi":"10.20517/energymater.2022.84","DOIUrl":"https://doi.org/10.20517/energymater.2022.84","url":null,"abstract":"","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"32 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78317848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.20517/energymater.2023.04
Bowei Du, Mingyue Wang, Qingzhou Zhao, Xiaofei Hu, Shujiang Ding
Phase change materials (PCMs) are considered one of the most promising energy storage methods owing to their beneficial effects on a larger latent heat, smaller volume change, and easier controlling than other materials. PCMs are widely used in solar energy heating, industrial waste heat utilization, energy conservation in the construction industry, and other fields. To avoid leakage, phase separation, and volatile problems of PCMs, the encapsulation technique typically uses organic polymer materials as shell structures of microcapsules. Furthermore, using inorganic materials to enhance the thermal property of phase change microcapsules is a popular approach in recent research. Especially, graphene oxide (GO) with high thermal conductivity was used as a common thermal conducting additive to improve the thermal performance of phase change microcapsules. Due to its amphiphilic property, GO combined with PCM microcapsules can achieve a variety of nanostructures for thermal energy storage. In this paper, four aspects have been summarized: configuration of PCMs, methods of combining GO with phase change microcapsules, position and content of GO, and applications of PCM/GO microcapsules. This work attempts to discuss preparation methods and heat-conducting properties of the PCM/GO microcapsules, which helps to better promote the application-targeted design and greatly improve the thermal properties of PCM microcapsules for various applications.
{"title":"Phase change materials microcapsules reinforced with graphene oxide for energy storage technology","authors":"Bowei Du, Mingyue Wang, Qingzhou Zhao, Xiaofei Hu, Shujiang Ding","doi":"10.20517/energymater.2023.04","DOIUrl":"https://doi.org/10.20517/energymater.2023.04","url":null,"abstract":"Phase change materials (PCMs) are considered one of the most promising energy storage methods owing to their beneficial effects on a larger latent heat, smaller volume change, and easier controlling than other materials. PCMs are widely used in solar energy heating, industrial waste heat utilization, energy conservation in the construction industry, and other fields. To avoid leakage, phase separation, and volatile problems of PCMs, the encapsulation technique typically uses organic polymer materials as shell structures of microcapsules. Furthermore, using inorganic materials to enhance the thermal property of phase change microcapsules is a popular approach in recent research. Especially, graphene oxide (GO) with high thermal conductivity was used as a common thermal conducting additive to improve the thermal performance of phase change microcapsules. Due to its amphiphilic property, GO combined with PCM microcapsules can achieve a variety of nanostructures for thermal energy storage. In this paper, four aspects have been summarized: configuration of PCMs, methods of combining GO with phase change microcapsules, position and content of GO, and applications of PCM/GO microcapsules. This work attempts to discuss preparation methods and heat-conducting properties of the PCM/GO microcapsules, which helps to better promote the application-targeted design and greatly improve the thermal properties of PCM microcapsules for various applications.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75223610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.20517/energymater.2022.82
Xue Gong, P. Song, Ce Han, Yi Xiao, Xuanhao Mei, Weilin Xu
Single-atom catalysts (SACs) with high activity, unique selectivity, and nearly 100% atom utilization efficiency are promising for broad applications in many fields. This review aims to provide a summary of the current development of SACs and point out their challenges and opportunities for commercial applications in the energy process. The discussion starts with an introduction of various types of SACs materials, followed by typical SACs synthetic methods with concrete examples and commonly used characterization methods. The state-of-the-art synthesis methods, whereby SACs with stabilized single metal atoms on the substrate without migration and agglomeration could be obtained, are emphasized. Next, we give an overview of different types of substrates and discuss the effects of substrate species on the structure and properties of SACs. Then we highlight the typical applications of SACs and the remaining challenges. Finally, a perspective on the opportunities for the development of SACs for future commercial applications is provided.
{"title":"Heterogeneous single-atom catalysts for energy process: recent progress, applications and challenges","authors":"Xue Gong, P. Song, Ce Han, Yi Xiao, Xuanhao Mei, Weilin Xu","doi":"10.20517/energymater.2022.82","DOIUrl":"https://doi.org/10.20517/energymater.2022.82","url":null,"abstract":"Single-atom catalysts (SACs) with high activity, unique selectivity, and nearly 100% atom utilization efficiency are promising for broad applications in many fields. This review aims to provide a summary of the current development of SACs and point out their challenges and opportunities for commercial applications in the energy process. The discussion starts with an introduction of various types of SACs materials, followed by typical SACs synthetic methods with concrete examples and commonly used characterization methods. The state-of-the-art synthesis methods, whereby SACs with stabilized single metal atoms on the substrate without migration and agglomeration could be obtained, are emphasized. Next, we give an overview of different types of substrates and discuss the effects of substrate species on the structure and properties of SACs. Then we highlight the typical applications of SACs and the remaining challenges. Finally, a perspective on the opportunities for the development of SACs for future commercial applications is provided.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"07 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83005981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.20517/energymater.2022.64
{"title":"Recent progress of multilayer polymer electrolytes for lithium batteries","authors":"","doi":"10.20517/energymater.2022.64","DOIUrl":"https://doi.org/10.20517/energymater.2022.64","url":null,"abstract":"","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"12 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84554936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.20517/energymater.2023.06
Yanfei Zhang, Qian Li, Guangxun Zhang, Tingting Lv, Pengbiao Geng, Yumeng Chen, H. Pang
{"title":"Recent advances in the type, synthesis and electrochemical application of defective metal-organic frameworks","authors":"Yanfei Zhang, Qian Li, Guangxun Zhang, Tingting Lv, Pengbiao Geng, Yumeng Chen, H. Pang","doi":"10.20517/energymater.2023.06","DOIUrl":"https://doi.org/10.20517/energymater.2023.06","url":null,"abstract":"","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88685696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.20517/energymater.2023.11
Andrew Nguyen, R. Verma, Pravin N. Didwal, Chan‐Jin Park
Potassium-ion batteries (PIBs) are a promising candidate for low-cost and large-scale energy storage due to their abundant potassium resources. However, the potassiation-depotassiation of K+ presents a significant challenge due to its large ionic radius, which results in the pulverization of active materials and poor cyclability. Thus, researchers are exploring anode materials with a high specific capacity, long cyclability, and excellent rate capability. In this context, alloy-type anode materials are exceptional candidates due to their high theoretical capacity and low working potential. Nonetheless, the large volume expansion of active materials limits their practical application. This review discusses various strategies for overcoming these challenges, including nanostructure design, heterostructure design, alloy engineering, and compositing. The review provides a comprehensive overview of the current state of research on alloy-based anodes for PIBs and offers insights into promising directions for future work toward commercializing PIBs.
{"title":"Challenges and design strategies for alloy-based anode materials toward high-performance future-generation potassium-ion batteries","authors":"Andrew Nguyen, R. Verma, Pravin N. Didwal, Chan‐Jin Park","doi":"10.20517/energymater.2023.11","DOIUrl":"https://doi.org/10.20517/energymater.2023.11","url":null,"abstract":"Potassium-ion batteries (PIBs) are a promising candidate for low-cost and large-scale energy storage due to their abundant potassium resources. However, the potassiation-depotassiation of K+ presents a significant challenge due to its large ionic radius, which results in the pulverization of active materials and poor cyclability. Thus, researchers are exploring anode materials with a high specific capacity, long cyclability, and excellent rate capability. In this context, alloy-type anode materials are exceptional candidates due to their high theoretical capacity and low working potential. Nonetheless, the large volume expansion of active materials limits their practical application. This review discusses various strategies for overcoming these challenges, including nanostructure design, heterostructure design, alloy engineering, and compositing. The review provides a comprehensive overview of the current state of research on alloy-based anodes for PIBs and offers insights into promising directions for future work toward commercializing PIBs.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"31 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74424176","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The rapid development of electronic technology and energy industry promotes the increasing desire for energy storage systems with high energy density, thus calling for the exploration of lithium metal anode. However, the enormous challenges, such as uncontrollable lithium deposition, side reaction, infinite volume change and dendrite generation, hinders its application. To address these problems, the deposition behavior of lithium must be exactly controlled and the anode/electrolyte interface must be stabilized. The deposition of lithium is a multi-step process influenced by multi-physical fields, where nucleation is the key to final morphology. Hence, increasing investigations have focused on the employment of lithiophilic materials that can regulate lithium nucleation in recent years. The lithiophilic materials introduced into the deposition hosts or solid electrolyte interphases can regulate the nucleation overpotential and facilitate uniform deposition. However, the concept of lithiophilicity is still undefined and the mechanism is still unrevealed. In this review, the recent advances in the regulation mechanisms of lithiophilicity are discussed, and the applications of lithiophilic materials in hosts and protective interphases are summarized. The in-depth exploration of lithiophilic materials can enhance our understanding of the deposition behavior of lithium and pave the way for practical lithium metal batteries.
{"title":"Recent advances in lithiophilic materials: material design and prospects for lithium metal anode application","authors":"Jiaxiang Liu, Nanbiao Pei, Xueying Yang, Ruiyang Li, Haiming Hua, Peng Zhang, Jinbao Zhao","doi":"10.20517/energymater.2023.08","DOIUrl":"https://doi.org/10.20517/energymater.2023.08","url":null,"abstract":"The rapid development of electronic technology and energy industry promotes the increasing desire for energy storage systems with high energy density, thus calling for the exploration of lithium metal anode. However, the enormous challenges, such as uncontrollable lithium deposition, side reaction, infinite volume change and dendrite generation, hinders its application. To address these problems, the deposition behavior of lithium must be exactly controlled and the anode/electrolyte interface must be stabilized. The deposition of lithium is a multi-step process influenced by multi-physical fields, where nucleation is the key to final morphology. Hence, increasing investigations have focused on the employment of lithiophilic materials that can regulate lithium nucleation in recent years. The lithiophilic materials introduced into the deposition hosts or solid electrolyte interphases can regulate the nucleation overpotential and facilitate uniform deposition. However, the concept of lithiophilicity is still undefined and the mechanism is still unrevealed. In this review, the recent advances in the regulation mechanisms of lithiophilicity are discussed, and the applications of lithiophilic materials in hosts and protective interphases are summarized. The in-depth exploration of lithiophilic materials can enhance our understanding of the deposition behavior of lithium and pave the way for practical lithium metal batteries.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"191 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75073768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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