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The Influence of Carburizing-Nitriding Composite Heat Treatment on the Friction and Wear Properties of 20Cr3MoWVA Steel 渗碳渗氮复合热处理对20Cr3MoWVA钢摩擦磨损性能的影响
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-22 DOI: 10.1002/srin.202500429
Yuguan Sun, Yilong Liang, Longyun Zhang, Guigui Peng, Zihao Li, Xing Ran

Herein, the 20Cr3MoWVA steel is subjected to carburizing and plasma nitriding composite heat treatment for strengthening. Ball-disk friction wear tests are conducted on three states (Untreated, C, C + PN) of the samples. The results show that after the composite heat treatment, a composite diffusion layer composed of γ′-Fe4N phase and ε-Fe2-3N phase is obtained. This diffusion layer has no compound layer and no vein-like grain boundaries, and its thickness is 150 micrometers. The surface hardness of the C + PN sample (1004 HV) is 4.2 times and 1.3 times that of the Untreated sample and the C sample, respectively, and its wear rate decreases by 97.34% and 74.38% compared to the untreated sample and the C sample, respectively. The C + PN sample has the lowest friction coefficient (0.5887), and the surface residual compressive stress reaches −883 MPa. During the plasma nitriding process, Cr-rich M7C3 carbides and V-rich MC carbides transform into M2-3(C, N) and M(C, N) carbonitrides, respectively. The wear mechanisms of the three specimen states involve oxidative wear and adhesive wear, with abrasive wear also present in the untreated and C specimens. During the wear process of the C + PN samples, nanocomposite self-lubricating oxides with excellent wear resistance are formed.

本文对20Cr3MoWVA钢进行渗碳和等离子体渗氮复合热处理。对样品的三种状态(未处理、C、C + PN)进行球盘摩擦磨损试验。结果表明:复合热处理后,得到了由γ′-Fe4N相和ε-Fe2-3N相组成的复合扩散层;该扩散层无复合层,无脉状晶界,厚度为150微米。C + PN样品的表面硬度(1004 HV)分别是未处理样品和C样品的4.2倍和1.3倍,其磨损率分别比未处理样品和C样品降低了97.34%和74.38%。C + PN试样的摩擦系数最低(0.5887),表面残余压应力达到- 883 MPa。在等离子体渗氮过程中,富cr的M7C3碳化物和富v的MC碳化物分别转化为M2-3(C, N)和M(C, N)碳氮化物。三种试样状态的磨损机制包括氧化磨损和黏着磨损,未处理和C试样也存在磨粒磨损。在C + PN样品的磨损过程中,形成了具有优异耐磨性的纳米复合自润滑氧化物。
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引用次数: 0
Honoring Seshadri Seetharaman 纪念赛沙德里·西塔拉曼
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-21 DOI: 10.1002/srin.202500091
Olena Volkova

Seshadri Seetharaman was born on December 5th, 1943, in Pudukottai, Tamil Nadu, India. He embarked on his scientific journey in 1966 at the Indian Institute of Science, where he earned a PhD in Metallurgical Engineering in 1971. Following his doctoral studies and post-doctoral research, he joined the Department of Metallurgy at the Royal Institute of Technology (KTH) in Stockholm, Sweden. At KTH, he initially served as an associate professor before being appointed as Professor of Theoretical Metallurgy in 1990. In 1996, he became Head of the Department of Metallurgy and subsequently Pro-Dean of the Faculty of Mechanical and Materials Engineering.

Professor Seshadri Seetharaman's research has significantly advanced the fields of thermochemistry and thermophysics of high-temperature metal and oxide systems. His work includes experimental measurements and modeling of properties such as viscosities, thermal diffusivities, and surface and interfacial tensions. His investigations into high-temperature reaction kinetics, including heat and mass transfer, property-structure relationships, and micro-phenomena, have provided profound insights into gas-solid reactions and slag-metal interactions. Notably, he proposed the concept of interfacial velocity in slag-metal reactions and published extensively on the valence changes of metallic components in slags.

With over 400 publications in peer-reviewed journals, 160 conference presentations, and 10 patents, Professor Seetharaman's contributions bridge the gap between fundamental research and practical applications. He has been a key reader and member of the editorial boards of esteemed journals such as Metallurgical and Materials Transactions and steel research international. Additionally, he has organized and chaired numerous international conferences, promoting collaboration and innovation in the scientific community. Renowned as a dedicated educator, he has been an inspiring teacher, a supportive PhD supervisor, and a respected colleague.

Professor Seetharaman's exceptional teaching abilities have been widely recognized. He was nominated eight times as the best teacher in the materials design program at KTH and received the President's Award for meritorious teaching in 1994. In 2004, he was named the best teacher at KTH. Among his many honors, he received the Brimacombe Prize in 2010 and has been recognized as an honorary member of the Iron and Steel Institute of Japan, an honorary doctor at Aalto University in Finland, and an honorary professor at the Metallurgical Academy of Ukraine and the University of Science and Technology Beijing. His renowed career also includes serving as a Mercator Professor at TU Bergakademie Freiberg, Germany (2011–2012), and a visiting professor at Kyoto University, Japan. In 2013, he was awarded the Distinguished Alumni Award by the Indian Institute of Science, Bangalore.

The scientific seminar marking Professor Seetharaman's retireme

Seshadri Seetharaman于1943年12月5日出生在印度泰米尔纳德邦的Pudukottai。1966年,他在印度科学研究所开始了他的科学之旅,并于1971年获得冶金工程博士学位。在完成博士和博士后研究后,他加入了瑞典斯德哥尔摩皇家理工学院(KTH)冶金系。在KTH,他最初担任副教授,1990年被任命为理论冶金学教授。1996年,他成为冶金系主任,随后成为机械与材料工程学院副院长。Seshadri Seetharaman教授的研究在高温金属和氧化物系统的热化学和热物理领域取得了重大进展。他的工作包括粘度、热扩散率、表面和界面张力等特性的实验测量和建模。他对高温反应动力学的研究,包括传热传质、性质结构关系和微观现象,为气固反应和渣金属相互作用提供了深刻的见解。值得注意的是,他提出了渣-金属反应界面速度的概念,并发表了大量关于渣中金属组分价态变化的文章。Seetharaman教授在同行评审期刊上发表了400多篇论文,在160次会议上发表了演讲,并获得了10项专利,他的贡献弥合了基础研究和实际应用之间的差距。他是《冶金与材料交易》和《国际钢铁研究》等知名期刊的主要读者和编委会成员。此外,他还组织和主持了许多国际会议,促进了科学界的合作和创新。作为一名敬业的教育家,他一直是一位鼓舞人心的老师,一位支持博士的导师,也是一位受人尊敬的同事。Seetharaman教授卓越的教学能力得到了广泛的认可。他曾八次被提名为香港理工大学材料设计专业的最佳教师,并于1994年获得校长有功教学奖。2004年,他被评为香港理工学院最佳教师。在他的众多荣誉中,他于2010年获得了Brimacombe奖,并被公认为日本钢铁研究所的荣誉会员,芬兰阿尔托大学的荣誉博士,以及乌克兰冶金学院和北京科技大学的荣誉教授。他的著名职业生涯还包括担任德国弗莱堡工业大学的墨卡托教授(2011 - - 2012),以及日本京都大学的客座教授。2013年,他被班加罗尔印度科学研究所授予杰出校友奖。标志着Seetharaman教授退休的科学研讨会是一个国际性事件,反映了他的影响力之广。作为百科全书式的《过程冶金论》第一版和第二版的主编,他为科学家和工程师提供了宝贵的资源,提供了该领域的全面概述。作为印度贾姆谢德布尔塔塔钢铁公司的客座教授,他继续为科学界做出贡献。这一期《国际钢铁研究》特刊是为了庆祝2023年12月纪念的Seshadri Seetharaman教授的80岁生日。我要感谢编辑们策划本期杂志,也感谢研究者们提供的宝贵意见。所有投稿人共同祝愿Seshadri Seetharaman教授的未来,特别是他的身体健康,并期待他即将出版的出版物。Seshadri Seetharaman教授
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引用次数: 0
Extraction of Vanadium from CaO–SiO2–MgO–Al2O3 Slags Based on Vaporization of Vanadium Pentoxide 基于五氧化二钒汽化法从CaO-SiO2-MgO-Al2O3渣中提取钒
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-21 DOI: 10.1002/srin.70053
Lukas Neubert, Tetiana Shyrokykh, Nataliia Tinkova, Sridhar Seetharaman, Olena Volkova

The cover image is based on the article Extraction of Vanadium from CaO-SiO2-MgO-Al2O3 Slags Based on Vaporization of Vanadium Pentoxide by Lukas Neubert et al., https://doi.org/10.1002/srin.202300681.

封面图片来自Lukas Neubert等人的文章《基于五氧化二钒汽化从CaO-SiO2-MgO-Al2O3渣中提取钒》https://doi.org/10.1002/srin.202300681。
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引用次数: 0
Contents: steel research int. 8/2025 内容:钢铁研究;8/2025
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-21 DOI: 10.1002/srin.70069
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引用次数: 0
Hybrid Reduction of Iron Ores by Biomass and Hydrogen Gas: Reduction Behavior 生物质和氢气混合还原铁矿石:还原行为
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-20 DOI: 10.1002/srin.202500444
Rongrong Wang, Alexander Babich, Dieter Senk, Min Wang

Biomass and H2 are characterized as environment-friendly, and can be used as reductant in the reduction process of iron oxides, therefore to achieve carbon neutrality of the shaft furnace direct reduction ironmaking process, and meanwhile produce carbon-containing direct reduced iron (DRI). For the synergistic utilization of biomass and H2, this study used H2 to reduce biomass embedded self-reducing pellets (SRP) to produce DRI. The relative mass loss ratio, reduction degree and metallization degree, and microstructure of pellets reduced under different conditions (750–950 °C, CO involved, H2 involved and N2 atmosphere) are analyzed to clarify the reduction behavior of torrefied biomass- and charcoal-embedded pellets. Results indicate that higher temperature, H2 involved atmosphere, and higher embedded biomass content favors the hybrid reduction of iron oxides; addition of biomass affects the reduction efficiency of pellets from two aspects, porosity and solid carbon reduction. Under the optimal reducing condition (950 °C and 40% H2%–60% N2 atmosphere), reduction degree of 87% can be achieved by reducing torrefied biomass embedded SRP, and DRI with acceptable carbon content is expected be produced.

生物质和H2具有环保性,可作为氧化铁还原过程的还原剂,从而实现竖炉直接还原炼铁过程的碳中和,同时生产含碳直接还原铁(DRI)。为了协同利用生物质和H2,本研究利用H2还原生物质包埋自还原颗粒(SRP)生产DRI。分析了不同条件(750 ~ 950℃,CO、H2和N2气氛)下还原球团的相对质量损失率、还原度、金属化程度和微观结构,阐明了碳化生物质和炭包埋球团的还原行为。结果表明,较高的温度、H2参与气氛和较高的包埋生物量有利于铁氧化物的混合还原;生物质的加入从孔隙率和固体碳还原两个方面影响颗粒的还原效率。在最佳还原条件(950℃,40% h2o2 ~ 60% N2气氛)下,通过还原碳化生物质包埋SRP,还原度可达87%,可制得含碳量可接受的DRI。
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引用次数: 0
Effect of Operating Parameters on the Kinetics of Dephosphorization in a 250 t Converter with Single-Flow Postcombustion Oxygen Lance 操作参数对250 t单流燃烧后氧枪转炉脱磷动力学的影响
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-17 DOI: 10.1002/srin.202500525
Chao Liu, Shuguo Zheng, Miaoyong Zhu

A coupled volume of fluid–discrete phase model (DPM) model is used to simulate the single-flow postcombustion oxygen lance gas–metal interaction behavior and dephosphorization behavior in a 250 t converter. The effects of different lance heights and operating pressures on the molten pool flow rate, phosphorus content, and endpoint phosphorus content are investigated, while the influence of phosphorus distribution ratios on the dephosphorization rate is also analyzed. The results show that as the lance height increases, the droplet fraction (percentage of droplets relative to the liquid steel mass) decreases, the average velocity of the steel surface increases, the dead zone area first increases and then decreases, and the dephosphorization rate gradually declines. When the operating pressure increases from 0.8 to 1.1 MPa, surface fluctuations intensify, more droplets are splashed, and the dephosphorization rate increases from 61.9% to 81.0%. For phosphorus distribution ratios of 40, 80, 120, and 160, the dephosphorization rates are 48.5%, 60.7%, 69.2%, and 75.1%, respectively. Industrial tests on a 250 t converter using a single-flow postcombustion oxygen lance show that the higher the total iron and CaO content in the slag, the higher the phosphorus distribution ratio; the dephosphorization rate gradually increases with the gradual increase of the phosphorus distribution ratio.

采用耦合体积-离散相模型(DPM)模拟了250t转炉内单流氧枪燃烧后气体-金属相互作用行为和脱磷行为。研究了不同喷枪高度和操作压力对熔池流量、磷含量和终点磷含量的影响,并分析了磷分配比对脱磷速率的影响。结果表明:随着喷枪高度的增加,液滴分数(液滴相对于钢液质量的百分比)减小,钢表面平均速度增大,死区面积先增大后减小,脱磷速率逐渐降低;当操作压力从0.8 MPa增加到1.1 MPa时,表面波动加剧,溅落液滴增多,脱磷率从61.9%增加到81.0%。当磷分布比为40、80、120和160时,脱磷率分别为48.5%、60.7%、69.2%和75.1%。250t转炉单流燃烧后氧枪工业试验表明,炉渣中总铁和总CaO含量越高,磷分配比越高;随着磷分配比的逐渐增大,脱磷速率逐渐增大。
{"title":"Effect of Operating Parameters on the Kinetics of Dephosphorization in a 250 t Converter with Single-Flow Postcombustion Oxygen Lance","authors":"Chao Liu,&nbsp;Shuguo Zheng,&nbsp;Miaoyong Zhu","doi":"10.1002/srin.202500525","DOIUrl":"https://doi.org/10.1002/srin.202500525","url":null,"abstract":"<p>A coupled volume of fluid–discrete phase model (DPM) model is used to simulate the single-flow postcombustion oxygen lance gas–metal interaction behavior and dephosphorization behavior in a 250 t converter. The effects of different lance heights and operating pressures on the molten pool flow rate, phosphorus content, and endpoint phosphorus content are investigated, while the influence of phosphorus distribution ratios on the dephosphorization rate is also analyzed. The results show that as the lance height increases, the droplet fraction (percentage of droplets relative to the liquid steel mass) decreases, the average velocity of the steel surface increases, the dead zone area first increases and then decreases, and the dephosphorization rate gradually declines. When the operating pressure increases from 0.8 to 1.1 MPa, surface fluctuations intensify, more droplets are splashed, and the dephosphorization rate increases from 61.9% to 81.0%. For phosphorus distribution ratios of 40, 80, 120, and 160, the dephosphorization rates are 48.5%, 60.7%, 69.2%, and 75.1%, respectively. Industrial tests on a 250 t converter using a single-flow postcombustion oxygen lance show that the higher the total iron and CaO content in the slag, the higher the phosphorus distribution ratio; the dephosphorization rate gradually increases with the gradual increase of the phosphorus distribution ratio.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"97 2","pages":"975-990"},"PeriodicalIF":2.5,"publicationDate":"2025-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146139718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure Evolution and Strengthening Mechanism of 30MnB5 and 40Mn2CrNbV Hot-Stamped Steel 30MnB5和40Mn2CrNbV热冲压钢组织演变及强化机理
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-17 DOI: 10.1002/srin.202500456
Zi Yao Wei, Shun Hu Zhang, Jing Wen Yan, Tian Han Yang, Xian Long Luo, Wei Jian Chen

The present investigation employs conventional hot-stamping methodology incorporating die quenching followed by 170 °C tempering to fabricate ultrahigh strength 40Mn2CrNbV hot-stamped steel. The alloy demonstrates exceptional mechanical characteristics, achieving an ultimate tensile strength of 2311 MPa while maintaining satisfactory ductility (total elongation of 9.8%). Quantitative evaluation of strengthening mechanisms reveals the dislocation strengthening as the predominant contributor (accounts for about 55.9% of yield strength), followed by precipitation strengthening. Compared with 30MnB5 steel and existing literature-reported systems, the 40Mn2CrNbV steel has excellent mechanical properties, mainly due to the synergistic interaction of Cr, Nb, and V microalloying elements. Specifically, the simultaneous incorporation of Nb and V facilitates the precipitation of nanoscale (Nb, V)C, induces grain refinement, and impedes dislocation motion through pinning effects. The average size of martensite block widths is 0.8 μm and the dislocation densities of 3.1 ± 0.4 × 1015 m−2 for 40Mn2CrNbV hot-stamped steel.

本研究采用传统的热冲压方法,包括模具淬火和170°C回火,以制备超高强度40Mn2CrNbV热冲压钢。该合金表现出优异的机械特性,在保持令人满意的延展性(总伸长率为9.8%)的同时,达到了2311 MPa的极限抗拉强度。强化机制的定量评价表明,位错强化是主要的强化机制(约占屈服强度的55.9%),其次是沉淀强化。与30MnB5钢和现有文献报道的体系相比,40Mn2CrNbV钢具有优异的力学性能,这主要是由于Cr、Nb和V微合金元素的协同作用。具体而言,Nb和V的同时掺入有利于纳米级(Nb, V)C的析出,诱导晶粒细化,并通过钉住效应阻碍位错运动。40Mn2CrNbV钢的平均马氏体块宽度为0.8 μm,位错密度为3.1±0.4 × 1015 m−2。
{"title":"Microstructure Evolution and Strengthening Mechanism of 30MnB5 and 40Mn2CrNbV Hot-Stamped Steel","authors":"Zi Yao Wei,&nbsp;Shun Hu Zhang,&nbsp;Jing Wen Yan,&nbsp;Tian Han Yang,&nbsp;Xian Long Luo,&nbsp;Wei Jian Chen","doi":"10.1002/srin.202500456","DOIUrl":"https://doi.org/10.1002/srin.202500456","url":null,"abstract":"<p>The present investigation employs conventional hot-stamping methodology incorporating die quenching followed by 170 °C tempering to fabricate ultrahigh strength 40Mn2CrNbV hot-stamped steel. The alloy demonstrates exceptional mechanical characteristics, achieving an ultimate tensile strength of 2311 MPa while maintaining satisfactory ductility (total elongation of 9.8%). Quantitative evaluation of strengthening mechanisms reveals the dislocation strengthening as the predominant contributor (accounts for about 55.9% of yield strength), followed by precipitation strengthening. Compared with 30MnB5 steel and existing literature-reported systems, the 40Mn2CrNbV steel has excellent mechanical properties, mainly due to the synergistic interaction of Cr, Nb, and V microalloying elements. Specifically, the simultaneous incorporation of Nb and V facilitates the precipitation of nanoscale (Nb, V)C, induces grain refinement, and impedes dislocation motion through pinning effects. The average size of martensite block widths is 0.8 μm and the dislocation densities of 3.1 ± 0.4 × 10<sup>15</sup> m<sup>−2</sup> for 40Mn2CrNbV hot-stamped steel.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"97 2","pages":"943-954"},"PeriodicalIF":2.5,"publicationDate":"2025-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146139720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Warm Rolling on the Evolution of Microstructure and Toughness in 100Cr6 Bearing Steel 温轧对100Cr6轴承钢组织和韧性演变的影响
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-17 DOI: 10.1002/srin.202500108
Shuai He, Tan Zhao, Qing Yin, Ye Liu, Chi Zhang, JunSheng Wang

Traditional spheroidization annealing of 100Cr6 bearing steel is time-consuming and energy-intensive. To address this, warm rolling is proposed as an efficient alternative for microstructure refinement and toughness enhancement. The influence of warm rolling at critical dual-phase (760 °C) and ferrite (700 °C, 650 °C) temperatures is investigated. At 760°C, dynamic recrystallization dominated with 90% recrystallized area, yielding equiaxed ferrite grains of 4–6 μm and normally distributed carbides averaging 0.37 μm in size with 32 vol%. Lower-temperature rolling at 650 °C intensified deformation bands to 3 μm spacing, promoting carbide precipitation to 47 vol% density at 15.7 particles μm−2 while suppressing recrystallization (90% area with GOS >2). Nanoscale carbides of 0.094 μm pinned grain boundaries, transitioning deformation mechanisms from grain-boundary sliding to intragranular slip. Impact toughness increased by 30%–40% in ferrite-zone rolled specimens due to crack deflection by laminated fibrous grains and fine carbides. This work clarifies how distortion energy storage drives deformation-induced carbide precipitation, providing a pathway to achieve high toughness through tailored warm-rolling processes.

传统的100Cr6轴承钢球化退火费时、耗能大。为了解决这一问题,提出了热轧作为一种有效的替代方法来改善组织和增强韧性。研究了临界双相温度(760℃)和铁素体温度(700℃、650℃)下热轧对合金性能的影响。在760℃时,动态再结晶以90%的再结晶面积为主,生成4 ~ 6 μm的等轴铁素体晶粒和平均尺寸为0.37 μm的正态分布碳化物,体积% 32。650℃低温轧制使变形带间距扩大到3 μm,在15.7 μm−2时析出密度达到47 vol%的碳化物,同时抑制再结晶(含GOS >;2的面积为90%)。0.094 μm的纳米碳化物钉住晶界,将晶界滑移转变为晶内滑移。铁素体区轧制试样的冲击韧性由于层状纤维晶粒和细碳化物的裂纹偏转而提高了30% ~ 40%。这项工作阐明了变形能量存储如何驱动变形诱导的碳化物析出,为通过定制的热轧工艺实现高韧性提供了一条途径。
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引用次数: 0
Microstructure Evolution and Strengthening Mechanism of 30MnB5 and 40Mn2CrNbV Hot-Stamped Steel 30MnB5和40Mn2CrNbV热冲压钢组织演变及强化机理
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-17 DOI: 10.1002/srin.202500456
Zi Yao Wei, Shun Hu Zhang, Jing Wen Yan, Tian Han Yang, Xian Long Luo, Wei Jian Chen

The present investigation employs conventional hot-stamping methodology incorporating die quenching followed by 170 °C tempering to fabricate ultrahigh strength 40Mn2CrNbV hot-stamped steel. The alloy demonstrates exceptional mechanical characteristics, achieving an ultimate tensile strength of 2311 MPa while maintaining satisfactory ductility (total elongation of 9.8%). Quantitative evaluation of strengthening mechanisms reveals the dislocation strengthening as the predominant contributor (accounts for about 55.9% of yield strength), followed by precipitation strengthening. Compared with 30MnB5 steel and existing literature-reported systems, the 40Mn2CrNbV steel has excellent mechanical properties, mainly due to the synergistic interaction of Cr, Nb, and V microalloying elements. Specifically, the simultaneous incorporation of Nb and V facilitates the precipitation of nanoscale (Nb, V)C, induces grain refinement, and impedes dislocation motion through pinning effects. The average size of martensite block widths is 0.8 μm and the dislocation densities of 3.1 ± 0.4 × 1015 m−2 for 40Mn2CrNbV hot-stamped steel.

本研究采用传统的热冲压方法,包括模具淬火和170°C回火,以制备超高强度40Mn2CrNbV热冲压钢。该合金表现出优异的机械特性,在保持令人满意的延展性(总伸长率为9.8%)的同时,达到了2311 MPa的极限抗拉强度。强化机制的定量评价表明,位错强化是主要的强化机制(约占屈服强度的55.9%),其次是沉淀强化。与30MnB5钢和现有文献报道的体系相比,40Mn2CrNbV钢具有优异的力学性能,这主要是由于Cr、Nb和V微合金元素的协同作用。具体而言,Nb和V的同时掺入有利于纳米级(Nb, V)C的析出,诱导晶粒细化,并通过钉住效应阻碍位错运动。40Mn2CrNbV钢的平均马氏体块宽度为0.8 μm,位错密度为3.1±0.4 × 1015 m−2。
{"title":"Microstructure Evolution and Strengthening Mechanism of 30MnB5 and 40Mn2CrNbV Hot-Stamped Steel","authors":"Zi Yao Wei,&nbsp;Shun Hu Zhang,&nbsp;Jing Wen Yan,&nbsp;Tian Han Yang,&nbsp;Xian Long Luo,&nbsp;Wei Jian Chen","doi":"10.1002/srin.202500456","DOIUrl":"https://doi.org/10.1002/srin.202500456","url":null,"abstract":"<p>The present investigation employs conventional hot-stamping methodology incorporating die quenching followed by 170 °C tempering to fabricate ultrahigh strength 40Mn2CrNbV hot-stamped steel. The alloy demonstrates exceptional mechanical characteristics, achieving an ultimate tensile strength of 2311 MPa while maintaining satisfactory ductility (total elongation of 9.8%). Quantitative evaluation of strengthening mechanisms reveals the dislocation strengthening as the predominant contributor (accounts for about 55.9% of yield strength), followed by precipitation strengthening. Compared with 30MnB5 steel and existing literature-reported systems, the 40Mn2CrNbV steel has excellent mechanical properties, mainly due to the synergistic interaction of Cr, Nb, and V microalloying elements. Specifically, the simultaneous incorporation of Nb and V facilitates the precipitation of nanoscale (Nb, V)C, induces grain refinement, and impedes dislocation motion through pinning effects. The average size of martensite block widths is 0.8 μm and the dislocation densities of 3.1 ± 0.4 × 10<sup>15</sup> m<sup>−2</sup> for 40Mn2CrNbV hot-stamped steel.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"97 2","pages":"943-954"},"PeriodicalIF":2.5,"publicationDate":"2025-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146139717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cup Deep Drawing Simulation of Commercially Pure Titanium for Varying-Shoulder-Radius Die Using Finite Element Method and Non-associated Flow Rule 用有限元法和非关联流动规律模拟工业纯钛变肩半径模具杯形拉深
IF 2.5 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-08-17 DOI: 10.1002/srin.202500026
Yuji Sato, Shogo Nishioka, Yutaro Akiguchi, Honghao Wang, Jun Yanagimoto

To test the ability of predicting earing height in finite element simulations with nonassociated flow rule for complex die configurations such as “varying-shoulder-radius die,” a 3D simulation of deep drawing of a commercially pure titanium sheet is conducted. Cup deep drawing experiments with single-radius die are first conducted to verify the accuracy of the simulation results, and the results are compared with the experimental measurements. Two types of nonassociated flow rules are applied: the Hill-Hill combination using Hill48 for both the yield function and plastic potential, and the Hill-Yld combination using Hill48 for the yield function and Yld2004-18p for the plastic potential. The results show that the Hill-Yld model reproduces the experimental results well in the range of 45°–90°. Subsequently, deep drawing using varying-shoulder-radius dies is simulated, and the results are compared with the experimental measurements. The results of the comparison show that the Hill-Yld model is able to qualitatively reproduce the experimental trend of the earing height. The results suggest that the Hill-Yld model with Yld2004-18p as the plastic potential can qualitatively reproduce the results of deep drawing experiments using varying-shoulder-radius dies.

为了测试在有限元模拟中对复杂模具结构(如“变肩半径模具”)使用非关联流动规则预测耳高的能力,对商业纯钛板的深拉深进行了三维模拟。首先进行了单半径模具杯形拉深实验,验证了仿真结果的准确性,并与实验测量结果进行了比较。应用了两种类型的非关联流动规则:Hill-Hill组合使用Hill48作为屈服函数和塑性势,Hill-Yld组合使用Hill48作为屈服函数和Yld2004-18p作为塑性势。结果表明,Hill-Yld模型在45°~ 90°范围内较好地再现了实验结果。随后,对变肩半径模具的拉深进行了仿真,并与实验结果进行了比较。对比结果表明,Hill-Yld模型能够定性再现耳廓高度的实验趋势。结果表明,以Yld2004-18p为塑性势的Hill-Yld模型可以定性地再现变肩半径模具拉深实验结果。
{"title":"Cup Deep Drawing Simulation of Commercially Pure Titanium for Varying-Shoulder-Radius Die Using Finite Element Method and Non-associated Flow Rule","authors":"Yuji Sato,&nbsp;Shogo Nishioka,&nbsp;Yutaro Akiguchi,&nbsp;Honghao Wang,&nbsp;Jun Yanagimoto","doi":"10.1002/srin.202500026","DOIUrl":"10.1002/srin.202500026","url":null,"abstract":"<p>To test the ability of predicting earing height in finite element simulations with nonassociated flow rule for complex die configurations such as “varying-shoulder-radius die,” a 3D simulation of deep drawing of a commercially pure titanium sheet is conducted. Cup deep drawing experiments with single-radius die are first conducted to verify the accuracy of the simulation results, and the results are compared with the experimental measurements. Two types of nonassociated flow rules are applied: the Hill-Hill combination using Hill48 for both the yield function and plastic potential, and the Hill-Yld combination using Hill48 for the yield function and Yld2004-18p for the plastic potential. The results show that the Hill-Yld model reproduces the experimental results well in the range of 45°–90°. Subsequently, deep drawing using varying-shoulder-radius dies is simulated, and the results are compared with the experimental measurements. The results of the comparison show that the Hill-Yld model is able to qualitatively reproduce the experimental trend of the earing height. The results suggest that the Hill-Yld model with Yld2004-18p as the plastic potential can qualitatively reproduce the results of deep drawing experiments using varying-shoulder-radius dies.</p>","PeriodicalId":21929,"journal":{"name":"steel research international","volume":"97 2","pages":"827-837"},"PeriodicalIF":2.5,"publicationDate":"2025-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/srin.202500026","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146139719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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