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Wind effects on stomatal conductance and leaf temperature of tree seedlings distributed in various habitats of the Nanjenshan forest, southern Taiwan. 风对南金山不同生境树木幼苗气孔导度和叶温的影响。
Q4 Agricultural and Biological Sciences Pub Date : 2011-03-01 DOI: 10.7075/TJFS.201103.0001
Kuo YauLun, Lee YanPing, Yang YehLin
Forests of Nanjenshan, located in southern Taiwan, are chronically disturbed by strong winds of the northeasterly monsoon for as long as 6 mo each year. However, not much is known about the effects of wind on stomatal activities of trees that are found there. This research chose seedlings of 18 species representing tree species either growing specifically at a windward site, a leeward site, or ubiquitously at both sites. We measured variations in stomatal conductance of these species in a walk-in growth chamber, where the wind speeds were adjusted to 1~4 m s^(-1). Results showed that at wind speeds of 1 and 2 m s^(-1), 9 and 17 species, respectively, of the 18 tested species showed significantly lower stomatal conductance than that of the control. Under wind speeds of 3 and 4 m s^(-1), reductions in the stomatal conductance of windward species were significantly less than those of species from the other 2 habitat types. At a wind speed of 4 m s^(-1), stomatal conductance of leeward species and ubiquitous species had decreased 43 and 34%, respectively, but had only decreased by 27% in windward species. The slope obtained from a linear regression analysis of variation in the percentages of stomatal conductance vs. increasing wind speeds of each species was also significantly steeper in leeward species than in windward species. In another experiment, we exposed seedlings of all 18 tested species to a wind speed of 6 m s^(-1) for 10 min and monitored variations in leaf temperatures. The leaf temperature of windward species decreased 3.4℃ on average, while it decreased 4.8℃ (significantly differing from the former) in leeward species. Species with a larger leaf mass per unit area or smaller leaf area were less affected by wind, in terms of both lowered leaf temperatures and decreased stomatal conductance. Windward species of the Nanjenshan forest, in contrast to leeward species, had larger leaf masses per unit area and smaller leaf areas; they did not exhibit substantial reductions in stomatal conductance or leaf temperatures under windy conditions. Possessing the aforementioned morphological and physiological characteristics, the windward species of the Nanjenshan forest clearly have adapted to the chronic wind stress of the northeasterly monsoon.
南jenshan的森林,位于台湾南部,长期受到东北季风强风的干扰,每年长达6个月。然而,人们对风对那里树木气孔活动的影响知之甚少。本研究选择了18种代表树种的幼苗,这些树种要么在迎风地点生长,要么在背风地点生长,要么在两个地点都普遍生长。在风速调节为1~4 m s^(-1)的步入式生长室内,我们测量了这些物种气孔导度的变化。结果表明,在风速为1 m s^(-1)和2 m s^(-1)时,18种被试树种中分别有9种和17种气孔导度显著低于对照。在3和4 m s^(-1)风速下,迎风树种气孔导度的减小幅度明显小于其他2种生境类型的物种。在4 m s^(-1)风速下,背风种和无所种的气孔导度分别下降了43%和34%,而迎风种的气孔导度仅下降了27%。对各树种气孔导度百分比随风速变化的线性回归分析也表明,背风树种的坡度明显大于迎风树种。在另一项实验中,我们将所有18种被测试物种的幼苗暴露在6米s^(-1)的风速下10分钟,并监测叶片温度的变化。迎风树种叶温平均下降3.4℃,背风树种叶温平均下降4.8℃(差异显著)。单位面积叶质量较大或叶面积较小的树种受风的影响较小,无论是叶片温度降低还是气孔导度降低。迎风树种单位面积叶质量比背风树种大,叶面积小;在有风的条件下,它们的气孔导度或叶片温度没有显著降低。南jenshan森林的迎风树种具有上述形态和生理特征,明显适应了东北季风的长期风胁迫。
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引用次数: 2
Seasonal variation in the foraging behaviors of the grey-cheeked fulvetta due to diet changes in the Fushan experimental forest, northeastern Taiwan. 台湾东北福山实验林灰颊富尔维塔觅食行为的季节变化与饮食变化。
Q4 Agricultural and Biological Sciences Pub Date : 2011-03-01 DOI: 10.7075/TJFS.201103.0033
Chao-Chieh Chen, L. Chou
A seasonal change in the diet of the Grey-cheeked Fulvetta (Alcippe morrisonia) was found in a previous study. In this study, we investigated seasonal variations in the foraging behavior of the Grey-cheeked Fulvetta between breeding and non-breeding seasons in the Fushan Experimental Forest, northeastern Taiwan. Attack behaviors, food types, and habitat characteristics of foraging locations of the Grey-cheeked Fulvetta were recorded throughout a complete annual cycle. The results showed that seasonal variations of all aspects of foraging parameters were significant, including attack behavior, food type, vegetation level, perch size, and the phenology of plants used by the Grey-cheeked Fulvetta. During the breeding season, the Grey-cheeked Fulvetta made significantly more-diverse foraging maneuvers for insects, and more often foraged in the subcaopy of larger trees and in areas with sparser vegetation. On the contrary, the Grey-cheeked Fulvetta applied more leg-powered maneuvers for more plant matter at the outer parts of smaller trees or shrubs in the understory during the non-breeding season. The patterns of resource use paralleled phenological changes in the plant species, with more new leaves on trees upon which the Grey-cheeked Fulvetta foraged in the breeding season, and more fruit on trees in the non-breeding season. In conclusion, seasonal variations in foraging behaviors of the Grey-cheeked Fulvetta were significant and mainly attributed to diet changes between the breeding and non-breeding seasons. This study is in accordance with the changing-availability hypothesis and can provide empirical evidence for adaptive evolution of birds' foraging strategies.
在之前的一项研究中发现了灰颊富尔韦塔(Alcippe morrisonia)饮食的季节性变化。本研究以台湾东北部福山实验林为研究对象,研究了灰颊富尔维塔在繁殖期和非繁殖期觅食行为的季节变化。在一个完整的年循环中记录了灰颊富尔韦塔的攻击行为、食物类型和觅食地点的栖息地特征。结果表明,灰颊富尔韦塔的攻击行为、食物类型、植被水平、栖木大小、植物物候等各方面的觅食参数均有显著的季节变化。在繁殖季节,灰颊富尔韦塔对昆虫的觅食方式更加多样化,而且更经常在大树的亚冠层和植被较少的地区觅食。相反,在非繁殖季节,灰颊富尔韦塔在下层林下较小的树木或灌木的外部使用更多的腿动力动作来获取更多的植物物质。资源利用模式与植物物候变化相一致,繁殖季节灰颊富尔塔采食的树上新叶较多,非繁殖季节果实较多。综上所述,灰颊富尔韦塔觅食行为的季节变化显著,主要归因于繁殖期和非繁殖期的饮食变化。该研究符合可得性变化假说,可为鸟类觅食策略的适应性进化提供经验依据。
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引用次数: 4
Preparation of novel non-halogen flame-retardant papers. 新型无卤阻燃纸的制备。
Q4 Agricultural and Biological Sciences Pub Date : 2011-03-01 DOI: 10.7075/TJFS.201103.0087
R. Yeh, Yi-ting Yang, Y. Perng
Halogen-containing flame-retardant paper products have both good efficacies and cost competitiveness. However, facing increasingly stringent environmental protection and safety requirements, these products could become a liability in service. Developing effective and cost-competitive non-halogen flame retardant paper products has thus become a goal of product development by the paper industry. In this study, we investigated the application of certain papermaking functional additives, particularly minerals, to develop fire-resistant agents or flame-retardant papers that are not liable to become soggy when exposed to moisture in the atmosphere. Five inorganic pigments (calcium carbonate, kaolin clay, magnesium hydroxide, aluminum hydroxide, and sericite mica) and a swelling-type flame-retardant (a phosphor-nitrogen (P-N) organic compound) were examined. We applied the minerals either by internal addition to a pulp furnish and formation into base sheets, or by surface coating applied to commercial copy paper substrates, and finally by adding the minerals at different proportions internally to the pulp furnish and then surface coating with the P-N compound. The prepared sheets were tested for their flame-retardation performance. Service environment-simulated treatments were also conducted on the papers to observe changes in their mechanical properties, so as to find the optimal flame-retarding filler ratios and coating amount formulations. The economic efficiencies of the various formulations were also analyzed to serve as a database for research and industrial reference. In total, 5 blended formulas allowed the papers to attain a class Ⅰ flame-retardation rating. After the degradation test and economic analysis, we deemed that aluminum hydroxide and magnesium hydroxide were too expensive, and were liable to lose their fire-resistance after degradation. Sericite mica-treated paper showed lower strength losses after degradation treatment; however, the fire rating decreased to class Ⅲ. Calcium carbonate- and kaolin clay-based papers had reduced fire ratings to class Ⅱ after degradation.
含卤阻燃纸制品既具有良好的阻燃效果,又具有成本竞争力。然而,面对日益严格的环保和安全要求,这些产品在使用中可能成为一种负担。因此,开发有效且具有成本竞争力的无卤阻燃纸产品已成为造纸工业产品开发的目标。在这项研究中,我们研究了某些造纸功能添加剂的应用,特别是矿物质,以开发阻燃剂或阻燃纸,当暴露在大气中的水分时不易变湿。研究了五种无机颜料(碳酸钙、高岭土、氢氧化镁、氢氧化铝和绢云母)和一种膨胀型阻燃剂(磷氮有机化合物)。我们通过将矿物内部添加到纸浆原料中并形成基片,或将其表面涂层应用于商业复印纸基材,最后将不同比例的矿物内部添加到纸浆原料中,然后表面涂层P-N化合物。对所制备的板材进行了阻燃性能测试。通过模拟使用环境的处理,观察其力学性能的变化,从而找到最佳的阻燃填料配比和涂覆量配方。还分析了各种配方的经济效率,作为研究和工业参考的数据库。总共有5种混合配方使纸张达到Ⅰ级阻燃等级。经过降解试验和经济分析,我们认为氢氧化铝和氢氧化镁过于昂贵,降解后容易失去耐火性能。绢云母纸经降解处理后强度损失较小;然而,防火等级下降到Ⅲ级。碳酸钙和高岭土基纸在降解后的防火等级降至Ⅱ级。
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引用次数: 1
Review, Current Status, and Prospects of the Bamboo Industry in Taiwan 台湾竹业的回顾、现状与展望
Q4 Agricultural and Biological Sciences Pub Date : 2011-03-01 DOI: 10.7075/TJFS.201103.0099
Yu-Jen Lin
Bamboo offers local people a variety of products for daily needs, and helps protect habitats in Taiwan. In the 1960~1980s, bamboo-related processing industries in Taiwan reached a maximum output value of US$ 44.7 million and greatly contributed to economic improvements for bamboo farmers, local communities, and governments. But these industries have been in decline for a long time due to surging labor costs and high competition from cheaper imported products from other Asian countries. For Taiwanese agricultural authorities, how to promote the amount of bamboo utilization to maintain the health of indigenous bamboo forest resources, and how to allow the bamboo processing industry and bamboo production to prosper again are important issues in making strategy. This paper first reviews the development history of the bamboo-processing industry in Taiwan, so that one can know the contributions and importance of the numerous ways that bamboo was utilized by local people in bygone years, then describes the current status of this industry and how programs for promoting bamboo utilization have been successfully carried out by the agricultural authorities. Finally, the paper mentions several beneficial coordinated programs in cooperation with other related governmental agencies to upgrade the bamboo industry in Taiwan and the prospects for the potential development of bamboo utilization including high value-added fine bamboo craft products, bamboo pyrolytic oil production, and bamboo pellet manufacture.
竹子为当地居民提供了各种日常用品,并有助于保护台湾的栖息地。1960~1980年代,台湾竹材加工业最高产值达4470万美元,为竹农、当地社区和政府的经济发展做出了巨大贡献。但由于劳动力成本飙升和来自其他亚洲国家的廉价进口产品的激烈竞争,这些产业长期以来一直处于衰退状态。对于台湾农业主管部门而言,如何提高竹的利用率以维持原生竹林资源的健康,以及如何让竹加工业和竹生产再次繁荣,是制定策略的重要问题。本文首先回顾台湾竹材加工业的发展历史,以了解当地人民多年来利用竹子的各种方式的贡献和重要性,然后介绍竹材加工业的现状以及农业当局如何成功地开展促进竹材利用的计划。最后,本文提出台湾政府与其他相关部门合作的几个有益的竹产业升级计划,以及竹利用的潜在发展前景,包括高附加值的精细竹工艺产品、竹热解油生产和竹颗粒制造。
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引用次数: 7
A study of ventilating and watertight resin on mudstone soil erosion control. 通风防水树脂对泥岩土壤侵蚀控制的研究。
Q4 Agricultural and Biological Sciences Pub Date : 2010-12-01 DOI: 10.7075/TJFS.201012.0291
Hsu ChungLi, Dai ShinYi
High-intensity rainfall usually causes runoff and inter-rill erosion on slopes, which are serious problems of soil and water conservation. To accelerate the re-vegetation of exposed landslide areas, hydroseeding is widely applied as an economically feasible way. However, various hydroseeding materials have different effective durations, the concentration for plant growth has some influence, and additives may be exuded. This research used a ventilating and watertight resin spray on a mudstone soil surface to investigate soil erosion, drainage water quality, and soil hardness using a rainfall simulator with various conditions of slope, rainfall intensity, and concentration. The results showed that soil erosion significantly decreased, suggesting a good erosion-resisting effect by the ventilation and watertight resin. Moreover, no significant variation in drainage water was observed, and chemical substances were not likely to be released after gelling. Nevertheless, the high resin density will result in poor workability as well as high costs; an adverse effect is that the mudstone will fracture due to raindrop impact. Therefore, realizing the benefits of the concentration of ventilating and watertight resin on erosion control improvements of mudstone soil for estimations and calculations will be conducted for future applications.
强降雨通常会造成坡面径流和沟间侵蚀,是严重的水土保持问题。为了加快露地滑坡区的植被恢复,加水播种作为一种经济可行的方式被广泛应用。但不同的播料有效时间不同,播料浓度对植物生长有一定影响,还可能有添加剂渗出。本研究在泥岩土壤表面采用通风防水树脂喷雾,利用降雨模拟器对不同坡度、降雨强度和浓度条件下的土壤侵蚀、排水水质和土壤硬度进行了研究。结果表明,土壤侵蚀明显减少,表明通风水密树脂具有良好的抗侵蚀效果。此外,排水没有明显变化,化学物质不太可能在凝胶化后释放。然而,树脂密度高会导致加工性差,成本高;不利的影响是泥岩会因雨滴撞击而破裂。因此,实现通风水密树脂浓度对改善泥岩土壤侵蚀的效益,进行估算和计算,为今后的应用做准备。
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引用次数: 3
Cutting Propagation by Water Culture of Casuarina equisetifolia 木麻黄水培养扦插繁殖研究
Q4 Agricultural and Biological Sciences Pub Date : 2010-09-01 DOI: 10.7075/TJFS.201009.0191
K. Ho, Shuhong Wei, Ming‐Jen Lee
Asexual reproduction ensures that advantageous genetic traits and characteristics of parental trees are passed onto progeny. Furthermore, seedlings grow very fast during the developmental period. To enhance the population size and improve reproduction of Casuarina equisetifolia, this study investigated how various factors influence the rooting quality of water-cultured C. equisetifolia. Using a recently developed technique, young branch cuttings were grown in water culture. To identify optimal conditions for water culture reproduction, various cuttings aged 3 and 6 mo were expored to a napthaleneacetic acid (NAA) concentration of 50 ppm. Cutting lengths of < 10 cm had better rooting quantity than 10~15-cm cuttings. The rooting percentage of cuttings with wound treatment was 86.7% compared to 73.3% for cuttings without wound treatment. The cutting types used in this 'water culture' of rooting quantity were 2.1 for cuttings with branches and 1.8 for those without branches. The results of this study can be used to develop techniques to improve the rooting rate and lower the costs of growing C. equisetifolia seedlings for use in coastal regions of Taiwan.
无性繁殖确保了亲本树的有利遗传性状和特征传递给后代。此外,幼苗在发育期间生长非常快。为了扩大木麻黄的种群规模,提高其繁殖能力,研究了水培养木麻黄生根质量的影响因素。采用最新开发的技术,在水中培养幼枝插枝。为了确定水培养繁殖的最佳条件,将3和6月龄的各种插穗暴露在浓度为50 ppm的萘乙酸(NAA)中。扦插长度< 10 cm比扦插长度10~15 cm生根量好。伤口处理插枝生根率为86.7%,未处理插枝生根率为73.3%。该“水培养”生根数量的扦插类型为有枝扦插2.1种,无枝扦插1.8种。本研究结果可为台湾沿海地区开发提高木参生根率和降低木参幼苗生长成本的技术提供参考。
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引用次数: 2
Lathraea purpurea (Scrophulariaceae): A New Generic Record in Taiwan 标题台湾一新属记录
Q4 Agricultural and Biological Sciences Pub Date : 2010-09-01 DOI: 10.7075/TJFS.201009.0265
Shih‐Wen Chung, T. Hsu, M. Jung, S. Hsiao, Wei-U Fang
Lathraea purpurea Cummins (Scrophulariaceae), a holoparasitic plant originally described from Sikkim, was recently found at high elevations of central Taiwan. It also represents a new generic record to the flora of Taiwan. We provide a description, illustration, and color photos of L.purpurea and report Yushania niitakayamensis as its host in Taiwan.
原产于锡金的一种全寄生植物,最近在台湾中部高海拔地区发现。它也代表了台湾植物区系的新属记录。我们提供了一篇描述,插图和彩色照片,并报道了在台湾的新塔卡山玉山是它的宿主。
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引用次数: 1
Forest scenic esthetic assessment - a case study of Taiwania cryptomerioides plantations in the Liouguei Experimental Forest. 森林景观审美评价——以柳桂实验林柳杉人工林为例
Q4 Agricultural and Biological Sciences Pub Date : 2010-09-01 DOI: 10.7075/TJFS.201009.0211
Yu-Jen Chiang, P. Yang, Chin-Shien Wu, Han-Ching Hsieh, Dar-Hsiung Wang
This study adopted integration of Scenic Beauty Estimation (SBE) and a cognition model as the research method to understand a sustainable approach to scenic esthetics of Taiwania plantations. The study site was located in Taiwania plantation forests in the Fang-Kang area of the Liouguei Experimental Forest. The respondents were investigated to reveal their scenic preferences, biophysical attributes, and perceptions of cognitive factors including formal esthetic attributes using projected photo images. RMRATE software was used to transfer scores of scenic preferences into SBE values. Then, all data were analyzed by a variance analysis and regression technique. The results indicated that no significant difference was shown in SBEs between students and non- students. It was shown that the ”unity” and ”graduation” of formal esthetic attributes of the investigated cognitive factors had positive effects on scenic preferences. In the analysis of the effect of biophysical attributes on scenic preferences, respondents preferred forest near-view scenes with greater percentage of herbaceous ground cover, less downed wood/debris on the ground, and a higher height to crown base of trees. Furthermore, it was observed that a greater percentage of herbaceous ground cover and less downed wood/debris resulted in higher ratings in the formal esthetic attributes of ”unity” and ”graduation” which positively influenced scenic preferences. Apparently, dealing with relationships of formal attributes (”unity” and ”graduation”) and biophysical attributes (percentage of herbaceous ground cover and downed wood/debris) should be seriously considered in designing scenic esthetics of Taiwania plantations.
本研究采用景观美评估(SBE)与认知模型相结合的研究方法,探讨台湾人工林景观美学的可持续发展路径。研究地点位于柳桂实验林方康地区的台湾人工林。通过对被调查者的调查,揭示了他们对风景的偏好、生物物理属性以及对包括形式审美属性在内的认知因素的看法。使用RMRATE软件将风景偏好得分转换为SBE值。然后,对所有数据进行方差分析和回归分析。结果显示,学生与非学生的自我行为能力无显著差异。结果表明,被调查认知因素形式审美属性的“统一性”和“分度性”对风景偏好具有正向影响。在生物物理属性对景观偏好的影响分析中,被调查者偏好草本地被植被比例较高、地面倒下的木材/碎片较少、树木冠底高度较高的森林近景景观。此外,我们还观察到,较高的草本地被比例和较少的倒下的木材/碎片导致更高的“统一”和“毕业”的形式美学属性评级,这对景观偏好产生了积极的影响。显然,处理形式属性(“统一”与“分度”)与生物物理属性(草本地被物与落木/残材比例)之间的关系,是台湾人工林景观美学设计中需要认真考虑的问题。
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引用次数: 0
Effects of Phosphoryl Triamide Treatment on the Strength and Dimensional Properties of Woodflour-Polypropylene Composites 磷酰三酰胺处理对木粉-聚丙烯复合材料强度和尺寸性能的影响
Q4 Agricultural and Biological Sciences Pub Date : 2010-09-01 DOI: 10.7075/TJFS.201009.0227
C. Hwang, Wen Ku, Hong-lin Lee
The purpose of this study was to investigate the effects of phosphoryl triamide treatment on the flexural properties, internal bond strength, and dimensional stability of woodflour-polypropylene composites. Factors investigated included 3 woodflour loading levels and 7 fire-retardant treatments. Results showed that fire-retardant treatments adversely affected the flexural strength, internal bond strength, and dimensional stability of composite panels at a 100% woodflour loading; however, all of the measured properties improved at higher polypropylene contents, except for the flexural stiffness which was unaffected by either factor. Woodflour loading and fire-retardant treatments collectively and interactively affected the performance of woodflour-polypropylene composites, with the woodflour content a more-important factor than the fire-retardant type.
本研究的目的是研究磷酰三酰胺处理对木粉-聚丙烯复合材料的弯曲性能、内部结合强度和尺寸稳定性的影响。研究因素包括3种木粉加载水平和7种阻燃处理。结果表明:在100%木粉负荷下,阻燃处理对复合材料板的抗弯强度、内部粘结强度和尺寸稳定性有不利影响;然而,在聚丙烯含量较高时,除抗弯刚度不受任何因素影响外,所有测量的性能都得到了改善。木粉加载和阻燃处理共同影响木粉-聚丙烯复合材料的性能,其中木粉含量比阻燃类型影响更大。
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引用次数: 0
Preparation and Characterization of Nanocrystalline Cellulose by Acid Hydrolysis of Cotton Linter 棉絮酸水解制备纳米晶纤维素及其性能研究
Q4 Agricultural and Biological Sciences Pub Date : 2010-09-01 DOI: 10.7075/TJFS.201009.0251
Chih-Ping Chang, I-Chen Wang, K. Hung, Y. Perng
The purpose of this study was to use acid hydrolysis of cotton linter to generate nanocrystal-line cellulose (NCC). Based on a 2^4 factorial design, the effects of sulfuric acid concentration, temperature, hydrolysis time, and the solid/liquid ratio on the NCC yield were examined. NCC specimens obtained from different sulfuric acid concentrations were subjected to a battery of analyses, including dynamic light scattering (DLS), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), 13C solid-state nuclear magnetic resonance (13CSNMR), and a thermal gravimetric analysis (TGA) to probe the particle size distribution, morphology, functional group shifts, position of the carbon, and thermal degradation properties of the ensuing NCC. The results indicated that the sulfuric acid concentration and solid/liquid ratio at higher levels, and temperature and reaction time at lower levels were significantly conducive to increases in NCC yields. The main effects in diminishing order were the acid concentration, temperature, hydrolysis time, and solid/liquid ratio. Results of DLS and TEM observations suggested that the NCC had a size distribution centered around 20~200 nm, with length-to-width ratios ranging 1:1~1:30. The FTIR analysis indicated that absorption peaks at 1010~1080 and 1150~1260 cm^(-1) were derived from sulfate ester bonds on the cellulosic chains. Solid state 13CNMR spectra indicated that the C4 atoms along the cellulosic chain were shifted from 87.4 ppm to a lower magnetic domain, indicating the sulfonic ester bonding position. The TGA indicated that the lower-sulfuric-acid NCC specimen began step 1 weight loss at ca. 149℃, whereas its starting temperature of step 2 weight loss was generally higher than the mid- and high-acid NCC, at 337 and 205℃, respectively. The high-acid NCC only showed marked weight loss at 243℃. The study found that a sulfuric acid concentration of 60%, a solid/liquid ratio of 1:20, a hydrolysis temperature of 45℃, and a hydrolysis time of 5 min produced the best yield of 54.4%.
本研究的目的是利用酸水解棉絮制备纳米晶线纤维素(NCC)。采用2^4因子设计,考察了硫酸浓度、温度、水解时间和料液比对NCC产率的影响。采用动态光散射(DLS)、透射电子显微镜(TEM)、傅里叶变换红外光谱(FTIR)、13C固态核磁共振(13CSNMR)和热重分析(TGA)等方法对不同硫酸浓度下的NCC样品进行了分析,探讨了NCC的粒径分布、形貌、官能团位移、碳的位置和热降解性能。结果表明,较高的硫酸浓度和料液比以及较低的温度和反应时间均有利于NCC产率的提高。主要影响因素依次为酸浓度、温度、水解时间和料液比。DLS和TEM结果表明,NCC的尺寸分布以20~200 nm为中心,长宽比为1:1~1:30。FTIR分析表明,1010~1080和1150~1260 cm^(-1)处的吸收峰来源于纤维素链上的硫酸盐酯键。固态13CNMR光谱表明,纤维素链上的C4原子从87.4 ppm转移到较低的磁畴,表明磺酸酯键的位置。TGA结果表明,低硫酸NCC试样在149℃左右开始第一步失重,而其第二步失重起始温度普遍高于中、高硫酸NCC,分别为337℃和205℃。高酸NCC仅在243℃时表现出明显的失重。研究发现,在硫酸浓度为60%、料液比为1:20、水解温度为45℃、水解时间为5 min的条件下,最佳得率为54.4%。
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引用次数: 26
期刊
Taiwan Journal of Forest Science
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