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2006 IEEE Conference on Electrical Insulation and Dielectric Phenomena最新文献

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Change in Heat Resistive, Electrical Insulating and Mechanical Properties of Hybrid Made with PDMS and TEOS for the Mole Ratio of Them PDMS和TEOS的摩尔比对其耐热性、电绝缘性和力学性能的影响
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.312061
T. Oakamoto, T. Shindou, M. Sugiura, S. Nakamura
Heat resistive, electrical insulating and mechanical properties of hybrids made with polydimethylsiloxane (PDMS) and tetraethoxysilane (TEOS) through the sol-gel reaction method have been studied by changing the mole ratio of TEOS to PDMS. It has been found that the weight loss of the hybrids is less than 3 % regardless of the mole ratio after ageing at 200 degC for 480 h in air. The expected weight loss of the hybrids after ageing for 20,000 h at 200 degC is less than 7 %. It has been found that the elastic modulus and the stress at break of the hybrids increases with increasing the mole ratio. Those mechanical properties are improved after the ageing because of further dehydration and condensation polymerization reactions through the ageing. The volume resistivity decreases and the dielectric loss tangent increases with increasing the mole ratio. Even at the mole ratio of 10, the resistivity is in the order of 1013 ohm-m at room temperature. Relative permittivity and AC dielectric breakdown strength of the hybrids are about 3 and 25 kV/mm. respectively. After the ageing, increases of volume resistivity, relative permittivity and a decrease of dielectric loss tangent of the hybrids have been observed and AC breakdown strength of them shows little change. It has been concluded that the hybrid made with TEOS and PDMS has the potential of a higher heat resistive insulating material.
通过改变聚二甲基硅氧烷(PDMS)和四乙氧基硅烷(TEOS)的摩尔比,研究了溶胶-凝胶反应法制备的聚二甲基硅氧烷(PDMS)和四乙氧基硅烷(TEOS)杂化材料的耐热性、电绝缘性和力学性能。结果表明,无论摩尔比如何,在200℃空气中老化480 h后,杂种材料的失重率均小于3%。在200℃下老化20,000小时后,杂种的预期重量损失小于7%。结果表明,随着摩尔比的增大,杂化材料的弹性模量和断裂应力均增大。由于在老化过程中发生了进一步的脱水和缩聚反应,这些机械性能在老化后得到了改善。随着摩尔比的增大,体积电阻率减小,介质损耗正切增大。即使在摩尔比为10时,室温下的电阻率也在1013 ω -m数量级。混合材料的相对介电常数和交流介电击穿强度分别为3和25 kV/mm。分别。老化后,杂化材料的体积电阻率、相对介电常数升高,介质损耗正切线减小,交流击穿强度变化不大。结果表明,TEOS与PDMS复合材料具有成为高耐热绝缘材料的潜力。
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引用次数: 1
Impact of the polymerization process on the electrical behavior of different impregnation varnishes 聚合工艺对不同浸渍清漆电性能的影响
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.312035
F. Aymonino, T. Lebey, D. Malec, C. Petit, J. Saint Michel, A. Anton
The machine thermal class is the main dimensioning factor for the insulating materials. Three main categories of insulation may be distinguished in rotating machines: namely turn to turn, turn to ground and phase to phase insulation. Nevertheless, most of the data available are given at room temperature. Little is known on their behavior versus the temperature. A better knowledge of these materials appears therefore necessary. In this paper, electrical characterizations are performed on turn to turn insulation materials. Formettes samples are realized. The enamel wire is the same for all the samples under study but different impregnation resins and the polymerization processes and mechanisms are envisaged. Conduction current measurements versus the type of impregnation varnish are presented and discussed. Changes in both transient and steady-state currents are studied versus temperature (up to 200 degC). Since most of the varnishes are synthesized with similar polymers but following different polymerization routes, the differences may been attributed to the polymerization process. Huge values of the conduction currents are measured at high temperature and are directly related to the chemistry of the polymerization process.
机器热等级是决定绝缘材料尺寸的主要因素。旋转机械的绝缘可分为三大类:即匝对匝、匝对地和相对相绝缘。然而,大多数可用的数据都是在室温下给出的。人们对它们在温度下的行为知之甚少。因此,有必要更好地了解这些材料。本文对匝间绝缘材料进行了电学表征。实现了Formettes样品。所研究的所有样品的漆包线都是相同的,但设想了不同的浸渍树脂和聚合工艺和机理。介绍并讨论了不同浸渍清漆类型下的传导电流测量。瞬态和稳态电流随温度(高达200摄氏度)的变化进行了研究。由于大多数清漆是由类似的聚合物合成的,但遵循不同的聚合路线,这些差异可能归因于聚合过程。在高温下测量的传导电流的巨大值与聚合过程的化学性质直接相关。
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引用次数: 2
Improved condition assessment of XLPE insulated cables using the isothermal relaxation current technique 用等温松弛电流法改进交联聚乙烯绝缘电缆的状态评定
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.311973
B. Oyegoke
Well-known procedures using the isothermal relaxation current method (IRC) use an empirically-derived ageing factor (the A-factor) to estimate the condition of cables. The A-factor is calculated from plots of the product of instantaneous value of IRC and the time to that value from the start of the current, against the log of time. A-factors are computed from a standard formula using constants determined from curve fits of measured depolarization currents. From measurements of the breakdown strength of samples of real and degraded cables it has been found that A-factors do not provide reliable estimates of XLPE cable condition. However, if semi-conducting material of the cable insulation is known and cables are classified according to semi-conducting material type it is possible to get better correlation between conditions of cables as indicated by A-factors and AC breakdown voltage. This paper contains a novel analysis of result from previous researcher and also includes result from tests on other cables. The refined procedure is found to give reasonable value of A-factor for all cable tested.
众所周知,使用等温松弛电流法(IRC)的程序使用经验推导的老化因子(a因子)来估计电缆的状态。a因子是根据IRC的瞬时值与从电流开始到该值的时间的乘积图与时间的对数来计算的。a因子由标准公式计算,使用由测量的去极化电流曲线拟合确定的常数。通过对真实电缆和退化电缆试样的击穿强度测量,发现a因子不能提供可靠的交联聚乙烯电缆状态估计。但是,如果知道电缆绝缘的半导体材料,并根据半导体材料类型对电缆进行分类,则可以得到a因子所表示的电缆状况与交流击穿电压之间更好的相关性。本文包含了前人研究结果的新分析,也包括了其他电缆的测试结果。改进后的方法对所有电缆的a系数都给出了合理的值。
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引用次数: 5
Dielectric response of SRBP as a function of oil and oil/moisture absorption. SRBP的介电响应随油和吸湿率的变化。
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.312037
M.A. Brown, S. Dodd, B. Ahern, J. Pettinger, F. Waite
Although insulation based on synthetic resin bonded paper (SRBP) is regarded as an old technology, insulation systems based on this material are still used within the electrical power industry. Much of these are coming to the end of their expected 40 year asset life and techniques for assessing the condition need to be developed such that an effective replacement strategy can be put in place. In this paper, dielectric spectroscopy is to be used to characterize the condition of SRBP. The dielectric response of synthetic resin bonded paper (SRBP) as a function of oil content, and oil plus absorbed moisture is presented over the temperature range 30 degC to 60 degC, and frequency range 5 mHz to 100 kHz. The spectra will be analysed using the Havriliak and Negami semi-empirical form of the Debye dispersion relations, (including a conduction term). The temperature and moisture dependence of the conduction will be discussed, and the relaxation times (tau) for the dispersion mechanisms will then be evaluated for the range of temperatures used
尽管基于合成树脂粘合纸(SRBP)的绝缘被认为是一种古老的技术,但基于这种材料的绝缘系统仍在电力工业中使用。其中大部分设备的预期寿命为40年,因此需要开发评估设备状况的技术,以便制定有效的更换策略。本文将利用介电光谱来表征SRBP的状态。在温度30℃~ 60℃,频率5 mHz ~ 100 kHz范围内,研究了合成树脂粘接纸(SRBP)的介电响应随含油量和油加吸收水分的变化规律。光谱将使用Havriliak和Negami的半经验形式的德拜色散关系(包括传导项)进行分析。将讨论传导的温度和湿度依赖性,然后评估色散机制的弛豫时间(tau)在所使用的温度范围内
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引用次数: 2
Electrical properties analysis of nano-filled epoxy by space charge characterization 利用空间电荷表征分析纳米填充环氧树脂的电性能
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.311940
J. Castellon, S. Agnel, A. Toureille, M. Frechette, K. Cole, D. Desgagnes
Numerous studies have shown that the presence and/or development of electric charges within polymers affect their properties with a significant order. These charges, intrinsic or extrinsic, that are called space charges, have been first observed for polymers used for electrotechnical applications, thus, at high electric fields. In many other studies, it has been observed that space charges are present into the polymers, even if these polymers were not exposed to additional stresses other than those associated with their synthesis and making. Moreover, the increase of the space charges seems directly linked with the deterioration of the physical properties of these materials since charge trapping is mainly associated with structure defects. These defects may have several origins, namely fabrication, interfaces, and stresses applied to the material. In this work, electrical properties of epoxy microcomposites with and without nanoclay are investigated under different conditions: without initial stress, and with subsequent electrical and thermal stresses. Correlating space charge measurements obtained by the Thermal Step Method with results observed in thermally stimulated-current experiments, the nature of the observed electric charges and the influence of the nanostructures can be discussed. Results and their scattering for cases including samples with and without nanoclay point certainly at the importance of the quality of the fabrication process.
大量研究表明,聚合物中电荷的存在和/或发展以显著的顺序影响其性能。这些电荷,无论是内在的还是外在的,都被称为空间电荷,首次在用于电工应用的聚合物中被观察到,因此,在高电场下。在许多其他的研究中,已经观察到空间电荷存在于聚合物中,即使这些聚合物除了与它们的合成和制造有关的应力外,没有暴露在额外的应力下。此外,空间电荷的增加似乎与这些材料的物理性能的恶化直接相关,因为电荷捕获主要与结构缺陷有关。这些缺陷可能有几个原因,即制造、界面和施加在材料上的应力。在这项工作中,研究了添加和不添加纳米粘土的环氧微复合材料在不同条件下的电学性能:没有初始应力,以及随后的电和热应力。将热步进法得到的空间电荷测量结果与热激电流实验结果相结合,可以讨论观察到的电荷的性质以及纳米结构的影响。实验结果及其散射对含和不含纳米粘土样品的影响,说明了纳米粘土制备工艺质量的重要性。
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引用次数: 5
Piezoelectricity of a single bubble formed by two oppositely charged Teflon® -FEP films 由两个相反电荷的Teflon®-FEP薄膜形成的单个气泡的压电性
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.312082
H. C. Basso, C.V. Aquino, R. Altafim, R. Altafim, R. Gerhard-Multhaupt
Multi-void space-charge electrets that have been formed by two fluoroethylenepropylene (Teflonreg-FEP) films with internal surface charge layers of opposite polarity exhibit high piezoelectric coefficients. In these electrets, several charged bubbles are arranged in parallel. A significant voltage is generated between the electrodes when the arrangement is submitted to a mechanical force that acts perpendicular to the electrodes (direct piezoelectricity). The arrangement thus works in a similar manner as a large number of tiny electret microphones. In view of this mechanism, the size and the shape of the bubbles are important aspects for the design of sensor and actuator devices. In this paper, we therefore investigate the behavior of single air bubbles formed by two fluoroethylenepropylene (Teflonreg-FEP) films theoretically and experimentally.
由两种内表面电荷层极性相反的氟乙烯-丙烯(Teflonreg-FEP)薄膜形成的多空空间电荷驻极体表现出较高的压电系数。在这些驻极体中,几个带电气泡平行排列。当电极受到垂直于电极的机械力(直接压电)作用时,电极之间会产生显著的电压。因此,这种安排的工作方式与大量微型驻极体麦克风类似。鉴于这种机理,气泡的大小和形状是传感器和执行机构设计的重要方面。因此,本文从理论上和实验上研究了两种氟乙烯丙烯(Teflonreg-FEP)薄膜形成的单个气泡的行为。
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引用次数: 3
A method to detect the deterioration of HTV silicone rubber under corona discharge 一种检测高温硅橡胶电晕放电劣化的方法
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.311981
Ying Liang, L. Ding, C.R. Li, Kun Yang, Y. Tu
This paper has investigated the thermally stimulated current (TSC) characteristics of the deteriorated HTV silicone rubber under varied corona discharge duration, the hydrophobicity, scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) of the corresponding test samples have also been measured. The experimental results show that the TSC characteristics of HTV silicone rubber gradually varied with the corona deterioration process, and it has relationship with the change of its hydrophobicity, SEM, and also FTIR. As a result, it could be suggested that the TSC characteristics might be used as an effective index for assessing the corona deterioration of HTV silicone rubber.
研究了变质后的HTV硅橡胶在不同电冕放电时间下的热激电流(TSC)特性,并对相应试样的疏水性、扫描电镜(SEM)和傅里叶变换红外(FTIR)进行了测量。实验结果表明,HTV硅橡胶的TSC特性随电晕变质过程逐渐发生变化,并与其疏水性、SEM和FTIR的变化有关。结果表明,TSC特性可作为评价HTV硅橡胶电晕劣化的有效指标。
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引用次数: 7
On-line time domain reflectometry measurements of temperature variations of an XLPE power cable XLPE电力电缆温度变化的在线时域反射测量
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.312059
V. Dubickas, H. Edin
In this paper an on-line time domain reflectometry system and a four-days measurements sequence are presented. Detected pulse velocity variations are attributed to temperature variations of the cable caused by a load cycling. The changes in the pulse velocity are verified by propagation constant measurements of a power cable at different temperatures in 300 kHz-500 MHz frequency range. Also an influence of temperature dependent semiconducting screens and XLPE insulation to the changes in the cable's capacitance is investigated.
本文介绍了一种在线时域反射测量系统和4天的测量序列。检测到的脉冲速度变化归因于负载循环引起的电缆温度变化。通过300 kHz-500 MHz频率范围内不同温度下电力电缆的传播常数测量,验证了脉冲速度的变化。此外,还研究了温度依赖性半导体屏和XLPE绝缘对电缆电容变化的影响。
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引用次数: 16
Oil reclamation - just a question of moisture? 石油回收-只是水分的问题?
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.312065
P. M. Mitchinson, P. Lewin, I. Hosier, G. Chen, P. Jarman
High voltage equipment (e.g. transformers and switchgear), use mineral oil and paper as a cost effective and well tried insulation medium. However, this insulation is known to age over time and usage. An obvious sign of ageing is the change in the colour of the oil which changes from pale yellow to reddish brown. This colour change can be measured by the technique of ultraviolet/visual (UV/Vis) spectroscopy. Other techniques such as acid number measurement and infrared (IR) spectroscopy can also be used as indicators of the age of the oil. In general, decisions can be taken by the operator, depending upon the results of these and other tests, as to when and how to maintain the equipment. Maintenance solutions include refurbishment of the transformer or the replacement of the mineral oil. However, these treatments are expensive and a more cost effective option is to use either oil purification or reclamation in order to cleanse the system before refurbishment becomes necessary. The question then becomes: which of these two processes is the more effective? There is little up-to-date research published on the effects of fuller's earth on transformer oil. This paper considers an experiment where aged oil is processed using fuller's earth and contrasts the results of selected ageing indicators against the known results of the oil purification process.
高压设备(如变压器和开关设备)使用矿物油和纸作为成本效益高且久经考验的绝缘介质。然而,这种绝缘材料会随着时间和使用而老化。老化的一个明显标志是油的颜色从淡黄色变成红棕色。这种颜色变化可以通过紫外/可见光谱学技术来测量。其他技术,如酸值测量和红外(IR)光谱也可以用作油的年龄指标。一般来说,操作员可以根据这些和其他测试的结果来决定何时以及如何维护设备。维护解决方案包括对变压器进行翻新或更换矿物油。然而,这些处理是昂贵的,一个更具成本效益的选择是使用油净化或回收,以便在需要翻新之前净化系统。那么问题就变成了:这两个过程中哪一个更有效?关于富勒氏接地对变压器油的影响的最新研究很少发表。本文考虑了使用富勒土处理老化油的实验,并将所选老化指标的结果与油净化过程的已知结果进行了对比。
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引用次数: 13
Interpretation of Several Key Phenomena Peculiar to Nano Dielectrics in terms of a Multi-core Model 用多核模型解释纳米电介质特有的几个关键现象
Pub Date : 2006-10-01 DOI: 10.1109/CEIDP.2006.311928
T. Tanaka
Some of the major dielectric phenomena observed in polymer nanocomposites are explained in terms of a multi-core model proposed by the author. They include characteristics associated with low field conductivity, high field conduction, permittivity, loss tan delta, the threshold field for space charge formation and EL inception, the increase in PD endurance and in treeing lifetime, and even a newly found crossover phenomenon. This model is characterized by individual and collective roles of multi-cores. The latter is related to carrier injection and tree growth at high electric field.
用作者提出的多核模型解释了在聚合物纳米复合材料中观察到的一些主要介电现象。它们包括与低场电导率、高场电导率、介电常数、损耗tan δ、空间电荷形成和EL起始的阈值场、PD耐久性和树寿命的增加,甚至是新发现的交叉现象相关的特性。该模型的特点是多核的个体角色和集体角色。后者与载流子注入和树木在高电场下的生长有关。
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引用次数: 42
期刊
2006 IEEE Conference on Electrical Insulation and Dielectric Phenomena
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