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4th International Conference on Adhesive Joining and Coating Technology in Electronics Manufacturing. Proceedings. Presented at Adhesives in Electronics 2000 (Cat. No.00EX431)最新文献

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Advanced environmental friendly materials for HDI applications 用于高密度互联应用的先进环保材料
K. Hanamura, N. Honda, T. Suzuki, M. Aoki
In reflection of increased environmental consciousness the world over, consideration toward the environment is becoming essential even in the case of electric/electronic equipment. In printed wiring board (PWB) materials brominated flame-retardants are used, and as a result there is concern that dioxin may be generated during combustion. We tackled the development of new flame-retarding method, and we have developed halogen-free FR-4 and resin coated copper foil. Meanwhile, a tendency is also seen to regulate lead within solder, causing progress in the development of lead-free solder. In this paper, we describe the effects of halogen-free materials on the lead-free solder process.
考虑到全世界环境意识的增强,即使在电气/电子设备的情况下,对环境的考虑也变得至关重要。在印刷线路板(PWB)材料中使用溴化阻燃剂,因此在燃烧过程中可能会产生二恶英。我们致力于开发新的阻燃方法,并开发了无卤FR-4和覆膜铜箔。与此同时,也有一种趋势是调节焊料中的铅,导致无铅焊料的发展取得进展。本文介绍了无卤材料对无铅焊料工艺的影响。
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引用次数: 0
Applying polymer process studies using molecular modeling 应用分子模型进行聚合物过程研究
N. Iwamoto
Although process studies are usually done experimentally within the microelectronics board and packaging industry, at Honeywell we have been concerned about facilitating such studies though use of molecular-scale simulation support. For instance, we have used bleed modeling for several years now to understand and target bleed modification additives and to help us predict the effect of both organic and inorganic components on underfill flow. In a similar strategy we have used an adhesion modeling extension to understand stress cycling reliability, and to predict the relative ability of our formulations to withstand thermal cycling. Most recently we have used thermal cycling to help us understand process differences in several resin coated copper foils used in circuit board manufacture. All of these studies have demonstrated usefulness in understanding specific interfacial mechanisms that could not be understood from larger scale simulations or experimental evidence alone. As these studies encompass aspects of both the pre-cure and post-cure state of the adhesive, they require different assumption bases as well as different methodologies to address the performance issues. In this paper we will discuss the strategies applied, their results in in-house formulation and the impacts of using the molecular perspective to increase adhesive understanding in a development scenario.
虽然工艺研究通常在微电子板和封装行业进行实验,但在霍尼韦尔,我们一直关注通过使用分子尺度模拟支持来促进此类研究。例如,我们多年来一直使用泄油模型来了解和定位泄油改性添加剂,并帮助我们预测有机和无机成分对下填体流量的影响。在类似的策略中,我们使用了粘合建模扩展来了解应力循环可靠性,并预测我们的配方承受热循环的相对能力。最近,我们使用热循环来帮助我们了解电路板制造中使用的几种树脂涂层铜箔的工艺差异。所有这些研究都证明了在理解特定界面机制方面的有用性,而这些机制仅通过大规模模拟或实验证据是无法理解的。由于这些研究既包括胶粘剂的固化前状态,也包括固化后状态,因此需要不同的假设基础和不同的方法来解决性能问题。在本文中,我们将讨论应用的策略,它们在内部配方中的结果以及在开发场景中使用分子视角来增加粘合剂理解的影响。
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引用次数: 9
Analyses of flip chip attach reliability 倒装芯片附件可靠性分析
R. Dudek, A. Schubert, B. Michel
Computer based thermo-mechanical design and performance optimization are in widespread use. They are mainly based on finite element (FE-) analyses. Applications of the method in performing parametric studies on the thermomechanical behavior of different flip chip assemblies are given. Both die size and underfill material are varied. It is shown that for flip-chip on board (FCOB) assemblies the die size is no key reliability parameter. Fatigue failure limits are estimated for both not underfilled and underfilled assemblies with small dies. Underfill materials with different characteristics, ranging from stiff to soft, are treated. Polymer materials are of special importance for this packaging technology. The theoretical analysis of stresses within polymeric material compounds induced by environmental conditions, especially temperature changes, requires the characterization of material properties, especially for the underfill and solder mask materials. Measurement results on typical commercially available electronic polymers are reported, which have been investigated by DMA and TMA measurements as well as tensile tests. Isothermal relaxation tests were performed on tensile specimens to study the viscoelastic material behavior at different temperatures.
基于计算机的热机械设计和性能优化得到了广泛的应用。它们主要基于有限元(FE-)分析。给出了该方法在对不同倒装芯片组件的热力学行为进行参数化研究中的应用。模具尺寸和底料都是不同的。研究表明,对于板上倒装芯片(FCOB)组件来说,芯片尺寸不是关键的可靠性参数。对小模具的未充填料和未充填料组件的疲劳失效极限进行估计。处理不同特性的下填料,从硬到软。高分子材料在这种封装技术中具有特殊的重要性。对环境条件,特别是温度变化引起的聚合物材料化合物内部应力的理论分析,需要对材料性能进行表征,特别是对下填充和阻焊材料。本文报道了典型商用电子聚合物的测量结果,并对其进行了DMA和TMA测量以及拉伸试验。对拉伸试样进行等温松弛试验,研究粘弹性材料在不同温度下的性能。
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引用次数: 12
Effect of cure temperature on impact resistance of conductive adhesives 固化温度对导电胶粘剂抗冲击性能的影响
S.R. MacDavitt, J. E. Morris
The experiments described look at the impact resistance of conductive adhesives. A standard drop test from 5 feet was used to test the adhesives. The goal of the experiments was to determine whether the adhesives successfully passed these tests. The effects of cure temperature on the mechanical bond of the adhesive are discussed as well. The focus of the results is on the effect of cure temperature on adhesion.
实验描述了导电胶粘剂的抗冲击性。使用标准的从5英尺高处跌落试验来测试粘合剂。实验的目的是确定粘合剂是否成功地通过了这些测试。讨论了固化温度对胶粘剂机械结合性能的影响。结果的重点是固化温度对附着力的影响。
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引用次数: 1
Development of a rework-technology for flip-chips, using no-flow underfills 采用无流底填的倒装芯片的返工技术的发展
K. Wolter, P. Fruhauf
Underfill is a material used for filling the gap between a flip-chip and the PCB. Usually the material is dispensed after reflowing the solder joints. Driven by capillary force, it fills the gap and encapsulates the solder balls. No-flow underfills are a new technique to eliminate the time consuming flow and curing step of regular materials. These materials are dispensed before reflowing. The curing and soldering takes place at the same time in a reflow oven. As with regular underfills, it is still almost impossible to rework a defective chip. Our goal is not to develop a reworkable underfill material, but to rework a flip-chip using a conventional no-flow underfill. Two approaches were taken into consideration: thermal and chemical rework. A combination of both, as the most likely way to successfully rework, was tested.
下填料是用来填充倒装芯片和PCB之间空隙的材料。通常材料是在焊点回流后分配的。在毛细管力的驱动下,填充空隙,封装焊锡球。无流底填是一种消除常规材料耗时的流动和固化步骤的新技术。这些材料在回流前被分配。固化和焊接在回流炉中同时进行。与常规的填充物一样,修复有缺陷的芯片几乎是不可能的。我们的目标不是开发一种可重复使用的底填料材料,而是使用传统的无流底填料对倒装芯片进行返工。考虑了两种方法:热工和化学返工。作为成功返工的最有可能的方式,两者的结合进行了测试。
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引用次数: 1
Reliability of flip chip die attach in multichip mechatronic power module 多芯片机电电源模块中倒装芯片封装的可靠性
M. Paulasto, T. Hauck, A. Kolbeck
Motorola's Interconnect Systems Laboratory in Munich has developed the assembly technology for a mechatronic multichip power module, a new intelligent connector for automotive applications. Product's requirements for simultaneous high power dissipation, current carrying and device interconnecting capability lead to selection of insulated metal substrate (IMS) as a substrate technology and electroplated eutectic solder bump as an interconnection technology. To develop robust processes capable of meeting high reliability in the automotive product environment, fundamental knowledge was needed about the behavior of the materials and interfaces in a flip chip assembly. This paper presents results of the parametric analysis of flip chip attach on IMS substrate. Impact of main variables, including die size, substrate thickness, underfill material, soldermask material and die passivation on the stress distribution and reliability in IMS assemblies was studied. The detailed stress analyses, materials compatibility and interface studies has resulted in a high level of process control and an excellent reliability performance.
摩托罗拉位于慕尼黑的互联系统实验室开发了一种机电一体化多芯片电源模块的组装技术,这是一种用于汽车应用的新型智能连接器。产品对同时具有高功耗、载流和器件互连能力的要求导致选择绝缘金属基板(IMS)作为基板技术和电镀共晶凸点作为互连技术。为了开发能够满足汽车产品环境中高可靠性的稳健工艺,需要对倒装芯片组装中材料和接口的行为有基本的了解。本文介绍了IMS基板上倒装芯片的参数分析结果。研究了模具尺寸、衬底厚度、衬底填充材料、掩焊材料和模具钝化等主要变量对IMS组件应力分布和可靠性的影响。详细的应力分析,材料相容性和界面研究导致了高水平的过程控制和卓越的可靠性性能。
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引用次数: 2
Conductive adhesive for plated Sn or Sn/Pb electrode 镀锡或锡/铅电极用导电胶
M. Komagata, G. Toida, T. Hocchi, K. Suzuki
New isotropic conductive adhesive (ICA) for plated Sn or Sn/Pb electrode was developed. The new ICA and our existing ICA were evaluated for SMT as lead containing solder replacement, using on-chip resistors with plated Sn/Pb (90/10) and fired Ag/Pd terminations, from contact resistance and adhesion strength points of view. The new ICA gave more stable contact resistance and adhesion strength through reliability testing, even in the case of using 0/spl Omega/ chip resistor with plated Sn/Pb termination. Formation of boundaries or Sn grains on the surface and diffusion of Ni into Sn/Pb layer in the cross section, after chip resistors with plated Sn/Pb termination exposed to several reliability conditions, were observed by SEM and EDX. Though degree of these changes of plated Sn/Pb termination depends on each exposure condition, it can be estimated that the new ICA gets less influence by the changes of plated Sn/Pb termination and that it has some effect which prevents changing by plated Sn/Pb termination before it occurs.
研制了一种用于镀锡或锡/铅电极的新型各向同性导电胶(ICA)。从接触电阻和粘附强度的角度来看,新的ICA和我们现有的ICA被评估为SMT含铅焊料替代品,使用镀Sn/Pb(90/10)和发射Ag/Pd终端的片上电阻。通过可靠性测试,新ICA提供了更稳定的接触电阻和粘附强度,即使在使用镀锡/铅端接的0/spl ω /片式电阻的情况下也是如此。通过SEM和EDX观察到,镀锡/铅端的片式电阻器在几种可靠性条件下,表面形成边界或Sn晶粒,Ni扩散到截面的Sn/Pb层中。虽然镀锡/铅终止的变化程度取决于不同的暴露条件,但可以估计,新的ICA受镀锡/铅终止变化的影响较小,并且在镀锡/铅终止发生之前具有一定的阻止作用。
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引用次数: 2
Laser processing of adhesives and polymeric materials for microelectronics packaging applications 用于微电子封装的粘合剂和聚合物材料的激光加工
Z. Illyefalvi-Vitéz
The microelectronics industry is moving toward smaller feature sizes. The main driving forces are to improve performance and to lower cost. From the performance point of view the small distances between chips together with the short interconnection routes have of great importance in order to achieve faster operation. The application of polymers, including electrically and/or thermally conductive and insulating polymeric adhesives, for functional insulating and protective layers of interconnect substrates is beneficial to the performance and to the cost of a circuit module as well. Laser processing of polymeric materials applied for via generation image transfer, contour cutting, etc. has proved to be an efficient tool for the fabrication of interconnects substrates. The paper describes the results of research projects that are aimed at the application of CO/sub 2/ and frequency multiplied Nd:YAG lasers for the drilling of polyester foils and glass fiber reinforced epoxy laminates with the aim of interconnect via preparation. The physics of processing using five wavelengths, i.e. 10600, 1064, 532, 355 and 266 nm, were modeled, examined and evaluated. Through contacting was carried out by screen-printing with polymer thick films, by wet chemical direct plating and by evaporation of thin metal layers, but the details of metallization are not given here. The conclusion refers to the possibilities and limitations of laser processing of polymeric materials in microelectronics packaging applications.
微电子工业正朝着更小的特征尺寸发展。主要驱动力是提高性能和降低成本。从性能的角度来看,芯片之间的小距离和短互连路线对于实现更快的运行具有重要意义。聚合物的应用,包括导电和/或导热和绝缘聚合物粘合剂,用于互连基板的功能绝缘和保护层,对电路模块的性能和成本也是有益的。聚合物材料的激光加工应用于通过生成图像转移、轮廓切割等,已被证明是制造互连基板的有效工具。本文介绍了利用CO/sub /和倍频Nd:YAG激光器钻削聚酯薄膜和玻璃纤维增强环氧层板,以制备互连为目的的研究项目成果。利用10600、1064、532、355和266 nm这5个波长进行物理模拟、检验和评价。通过接触进行了丝网印刷与聚合物厚膜,湿化学直接电镀和蒸发薄金属层,但金属化的细节在这里没有给出。结论指出了激光加工高分子材料在微电子封装中的应用的可能性和局限性。
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引用次数: 21
Adhesion comparison between thermosetting and thermoplastic resin systems based on poly(bisphenol A-co-epichlorohydrin) chemistry 基于聚双酚a -共聚环氧氯丙烷化学的热固性和热塑性树脂体系的附着力比较
L. Fan, C. Wong
The application of the underfill materials has been to enhance the solder joint fatigue life in flip chip assembly, where normally only thermosetting systems have been extensively employed in industry. However, thermoplastics may be of great economic/cost interest as underfill for some low end use microelectronic products; and furthermore, such investigations could enrich our understanding of the potential thermoplastic systems. In this paper both thermosetting and thermoplastic epoxy resins were studied for the feasibility as underfill materials. The former includes basic liquid resin and advanced solid resin of different molecular weight, while the latter is the so-called phenoxy resin. The solution and hot melt approach were taken for the assembly procedure of the die shear strength test at selected solid content and curing/drying condition. The die shear strength of the systems was collected, which could enable us to get insights into the effects of aging, temperature and coupling agent, etc., for the thermosetting and thermoplastic materials.
下填充材料的应用一直是为了提高倒装芯片组装中的焊点疲劳寿命,通常只有热固性系统在工业中得到广泛应用。然而,热塑性塑料作为一些低端微电子产品的底填料可能具有很大的经济/成本效益;此外,这些研究可以丰富我们对潜在热塑性体系的理解。本文研究了热固性环氧树脂和热塑性环氧树脂作为下填料的可行性。前者包括不同分子量的碱性液体树脂和高级固体树脂,后者就是所谓的苯氧树脂。在选定固含量和固化/干燥条件下,采用溶液法和热熔法进行模具抗剪强度试验的装配过程。收集了系统的模具抗剪强度,从而可以深入了解老化、温度、偶联剂等因素对热固性和热塑性材料的影响。
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引用次数: 4
Adhesion between photosensitive epoxy and electroless copper 光敏环氧树脂与化学铜之间的附着力
J. Ge, R. Tuominen, J. Kivilahti
The adhesion between the photosensitive epoxy and electroless copper was measured with a pull test designed and executed in this work. The test pads were fabricated on the substrate by using semi-additive plating process. The pull strength was measured with a mechanical tester. The chemical treatment was used to roughen the polymer surface, two sets of specimens were tested with different swelling time and etching time to get the optimal adhesion strength. Effects of the chemical treatment on surface morphology and adhesion were studied. The surface morphology of the polymer was examined with optical microscopy and the SEM/EDS technique. The ranges of swelling time and etching time, which result in good adhesion, were given. It was confirmed that the swelling and etching processes have to be optimised with respect to each other for achieving the desired polymer surface properties without altering the bulk properties.
本文设计并实施了一种拉力试验,测量了光敏环氧树脂与化学铜之间的附着力。采用半添加剂镀工艺在衬底上制备了测试垫。用力学试验机测定拉伸强度。采用化学处理方法对聚合物表面进行粗化处理,并对两组试样进行不同溶胀时间和蚀刻时间的测试,以获得最佳的粘接强度。研究了化学处理对表面形貌和附着力的影响。利用光学显微镜和SEM/EDS技术对聚合物的表面形貌进行了表征。给出了具有良好附着力的溶胀时间和蚀刻时间范围。研究证实,为了在不改变聚合物体性能的情况下获得所需的聚合物表面性能,必须对溶胀和蚀刻工艺进行优化。
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引用次数: 2
期刊
4th International Conference on Adhesive Joining and Coating Technology in Electronics Manufacturing. Proceedings. Presented at Adhesives in Electronics 2000 (Cat. No.00EX431)
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