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Triethanolamine assisted synthesis of bimetallic nickel cobalt nitride/nitrogen-doped carbon hollow nanoflowers for supercapacitor 三乙醇胺辅助合成双金属氮化镍钴/氮掺杂碳空心纳米花
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-01 DOI: 10.20517/microstructures.2022.41
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引用次数: 1
Crystallographic variant mapping using precession electron diffraction data 利用进动电子衍射数据的晶体变分图
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-01 DOI: 10.20517/microstructures.2023.17
Marcus H. Hansen
In this work, we developed three methods to map crystallographic variants of samples at the nanoscale by analyzing precession electron diffraction data using a high-temperature shape memory alloy and a VO2 thin film on sapphire as the model systems. The three methods are (I) a user-selecting-reference pattern approach, (II) an algorithm-selecting-reference-pattern approach, and (III) a k-means approach. In the first two approaches, Euclidean distance, Cosine, and Structural Similarity (SSIM) algorithms were assessed for the diffraction pattern similarity quantification. We demonstrated that the Euclidean distance and SSIM methods outperform the Cosine algorithm. We further revealed that the random noise in the diffraction data can dramatically affect similarity quantification. Denoising processes could improve the crystallographic mapping quality. With the three methods mentioned above, we were able to map the crystallographic variants in different materials systems, thus enabling fast variant number quantification and clear variant distribution visualization. The advantages and disadvantages of each approach are also discussed. We expect these methods to benefit researchers who work on martensitic materials, in which the variant information is critical to understand their properties and functionalities.
在这项工作中,我们开发了三种方法,通过分析进动电子衍射数据,以高温形状记忆合金和蓝宝石上的VO2薄膜为模型系统,在纳米尺度上绘制样品的晶体学变化。这三种方法是(I)用户选择参考模式方法,(II)算法选择参考模式方法,以及(III) k-means方法。在前两种方法中,评估了欧几里得距离、余弦和结构相似性(SSIM)算法用于衍射图案相似性量化。我们证明了欧氏距离和SSIM方法优于余弦算法。进一步揭示了衍射数据中的随机噪声会显著影响相似性量化。去噪处理可以提高晶体成像质量。通过上述三种方法,我们能够绘制不同材料体系中的晶体变异体,从而实现快速的变异体数量量化和清晰的变异体分布可视化。讨论了每种方法的优缺点。我们希望这些方法能使马氏体材料的研究人员受益,因为在马氏体材料中,变异信息对理解其性质和功能至关重要。
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引用次数: 2
Emerging microporous materials as novel templates for quantum dots 新兴微孔材料作为量子点的新模板
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-01 DOI: 10.20517/microstructures.2023.08
Jaeho Lee, Lianzhou Wang, Jingwei Hou
Microporous structures have attracted significant attention in recent years. In particular, metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) have received considerable attention due to their tailorable structures that offer a wide range of choices in terms of molecular building blocks. Due to their high tunability, these materials are considered as ideal host matrices for templating and encapsulating guest materials, particularly quantum dots (QDs). QDs are investigated heavily for various applications such as light-emitting diodes (LED), biosensors, catalysts, and solar cells due to their unique properties from the quantum confinement effect. However, one of the drawbacks of QDs is their tendency to aggregate and exhibit low stability due to their small size and kinetic trapping in nanoparticle form. This perspective highlights promising approaches to enhance the performance and stability of QDs by using microporous materials as an encapsulation layer. Additionally, potential mitigating strategies are discussed to overcome current challenges and improve the practicality of QDs embedded in microporous nanocomposites.
近年来,微孔结构引起了人们的广泛关注。特别是金属有机框架(MOFs)和共价有机框架(COFs)由于其可定制的结构提供了广泛的分子构建模块选择而受到了相当大的关注。由于其高可调性,这些材料被认为是模板化和封装客体材料,特别是量子点(QDs)的理想宿主矩阵。由于量子限制效应的独特性质,量子点在发光二极管(LED)、生物传感器、催化剂和太阳能电池等各种应用中得到了广泛的研究。然而,量子点的缺点之一是由于它们的小尺寸和纳米颗粒形式的动力学捕获,它们倾向于聚集和表现出低稳定性。这一观点强调了利用微孔材料作为封装层来提高量子点性能和稳定性的有希望的方法。此外,讨论了潜在的缓解策略,以克服当前的挑战,提高嵌入微孔纳米复合材料的量子点的实用性。
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引用次数: 0
180° head-to-head flat domain walls in single crystal BiFeO3 单晶BiFeO3中180°头对头平面畴壁
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-01 DOI: 10.20517/microstructures.2023.13
Wanbing Ge, R. Beanland, M. Alexe, Q. Ramasse, A. Sanchez
We investigate flux-grown BiFeO3 crystals using transmission electron microscopy (TEM). This material has an intriguing ferroelectric structure of domain walls with a period of approximately 100 nm, alternating between flat and sawtooth morphologies. We show that all domain walls are of 180° type and that the flat walls, lying on (112) planes, are reconstructed with an excess of Fe and a deficiency of Bi. This reconstruction is similar to that observed in several previous studies of deposited layers of BiFeO3. The negative charge of the reconstructed layer induces head-to-head polarisation in the surrounding material and a rigid-body shift of one domain relative to the other. These characteristics pin the flat 180° domain walls and determine the domain structure of the material. Sawtooth 180° domain walls provide the necessary reversal of polarisation between flat walls. The high density of immobile domain walls suppresses the ferroelectric properties of the material, highlighting the need for careful control of growth conditions.
我们用透射电子显微镜(TEM)研究了磁通生长的BiFeO3晶体。该材料具有有趣的畴壁铁电结构,周期约为100 nm,在平面和锯齿形态之间交替。我们发现所有的畴壁都是180°型的,并且在(112)平面上的平壁被重建为铁过量而Bi缺乏。这种重建与之前对BiFeO3沉积层的研究相似。重构层的负电荷在周围材料中引起头对头的极化和一个域相对于另一个域的刚体位移。这些特性固定了平坦的180°畴壁,并确定了材料的畴结构。锯齿状180°畴壁在平壁之间提供必要的极化反转。高密度的不可移动畴壁抑制了材料的铁电性能,突出了需要仔细控制生长条件。
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引用次数: 2
Structure, magnetism and low thermal expansion in Tb1-xErxCo2Mny intermetallic compounds t_1 - xerxco2mine金属间化合物的结构、磁性和低热膨胀
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-01 DOI: 10.20517/microstructures.2023.03
Yanming Sun, Yili Cao, Y. Ren, S. Lapidus, Qiang Li, J. Deng, Jun Miao, K. Lin, X. Xing
Here, we obtained a series of controllable thermal expansion alloys Tb1-xErxCo2Mny (x = 0-0.5, y = 0-0.4) by incorporating double rare earth doping and introducing non-stoichiometric Mn content. By varying the amount of Er or Mn, a low thermal expansion (LTE) is achieved in Tb0.6Er0.4Co2Mn0.1 (TECM, α1 = 1.23 × 10-6 K-1, 125~236 K). The macroscopic linear expansion and magnetic properties reveal that anomalous thermal expansion is closely related to the magnetic phase transition. Synchrotron X-ray powder diffraction results show that TECM is a cubic phase (space group: Fd-3m) at high temperatures, and a structural transition to a rhombohedral phase (space group: R-3m) occurs as temperature decreases. The negative thermal expansion c-axis compensates for the normal positive thermal expansion of the basal plane, resulting in the volumetric LTE. This study provides a new metallic and magnetic ZTE material.
本文通过双稀土掺杂和引入非化学计量Mn含量,获得了一系列可控热膨胀合金Tb1-xErxCo2Mny (x = 0-0.5, y = 0-0.4)。通过改变Er或Mn的量,Tb0.6Er0.4Co2Mn0.1 (TECM, α1 = 1.23 × 10-6 K-1, 125~236 K)得到了较低的热膨胀(LTE),宏观线性膨胀和磁性能表明异常热膨胀与磁相变密切相关。同步加速器x射线粉末衍射结果表明,TECM在高温下为立方相(空间群:Fd-3m),随着温度的降低,结构转变为菱面体相(空间群:R-3m)。负热膨胀c轴补偿基面正常的正热膨胀,导致体积LTE。本研究提供了一种新的金属磁性中兴材料。
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引用次数: 0
Strong metal-support interaction of Pt-based electrocatalysts with transition metal oxides/nitrides/carbides for oxygen reduction reaction pt基电催化剂与过渡金属氧化物/氮化物/碳化物在氧还原反应中的强金属支撑相互作用
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-01 DOI: 10.20517/microstructures.2023.12
Min Chen
The practical application of carbon-supported Pt-based catalysts for the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs) still faces many limitations, including carbon corrosion and their weak interaction with Pt-based nanoparticles (NPs). Harnessing the strong metal-support interaction (SMSI) effects at the interface between Pt-based nanoparticles and alternative corrosion-resistant non-carbon support is an effective strategy to address these issues. The rational design of Pt-based catalysts with favorable SMSI and elucidation of the mechanisms underlying such interactions is indispensable for achieving desirable activity and stability. In this review, first, the basic principles of the ORR are briefly introduced. Next, the formation process of SMSI, construction strategies, and the advantages and drawbacks of representative supports, including transition metal oxides, nitrides, and carbides (TMOs, TMCs, and TMNs, respectively), are fully discussed. Finally, the challenges and prospects in promoting the practical applications of the SMSI effect for ORR are highlighted.
碳负载pt基催化剂在质子交换膜燃料电池(pemfc)中氧还原反应(ORR)的实际应用仍然面临许多限制,包括碳腐蚀和与pt基纳米颗粒(NPs)的弱相互作用。利用pt基纳米颗粒与替代耐腐蚀非碳载体之间界面上的强金属-载体相互作用(SMSI)效应是解决这些问题的有效策略。合理设计具有良好SMSI的pt基催化剂并阐明这种相互作用的机制对于获得理想的活性和稳定性是必不可少的。本文首先简要介绍了ORR的基本原理。接下来,详细讨论了SMSI的形成过程、构建策略以及代表性载体,包括过渡金属氧化物、氮化物和碳化物(分别为TMOs、TMCs和TMNs)的优缺点。最后,指出了SMSI效应在ORR中实际应用中面临的挑战和前景。
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引用次数: 1
Microstructural constructing 2D tin allotropes on Al(111): from quasi-periodic lattice to square-like lattice Al(111)上二维锡同素异形体的微观结构:从拟周期晶格到方形晶格
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-01 DOI: 10.20517/microstructures.2023.01
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引用次数: 0
Grain engineering of high energy density BaTiO3 thick films integrated on Si Si上高能量密度BaTiO3厚膜的颗粒工程
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-01 DOI: 10.20517/microstructures.2023.22
J. Ouyang, Xiaoman Teng, Meiling Yuan, Kun Wang, Yuyao Zhao, Hongbo Cheng, Hanfei Zhu, Chao-Te Liu, Yongguang Xiao, M. Tang, Wei Zhang, W. Pan
Ferroelectric (FE) ceramics with a large relative dielectric permittivity and a high dielectric strength have the potential to store or supply electricity of very high energy and power densities, which is desirable in many modern electronic and electrical systems. For a given FE material, such as the commonly-used BaTiO3, a close interplay between defect chemistry, misfit strain, and grain characteristics must be carefully manipulated for engineering its film capacitors. In this work, the effects of grain orientation and morphology on the energy storage properties of BaTiO3 thick films were systematically investigated. These films were all deposited on Si at 500 °C in an oxygen-rich atmosphere, and their thicknesses varied between ~500 nm and ~2.6 μm. While a columnar nanograined BaTiO3 film with a (001) texture showed a higher recyclable energy density Wrec (81.0 J/cm3vs. 57.1 J/cm3 @3.2 MV/cm, ~40% increase) than that of a randomly-oriented BaTiO3 film of about the same thickness (~500 nm), the latter showed an improved energy density at a reduced electric field with an increasing film thickness. Specifically, for the 1.3 μm and 2.6 μm thick polycrystalline films, their energy storage densities Wrec reached 46.6 J/cm3 and 48.8 J/cm3 at an applied electric field of 2.31 MV/cm (300 V on 1.3 μm film) and 1.77 MV/cm (460 V on 2.6 μm film), respectively. This ramp-up in energy density can be attributed to increased polarizability with a growing grain size in thicker polycrystalline films and is desirable in high pulse power applications.
铁电(FE)陶瓷具有较大的相对介电常数和高介电强度,具有存储或提供非常高的能量和功率密度的电力的潜力,这在许多现代电子和电气系统中是理想的。对于给定的FE材料,例如常用的BaTiO3,必须仔细处理缺陷化学,失配应变和晶粒特性之间的密切相互作用,以设计其薄膜电容器。本文系统地研究了晶粒取向和形貌对BaTiO3厚膜储能性能的影响。这些薄膜均在500℃富氧气氛下沉积在Si表面,厚度在~500 nm ~ ~2.6 μm之间。而具有(001)织构的柱状纳米BaTiO3薄膜具有较高的可回收能量密度(81.0 J/cm3vs)。57.1 J/cm3 @3.2 MV/cm,比相同厚度(~500 nm)的随机取向BaTiO3薄膜的能量密度提高了约40%,随着薄膜厚度的增加,后者在电场减小的情况下表现出更高的能量密度。其中,1.3 μm和2.6 μm厚的多晶薄膜在2.31 MV/cm(在1.3 μm薄膜上施加300 V)和1.77 MV/cm(在2.6 μm薄膜上施加460 V)的外加电场下,储能密度分别达到46.6 J/cm3和48.8 J/cm3。这种能量密度的增加可以归因于在较厚的多晶薄膜中随着晶粒尺寸的增长而增加的极化率,并且在高脉冲功率应用中是理想的。
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引用次数: 0
What lies beneath? Investigations of atomic force microscopy-based nano-machining to reveal sub-surface ferroelectric domain configurations in ultrathin films 下面是什么?基于原子力显微镜的纳米加工研究揭示超薄膜的亚表面铁电畴结构
3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2023-01-01 DOI: 10.20517/microstructures.2023.41
Lynette Keeney, Louise Colfer, Debismita Dutta, Michael Schmidt, Guannan Wei
Multiferroic materials, encompassing simultaneous ferroelectric and ferromagnetic polarization states, are enticing multi-state materials for memory scaling beyond existing technologies. Aurivillius phase B6TFMO (Bi6TixFeyMnzO18) is a unique room temperature multiferroic material that could ideally be suited to future production of revolutionary memory devices. As miniaturization of electronic devices continues, it is crucial to characterize ferroelectric domain configurations at very small (sub-10 nm) thickness. Direct liquid injection chemical vapor deposition allows for frontier development of ultrathin films at fundamental (close to unit cell) dimensions. However, layer-by-layer growth of ultrathin complex oxides is subject to the formation of surface contaminants and 2D islands and pits, which can obscure visualization of domain patterns using piezoresponse force microscopy (PFM). Herein, we apply force from a sufficiently stiff diamond cantilever while scanning over ultrathin films to perform atomic force microscopy (AFM)-based nano-machining of the surface layers. Subsequent lateral PFM imaging of sub-surface layers uncovers 45° orientated striped twin domains, entirely distinct from the randomly configured piezoresponse observed for the pristine film surface. Furthermore, our investigations indicate that these sub-surface domain structures persist along the in-plane directions throughout the film depth down to thicknesses of less than half of an Aurivillius phase unit cell (˂ 2.5 nm). Thus, AFM-based nano-machining in conjunction with PFM allows demonstration of stable in-plane ferroelectric domains at thicknesses lower than previously determined for multiferroic B6TFMO. These findings demonstrate the technological potential of Aurivillius phase B6TFMO for future miniaturized memory storage devices. Next-generation devices based on ultrathin multiferroic tunnel junctions are projected.
多铁性材料,包括同时的铁电和铁磁极化状态,是诱人的多态材料的存储扩展超越现有的技术。Aurivillius相B6TFMO (Bi6TixFeyMnzO18)是一种独特的室温多铁性材料,可以理想地适用于未来革命性存储器件的生产。随着电子器件的不断小型化,表征非常小(低于10纳米)厚度的铁电畴结构至关重要。直接液体注入化学气相沉积允许超薄膜在基本(接近单位电池)尺寸的前沿发展。然而,超薄复合氧化物的逐层生长受到表面污染物和2D岛和坑的形成的影响,这可能会模糊使用压电响应力显微镜(PFM)的畴图案的可视化。在这里,我们在超薄薄膜扫描的同时,从一个足够坚硬的金刚石悬臂施加力,对表层进行基于原子力显微镜(AFM)的纳米加工。随后对亚表层的横向PFM成像发现了45°取向的条纹双畴,与原始膜表面观察到的随机配置的压电响应完全不同。此外,我们的研究表明,这些亚表面结构在整个薄膜深度沿平面方向持续存在,厚度小于一个奥瑞维利乌斯相单位电池的一半(小于2.5 nm)。因此,基于afm的纳米加工与PFM相结合,可以在厚度低于先前确定的多铁性B6TFMO的厚度下展示稳定的平面内铁电畴。这些发现证明了Aurivillius phase B6TFMO在未来小型化存储设备中的技术潜力。提出了基于超薄多铁隧道结的下一代器件。
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引用次数: 0
Deterrence of birds with an artificial predator, the RobotFalcon. 用人工捕食者 "机器猎鹰 "威慑鸟类。
IF 3.7 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-10-01 Epub Date: 2022-10-26 DOI: 10.1098/rsif.2022.0497
Rolf F Storms, Claudio Carere, Robert Musters, Hans van Gasteren, Simon Verhulst, Charlotte K Hemelrijk

Collisions between birds and airplanes can damage aircrafts, resulting in delays and cancellation of flights, costing the international civil aviation industry more than 1.4 billion US dollars annually. Driving away birds is therefore crucial, but the effectiveness of current deterrence methods is limited. Live avian predators can be an effective deterrent, because potential prey will not habituate to them, but live predators cannot be controlled entirely. Thus, there is an urgent need for new deterrence methods. We developed the RobotFalcon, a device modelled after the peregrine falcon, and tested its effectiveness to deter flocks of corvids, gulls, starlings and lapwings. We compared its effectiveness with that of a drone, and of conventional methods routinely applied at a military airbase. The RobotFalcon scared away bird flocks from fields immediately, and these fields subsequently remained free of bird flocks for hours. The RobotFalcon outperformed the drone and the best conventional method at the airbase (distress calls). Importantly, there was no evidence that bird flocks habituated to the RobotFalcon over the course of the fieldwork. We conclude that the RobotFalcon is a practical and ethical solution to drive away bird flocks with all advantages of live predators but without their limitations.

鸟类与飞机之间的碰撞会损坏飞机,导致航班延误和取消,使国际民航业每年损失超过 14 亿美元。因此,驱赶鸟类至关重要,但目前的威慑方法效果有限。活的鸟类捕食者可以起到有效的威慑作用,因为潜在的猎物不会对它们产生习性,但活的捕食者是无法完全控制的。因此,迫切需要新的威慑方法。我们开发了以游隼为模型的 RobotFalcon,并测试了它对成群乌鸦、海鸥、椋鸟和百灵鸟的威慑效果。我们将其效果与无人机和军事空军基地常规使用的传统方法进行了比较。RobotFalcon 立即将鸟群从田野中吓走,随后几个小时这些田野中都没有鸟群。机器猎鹰的表现优于无人机和空军基地的最佳常规方法(求救信号)。重要的是,在实地考察过程中,没有证据表明鸟群对机器猎鹰产生了习性。我们的结论是,"机器猎鹰 "是一种实用且符合道德规范的驱赶鸟群的解决方案,它具有活体捕食者的所有优点,但却没有其局限性。
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引用次数: 0
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Superlattices and Microstructures
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