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Challenges in the design of a prototype contactor assembly for the recovery of uranium from seawater 从海水中回收铀的原型接触器组件设计中的挑战
Pub Date : 2009-04-02 DOI: 10.1504/IJND.2009.024334
N. Prasad, K. Pathak, Manish Kumar, A. Matkar, T. Prasad, A. Saxena
The total estimated quantity of uranium in oceans is around four and a half billion tonnes. Harvesting uranium from seawater is much less taxing to the environment. Thus, when uranium is harvested from seawater with near-zero environmental burdens, it will become a totally green fuel in the hands of humankind, as uranium generates primary calories without giving CO2 emissions and leaves no mill tailings at the recovery site while recovering it for use in reactors. To extract uranium from seawater, a contactor assembly that contains radiation-grafted polyacrylamid oxime (PAO) is used to trap the loosely bonded uranyl ion. Some of the design constraints for contractor assembly are the maximisation of the grafted sheet area and strength to withstand extreme marine conditions. The material should be compatible with the hot processing chemicals and be extremely cost effective, as well as lightweight. Design also has to take into account the ease of loading/unloading of grafted sheet modules, ease of replacement of grafted sheets, fixing of cage modules in seabed and load equilibrium even in high and low tide. This paper will cover the various challenges involved in designing a contactor assembly.
据估计,海洋中铀的总量约为45亿吨。从海水中获取铀对环境的影响要小得多。因此,当从海水中获取铀时,环境负担几乎为零,它将成为人类手中完全绿色的燃料,因为铀产生初级卡路里而不产生二氧化碳排放,并且在回收时不会在回收地点留下任何工厂尾矿用于反应堆。为了从海水中提取铀,使用含有辐射接枝聚丙烯酰胺肟(PAO)的接触器组件来捕获松散结合的铀酰离子。承包商装配的一些设计限制是最大限度地增加接枝板的面积和强度,以承受极端的海洋条件。该材料应与热加工化学品兼容,并具有极高的成本效益,以及重量轻。设计还需要考虑接枝板模块的易装卸性、接枝板的易更换性、保持架模块在海底的固定以及涨潮和退潮时的载荷平衡。本文将涵盖设计接触器组件所涉及的各种挑战。
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引用次数: 4
Technological approaches to providing safe drinking water for rural and remote areas 为农村和偏远地区提供安全饮用水的技术方法
Pub Date : 2008-09-10 DOI: 10.1504/IJND.2008.020219
S. Prabhakar
Provision of safe drinking water is one of the key drivers in our technological pursuits. A number of habitations are suffering from a variety of water quality problems such as excess salinity, iron, arsenic, fluoride, nitrate and microbial contamination. Simplicity of operation, less dependence on external sources of power supply, minimisation of wastewater, etc., are some of the ground rules to ensure reliability and sustainability of water purification technologies/devices. The experience over the last two decades has indicated that the objective of providing safe drinking water in totality can be achieved only with the technologies in tune with the village environment and the total participation of the user group. Domestic water purifier based on ultrafiltration can be used as a point-of-use device in almost all households to provide microbiologically safe drinking water. With suitable modifications, these devices can be used for removal of contaminants such as iron, and marginal contamination of fluorides and arsenic. The use of reverse osmosis can tackle salinity and other contaminants. Safe quality water is costlier due to the use of the device and hence its use should be only to the extent required. It is necessary therefore to promote quality linked usage of water to ensure sustainability and reliability.
提供安全的饮用水是我们追求科技的关键驱动力之一。许多居住地正遭受各种水质问题的困扰,例如盐度过高、铁、砷、氟化物、硝酸盐和微生物污染。操作简单、减少对外部电源的依赖、尽量减少废水等,是确保水净化技术/设备的可靠性和可持续性的一些基本原则。过去二十年的经验表明,只有采用与村庄环境相协调的技术和用户群体的全面参与,才能实现总体上提供安全饮用水的目标。基于超滤技术的家用净水器几乎可以在所有家庭中作为使用点设备,提供微生物安全的饮用水。经过适当的修改,这些装置可用于去除污染物,如铁,以及氟化物和砷的边缘污染。使用反渗透可以处理盐分和其他污染物。由于使用该装置,安全优质的水的成本更高,因此应仅在需要的范围内使用。因此,有必要促进与质量挂钩的用水,以确保可持续性和可靠性。
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引用次数: 0
Application of an artificial neural network in wastewater quality monitoring: prediction of water quality index 人工神经网络在污水水质监测中的应用:水质指标预测
Pub Date : 2008-09-10 DOI: 10.1504/IJND.2008.020223
Ayan Hore, S. Dutta, S. Datta, C. Bhattacharjee
Water bodies have become more and more polluted owing to discharge of industrial waste. Therefore, it has been the chief concern of scientists, engineers and ecologists to decrease the water pollution level around the globe to maintain living viability and ecological balance. In this paper, the seasonal and positional variation of wastewater parameters in a natural flowing stream has been observed and an Artificial Neural Network (ANN) model is proposed to predict the water quality. Tolly's Canal was chosen as the purview of this case study. Wastewater and sediment samples were collected from Tolly's Canal and the River Ganges at different points and different seasons both at high and low tide conditions on a particular day. All the important water quality parameters were evaluated. To summarise and report river-water quality, a new term, 'Water Quality Index' (WQI), has been introduced. The WQI value is a dimensionless number ranging from 0 to 100 (best quality). In this study, the WQI is predicted by a simulative model using an ANN. This model has been developed for the assessment of the WQI and compared with the conventionally determined values of WQI. A Multilayer-Perceptron (MLP) network with a single hidden layer was used along with back-propagation algorithm. The results were found to be quite impressive. Thus, the ANN proved to be an efficient tool to assess the WQI of any sample.
由于工业废水的排放,水体污染越来越严重。因此,降低全球水污染水平以维持生物生存能力和生态平衡一直是科学家、工程师和生态学家关注的首要问题。本文通过对自然水流中污水参数的季节和位置变化进行观测,提出了一种人工神经网络(ANN)模型来预测水质。托利运河被选为本案例研究的范围。废水和沉积物样本是在某一天的不同时间和不同季节的涨潮和退潮条件下从托利运河和恒河收集的。对各重要水质参数进行了评价。为了总结和报告河流水质,引入了一个新的术语“水质指数”(WQI)。WQI值为无因次数,取值范围为0 ~ 100(最佳质量)。在本研究中,采用人工神经网络的模拟模型预测了WQI。该模型是为评估WQI而开发的,并与常规确定的WQI值进行了比较。采用单隐层多层感知器(MLP)网络和反向传播算法。结果令人印象深刻。因此,人工神经网络被证明是评估任何样本WQI的有效工具。
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引用次数: 13
A novel super-cooled humidification?dehumidification system driven by thermal vapour compression unit for seawater desalination 一种新型的过冷加湿?海水淡化用热蒸汽压缩装置驱动的除湿系统
Pub Date : 2008-09-10 DOI: 10.1504/IJND.2008.020225
M. Saadawy, A. Karameldin, E. Negeed
The current study presents the concept of a novel seawater desalination system that is configured by a humidification?dehumidification unit based on the vapour-compression process (HDDTVC). The coupled refrigeration unit employs the thermal compression of vapour by a jet-ejector. The new technical idea of proposed desalination system depends mainly upon the creation of a super-cooled temperature under the ambient condition (near 0°C) for the dehumidification process, instead of using the heat sink in the cooling process. Subsequently, the significant development in the unit performance is achieved by increasing its availability owing to the condensation and collection of the dew from the atmospheric vapour as an additional source of water production, in addition to the product from the main source of seawater. A computer program based on a simulation mathematical model is constructed and a comprehensive analysis is discussed for the new system. The alternate novel process is characterised with the ability to recuperate the retrogressive water production in traditional process, where the productivity of freshwater may increase up to eight times compared with the conventional humidification?dehumidification process applied for the countries with hot and tropical climatological conditions. The amount of extracted and retrieved water from dew in most humid regions can reach around 51% and 37% of the new unit production. In this investigation, enhancement of the unit performance is the main objective. The influence of changing the characteristics of the jet-ejector (the cornerstone of the thermal refrigeration vapour-compression unit) on the system performance is discussed and analysed so as to clarify the controlling parameters. Also, the applicability of different working fluids is tested for the vapour compression process. Based on the current work, the new HDDTVC is suggested as a promising unit of medium-scale commercial production to provide arid and isolated communities with their requirements for potable water.
目前的研究提出了一种新型海水淡化系统的概念,该系统由加湿?基于蒸汽压缩过程(HDDTVC)的除湿装置。耦合制冷装置利用喷射喷射器对蒸汽进行热压缩。拟议的海水淡化系统的新技术理念主要依赖于在环境条件下为除湿过程创造过冷温度(接近0°C),而不是在冷却过程中使用散热器。随后,通过增加其可用性来实现装置性能的重大发展,这是由于大气蒸汽中的露水的冷凝和收集,作为主要海水来源的产品之外的另一种水生产来源。建立了基于仿真数学模型的计算机程序,并对新系统进行了综合分析。替代新工艺的特点是能够恢复传统工艺中倒退的产水,其中淡水的生产率可能比传统的加湿提高8倍。除湿工艺适用于炎热和热带气候条件的国家。在大多数潮湿地区,从露水中提取和回收的水量可以达到新装置产量的51%和37%左右。在本研究中,提高机组性能是主要目标。讨论和分析了改变喷射器(热制冷蒸汽压缩机组的基石)的特性对系统性能的影响,从而明确了控制参数。此外,还测试了不同工质在蒸汽压缩过程中的适用性。基于目前的工作,新的HDDTVC被认为是一个有前景的中等规模商业化生产单元,为干旱和偏远社区提供他们对饮用水的需求。
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引用次数: 1
Nuclear seawater desalination plant coupled with 200 MW heating reactor 配有200兆瓦加热反应堆的核海水淡化装置
Pub Date : 2008-09-10 DOI: 10.1504/IJND.2008.020227
H. Jia, Yajun Zhang
A feasibility study on nuclear seawater desalination plant in which a 200 MW nuclear heating reactor (NHR-200) is coupled with MED processes has been completed, and the Chinese government has agreed to build a nuclear seawater desalination plant of this type in the Shandong Peninsula of China. Two different kinds of MED processes, high temperature stacked VTE-MED and low-temperature horizontal tube MED-TVC, have been investigated and compared, and their capacities for freshwater production are 160,000 m³/d and 120,000 m³/d, respectively. Based on the results of the feasibility study, the VTE-MED plant is more economical than the MED-TVC, but not on the technology maturity for a very large nuclear desalination plant. The two kinds of different nuclear desalination schemes and their primary economic results are presented in this paper.
200兆瓦核加热堆(NHR-200)与MED工艺相结合的核海水淡化厂可行性研究已经完成,中国政府已同意在中国山东半岛建设该类型的核海水淡化厂。对高温堆叠式VTE-MED和低温水平管式MED- tvc两种不同的MED工艺进行了研究和比较,其淡水生产能力分别为16万m³/d和12万m³/d。根据可行性研究的结果,VTE-MED装置比MED-TVC装置更经济,但就技术成熟度而言,对于一个非常大的核海水淡化装置来说,并非如此。本文介绍了两种不同的核脱盐方案及其初步经济效果。
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引用次数: 12
Seawater desalination technologies 海水淡化技术
Pub Date : 2008-09-10 DOI: 10.1504/IJND.2008.020222
R. Bharadwaj, Deepika Singh, A. Mahapatra
The distribution of the total water available in various places on the earth is delineated in this paper. This paper discusses various desalination technologies like membrane technology and thermal technology. Membrane technology includes Reverse Osmosis and Nanofiltration, Electrodialysis and Electrodialysis Reversal, whereas thermal technology includes Multi-Stage Flash (MSF) Distillation, Multi-Effect Distillation (MED) Vapour Compression Distillation (VCD). The advantages and disadvantages of all these processes are tabulated. The distribution of various desalination plants worldwide, with their capacities, is given in this paper. The various characteristics, like quality of raw water used, the quality of product water, the capital costs per installed gallon per day and the cost of water produced by using these methods, are also tabulated in this paper. Bhabha Atomic Research Centre (BARC) has installed a large number of desalination plants of various capacities at different places in India using both thermal and membrane technologies.
本文描绘了地球上各地总可用水量的分布。本文讨论了各种脱盐技术,如膜技术和热技术。膜技术包括反渗透和纳滤,电渗析和电渗析反转,而热技术包括多级闪蒸(MSF)蒸馏,多效蒸馏(MED)蒸汽压缩蒸馏(VCD)。所有这些过程的优点和缺点都列在表格中。本文给出了世界上各种海水淡化厂的分布及其生产能力。各种特性,如使用的原水的质量,产品水的质量,每安装加仑每天的资本成本和使用这些方法产生的水的成本,也在本文中列出。Bhabha原子研究中心(BARC)在印度不同的地方安装了大量不同容量的海水淡化厂,使用热和膜技术。
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引用次数: 13
Electrochlorination system: a unique method of prevention of biofouling in seawater desalination 电氯化系统:海水淡化中防止生物污染的独特方法
Pub Date : 2008-09-10 DOI: 10.1504/IJND.2008.020220
R. Thangappan, S. T. Sampathkumaran
Desalination plants require huge volumes of seawater for the generation of fresh water. Seawater contains large amounts of microbiological fluids which, when passed through the piping system, form biofouling in the inner surface of the pipeline, which results in the reduction of the flow rate of water without proper chemical treatment. Chlorine is the most commonly used disinfectant for water treatment applications for the prevention of biofouling. The chlorine is available in many conventional forms, but due to various limitations of the conventional methods, the electrochlorinators that work on the principle of electrolysis are preferred across the globe for seawater inlet system treatment. The electrochlorinator is a simple machine, which produces onsite sodium hypochlorite solution by using only seawater as the raw material. The hypochlorite generated by this unique technology is very safe, environmentally friendly and economical. The equipment is user friendly and operates automatically depending on the need. The process involved in the generation of sodium hypochlorite is a simple electrolysis of seawater. The seawater is made to pass through the electrolysers, which are fitted with dimensionally stable electrodes. When DC power is passed through the electrolysers, the exothermic chemical reaction takes place and sodium chloride in the seawater gets converted into sodium hypochlorite solution (NaOCl).
海水淡化厂需要大量的海水来生产淡水。海水中含有大量的微生物流体,当这些微生物流体通过管道系统时,会在管道内表面形成生物污垢,如果不进行适当的化学处理,就会导致水的流速降低。氯是水处理应用中最常用的消毒剂,用于防止生物污染。氯有许多传统形式,但由于传统方法的各种限制,在电解原理上工作的电氯化器在全球范围内首选用于海水进口系统处理。电氯化器是一种简单的机器,仅以海水为原料就地生产次氯酸钠溶液。通过这种独特的技术生产的次氯酸盐非常安全、环保和经济。该设备是用户友好的,并根据需要自动操作。生成次氯酸钠的过程是对海水进行简单的电解。海水通过配有尺寸稳定电极的电解槽。当直流电通过电解槽时,发生放热化学反应,海水中的氯化钠转化为次氯酸钠溶液(NaOCl)。
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引用次数: 6
Experimental investigation of the effect of ejector geometry on its performance 引射器几何形状对其性能影响的实验研究
Pub Date : 2008-09-10 DOI: 10.1504/IJND.2008.020226
M. Elkady, A. Karameldin, E. Negeed, Ramadan El-Bayoumy
This paper describes the experimental investigation of the performance of the ejector used in desalination applications, using air as the working fluid. The aim of this study is to investigate experimentally the effect of the operating conditions and ejector geometry on the ejector performance. The effect of the relative position of the primary nozzle exit within the mixing chamber on the performance of the ejector is also investigated. The results show that using a convergent?divergent nozzle enhances the performance of the ejector. Also, the ejector performance is improved by decreasing the primary nozzle throat diameter and also by increasing the suction pressure. Moreover, the performance of the ejector is affected by the nozzle position, and the optimum position, which yields a maximum entrainment ratio for all nozzles, is at the inlet of the mixing chamber section of the ejector. As the constant area-mixing length to diameter ratio L/D increases, the entrainment ratio increases. And the increase in the entrainment becomes very small and can be negligible for L/D greater than 7.5. The entrainment ratio increases with increasing primary pressure, and the entrained flow reaches a maximum at a certain primary pressure. Beyond this value, the entrained flow will decrease.
本文介绍了以空气为工作流体的海水淡化用喷射器的性能试验研究。本研究的目的是通过实验研究工作条件和喷射器几何形状对喷射器性能的影响。研究了混合腔内主喷管出口相对位置对喷射器性能的影响。结果表明,使用收敛的?发散式喷管提高了喷射器的性能。此外,通过减小主喷管喉部直径和增加吸压,可以提高喷射器的性能。此外,喷射器的性能受喷嘴位置的影响,最佳位置是喷射器混合室段的入口,所有喷嘴的吸入比都最大。随着等面积混合长径比L/D的增大,夹带比增大。当L/D大于7.5时,夹带的增加变得非常小,可以忽略不计。随着主压力的增加,夹带比增大,在一定的主压力下,夹带流量达到最大值。超过这个值,夹带流量就会减少。
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引用次数: 7
Experience feedback on operation of low-temperature vacuum evaporation-based desalination plant integrated with CIRUS 与CIRUS集成的低温真空蒸发海水淡化装置运行经验反馈
Pub Date : 2008-09-10 DOI: 10.1504/IJND.2008.020218
Rakesh Ranjan, Surinder Kumar, N. Ramesh, R. Sharma
CIRUS is a 40 MWth, heavy water-moderated, light water-cooled and natural uranium-fuelled research reactor located at Trombay, Mumbai. The reactor has been in operation since 1960 with an average availability factor of about 70% for about three decades. During the early 1990s, the reactor exhibited signs of ageing. It was refurbished and put back into operation at high power in 2003. Bhabha Atomic Research Centre (BARC) has been engaged in R&D activities related to desalination. Using low-temperature vacuum evaporation technology, the centre has been studying the possibility of using the waste heat of nuclear reactors for seawater desalination. Based on this know-how, a 30 cu m per day (30 tonnes/day) pilot plant has been designed. With the aim of demonstrating the utilisation of waste heat from research reactor, it was decided to integrate the unit to CIRUS during refurbishing outage of the reactor. The work involved the design, installation and commissioning of a set-up to transfer heat from the primary coolant of CIRUS to the desalination unit through an intermediate demineralised water circuit. The unit has been operated at its rated capacity and its performance has been satisfactory. The product water has been utilised to augment the demineralised water inventory of the primary coolant system. This paper highlights the experience gained during the installation, commissioning and operation of the desalination unit.
CIRUS是一个40兆瓦的重水慢化、轻水冷却和天然铀燃料研究堆,位于孟买的Trombay。该反应堆自1960年以来一直在运行,在大约30年的时间里,平均可用系数约为70%。在20世纪90年代早期,反应堆显示出老化的迹象。2003年,该厂进行了翻新,并大功率投入运行。巴巴原子研究中心(BARC)一直从事与海水淡化相关的研发活动。利用低温真空蒸发技术,该中心一直在研究利用核反应堆废热进行海水淡化的可能性。基于这一技术,设计了一个30立方米/天(30吨/天)的中试工厂。为了展示研究堆余热的利用,决定在反应堆整修停运期间将该装置集成到CIRUS。这项工作包括设计、安装和调试一套装置,将CIRUS主冷却剂的热量通过中间去盐水回路传递到海水淡化装置。该机组已按额定容量运行,运行效果令人满意。产品水已被用来增加初级冷却剂系统的脱盐水库存。本文着重介绍了海水淡化装置在安装、调试和运行过程中所取得的经验。
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引用次数: 0
Potential of carbon nanotubes in water purification: an approach towards the development of an integrated membrane system 碳纳米管在水净化中的潜力:一种开发集成膜系统的方法
Pub Date : 2008-09-10 DOI: 10.1504/IJND.2008.020221
S. Kar, R. C. Bindal, S. Prabhakar, P. K. Tewari, K. Dasgupta, D. Sathiyamoorthy
The problems of water shortages and lack of access to safe drinking water have been and will continue to grow as major global problems. To alleviate these problems, water purification technologies are being updated. Recent years have witnessed impressive breakthroughs towards practical application of nanostructured materials such as Carbon Nanotubes (CNTs) in the field of water purification owing to their unique thermal, electrical and mechanical properties. These nanoscale structures need to be arranged into well-defined configurations in order to build integrated systems with high efficiency (the nanotubes being reusable, whereas the traditional membranes foul easily and require frequent replacements), high flux (owing to the hydrophobic super smooth inner surface of nanotubes), and with improvements in chemical selectivity (through suitable chemical functionalisation of the CNTs), so that the idea of using CNTs in separation technology can be made realistic and the potential benefits of practical application of these unique materials can be exploited. This paper assesses the CNTs as an emerging technology in water purification system, particularly with respect to its potential for the removal of arsenic, fluoride, heavy metals and toxic organic components.
水资源短缺和无法获得安全饮用水的问题已经并将继续成为主要的全球问题。为了缓解这些问题,人们正在更新水净化技术。近年来,碳纳米管等纳米结构材料由于其独特的热学、电学和力学性能,在水净化领域的实际应用取得了令人瞩目的突破。为了构建高效(纳米管可重复使用,而传统膜容易损坏且需要频繁更换)、高通量(由于纳米管的疏水超光滑内表面)和提高化学选择性(通过适当的碳纳米管的化学功能化)的集成系统,这些纳米级结构需要被安排成明确的配置。从而使在分离技术中使用碳纳米管的想法成为现实,并开发这些独特材料实际应用的潜在效益。本文评估了碳纳米管作为水净化系统中的新兴技术,特别是其在去除砷、氟化物、重金属和有毒有机成分方面的潜力。
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引用次数: 19
期刊
International Journal of Nuclear Desalination
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