首页 > 最新文献

Superlattices and Microstructures最新文献

英文 中文
An intriguing canting dipole configuration and its evolution under an electric field in La-doped Pb(Zr,Sn,Ti)O3 perovskites la掺杂Pb(Zr,Sn,Ti)O3钙钛矿中一个有趣的倾斜偶极子结构及其在电场下的演变
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.03
B. Gao, Hui Liu, Zhengyang Zhou, Ke Xu, He Qi, Shiqing Deng, Yang Ren, Junliang Sun, Houbing Huang, Jun Chen
Despite the fact that electric dipole ordering plays a key role in the unique physical properties of dielectric materials, electric dipole configurations mostly appear simply as either parallel or antiparallel. Here, we report a canting electric dipole configuration in La-doped Pb(Zr,Sn,Ti)O3 perovskites based on advanced neutron, synchrotron X-ray and three-dimensional electron diffraction techniques. It is revealed that, arising from the coupling between the atomic displacement and oxygen octahedral tilting, this unique electric dipole configuration displays a canting arrangement aligned in the (110)p plane that possesses an antiparallel component along the [110]P direction and a parallel component along the [001]P direction. Remarkably, under an in-situ electric field, the electric dipoles continuously rotate with a gradually reduced canting angle, as confirmed by phase-field simulations, and ultimately evolve into a ferroelectric ordering. Such an evolution gives rises to a small hysteresis and an equivalent lattice strain to the macroscopic strain. These findings enrich the current understanding of the types of electric dipole configurations in dielectric materials and are expected to aid the design of new dielectric materials with emergent properties.
尽管电偶极子的排列顺序在介电材料独特的物理性质中起着关键作用,但电偶极子的排列大多表现为简单的平行或反平行。在这里,我们报道了基于先进中子、同步x射线和三维电子衍射技术的la掺杂Pb(Zr,Sn,Ti)O3钙钛矿的倾斜电偶极子结构。结果表明,由于原子位移和氧八面体倾斜之间的耦合,这种独特的电偶极子结构在(110)p平面上呈现倾斜排列,具有沿[110]p方向的反平行分量和沿[001]p方向的平行分量。值得注意的是,在原位电场作用下,电偶极子连续旋转,倾斜角逐渐减小,相场模拟证实了这一点,并最终演变为铁电有序。这样的演化产生了一个小的迟滞和一个等效的晶格应变。这些发现丰富了目前对介电材料中电偶极子构型类型的理解,并有望帮助设计具有涌现特性的新型介电材料。
{"title":"An intriguing canting dipole configuration and its evolution under an electric field in La-doped Pb(Zr,Sn,Ti)O3 perovskites","authors":"B. Gao, Hui Liu, Zhengyang Zhou, Ke Xu, He Qi, Shiqing Deng, Yang Ren, Junliang Sun, Houbing Huang, Jun Chen","doi":"10.20517/microstructures.2022.03","DOIUrl":"https://doi.org/10.20517/microstructures.2022.03","url":null,"abstract":"Despite the fact that electric dipole ordering plays a key role in the unique physical properties of dielectric materials, electric dipole configurations mostly appear simply as either parallel or antiparallel. Here, we report a canting electric dipole configuration in La-doped Pb(Zr,Sn,Ti)O3 perovskites based on advanced neutron, synchrotron X-ray and three-dimensional electron diffraction techniques. It is revealed that, arising from the coupling between the atomic displacement and oxygen octahedral tilting, this unique electric dipole configuration displays a canting arrangement aligned in the (110)p plane that possesses an antiparallel component along the [110]P direction and a parallel component along the [001]P direction. Remarkably, under an in-situ electric field, the electric dipoles continuously rotate with a gradually reduced canting angle, as confirmed by phase-field simulations, and ultimately evolve into a ferroelectric ordering. Such an evolution gives rises to a small hysteresis and an equivalent lattice strain to the macroscopic strain. These findings enrich the current understanding of the types of electric dipole configurations in dielectric materials and are expected to aid the design of new dielectric materials with emergent properties.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"130 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74542355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Study of thermochromic and photocatalytic properties of MoO3 thin films MoO3薄膜的热致变色和光催化性能研究
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.1016/j.spmi.2021.107096
V.R. Sreelakshmi , A. Anu Kaliani , M. Jithin

Molybdenum trioxide (MoO3) thin films with thicknesses 300, 400 and 500 nm were deposited on an FTO substrate by thermal evaporation method. The prepared thin films showed both thermochromic and photocatalytic dye degradation properties. The thermochromic property of the prepared thin films was induced by exposing the thin films to argon gas at a temperature varying from 100 °C to 300 °C (in steps of 50 °C). The photocatalytic dye degradation ability of the films were examined by the photodegradation of methylene blue (MB) dye solution under visible light irradiation. MoO3 thin film with 300 nm thickness is seen to have good thermochromic and photocatalytic dye degradation ability and both of these properties are necessary for smart window applications.

采用热蒸发法在FTO衬底上制备了厚度分别为300、400和500 nm的三氧化钼(MoO3)薄膜。制备的薄膜具有热致变色和光催化降解染料的性能。将薄膜在100 ~ 300℃的氩气中(以50℃为步骤)暴露,可诱导薄膜的热致变色性能。通过可见光下亚甲基蓝(MB)染料溶液的光降解实验,考察了膜的光催化降解染料能力。厚度为300 nm的MoO3薄膜具有良好的热致变色和光催化染料降解能力,这两种性能都是智能窗应用所必需的。
{"title":"Study of thermochromic and photocatalytic properties of MoO3 thin films","authors":"V.R. Sreelakshmi ,&nbsp;A. Anu Kaliani ,&nbsp;M. Jithin","doi":"10.1016/j.spmi.2021.107096","DOIUrl":"10.1016/j.spmi.2021.107096","url":null,"abstract":"<div><p>Molybdenum trioxide (MoO<sub>3</sub><span><span><span><span>) thin films<span> with thicknesses 300, 400 and 500 nm were deposited on an FTO substrate by thermal evaporation method. The prepared thin films showed both </span></span>thermochromic<span> and photocatalytic dye degradation properties. The thermochromic property of the prepared thin films was induced by exposing the thin films to argon </span></span>gas at a temperature varying from 100 °C to 300 °C (in steps of 50 °C). The photocatalytic dye degradation ability of the films were examined by the photodegradation of methylene blue (MB) dye solution under </span>visible light irradiation. MoO</span><sub>3</sub> thin film with 300 nm thickness is seen to have good thermochromic and photocatalytic dye degradation ability and both of these properties are necessary for smart window applications.</p></div>","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"161 ","pages":"Article 107096"},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48566502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
BaTiO3-NaNbO3 energy storage ceramics with an ultrafast charge-discharge rate and temperature-stable power density 具有超快充放电速率和温度稳定功率密度的BaTiO3-NaNbO3储能陶瓷
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.21
Peiyao Zhao, Longtu Li, Xiao-hui Wang, Prof. Xiaohui Wang, Shiqing Deng, R. Zuo, Shujun Zhang
Dielectric capacitors with ultrafast charge-discharge rates are extensively used in electrical and electronic systems. To meet the growing demand for energy storage applications, researchers have devoted significant attention to dielectric ceramics with excellent energy storage properties. As a result, the awareness of the importance of the pulsed discharge behavior of dielectric ceramics and conducting characterization studies has been raised. However, the temperature stability of pulsed discharge behavior, which is significant for pulsed power applications, is still not given the necessary consideration. Here, we systematically investigate the microstructures, energy storage properties and discharge behaviors of nanograined (1-x)BaTiO3-xNaNbO3 ceramics prepared by a two-step sintering method. The 0.60BaTiO3-0.40NaNbO3 ceramics with relaxor ferroelectric characteristics possess an optimal discharge energy density of 3.07 J cm-3, a high energy efficiency of 92.6%, an ultrafast discharge rate of 39 ns and a high power density of 100 MW cm-3. In addition to stable energy storage properties in terms of frequency, fatigue and temperature, the 0.60BaTiO3-0.40NaNbO3 ceramics exhibit temperature-stable power density, thereby illustrating their significant potential for power electronics and pulsed power applications.
具有超快充放电速率的介质电容器广泛应用于电气和电子系统中。为了满足日益增长的储能应用需求,具有优异储能性能的介电陶瓷受到了研究人员的极大关注。因此,人们对介电陶瓷脉冲放电特性和导电特性研究的重要性有了更高的认识。然而,对脉冲功率应用具有重要意义的脉冲放电行为的温度稳定性仍然没有得到必要的考虑。本文系统地研究了两步烧结法制备的纳米(1-x)BaTiO3-xNaNbO3陶瓷的微观结构、储能性能和放电行为。具有弛豫铁电特性的0.60BaTiO3-0.40NaNbO3陶瓷的最佳放电能量密度为3.07 J cm-3,高能量效率为92.6%,超快放电率为39 ns,功率密度为100 MW cm-3。除了在频率、疲劳和温度方面具有稳定的储能性能外,0.60BaTiO3-0.40NaNbO3陶瓷还具有温度稳定的功率密度,从而表明其在电力电子和脉冲功率应用方面的巨大潜力。
{"title":"BaTiO3-NaNbO3 energy storage ceramics with an ultrafast charge-discharge rate and temperature-stable power density","authors":"Peiyao Zhao, Longtu Li, Xiao-hui Wang, Prof. Xiaohui Wang, Shiqing Deng, R. Zuo, Shujun Zhang","doi":"10.20517/microstructures.2022.21","DOIUrl":"https://doi.org/10.20517/microstructures.2022.21","url":null,"abstract":"Dielectric capacitors with ultrafast charge-discharge rates are extensively used in electrical and electronic systems. To meet the growing demand for energy storage applications, researchers have devoted significant attention to dielectric ceramics with excellent energy storage properties. As a result, the awareness of the importance of the pulsed discharge behavior of dielectric ceramics and conducting characterization studies has been raised. However, the temperature stability of pulsed discharge behavior, which is significant for pulsed power applications, is still not given the necessary consideration. Here, we systematically investigate the microstructures, energy storage properties and discharge behaviors of nanograined (1-x)BaTiO3-xNaNbO3 ceramics prepared by a two-step sintering method. The 0.60BaTiO3-0.40NaNbO3 ceramics with relaxor ferroelectric characteristics possess an optimal discharge energy density of 3.07 J cm-3, a high energy efficiency of 92.6%, an ultrafast discharge rate of 39 ns and a high power density of 100 MW cm-3. In addition to stable energy storage properties in terms of frequency, fatigue and temperature, the 0.60BaTiO3-0.40NaNbO3 ceramics exhibit temperature-stable power density, thereby illustrating their significant potential for power electronics and pulsed power applications.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"12 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79983053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Modulation of photogenerated holes for enhanced photoelectrocatalytic performance 提高光电催化性能的光生孔调制
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.23
N. Liu, Yixian Liu, Yunliang Liu, Yaxi Li, Yuanyuan Cheng, Hai-tao Li
Utilizing clean energy derived from photoelectrocatalytic reactions is expected to be an excellent choice to fundamentally solve the problem of the human energy crisis. Photoelectrochemical (PEC) cell can effectively promote charge separation and improve solar energy conversion efficiency since it combines the advantages of photocatalysis and electrocatalysis. However, the hole transfer and subsequent oxidation reaction in the PEC process are slow, resulting in the rapid recombination of photogenerated electron-hole pairs and low PEC performance. The half-oxidation reaction involving photogenerated holes is the bottleneck of PEC water splitting. Therefore, hole modulation has been an important research area in the field of catalysis. However, compared with electron modulation, research on hole modulation is limited and still faces great challenges. It is therefore of great significance to develop effective modulation strategies for photogenerated holes. This review summarizes the hole modulation strategies developed in the last five years, including hole sacrificial agents, nanostructural modification, heterostructure construction and cocatalyst modification. Hole modulation dynamics studies, such as transient absorption spectroscopy, time-resolved photoluminescence spectroscopy, transient photovoltage and scanning electrochemical microscopy, are also summarized. Moreover, relevant conclusions and an outlook are proposed.
利用光电催化反应产生的清洁能源有望成为从根本上解决人类能源危机问题的绝佳选择。光电化学(PEC)电池结合了光催化和电催化的优点,可以有效地促进电荷分离,提高太阳能转换效率。然而,在PEC过程中空穴转移和随后的氧化反应较慢,导致光生电子-空穴对的快速重组,降低了PEC性能。光生空穴的半氧化反应是PEC水裂解的瓶颈。因此,空穴调制一直是催化领域的一个重要研究方向。然而,与电子调制相比,空穴调制的研究是有限的,仍然面临着很大的挑战。因此,开发有效的光生空穴调制策略具有重要意义。本文综述了近五年来发展起来的空穴调制策略,包括空穴牺牲剂、纳米结构修饰、异质结构构建和助催化剂修饰。综述了空穴调制动力学的研究,如瞬态吸收光谱、时间分辨光致发光光谱、瞬态光电压和扫描电化学显微镜。并提出了相关结论和展望。
{"title":"Modulation of photogenerated holes for enhanced photoelectrocatalytic performance","authors":"N. Liu, Yixian Liu, Yunliang Liu, Yaxi Li, Yuanyuan Cheng, Hai-tao Li","doi":"10.20517/microstructures.2022.23","DOIUrl":"https://doi.org/10.20517/microstructures.2022.23","url":null,"abstract":"Utilizing clean energy derived from photoelectrocatalytic reactions is expected to be an excellent choice to fundamentally solve the problem of the human energy crisis. Photoelectrochemical (PEC) cell can effectively promote charge separation and improve solar energy conversion efficiency since it combines the advantages of photocatalysis and electrocatalysis. However, the hole transfer and subsequent oxidation reaction in the PEC process are slow, resulting in the rapid recombination of photogenerated electron-hole pairs and low PEC performance. The half-oxidation reaction involving photogenerated holes is the bottleneck of PEC water splitting. Therefore, hole modulation has been an important research area in the field of catalysis. However, compared with electron modulation, research on hole modulation is limited and still faces great challenges. It is therefore of great significance to develop effective modulation strategies for photogenerated holes. This review summarizes the hole modulation strategies developed in the last five years, including hole sacrificial agents, nanostructural modification, heterostructure construction and cocatalyst modification. Hole modulation dynamics studies, such as transient absorption spectroscopy, time-resolved photoluminescence spectroscopy, transient photovoltage and scanning electrochemical microscopy, are also summarized. Moreover, relevant conclusions and an outlook are proposed.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"73 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83267360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Near-room-temperature reversible switching of quadratic optical nonlinearities in a one-dimensional perovskite-like hybrid 一维钙钛矿类杂化材料中二次光学非线性的近室温可逆开关
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.09
Qing-bin Fan, Yu Ma, Haojie Xu, Yipeng Song, Yi Liu, Junhua Luo, Zhihua Sun
The switching of quadratic nonlinear optical (NLO) effects between two or more NLO states of solid-state materials represents an intriguing new branch in the field of photoelectrics and optics. While structural phase transitions have shown potential in this field, near-room-temperature reversible NLO switches have rarely been reported. To exploit new NLO switching materials within the structurally flexible class of hybrid perovskites, here, we synthesize a one-dimensional perovskite-like hybrid, (MP)PbBr3 (where MP+ is a 1-methylpyrrolidinium cation), through a facile solution method, which exhibits strong second harmonic generation (SHG) activities with an intensity of ~1.6 times as large as potassium dihydrogen phosphate. Intriguingly, (MP)PbBr3 enables the near-room temperature reversible switching of SHG properties, showing a large NLO switching contrast of up to ~40 between its SHG-active and SHG-inactive phases, beyond most of its liquid counterparts. Further microscopic structural analyses reveal that the dynamic ordering of the organic MP+ cation and inorganic chain-like skeleton triggers its centrosymmetric (P63/mmc) to acentric (P212121) phase transition at 316 K upon cooling, resulting in a crucial contribution to its NLO switching properties. This work illustrates the potential of this material as a candidate for solid-state NLO switches and will promote the development of NLO materials within the family of low-dimensional hybrid perovskites.
二次非线性光学(NLO)效应在固态材料的两个或多个NLO态之间的切换是光电光学领域一个有趣的新分支。虽然结构相变在该领域显示出潜力,但近室温可逆NLO开关很少被报道。为了在结构灵活的杂化钙钛矿中开发新的NLO开关材料,本文通过易溶法合成了一维类钙钛矿杂化物(MP)PbBr3(其中MP+是1-甲基吡啶鎓离子),该杂化物具有强的二次谐波生成(SHG)活性,强度约为磷酸二氢钾的1.6倍。有趣的是,(MP)PbBr3能够实现近室温下SHG性质的可逆切换,在其SHG活性相和SHG非活性相之间显示出高达~40的NLO切换对比度,超过了大多数液体对应物。进一步的微观结构分析表明,有机MP+阳离子和无机链状骨架的动态排序触发了其中心对称(P63/mmc)到非中心(P212121)的相变,导致其NLO开关性能的关键贡献。这项工作说明了这种材料作为固态NLO开关的候选材料的潜力,并将促进低维混合钙钛矿家族中NLO材料的发展。
{"title":"Near-room-temperature reversible switching of quadratic optical nonlinearities in a one-dimensional perovskite-like hybrid","authors":"Qing-bin Fan, Yu Ma, Haojie Xu, Yipeng Song, Yi Liu, Junhua Luo, Zhihua Sun","doi":"10.20517/microstructures.2022.09","DOIUrl":"https://doi.org/10.20517/microstructures.2022.09","url":null,"abstract":"The switching of quadratic nonlinear optical (NLO) effects between two or more NLO states of solid-state materials represents an intriguing new branch in the field of photoelectrics and optics. While structural phase transitions have shown potential in this field, near-room-temperature reversible NLO switches have rarely been reported. To exploit new NLO switching materials within the structurally flexible class of hybrid perovskites, here, we synthesize a one-dimensional perovskite-like hybrid, (MP)PbBr3 (where MP+ is a 1-methylpyrrolidinium cation), through a facile solution method, which exhibits strong second harmonic generation (SHG) activities with an intensity of ~1.6 times as large as potassium dihydrogen phosphate. Intriguingly, (MP)PbBr3 enables the near-room temperature reversible switching of SHG properties, showing a large NLO switching contrast of up to ~40 between its SHG-active and SHG-inactive phases, beyond most of its liquid counterparts. Further microscopic structural analyses reveal that the dynamic ordering of the organic MP+ cation and inorganic chain-like skeleton triggers its centrosymmetric (P63/mmc) to acentric (P212121) phase transition at 316 K upon cooling, resulting in a crucial contribution to its NLO switching properties. This work illustrates the potential of this material as a candidate for solid-state NLO switches and will promote the development of NLO materials within the family of low-dimensional hybrid perovskites.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"20 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73444026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Tunable negative thermal expansion in La(Fe, Si)13/resin composites with high mechanical property and long-term cycle stability La(Fe, Si)13/树脂复合材料的可调负热膨胀,具有高力学性能和长期循环稳定性
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.13
He Zhou, Yuwei Liu, Rongjin Huang, Bo Chen, Min Xia, Ziyuan Yu, Haodong Chen, K. Qiao, J. Cong, S. Taskaev, K. Chu, Hu Zhang
Materials with tunable negative thermal expansion (NTE) are highly demanded in various functional devices. La(Fe, Si)13-based compounds are promising NTE materials due to their outstanding NTE properties. However, their poor mechanical properties and related short service life restrict their practical applications. In this work, epoxy resin with positive thermal expansion is used to synthesize La-Fe-Si/resin composites. The NTE of La-Fe-Si/resin composites can be manipulated by optimizing the La-Fe-Si particle size and resin content, and tailoring resin content could tune the NTE more effectively. The average linear coefficient of thermal expansion of the composites decreases from -275.0 × 10-6 K-1 to -4.9 × 10-6 K-1 over the magnetic transition temperature range as the resin content increases from 3 wt.% to 80 wt.%. In addition, zero thermal expansion is achieved in the La-Fe-Si/resin composite with 20 wt.% resin. The resin would reinforce the binding force by filling the pores between the particles. The La-Fe-Si/resin composite with 80 wt.% resin exhibits highly improved mechanical properties; for example, its compressive strength of 205 MPa is 75% higher than that of the La-Fe-Si/resin composite with 3 wt.% resin. The prepared La-Fe-Si/resin composites can be machined into different shapes for practical applications, such as thin plates, strips, and rods. Furthermore, the La-Fe-Si/resin composites can undergo 1000 thermal cycles without NTE performance degradation and mechanical integrity loss, indicating durable cycle stability. Hence, significantly tunable NTE with high mechanical properties and long-term cycle stability makes La-Fe-Si/resin composites present great application potential as NTE materials.
具有可调负热膨胀(NTE)的材料在各种功能器件中都有很高的需求。La(Fe, Si)13基化合物因其优异的NTE性能而成为很有前途的NTE材料。但其力学性能差,使用寿命短,限制了其实际应用。本文采用正热膨胀的环氧树脂合成了La-Fe-Si/树脂复合材料。La-Fe-Si/树脂复合材料的NTE可以通过优化La-Fe-Si的粒径和树脂含量来控制,而调整树脂含量可以更有效地调节NTE。在磁转变温度范围内,随着树脂含量从3 wt.%增加到80 wt.%,复合材料的平均热膨胀线性系数从-275.0 × 10-6 K-1降低到-4.9 × 10-6 K-1。此外,在含20 wt.%树脂的La-Fe-Si/树脂复合材料中实现了零热膨胀。树脂会通过填充颗粒之间的孔隙来增强结合力。含80 wt.%树脂的La-Fe-Si/树脂复合材料的力学性能得到了显著改善;例如,其抗压强度为205 MPa,比含有3 wt.%树脂的La-Fe-Si/树脂复合材料的抗压强度提高75%。制备的La-Fe-Si/树脂复合材料可以加工成不同形状的实际应用,如薄板,条状和棒状。此外,La-Fe-Si/树脂复合材料可以经历1000次热循环而不会导致NTE性能下降和机械完整性损失,表明持久的循环稳定性。因此,具有高机械性能和长期循环稳定性的显著可调NTE使得La-Fe-Si/树脂复合材料作为NTE材料具有很大的应用潜力。
{"title":"Tunable negative thermal expansion in La(Fe, Si)13/resin composites with high mechanical property and long-term cycle stability","authors":"He Zhou, Yuwei Liu, Rongjin Huang, Bo Chen, Min Xia, Ziyuan Yu, Haodong Chen, K. Qiao, J. Cong, S. Taskaev, K. Chu, Hu Zhang","doi":"10.20517/microstructures.2022.13","DOIUrl":"https://doi.org/10.20517/microstructures.2022.13","url":null,"abstract":"Materials with tunable negative thermal expansion (NTE) are highly demanded in various functional devices. La(Fe, Si)13-based compounds are promising NTE materials due to their outstanding NTE properties. However, their poor mechanical properties and related short service life restrict their practical applications. In this work, epoxy resin with positive thermal expansion is used to synthesize La-Fe-Si/resin composites. The NTE of La-Fe-Si/resin composites can be manipulated by optimizing the La-Fe-Si particle size and resin content, and tailoring resin content could tune the NTE more effectively. The average linear coefficient of thermal expansion of the composites decreases from -275.0 × 10-6 K-1 to -4.9 × 10-6 K-1 over the magnetic transition temperature range as the resin content increases from 3 wt.% to 80 wt.%. In addition, zero thermal expansion is achieved in the La-Fe-Si/resin composite with 20 wt.% resin. The resin would reinforce the binding force by filling the pores between the particles. The La-Fe-Si/resin composite with 80 wt.% resin exhibits highly improved mechanical properties; for example, its compressive strength of 205 MPa is 75% higher than that of the La-Fe-Si/resin composite with 3 wt.% resin. The prepared La-Fe-Si/resin composites can be machined into different shapes for practical applications, such as thin plates, strips, and rods. Furthermore, the La-Fe-Si/resin composites can undergo 1000 thermal cycles without NTE performance degradation and mechanical integrity loss, indicating durable cycle stability. Hence, significantly tunable NTE with high mechanical properties and long-term cycle stability makes La-Fe-Si/resin composites present great application potential as NTE materials.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"20 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87430927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Design of super-elastic freestanding ferroelectric thin films guided by phase-field simulations 基于相场模拟的超弹性独立铁电薄膜设计
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.20
Changqing Guo, Houbing Huang
Understanding the dynamic behavior of domain structures is critical to the design and application of super-elastic freestanding ferroelectric thin films. Phase-field simulations represent a powerful tool for observing, exploring and revealing the domain-switching behavior and phase transitions in ferroelectric materials at the mesoscopic scale. This review summarizes the recent theoretical progress regarding phase-field methods in freestanding ferroelectric thin films and novel buckling-induced wrinkled and helical structures. Furthermore, the strong coupling relationship between strain and ferroelectric polarization in super-elastic ferroelectric nanostructures is confirmed and discussed, resulting in new design strategies for the strain engineering of freestanding ferroelectric thin film systems. Finally, to further promote the innovative development and application of freestanding ferroelectric thin film systems, this review provides a summary and outlook on the theoretical modeling of freestanding ferroelectric thin films.
了解畴结构的动力学行为对超弹性独立铁电薄膜的设计和应用至关重要。相场模拟是在介观尺度上观察、探索和揭示铁电材料的畴切换行为和相变的有力工具。本文综述了近年来在独立铁电薄膜和新型屈曲诱导的起皱和螺旋结构中的相场方法的理论进展。此外,还证实并讨论了超弹性铁电纳米结构中应变与铁电极化之间的强耦合关系,为独立铁电薄膜系统的应变工程设计提供了新的策略。最后,为了进一步促进独立铁电薄膜系统的创新发展和应用,本文对独立铁电薄膜的理论建模进行了总结和展望。
{"title":"Design of super-elastic freestanding ferroelectric thin films guided by phase-field simulations","authors":"Changqing Guo, Houbing Huang","doi":"10.20517/microstructures.2022.20","DOIUrl":"https://doi.org/10.20517/microstructures.2022.20","url":null,"abstract":"Understanding the dynamic behavior of domain structures is critical to the design and application of super-elastic freestanding ferroelectric thin films. Phase-field simulations represent a powerful tool for observing, exploring and revealing the domain-switching behavior and phase transitions in ferroelectric materials at the mesoscopic scale. This review summarizes the recent theoretical progress regarding phase-field methods in freestanding ferroelectric thin films and novel buckling-induced wrinkled and helical structures. Furthermore, the strong coupling relationship between strain and ferroelectric polarization in super-elastic ferroelectric nanostructures is confirmed and discussed, resulting in new design strategies for the strain engineering of freestanding ferroelectric thin film systems. Finally, to further promote the innovative development and application of freestanding ferroelectric thin film systems, this review provides a summary and outlook on the theoretical modeling of freestanding ferroelectric thin films.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"6 1 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72975251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Normally-off AlGaN/AlN/GaN HEMT with a composite recessed gate 常关AlGaN/AlN/GaN HEMT与复合凹槽栅极
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.1016/j.spmi.2021.107064
Jialin Li , Yian Yin , Ni Zeng , Fengbo Liao , Mengxiao Lian , Xichen Zhang , Keming Zhang , Jingbo Li

As we all know, the normally-off HEMT is very important to the safety of power electronic systems. To increase the threshold voltage of the device, this article proposes to cover Al2O3 on the recessed P-GaN to form the recessed p-GaN HEMT covered with Al2O3. Through simulation calculation, covering Al2O3 on P-GaN can effectively increase the threshold voltage, but the saturation current and transconductance will be severely reduced. Therefore, this article optimizes the structure and proposes a composite recessed-gate HEMT for the first time. It can obtain high saturation current and high transconductance while maintaining a high threshold voltage. Compared with the recessed p-GaN HEMT covered with Al2O3, the transconductance and saturation current of the composite recessed-gate HEMT are increased by 13.14% and 121.33%, respectively, while the threshold voltage is only reduced by 4.44% (4.3 V). In addition, the gate dielectric has a greater impact on device performance. Therefore, this paper analyzes the influence of the thickness of the Al2O3 layer on the device through theoretical calculations and obtains the optimal value of the thickness. (T1 = 18.3 nm, Vth = 4.5 V, Isat = 456 mA/mm). The results show that the composite recessed gate has broad application prospects in the next generation of normally-off power device applications.

众所周知,正常关闭的HEMT对电力电子系统的安全至关重要。为了提高器件的阈值电压,本文提出在凹槽P-GaN上覆盖Al2O3,形成覆盖Al2O3的凹槽P-GaN HEMT。通过仿真计算,在P-GaN表面覆盖Al2O3可以有效提高阈值电压,但会严重降低饱和电流和跨导。因此,本文对结构进行了优化,首次提出了一种复合凹栅HEMT。它可以在保持高阈值电压的同时获得高饱和电流和高跨导。与覆盖Al2O3的凹槽p-GaN HEMT相比,复合凹槽栅HEMT的跨导和饱和电流分别提高了13.14%和121.33%,而阈值电压仅降低了4.44% (4.3 V)。此外,栅极介质对器件性能的影响更大。因此,本文通过理论计算分析了Al2O3层厚度对器件的影响,得到了厚度的最优值。(T1 = 18.3 nm, Vth = 4.5 V, Isat = 456 mA/mm)。结果表明,复合凹槽栅极在下一代常关电源器件应用中具有广阔的应用前景。
{"title":"Normally-off AlGaN/AlN/GaN HEMT with a composite recessed gate","authors":"Jialin Li ,&nbsp;Yian Yin ,&nbsp;Ni Zeng ,&nbsp;Fengbo Liao ,&nbsp;Mengxiao Lian ,&nbsp;Xichen Zhang ,&nbsp;Keming Zhang ,&nbsp;Jingbo Li","doi":"10.1016/j.spmi.2021.107064","DOIUrl":"10.1016/j.spmi.2021.107064","url":null,"abstract":"<div><p><span>As we all know, the normally-off HEMT is very important to the safety of power electronic systems. To increase the threshold voltage of the device, this article proposes to cover Al</span><sub>2</sub>O<sub>3</sub> on the recessed P-GaN to form the recessed p-GaN HEMT covered with Al<sub>2</sub>O<sub>3</sub>. Through simulation calculation, covering Al<sub>2</sub>O<sub>3</sub> on P-GaN can effectively increase the threshold voltage, but the saturation current and transconductance will be severely reduced. Therefore, this article optimizes the structure and proposes a composite recessed-gate HEMT for the first time. It can obtain high saturation current and high transconductance while maintaining a high threshold voltage. Compared with the recessed p-GaN HEMT covered with Al<sub>2</sub>O<sub>3</sub><span>, the transconductance and saturation current of the composite recessed-gate HEMT are increased by 13.14% and 121.33%, respectively, while the threshold voltage is only reduced by 4.44% (4.3 V). In addition, the gate dielectric has a greater impact on device performance. Therefore, this paper analyzes the influence of the thickness of the Al</span><sub>2</sub>O<sub>3</sub> layer on the device through theoretical calculations and obtains the optimal value of the thickness. (T1 = 18.3 nm, Vth = 4.5 V, Isat = 456 mA/mm). The results show that the composite recessed gate has broad application prospects in the next generation of normally-off power device applications.</p></div>","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"161 ","pages":"Article 107064"},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47505236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Performance optimization of single graded CIGS absorber and buffer layers for high efficiency: A numerical approach 单梯度CIGS吸收体和高效缓冲层的性能优化:数值方法
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.1016/j.spmi.2021.107094
R. Prasad, Rajarshi Pal, Udai P. Singh

We present a numerical simulation based study of single graded Cu(In,Ga)Se2 (Copper Indium Gallium Diselenide) thin film solar cell. In this work, initially a basic CIGS single graded cell structure is optimized in terms of thickness, band-gap and doping concentration. CdS is kept as the buffer layer, which is widely used for high efficiency CIGS solar cells. In the next step, CdS is replaced with ZnMgO as the buffer layer in order to exploit its greater photon absorption ability due to its higher band-gap which further enhances the cell efficiency. A thorough analysis is carried out on the solar cell parameters open circuit voltage (Voc), short circuit current density (Jsc), fill factor (FF) and quantum efficiency (η) of the photovoltaic cell structure. An intermediate layer of p-type MoS2 is inserted in between the single graded CIGS absorber layers. The objective is to limit the unintentional Ga inter diffusion and maintain the desired grading during the high temperature annealing for the absorber preparation. The power conversion efficiency of the bilayer device structure with Ga fraction x=(0.31) of the top absorber layer along with Ga fraction y=(0.25) of the bottom absorber layer exhibits an improved efficiency from 24.02% (CdS as the buffer layer) to 25.37% (ZnMgO as buffer layer). An excellent power efficiency of η = 26.78% is reported after adding the intermediate layer of p-type MoS2 and optimizing its thickness and the carrier concentration.

我们提出了一种基于数值模拟的单梯度Cu(In,Ga)Se2(铜铟镓二硒化物)薄膜太阳能电池。在这项工作中,首先从厚度、带隙和掺杂浓度方面优化了基本的CIGS单梯度电池结构。CdS作为缓冲层,广泛应用于高效CIGS太阳能电池。下一步,将CdS替换为ZnMgO作为缓冲层,利用其更高的带隙带来的更强的光子吸收能力,进一步提高电池效率。对太阳能电池结构的开路电压(Voc)、短路电流密度(Jsc)、填充系数(FF)和量子效率(η)等参数进行了深入分析。在单梯度CIGS吸收层之间插入p型二硫化钼中间层。目的是在吸收剂制备的高温退火过程中限制无意的Ga间扩散并保持所需的分级。顶部吸收层Ga分数x=(0.31),底部吸收层Ga分数y=(0.25)的双层器件结构的功率转换效率从24.02% (CdS为缓冲层)提高到25.37% (ZnMgO为缓冲层)。加入p型二硫化钼中间层并优化其厚度和载流子浓度后,功率效率达到了26.78%。
{"title":"Performance optimization of single graded CIGS absorber and buffer layers for high efficiency: A numerical approach","authors":"R. Prasad,&nbsp;Rajarshi Pal,&nbsp;Udai P. Singh","doi":"10.1016/j.spmi.2021.107094","DOIUrl":"10.1016/j.spmi.2021.107094","url":null,"abstract":"<div><p>We present a numerical simulation based study of single graded Cu(In,Ga)Se<sub>2</sub><span><span> (Copper Indium </span>Gallium<span><span> Diselenide) thin film<span> solar cell. In this work, initially a basic CIGS single graded cell structure is optimized in terms of thickness, band-gap and doping concentration. CdS is kept as the buffer layer, which is widely used for high efficiency CIGS solar cells. In the next step, CdS is replaced with ZnMgO as the buffer layer in order to exploit its greater </span></span>photon absorption ability due to its higher band-gap which further enhances the cell efficiency. A thorough analysis is carried out on the solar cell parameters open circuit voltage (V</span></span><sub>oc</sub>), short circuit current density (J<sub>sc</sub><span>), fill factor (FF) and quantum efficiency (η) of the photovoltaic cell structure. An intermediate layer of p-type MoS</span><sub>2</sub><span> is inserted in between the single graded CIGS absorber layers. The objective is to limit the unintentional Ga inter diffusion and maintain the desired grading during the high temperature annealing for the absorber preparation. The power conversion efficiency of the bilayer device structure with Ga fraction x=(0.31) of the top absorber layer along with Ga fraction y=(0.25) of the bottom absorber layer exhibits an improved efficiency from 24.02% (CdS as the buffer layer) to 25.37% (ZnMgO as buffer layer). An excellent power efficiency of η = 26.78% is reported after adding the intermediate layer of p-type MoS</span><sub>2</sub> and optimizing its thickness and the carrier concentration.</p></div>","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"161 ","pages":"Article 107094"},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45121827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Topochemical synthesis and structural characteristics of orientation-controlled (Bi0.5Na0.5)0.94Ba0.06TiO3 perovskite microplatelets 取向可控(Bi0.5Na0.5)0.94Ba0.06TiO3钙钛矿微血小板的拓扑化学合成及结构特性
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2021.13
Yaqing Ma, H. Xie, Yuan Sun, Q. Kou, Linjing Liu, Bin Yang, W. Cao, Yunfei Chang, Feifang Li
{"title":"Topochemical synthesis and structural characteristics of orientation-controlled (Bi0.5Na0.5)0.94Ba0.06TiO3 perovskite microplatelets","authors":"Yaqing Ma, H. Xie, Yuan Sun, Q. Kou, Linjing Liu, Bin Yang, W. Cao, Yunfei Chang, Feifang Li","doi":"10.20517/microstructures.2021.13","DOIUrl":"https://doi.org/10.20517/microstructures.2021.13","url":null,"abstract":"","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":"762 ","pages":""},"PeriodicalIF":3.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72437897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
Superlattices and Microstructures
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1