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4th International Conference on Adhesive Joining and Coating Technology in Electronics Manufacturing. Proceedings. Presented at Adhesives in Electronics 2000 (Cat. No.00EX431)最新文献

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Cluster effects on electrical conductance of isotropically conductive adhesive 簇效应对各向同性导电胶粘剂电导率的影响
Y. Fu, M. Willander, J. Liu
We have studied the DC electric conductance of isotropically conductive adhesive (ICA). It was demonstrated theoretically that assuming completely random distribution of the metal fillers in the ICA, the volume percentage of the metal fillers can be significantly reduced by adding nano-size fillers into the system originally containing only micro-size fillers. It is however shown experimentally that due to the surface tension nanofillers tend to gather around microfillers as well as form clusters themselves so that the resistivity of the ICA increases following the increase of the nanofillers' volume percentage. In the present work we try to study theoretically these cluster effects by simulating the detailed random walkings of the nanofillers and microfillers in the system. It has been concluded eventually that the cluster effects of the nanofillers deteriorate the electric conductivity of the ICA by separating the microfillers from each other so that electric conduction path becomes more difficult to form in the electric conducting network of the ICA.
研究了各向同性导电胶粘剂(ICA)的直流电导率。从理论上证明,假设金属填料在ICA中的完全随机分布,在原先只含有微粒径填料的体系中加入纳米级填料可以显著降低金属填料的体积百分比。然而,实验表明,由于表面张力,纳米填料倾向于聚集在微填料周围并形成团簇,使得ICA的电阻率随着纳米填料体积百分比的增加而增加。在本工作中,我们试图通过模拟系统中纳米填料和微填料的详细随机游动,从理论上研究这些簇效应。最后得出结论:纳米填料的团簇效应会使微填料相互分离,从而导致ICA的电导率下降,使得导电路径在ICA的导电网络中更难形成。
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引用次数: 0
Modeling stresses in ultra-thin flip chips 超薄倒装芯片中的应力建模
P. Marjamaki, T. Reinikainen, J. Kivilahti
In the present study the effect of chip thickness on life expectancy of solder joints and on stresses in the chip in an underfilled flip chip assembly was investigated with FE analysis. By reducing the thickness of the silicon chip expected lifetime of the joints increased markedly. The life expectancies of the solderjoint based on energy method were 700, 860 and 1060 cycles for 600, 60 and 30 /spl mu/m thick chips, respectively. However, the reduction of the chip thickness increased normal stresses in the chip significantly. In the case of the thickest chip the highest compressive stress in the chip was about 90 MPa, while in the case of the thinnest chip it was about 290 MPa. So, by reducing the thickness the reliability of the solder joints increases but high stresses may cause reliability problems in the active chip.
本文采用有限元分析的方法研究了芯片厚度对欠填充倒装芯片中焊点寿命和芯片应力的影响。通过减小硅片厚度,可显著提高接头的预期寿命。对于600、60和30 /spl mu/m厚的芯片,基于能量法的焊点寿命分别为700、860和1060次循环。然而,切屑厚度的减小显著增加了切屑中的法向应力。在最厚的芯片中,芯片的最高压应力约为90 MPa,而在最薄的芯片中,芯片的最高压应力约为290 MPa。因此,通过减少厚度,焊点的可靠性增加,但高应力可能会导致有源芯片的可靠性问题。
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引用次数: 6
Modeling of branched crosslinked composites, using the statistical polymer method 支链交联复合材料的建模,采用统计聚合物方法
O. Figovsky, F. Romm, V. Karchevsky
Summary form only given. The problem of modeling of branched cross-linked structures is one of most complicated in composite science. Most existing composite materials have branched cross-linked structure, and their theoretical study is indispensable for their optimal application in practical needs. Conventional methods of description of branched cross-linked structures are numerical and do not allow solution in the general case. Their application needs complicated and long computing and the physical sense of the obtained results is not always clear. Some researchers try application of classical chain models to branched systems, although such approximation is incorrect and may cause serious errors. The problem of modeling of branched cross-linked structures was recently solved by statistical polymer method. This method is based on the consideration of averaged structures (statistical polymers). In such approximation, all reactions in equilibrium are considered as reactions between statistical polymers. The statistical polymer method was tested directly and indirectly. The direct test comprised the exact reproduction of Trommsdorf effect for non-equilibrium polymers, whereas the indirect test allowed the theoretical interpretation of adsorption isotherms for silica and alumina gels. In all cases, the correlation of experimental and theoretical results was very good. The statistical polymer method allows modeling of composites, e.g. materials based on quaternary ammonium silicates. Silica globulaes in solution or solid are successfully modeled. Such modeling allows serious reduction (for hundreds-thousands times) of the number of numerical experiments. The proposed statistical polymer method is commendable for description of all kinds of composites with complex structure.
只提供摘要形式。支链交联结构的建模问题是复合材料科学中最复杂的问题之一。现有的复合材料大多具有支链交联结构,对其进行理论研究是其优化应用的必要条件。传统的描述支链交联结构的方法是数值的,在一般情况下不允许求解。它们的应用需要复杂和长时间的计算,所得到的结果的物理意义并不总是清晰的。一些研究人员尝试将经典链模型应用于分支系统,但这种近似是不正确的,可能会造成严重的误差。近年来,统计聚合物方法解决了支链交联结构的建模问题。这种方法是基于对平均结构(统计聚合物)的考虑。在这种近似下,所有处于平衡状态的反应都被认为是统计聚合物之间的反应。对统计聚合物法进行了直接和间接的验证。直接测试包括对非平衡聚合物的特罗姆斯多夫效应的精确再现,而间接测试允许对二氧化硅和氧化铝凝胶的吸附等温线进行理论解释。在所有情况下,实验结果与理论结果的相关性都很好。统计聚合物方法允许对复合材料进行建模,例如基于季铵盐的材料。成功地模拟了溶液或固体中的硅球。这样的建模使数值实验的数量大大减少(数十万倍)。所提出的统计聚合物方法可用于描述各种复杂结构的复合材料。
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引用次数: 0
Characterization and performance of electrically conductive adhesives for microwave applications 微波用导电胶粘剂的特性和性能
J. Felba, K.P. Friedel, A. Moscicki
The main advantage of isotropically conductive adhesives used for assembling electronic circuits is lack of lead and other toxic metals in resultant joints. The objective of this paper was to find the best formulation of isotropically conductive adhesive for solder replacement in microwave applications. As a result of the screening experiment the different adhesive formulations were investigated in order to identify the significant factors, which influence the electrical resistance of joints. In these formulations the adhesive base material as well as type of main and additional filler materials were changed. Silver, nickel and graphite were used as a main filler material, whereas soot and heavy silver were filler additives. The adhesive formulations were tested in standard microstrip bandpass filters, which were supplied with an additional gap in the gold strip and bridged by adhesive bonded silver jumper. As the figure-of-merit the quality factor Q and loss L of such a microwave circuit have been investigated. Both the Q-factor and loss of the filter with bonded jumper were measured at the frequency of 3.5 GHz in preliminary experiment and at 3.5 GHz as well as 14 GHz in final experiment. For identifying the best adhesive formulation the experimental design method based on Taguchi techniques for quality engineering has been used. It was stated that to each adhesive, which is prepared on the base of specific type of resin, the strictly defined type of silver filler should be added and strictly defined volume content of the filler should be selected.
用于组装电子电路的各向同性导电胶粘剂的主要优点是在接合处不含铅和其他有毒金属。本文的目的是寻找微波应用中焊料替代用各向同性导电胶粘剂的最佳配方。通过筛选实验,研究了不同胶粘剂配方对接头电阻的影响。在这些配方中,粘合剂基材以及主要和附加填充材料的类型都发生了变化。以银、镍和石墨为主要填料,烟灰和重银为填料添加剂。在标准微带带通滤波器中测试了胶粘剂配方,该标准微带带通滤波器在金带中提供了额外的间隙,并用胶粘剂粘合银跳线桥接。本文研究了该微波电路的质量因数Q和损耗L作为优值。初步实验在3.5 GHz频率下测量了带键合跳线滤波器的q因子和损耗,最终实验在3.5 GHz和14 GHz频率下测量了q因子和损耗。为了确定最佳胶粘剂配方,采用了基于田口质量工程技术的试验设计方法。对每一种以特定类型树脂为基础制备的胶粘剂,应加入严格规定的银填料类型,并选择严格规定的填料体积含量。
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引用次数: 10
Concepts for ultra thin packaging technologies 超薄封装技术的概念
Aschenbrenner, F. Ansorge, M. Feil, C. Landesberger, E. Jung, A. Ostmann, H. Reichl
As the number of applications for flexible assemblies is growing there is also a larger variation of requirements for such packages. Therefore different technologies have been developed for applications from CSP's to smart cards. The scope of the paper is to describe different approaches for packaging using ultra-thin and flexible chips. This includes the assembly processes as well as packaging concepts e.g. CSP's, 3D modules and volumetric integration of passive and active components into modules and substrates.
随着柔性组件的应用数量不断增长,对此类封装的要求也有更大的变化。因此,从CSP到智能卡的应用开发了不同的技术。本文的范围是描述使用超薄和柔性芯片封装的不同方法。这包括组装过程以及封装概念,例如CSP, 3D模块以及无源和有源组件在模块和基板中的体积集成。
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引用次数: 4
Bismuth-filled anisotropically conductive adhesive for flip chip bonding 用于倒装芯片粘合的铋填充各向异性导电胶粘剂
M. Vuorela, M. Holloway, S. Fuchs, F. Stam, J. Kivilahti
In this communication a new bismuth (Bi)-filled anisotropically conductive adhesive (ACA), which can be used to bond pure tin (Sn) or any Sn-based contact areas, is presented. In this study the adhesive was used to join tin-lead (SnPb) -bumped test chips to SnPb-coated contact pads on FR4-substrate. Due to the metallurgical characteristics of the SnPbBi system, the process temperature and bonding pressure remain low. With the help of pure Bi particles, the SnPb bumps are fused with the SnPb-coated contact pads above 92/spl deg/C forming small local solder joints, while the adhesive acts as an underfill. The microscopic solder interconnections retain their electrically continuity even though the adhesive matrix relaxes in service. Good quality metallurgical interconnections were produced by the bonding procedure with relatively low bonding temperature (160/spl deg/C) and pressure (24.5 g/bump). No intermetallics are formed in this bonding system. The Bi-filled ACA exhibits good reliability under high temperature and high humidity conditions (85/spl deg/C/85%RH). Thermal shock test (-40/spl deg/C/+125/spl deg/C, total cycle time 1 hour) showed that good reliability can be achieved even though the bonding process is not yet optimized. The failure of the joints is due to the formation of small liquid phases in the Bi-rich (over 10 at-%) areas in the solid lentils at the upper thermal shock temperature. This can be avoided by using higher bonding temperature. The discrepancy of reliability results is explained by the fact that the temperature of bonding has not been exactly the same for all the samples bonded.
在本通讯中,提出了一种新的铋(Bi)填充的各向异性导电胶(ACA),它可以用于粘合纯锡(Sn)或任何锡基接触区域。在这项研究中,使用粘合剂将锡铅(SnPb)碰撞测试芯片连接到fr4衬底上涂有SnPb的接触垫上。由于SnPbBi体系的冶金特性,工艺温度和键合压力保持较低。在纯Bi颗粒的帮助下,SnPb凸起与涂有SnPb的触点在92/spl℃以上熔合形成小的局部焊点,而粘合剂则起到下填充的作用。即使粘合剂基体在使用过程中松弛,微观焊料互连仍保持其电连续性。在较低的结合温度(160/spl℃)和压力(24.5 g/bump)下,获得了高质量的冶金互连。在该键合体系中不形成金属间化合物。双填充ACA在高温高湿条件下(85/spl℃/85%RH)表现出良好的可靠性。热冲击试验(-40/spl℃/+125/spl℃/C,总循环时间1小时)表明,即使粘合工艺尚未优化,也可以获得良好的可靠性。接头的破坏是由于在高热冲击温度下,固体扁豆中富bi(超过10% at-%)区域形成了小的液相。这可以通过使用更高的键合温度来避免。可靠性结果的差异可以解释为键合温度对所有的键合样品并不完全相同。
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引用次数: 4
Smart cards and smart labels-high volume applications of adhesive flip-chip technologies 智能卡和智能标签——粘合剂倒装芯片技术的大量应用
T. Seidowski, F. Kriebel, J. Galties
Adhesive FC technologies have proven to be very competitive to classic solder FC technologies. Smart card and applications require chip connections with thickness of the entire card or label. Only FC technologies can meet these low cost, high throughput and thin packaging demands. The use of isotropic conductive adhesive (ICA) for bumping and assembly for smart cards results in a number of advantages such as a simple versatile process, lower temperatures and environmental friendliness. Using an anisotropic conductive adhesive (ACA) or an nonconductive adhesive (NCA) for smart label production allows a high throughput from reel to reel. All technologies require suitable bond pads. The commonly used aluminum alloys results in unstable contacts for the conductive adhesives and hence there's an urgent need for an additional under bump metallization for these technologies. KSW Microtec has developed a technology which is based on electroless deposition of palladium. This metallization is performed as backend process. An homogeneous film of palladium with the required thickness of about 1 /spl mu/m for the ICA process and about 15 /spl mu/m for metallic bumps is deposited. In this article an introduction to adhesive FC technologies is given. Several bumping technologies used for the assembly process are shown. The authors explain their mass production experiences in KSW Microtec and advantages and disadvantages of each of the technologies. Detailed reliability tests performed on some adhesive FC technologies are shown. Practical experiences in mass production of smart cards and smart label especially in a reel to reel assembly process are discussed.
粘合剂FC技术已被证明是非常有竞争力的传统焊接FC技术。智能卡和应用程序需要与整个卡或标签厚度的芯片连接。只有FC技术才能满足这些低成本、高吞吐量和薄封装的需求。使用各向同性导电粘合剂(ICA)进行智能卡的碰撞和组装,具有许多优点,例如简单通用的过程,较低的温度和环保。使用各向异性导电粘合剂(ACA)或非导电粘合剂(NCA)进行智能标签生产,可以实现卷到卷的高吞吐量。所有的技术都需要合适的焊盘。常用的铝合金导致导电胶粘剂的接触不稳定,因此迫切需要为这些技术增加碰撞下金属化。KSW Microtec开发了一种基于化学沉积钯的技术。这种金属化作为后端过程执行。沉积了一层均匀的钯膜,ICA工艺所需的厚度约为1 /spl mu/m,金属凸起所需的厚度约为15 /spl mu/m。本文对胶粘剂FC技术进行了介绍。展示了装配过程中使用的几种碰撞技术。作者解释了他们在KSW Microtec的量产经验以及每种技术的优缺点。给出了对一些粘接FC技术进行的详细可靠性试验。讨论了智能卡和智能标签批量生产的实践经验,特别是卷筒到卷筒的装配过程。
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引用次数: 5
Roadmap "Adhesives Technologies in Automotive and Harsh Environment Applications" 路线图“汽车和恶劣环境应用中的粘合剂技术”
O. Rusanen, H. Rohde, V. Brielmann
Within the European Thematic Network "Adhesives in Electronics" a Roadmap has been prepared to establish the present status of adhesive use in automotive electronics and to find out the most important requirements for the future. Presently non and isotropically conductive adhesives are used for die bonding and underfills for solder flip chip processes. The biggest challenge for automotive electronics is the harsh environment that results in demands on device and materials reliability. Processing aspects such as short curing times are also an important criteria in material selection. In addition, the materials should be low cost.
在欧洲主题网络“电子粘合剂”中,已经准备了一个路线图,以确定粘合剂在汽车电子中的使用现状,并找出未来最重要的要求。目前,非导电和各向同性导电胶粘剂被用于焊接倒装工艺的模具粘合和衬底填充。汽车电子面临的最大挑战是恶劣的环境,这导致了对器件和材料可靠性的要求。加工方面,如短固化时间也是材料选择的重要标准。此外,材料成本要低。
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引用次数: 2
Effect of black copper oxide on interface adhesion between copper substrate and glob-top resin 黑氧化铜对铜基材与球形顶树脂界面附着力的影响
M. Lebbai, J.K. Kim, M. Yuen, P. Tong
A study is made of the effects of black copper oxide coating and other plating variables on adhesion strength of glob-top resin to copper substrates for Tape Ball Grid Array (TBGA) package applications. The button shear test was performed to measure the interfacial bonding strength. Several surface analytical techniques were employed to establish the correlations between the interface bond strength and various surface parameters, such as surface free energy, chemical element, surface roughness and fracture morphology. The experimental results showed that the presence of black oxide coating (Sample C) resulted in significantly higher interface bond strength than the bare copper (Sample A) or nickel coated (Sample B) surfaces. Further processes (Samples D and E) after the black oxide coating exhibited detrimental effects, to a varying degree, on interface bond strength. The interface bond strength was approximately proportional both to surface free energy and roughness of surface finishes, indicating that wettability and mechanical interlocking both played a significant role in forming adhesion with glob top resins.
研究了黑氧化铜涂层及其他镀层参数对TBGA封装用球形顶树脂与铜基体结合强度的影响。采用按钮剪切试验测量界面结合强度。采用多种表面分析技术建立了界面结合强度与表面自由能、化学元素、表面粗糙度和断口形貌等表面参数之间的关系。实验结果表明,黑色氧化物涂层(样品C)的存在导致界面结合强度明显高于裸铜(样品A)或镍涂层(样品B)表面。黑色氧化物涂层后的进一步处理(样品D和E)对界面结合强度有不同程度的不利影响。界面结合强度与表面自由能和表面粗糙度大致成正比,表明润湿性和机械联锁在与球形顶部树脂形成粘合方面都起着重要作用。
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引用次数: 9
A build-up substrate utilizing a new via fill technology by electroplating 一种利用新的通过电镀填充技术的堆积基板
S. Wakabayashi, S. Koyama, T. Iijima, M. Nakazawa, N. Kaneko
A build-up substrate consisting of PPE resin (poly-phenylene ether) was developed to mount high pin count flip chips. It is essential to achieve high density patterns with controlled characteristic impedance for MPU packages and telecommunication devices. Via fill technology by electroplating incorporated with new via designs is effective for this application. Stacked via design and the technology to fill the via are an essential part of the technology for future packages. It is effective to stabilize the power supply to the chip since it shortens the continuum of the chip to substrate. To realize the micro via filling, a new copper electrolytic plating solution and plating method were investigated. The copper solution used for via fill contains chloride ions, polyester type polymers, sulfur-containing brighteners and dyes as additives. It was confirmed that the adsorption behavior of the additives, agitation strength and current waveform for the plating influenced strongly the via filling phenomena. The optimum plating conditions for the large boards were determined and the micro vias on the large boards were confirmed well filled with copper electroplating. The mechanism of the via filling was explained based on the data of the electrochemical measurements, SEM observation and relevant information available in the literature.
开发了一种由PPE树脂(聚苯醚)组成的组装基板,用于安装高引脚计数倒装芯片。对于MPU封装和电信设备来说,实现具有可控特性阻抗的高密度模式是必不可少的。电镀补孔技术与新型补孔设计相结合,是一种有效的补孔技术。堆叠通孔设计和填充通孔技术是未来封装技术的重要组成部分。它缩短了芯片到衬底的连续时间,有效地稳定了芯片的电源供应。为实现微孔填充,研究了一种新的铜电解镀液和镀铜方法。通孔填充用的铜溶液中含有氯离子、聚酯型聚合物、含硫增白剂和染料等添加剂。结果表明,添加剂的吸附行为、搅拌强度和电镀电流波形对孔填充现象有较大影响。确定了大板的最佳电镀工艺条件,并确定了大板上的微孔镀铜良好。根据电化学测量数据、扫描电镜观察数据及相关文献资料,对孔道填充机理进行了解释。
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引用次数: 6
期刊
4th International Conference on Adhesive Joining and Coating Technology in Electronics Manufacturing. Proceedings. Presented at Adhesives in Electronics 2000 (Cat. No.00EX431)
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