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Recovery of uranium and vanadium from brine streams and oceans 从盐水溪流和海洋中回收铀和钒
Pub Date : 2009-10-12 DOI: 10.1504/IJND.2009.028860
A. Saxena
Research and technological developments are being pursued vigorously all over the globe to reduce the cost of desalinated water. One approach can be to retrofit 'value addition' by the recovery of uranium and vanadium from reject brine streams. Bench-scale field trials that have been carried out are presented in this paper. Coupling 'uranium recovery' with desalination plants for partly mitigating brine-related environmental issues is an added advantage. The paper describes developmental works since their inception in July 1999, including results from the 100 gpy plant commissioned at Trombay in May 2006.
全世界都在大力进行研究和技术发展,以降低淡化水的成本。一种方法是通过从废弃盐水流中回收铀和钒来改造“增值”。本文介绍了已进行的台架规模的现场试验。将“铀回收”与海水淡化厂结合起来,在一定程度上减轻了与盐水有关的环境问题,这是一个额外的优势。该文件描述了自1999年7月启动以来的发展工作,包括2006年5月在特罗姆贝投入使用的100千兆瓦核电站的结果。
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引用次数: 1
A study on the distribution coefficient of iodide ions from aqueous solution on some strongly basic anion exchange resins 水溶液中碘离子在强碱性阴离子交换树脂上分布系数的研究
Pub Date : 2009-10-12 DOI: 10.1504/IJND.2009.028865
P. Singare, R. Lokhande, S. Parab, A. Patil
The ion exchange resins Duolite A-116, Indion 830 Type-1 and Indion N-IP Type-2 in iodide form were equilibrated separately with labelled radioactive iodide ion solutions of different concentrations varying from 0.005 M to 0.020 M in the temperature range of 25.0°C to 40.0°C. The Kd values of iodide ions for Duolite A-116 and Indion N-IP Type-2 were higher than that for Indion 830 Type-1 under identical experimental conditions. The difference in the Kd values of iodide ions for the three resins was mainly because of the swelling pressure, which depends on their water-holding capacities.
离子交换树脂Duolite A-116、Indion 830 Type-1和Indion N-IP Type-2分别在25.0℃~ 40.0℃的温度范围内与不同浓度(0.005 ~ 0.020 M)的放射性碘离子溶液进行平衡。在相同的实验条件下,Duolite A-116和N-IP型-2的碘离子Kd值高于型-1。三种树脂的碘离子Kd值的差异主要是由于膨胀压力,这取决于它们的持水能力。
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引用次数: 1
A global overview on nuclear desalination 核脱盐的全球概况
Pub Date : 2009-10-12 DOI: 10.1504/IJND.2009.028859
I. Khamis
Nuclear desalination is considered one of the viable sources of producing the fresh water needed in arid areas. Nowadays, several countries have shown interest in the use of nuclear energy for seawater desalination, because recent studies have demonstrated that nuclear desalination is not only feasible but also economical, and this has already been demonstrated in several countries. Although the future requires the effective integration of energy resources to produce power and desalinated water economically with proper consideration for the environment, the significant increase in fuel energy cost and material cost has resulted in a dramatic impact on the capital and operational costs of desalination and power plants. The impact of any increase in the price of fossil fuels (as in the case before mid-2008) and the high demand for raw materials (e.g., steel, copper, nickel) will increase the pressure to develop novel solutions to minimise fossil energy consumption and reduce the capital expenditure of desalination plants. This, in turn, is causing a renewed global interest in nuclear energy. However, nuclear desalination may face some challenges, among which are public perception, financing, the transfer of nuclear technology and considerations for the safety of the coupling options selected.
核脱盐被认为是生产干旱地区所需淡水的可行来源之一。目前,有几个国家对利用核能进行海水淡化表现出兴趣,因为最近的研究表明,核淡化不仅可行,而且经济,这已经在几个国家得到了证明。虽然未来需要有效整合能源资源,经济地生产电力和淡化水,并适当考虑环境,但燃料能源成本和材料成本的显著增加导致海水淡化和发电厂的资金和运营成本受到巨大影响。化石燃料价格的任何上涨(如2008年中期之前的情况)和对原材料(如钢铁、铜、镍)的高需求的影响将增加开发新解决方案的压力,以最大限度地减少化石能源消耗和减少海水淡化厂的资本支出。这反过来又引起了全球对核能的新一轮兴趣。然而,核脱盐可能面临一些挑战,其中包括公众认知、融资、核技术转让以及所选耦合方案的安全性考虑。
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引用次数: 16
Carbon nanotube membrane for water desalination 用于海水淡化的碳纳米管膜
Pub Date : 2009-10-12 DOI: 10.1504/IJND.2009.028863
H. Raval, J. Gohil
This is a review of carbon nanotube membranes with an emphasis on their water desalination applications. Particular attention is given to carbon nanotube preparation, types and properties. The concept of desalination in the context of carbon nanotubes is discussed. The different processes for the manufacture of carbon nanotube membranes are electric arc discharge, laser ablation and Chemical Vapour Deposition (CVD). Out of these, the CVD method is widely used because of its certain characteristics. Different types of carbon nanotubes, such as aligned carbon nanotubes, Multiwalled Carbon Nanotube (MWNT)/active carbon combination electrodes, MWNT/polysulfone (PS) blend membranes, carbonised hot-pressed carbon nanotube electrodes, aligned carbon nanotubes, alumina-supported carbon nanotubes and ceria nanoparticles-supported carbon nanotubes, are discussed with their application and performance. While the research in this area is in its infancy, it is growing at a considerable pace. The challenges to this technology are the reduction in capital cost, understanding of the exact mechanism for water transport, and scale-up. This technology has a potential to replace state-of-the-art desalination technology based on polymeric membranes or thermal desalination.
本文综述了碳纳米管膜的研究进展,重点介绍了其在海水淡化中的应用。重点介绍了碳纳米管的制备、类型和性能。在碳纳米管的背景下讨论了海水淡化的概念。制备碳纳米管膜的工艺有电弧放电、激光烧蚀和化学气相沉积。其中,CVD法因其具有一定的特性而得到广泛应用。讨论了排列碳纳米管、多壁碳纳米管/活性炭复合电极、多壁碳纳米管/聚砜共混膜、碳化热压碳纳米管电极、排列碳纳米管、氧化铝负载碳纳米管和氧化铈纳米颗粒负载碳纳米管等不同类型的碳纳米管的应用和性能。虽然这一领域的研究还处于起步阶段,但它正以相当快的速度发展。该技术面临的挑战是降低资本成本,了解水运的确切机制,以及扩大规模。这项技术有可能取代基于聚合物膜或热脱盐的最先进的脱盐技术。
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引用次数: 14
Behaviour of radioactive iodine and bromine from aqueous solutions on the ion-exchange resin Duolite A-113 水溶液中放射性碘和溴在离子交换树脂Duolite A-113上的行为
Pub Date : 2009-10-12 DOI: 10.1504/IJND.2009.028864
P. Singare, R. Lokhande, M. Dole
The iodide and bromide forms of the ion exchange resin Duolite A-113 were equilibrated separately with respectively labelled iodide and bromide ion solutions of different concentrations, varying from 0.005 M to 0.100 M in the temperature range of 26.0°C to 43.0°C. The distribution coefficient Kd values calculated for iodide and bromide ion exchanges increase with the ionic concentration of the external solution; however, with a rise in temperature, the Kd values calculated were found to decrease. Also, the Kd values were higher for iodide exchanges than for bromide exchanges.
在26.0℃~ 43.0℃的温度范围内,分别用不同浓度(0.005 M ~ 0.100 M)的碘化和溴化离子溶液对离子交换树脂Duolite A-113的碘化和溴化形态进行了平衡。碘化物和溴化物离子交换的分配系数Kd值随着外溶液离子浓度的增加而增加;然而,随着温度的升高,计算得到的Kd值减小。同时,碘离子交换的Kd值高于溴离子交换的Kd值。
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引用次数: 0
Enhancement of ejector performance for a desalination system 海水淡化系统喷射器性能的提高
Pub Date : 2009-04-02 DOI: 10.1504/IJND.2009.024335
E. Negeed
This paper describes the use of Computational Fluid Dynamics (CFD) to investigate the performance of the ejector used in desalination applications that use air as the working fluid. A three-dimensional model for the CFD was used to investigate the effect of operating conditions and ejector geometry on ejector performance. The results show that ejector performance increases by increasing the primary nozzle throat diameter and the entrained flow reaches a maximum at a certain diameter; beyond this value, the entrained flow will decrease. Also, the entrainment ratio increases with an increasing suction pressure. Moreover, the results determine the optimum position with respect to the ejector's mixing chamber, which yields a maximum entrainment ratio. Also, the results determine the optimum constant area mixing length to diameter (L/D) ratio, which yields a maximum ejector performance. As this ratio increases, the entrainment ratio increases. Besides, the increase in entrainment becomes very small and can be neglected for an L/D ratio greater than 7.5. Also, for the high value of the primary pressure, constructing the constant area mixing section through multichannel tubes enhances ejector performance. A comparison between the present results and experimental results from other researchers gave a good agreement between them.
本文介绍了用计算流体动力学(CFD)来研究以空气为工作流体的海水淡化应用中喷射器的性能。采用三维CFD模型研究了工作条件和喷射器几何形状对喷射器性能的影响。结果表明:随着主喷管喉部直径的增大,引射器的性能有所提高,在一定的喉部直径下引射流量达到最大值;超过这个值,夹带流量就会减少。吸入压力越大,吸入比越高。此外,结果确定了相对于喷射器混合室的最佳位置,从而产生最大的夹带比。结果还确定了最佳的等面积混合长径比(L/D),从而获得最大的喷射器性能。随着这个比率的增加,夹带比也随之增加。此外,夹带的增加变得非常小,当L/D比大于7.5时可以忽略。同时,在一次压力较大的情况下,通过多道管构造等面积混合段可以提高喷射器的性能。本文的结果与其他研究人员的实验结果相比较,两者吻合得很好。
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引用次数: 5
An experimental study on the electroforming of ternary Ni-Co-Mn alloy 电铸镍钴锰三元合金的实验研究
Pub Date : 2009-04-02 DOI: 10.1504/IJND.2009.024339
Tee-Yuan Chen, Dau-Chung Wang
The goal of this research is to develop a new additive for Ni-Co-Mn ternary alloy electroforming. Under the new recipe, we can control the composition of Ni-Co-Mn, and prove that electroformed ternary Ni-Co-Mn alloy has better mechanical properties than electroformed Ni-Co alloy. This paper also discusses the effect of the Mn concentration on the resulting mechanical properties of electroformed Ni-Co-Mn alloy.
本研究的目的是开发一种用于镍钴锰三元合金电铸的新型添加剂。在新配方下,我们可以控制Ni-Co- mn的组成,并证明电铸三元Ni-Co- mn合金比电铸Ni-Co合金具有更好的力学性能。讨论了Mn浓度对电铸Ni-Co-Mn合金力学性能的影响。
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引用次数: 1
Fabrication of 4500 cu.m/day MSF plant equipment 制造4500立方米。m/day MSF工厂设备
Pub Date : 2009-04-02 DOI: 10.1504/IJND.2009.024337
M. Chandrasekhar, K. G. Shivale, M. D. Nair, S. Shivayyanamath, V. Srivastava
The 4500 M³/day Multistage Flash (MSF) plant fabrication is nearing completion in Kalpakkam, India. This includes in total the fabrication of brine heater, deaerator, vacuum system consisting of steam jet ejector and condensers, process tanks, pumps, piping system and ten rectangular vessels meant for heat recovery and heat rejection in the MSF desalination process. This paper describes the various stages of fabrication using many efficient, similar and dissimilar metal weld joints.
位于印度Kalpakkam的这个4500立方米/天的多级闪蒸(MSF)工厂即将完工。这包括盐水加热器、除氧器、由蒸汽喷射器和冷凝器组成的真空系统、工艺罐、泵、管道系统和用于MSF脱盐过程中热回收和热排除的十个矩形容器的制造。本文描述了使用许多高效的、相似的和不同的金属焊接接头的制造的各个阶段。
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引用次数: 0
Heat transfer enhancement of falling film evaporation on a horizontal tube bundle 水平管束降膜蒸发强化传热
Pub Date : 2009-04-02 DOI: 10.1504/IJND.2009.024338
M. M. Awad, E. Negeed
The enhancement of the evaporation heat transfer coefficient is important for the design and operation of horizontal tube spray film evaporators. The water spray on a horizontal tube bundle is numerically studied in steady state conditions. The objective of the present work is to numerically study the effect of the tube configuration and the operating conditions on the evaporation heat transfer coefficient. In addition, the enhancement of the evaporation rate ratio by constructing a water collector around the bottom-heated tube is also numerically studied. In order to evaluate the evaporation rate ratio and the heat transfer coefficient of the falling liquid film on the horizontal tube bundle, the nondimensional governing equations of the mass, momentum and energy of the created liquid film around the hot tube surface are solved numerically using the finite difference method. The results show that the evaporation rate ratio is mainly increased by increasing both the surface temperature and the tube's outer diameter. The evaporation rate ratio enhances by decreasing the chamber pressure and inlet liquid subcooling. The falling distance has little influence on the evaporation rate ratio. Moreover, constructing a water collector around the bottom-heated tube enhances the evaporation rate ratio. The increase in the evaporation rate ratio increases by higher heat flux and also by larger the gap between the collector and the tube surface.
提高蒸发换热系数对水平管喷雾膜蒸发器的设计和运行具有重要意义。对稳态条件下水平管束上的水雾进行了数值研究。本文的目的是数值研究管型和操作条件对蒸发换热系数的影响。此外,还对在底加热管周围设置集水器对蒸发速率比的提高进行了数值研究。为了计算水平管束上下降液膜的蒸发速率比和传热系数,采用有限差分法对热管表面周围形成的液膜的质量、动量和能量的无量纲控制方程进行了数值求解。结果表明:增加表面温度和增大管外径是提高蒸发速率比的主要途径;通过降低腔室压力和进口液体过冷度来提高蒸发速率比。下落距离对蒸发速率比影响不大。此外,在底部加热管周围设置集水器可以提高蒸发速率比。随着热流密度的增大和集热器与管表面间隙的增大,蒸发速率比的增大也随之增大。
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引用次数: 8
Evaluation of the efficiency of polysulfone ultrafiltration membrane-based water purifiers for microbiological decontamination 聚砜超滤膜净水器微生物去污效能评价
Pub Date : 2009-04-02 DOI: 10.1504/IJND.2009.024336
V. Nagar, R. Shashidhar, Arun Sharma, J. Bandekar, R. C. Bindal, S. Prabhakar, P. K. Tewari
Indigenously developed polysulfone Ultrafiltration (UF) membrane-based domestic and industrial water purification units were evaluated for their ability to filter bacteria and viruses from water. Escherichia coli (105 cfu/ml) and P1 phage (106 pfu/ml) were filtered through a Domestic Water Purifier (DWP) (dead-end UF unit) and a large-scale spiral water purifier (cross-flow UF unit) and the filtrates were analysed for bacterial and phage counts. Both units were found to be efficient in the complete removal of E. coli and a 99.99% removal of the P1 phage was observed. Both the domestic and industrial water purifiers are highly efficient in the removal of bacteria and viruses. UF membranes were also characterised for Molecular Weight Cut-Off (MWCO) by the polyethylene glycol and polyethylene oxide methods, which showed that MWCO was 60–65 kDa. These MWCO results were further validated using the Bovine Serum Albumin (BSA) rejection behaviour of these membranes, which showed about 90% rejection. The technique involving the estimation of MWCO, coupled with the rejection characteristics of E. coli and P1 phage, provides an excellent tool to evaluate the efficiency of water purifiers based on UF membrane technology.
对国产聚砜超滤(UF)膜为基础的家用和工业净水装置对水中细菌和病毒的过滤能力进行了评价。大肠杆菌(105 cfu/ml)和P1噬菌体(106 pfu/ml)分别通过家用净水器(DWP)(终端UF装置)和大型螺旋净水器(交叉流UF装置)过滤,并对滤液进行细菌和噬菌体计数分析。这两种装置都能有效地完全去除大肠杆菌,并观察到P1噬菌体的去除率为99.99%。家用和工业用净水器都能高效去除细菌和病毒。用聚乙二醇和聚氧化物对超滤膜进行了分子量切断(MWCO)表征,MWCO为60-65 kDa。利用这些膜的牛血清白蛋白(BSA)排斥行为进一步验证了这些MWCO结果,其排斥率约为90%。该技术结合大肠杆菌和P1噬菌体的拒斥特性,为UF膜技术净水器的效率评估提供了一个很好的工具。
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引用次数: 0
期刊
International Journal of Nuclear Desalination
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