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Nanotechnology for water purification 纳米技术用于水净化
Pub Date : 2010-07-01 DOI: 10.1504/IJND.2010.033766
F. Valli, Karishma Tijoriwala, A. Mahapatra
This paper provides an overview of the different water treatment devices that incorporate nanotechnology. New sensor technology combined with micro and nanofabrication technology is expected to lead to small, portable and highly accurate sensors to detect chemical and biochemical parameters in water. Potential opportunities and risks associated with this technology are also highlighted.
本文概述了采用纳米技术的不同水处理设备。新型传感器技术与微纳米加工技术相结合,有望产生小型、便携式和高精度的传感器,用于检测水中的化学和生化参数。与该技术相关的潜在机会和风险也得到了强调。
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引用次数: 7
Recovery and pre-concentration of uranium from secondary effluent using novel resin 新型树脂回收和预富集二次出水中的铀
Pub Date : 2010-07-01 DOI: 10.1504/IJND.2010.033764
Sangita Pal, S. Satpati, K. N. Hareendran, Sanjukta A. Kumar, K. L. Thalor, S. Roy, P. K. Tewari
The act of enrichment or improving the quality of product concentration, i.e. 'pre-concentration', has been studied with respect to uranium plant effluent, which contains uranium in 10?30 ppm level intermingled with a huge number of interfering ions, such as magnesium, in percent level. The effects of different operating conditions, such as concentration of uranium in the effluent, pH, the time required for uptake of uranium and the effect of the presence of other elements in the effluent, in batch experiments have been investigated. Using this in-house novel resin for preferential uranium uptake, the sorbed matrix has been eluted with different eluant concentration for further enrichment of radionuclides in the elute. High uptake values for uranium ions prove its selectivity, and fractional elution ensures further reuse of sorbent and significant improvement in uranium enrichment.
浓缩或提高产品浓缩质量的行为,即:对铀厂排出物进行了"预浓缩"研究,其中含有10?30 PPM水平与大量干扰离子,如镁,以百分比水平混合。在间歇式实验中,研究了不同操作条件的影响,如出水中铀的浓度、pH值、吸收铀所需的时间以及出水中存在的其他元素的影响。利用这种内部新型树脂对铀的优先吸收,吸附的基质被不同浓度的洗脱液洗脱,以进一步富集洗脱液中的放射性核素。对铀离子的高吸收值证明了其选择性,分级洗脱确保了吸附剂的进一步再利用和铀浓缩的显着改善。
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引用次数: 10
Effect of functionalisation on polysulfone-based ultrafiltration membranes 功能化对聚砜基超滤膜的影响
Pub Date : 2010-07-01 DOI: 10.1504/IJND.2010.033763
S. Raj, S. Rajesh, K. Lakshmi, K. Shobana, D. Mohan
Polysulfone membranes possess excellent mechanical, biological and chemical stability but they suffer from fouling which leads to flux decline. Fouling can be minimised by functionalisation. In an attempt to overcome this limitation, the polysulfone was both sulphonated and carboxylated. The presence of sulphonic and carboxylic groups was confirmed through IR and NMR studies. Incorporation of sulphonic and carboxylic groups in the polymeric chain increases the hydrophilic nature of the membrane as well as the thermal stability, chemical tolerance, mechanical strength, etc. It was observed that the Pure Water Flux (PWF) value of CPSf was greater than that of SPSf and PSf. The actual angle of inclination of the two rings depends on the nature and number of substituent groups. In CPSf the angle of inclination of the two rings is higher than in SPSf. This results in the chains moving apart from each other in the case of CPSf, which could explain its higher flux.
聚砜膜具有良好的机械稳定性、生物稳定性和化学稳定性,但易受污染而导致通量下降。通过功能化可以最大限度地减少污垢。为了克服这一限制,聚砜被磺化和羧化。通过红外和核磁共振研究证实了磺酸基和羧基的存在。在聚合链中加入磺酸基和羧基,增加了膜的亲水性,以及热稳定性、耐化学性、机械强度等。观察到CPSf的纯水通量(PWF)值大于SPSf和PSf。两个环的实际倾斜角取决于取代基的性质和数量。在CPSf中,两个环的倾角比SPSf大。在CPSf的情况下,这导致链相互远离,这可以解释其更高的通量。
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引用次数: 1
Sustainable desalination technologies for future 未来可持续的海水淡化技术
Pub Date : 2010-07-01 DOI: 10.1504/IJND.2010.033765
B. Misra
This paper deals with some aspects concerning the dual objectives of cost-effectiveness and favourable environmental impact of desalination plants, resulting in a sustainable alternative source of fresh water for future needs. These include some case studies on the use of waste heat for the thermal desalination plants, replacement of conventional pre-treatments in membrane plants with cleaner processes, deployment of hybrid desalination systems and use of non-fossil fuel sources for both types of desalination plant. In particular, the role of nuclear and renewable energy sources (wind and solar) has been examined. The environmental impact of the desalination processes has been discussed and benefits from suggested technologies under CDM have been outlined. With the current environmental concerns, it is desirable to consider use of alternate energy sources for desalination, even though at present these appear not that economical. They may become so once credit for clean energy is available. A real breakthrough in development of near ideal membranes will of course go a long way in desalination economics. Efforts need to be continued in this area.
本文讨论有关海水淡化厂的成本效益和有利环境影响的双重目标的一些方面,从而为未来的需要提供可持续的替代淡水来源。其中包括对热海水淡化厂使用废热的一些案例研究,用更清洁的工艺取代膜厂的传统预处理,部署混合海水淡化系统以及在两种类型的海水淡化厂使用非化石燃料来源。特别审查了核能和可再生能源(风能和太阳能)的作用。讨论了海水淡化过程对环境的影响,并概述了清洁发展机制下建议技术的好处。鉴于目前的环境问题,考虑使用替代能源进行海水淡化是可取的,尽管目前看来这些能源并不那么经济。一旦清洁能源获得信贷,它们可能会变得如此。在接近理想膜的开发上取得真正的突破,当然会对海水淡化经济学有很大的帮助。在这方面需要继续作出努力。
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引用次数: 4
Enhancement of the performance of the vapour compression plant 提高蒸汽压缩装置的性能
Pub Date : 2010-07-01 DOI: 10.1504/IJND.2010.033770
E. Negeed
The objective of the present work is to study the performance of ejector vapour compression desalination plant with water spray on horizontal tube bundles. The effects of the operating conditions and the ejector geometry on the total distilled collected water are studied. The amount of evaporation rate due the flash evaporation is calculated by applying the mass and energy of the sprayed water governing equations. The evaporation rate of the falling liquid film around the horizontal tube bundles is evaluated by the non-dimensional mass, momentum and energy equations solved numerically using the finite difference method. The results presented the effect of the change in evaporation pressure, inlet liquid temperature, hot surface heat flux and inlet sprayed mass flow rate. Also, the results determine the effect of the ejector geometry, motive steam temperature, evaporator temperature and the compression ratio across the evaporator on the performance of the vapour compression plant.
本文研究了水平管束喷水喷射式蒸汽压缩海水淡化装置的性能。研究了操作条件和喷射器几何形状对总蒸馏集水量的影响。利用喷淋水的质量和能量控制方程,计算了闪蒸引起的蒸发速率。利用有限差分法数值求解的无因次质量、动量和能量方程,计算了水平管束周围下降液膜的蒸发速率。结果表明,蒸发压力、进口液体温度、热表面热流密度和进口喷射质量流量的变化对喷油效果的影响。此外,研究结果还确定了喷射器几何形状、动力蒸汽温度、蒸发器温度和蒸发器间压缩比对蒸汽压缩装置性能的影响。
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引用次数: 1
Experimental study of falling film evaporation on horizontal tube bundle for a desalination unit 淡化装置水平管束降膜蒸发实验研究
Pub Date : 2010-07-01 DOI: 10.1504/IJND.2010.033762
E. Negeed, M. M. Awad
The objective of the present research is to experimentally study the effect of the tube configuration and also the effect of the operating conditions on the evaporation rate of the horizontal tube bundle. An experimental test loop was installed and the water spray on a horizontal tube bundle with three nozzles of fan-jet flat nozzle type. The results show that evaporation rate and Nusselt number are increased by increasing the tube surface temperature, increasing the tube's outer diameter, decreasing the evaporation pressure and decreasing the inlet liquid sub-cooling. The falling distance has little influence on the evaporation rate. Constructing water collector around the bottom-heated tubes enhances the evaporation rate. Also, increasing the gap between the water collector and the outer tube surface, from 0.0 to 4.0 mm, results in increasing the evaporation rate. An empirical correlation has been deduced describing the relation between the average heat transfer coefficient and the affecting operating parameters.
本研究的目的是实验研究管的结构和操作条件对水平管束蒸发速率的影响。在水平管束上安装了一个实验测试回路,采用三喷嘴的风机-射流平面喷嘴进行喷水。结果表明:提高管表面温度、增大管外径、减小蒸发压力和减小进口液体过冷度均能提高蒸发速率和努塞尔数;下落距离对蒸发速率影响不大。在底加热管周围设置集水器,提高了蒸发速率。此外,增加集水器与外管表面之间的间隙,从0.0 mm增加到4.0 mm,导致蒸发速率增加。推导了平均换热系数与影响运行参数之间的经验相关关系。
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引用次数: 4
Development of antifouling ultrafiltration membranes by surface modification 表面改性防污超滤膜的研制
Pub Date : 2010-07-01 DOI: 10.1504/IJND.2010.033767
K. Shobana, R. Ramya, D. Mohan
Poly(vinylidene fluoride) (PVDF) membranes were prepared by phase inversion technique. The effects of polystyrene (PS) concentrations on the blend membrane performance were investigated. The membranes were characterised in terms of shrinkage ratio, pure water flux, and porosity. The hydrophobicity of the membrane was modified by poly(vinyl alcohol) (PVA) through adsorption and crosslinking. The performance of the modified membrane was investigated for its antifouling property with BSA solution. 70/30wt% blend PVDF/PS blend membrane showed better antifouling property than other membranes owing to its high hydrophilic property incorporated by adsorption crosslinking of PVA on to the membrane.
采用相转化法制备了聚偏氟乙烯(PVDF)膜。研究了聚苯乙烯(PS)浓度对共混膜性能的影响。膜的收缩率、纯水通量和孔隙率进行了表征。用聚乙烯醇(PVA)通过吸附和交联对膜的疏水性进行了改性。研究了改性膜在BSA溶液中的防污性能。70/30wt%共混PVDF/PS共混膜通过吸附交联PVA而具有较高的亲水性,其防污性能优于其他膜。
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引用次数: 0
Experiences with the seawater reverse osmosis plant at the Kudankulam nuclear power plant 库丹库拉姆核电站海水反渗透装置的经验
Pub Date : 2009-10-12 DOI: 10.1504/IJND.2009.028862
C. Balasubramanian, P. Selvavinayagam, S. Singaravelan, R. Ramdoss, R. Sundar
The Seawater Reverse Osmosis Plant (SWROP) of the Kudankulam nuclear power plant is located at Anuvijay township, Chettikulam, Tirunelveli District, Tamil Nadu. The objective is to produce 2400 M³ of potable water per day. The plant consists of four streams, each having a capacity of 25 M³/h. Each stream has nine pressure tubes in parallel and each pressure tube has six polyamide spiral-wound membranes in series.
库丹库拉姆核电站的海水反渗透厂(SWROP)位于泰米尔纳德邦蒂鲁内尔韦利区切蒂库拉姆的Anuvijay镇。目标是每天生产2400立方米的饮用水。该装置由四条溪流组成,每条溪流的容量为25立方米/小时。每个流有九个平行的压力管,每个压力管有六个聚酰胺螺旋缠绕膜串联。
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引用次数: 1
Practical Application of the RUTA Safe Pool-type Nuclear Reactor to Demonstrate the Advantages of Atomic Energy Use RUTA安全池型核反应堆的实际应用,展示原子能利用的优势
Pub Date : 2009-10-12 DOI: 10.1504/IJND.2009.028867
A. Romenkov
The concept of the RUTA water-cooled, water-moderated pool-type nuclear reactor is presented. The basic findings of the RUTA-70 pilot district-heating plant in the science town of Obninsk, Kaluga Region, Russia, and its capabilities for nuclear technology research purposes, are shown. The basic technical data of the reactor facility are presented and its design is described in brief. The potential of using low-grade heat in the town's heating networks is shown. The technical aspects of using the reactor's thermal power in a thermal seawater desalination facility are considered. Issues related to the application of the nuclear reactor as a neutron source for implementing modern nuclear technologies are discussed.
提出了RUTA水冷、水慢化池型核反应堆的概念。图中展示了俄罗斯卡卢加地区奥布宁斯克科学城RUTA-70试点区域供热厂的基本成果及其用于核技术研究目的的能力。介绍了该反应堆设施的基本技术资料,并简要介绍了其设计。展示了在城镇供暖网络中使用低品位热量的潜力。考虑了在热海水淡化设施中使用反应堆热电的技术方面。讨论了应用核反应堆作为中子源实施现代核技术的有关问题。
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引用次数: 2
The role and importance of nuclear desalination 核脱盐的作用和重要性
Pub Date : 2009-10-12 DOI: 10.1504/IJND.2009.028861
A. Barak
Desalination needs energy and saline water as the process raw material. The desalination process where the needed energy is generated by nuclear sources and/or the saline water is supplied from a nuclear installation, such as cooling water from the power unit, is usually called nuclear desalination. Comparing nuclear desalination with alternative water sources in general and to nonnuclear desalination in particular is the main goal of this paper. There are, obviously, advantages and drawbacks for nuclear desalination compared with the alternatives. Projects where those advantages are prominent under site-specific conditions will of course favour nuclear desalination. The following presentation describes the details of the above-stated generality covering these advantages and drawbacks and referring to the potential cases that will justify using nuclear desalination.
海水淡化需要能源和咸水作为工艺原料。由核源产生所需能量和/或由核设施(如动力装置的冷却水)提供盐水的脱盐过程通常被称为核脱盐。本文的主要目的是将核脱盐与替代水源进行比较,特别是与非核脱盐进行比较。显然,与其他替代方法相比,核脱盐有优点也有缺点。在特定场地条件下,这些优势突出的项目当然会青睐核脱盐。下面的介绍详细介绍了上述概述,涵盖了这些优点和缺点,并提到了使用核脱盐的潜在案例。
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引用次数: 4
期刊
International Journal of Nuclear Desalination
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