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The impact of future atmospheric circulation changes over the Euro-Atlantic sector on urban PM2.5 concentrations 未来欧洲-大西洋区域大气环流变化对城市PM2.5浓度的影响
Pub Date : 2018-01-01 DOI: 10.1080/16000889.2018.1468704
G. Messori, Dave van Wees, F. Pausata, J. A. Acosta Navarro, A. Hannachi, F. Dentener
Abstract Air quality management is strongly driven by legislative aspects related to the exceedance of air quality limit values. Here, we use the Norwegian Climate Centre’s Earth System Model to assess the impact of a future scenario of maximum feasible aerosol emission abatement and increasing greenhouse gases (RCP4.5) on urban PM2.5 concentrations in Europe. Daily PM2.5 concentrations are assessed using a novel downscaling method which allows us to compute exceedances of current and planned air quality thresholds. For the latter, we assume that future ambitious emission reductions are likely to be accompanied by stricter air quality thresholds. The changes in PM2.5 concentrations are discussed in the context of the large-scale atmospheric changes observed relative to the present-day climate. Our results show a more positive North Atlantic Oscillation mean state in the future, combined with a large eastward shift of both North Atlantic sea-level pressure centres of action. This is associated with more frequent mid-latitude blocking and a northward shift of the jet stream. These changes favour higher than expected anthropogenic urban PM2.5 concentrations in Southern Europe, while they have the opposite effect on the northern half of the continent. In the future scenario, PM concentrations in substantial parts of Southern Europe are found to exceed the World Health Organisation Air Quality Guideline daily limit of 25 μg/m3 on 25 to over 50 days per year, and annual guidelines of 10 µg/m3 on more than 80% of the 30 years analysed in our study. We conclude that alterations in atmospheric circulation in the future, induced by stringent maximum feasible air pollution mitigation as well as GHG emissions, will negatively influence the effectiveness of these emission abatements over large parts of Europe. This has important implications for future air quality policies.
空气质量管理受到与空气质量超标有关的立法方面的强烈推动。在这里,我们使用挪威气候中心的地球系统模型来评估最大可行气溶胶排放减少和温室气体增加(RCP4.5)的未来情景对欧洲城市PM2.5浓度的影响。每日PM2.5浓度的评估使用一种新颖的降尺度方法,使我们能够计算当前和计划的空气质量阈值的超出情况。对于后者,我们假设未来雄心勃勃的减排可能伴随着更严格的空气质量门槛。PM2.5浓度的变化是在观测到的相对于当今气候的大尺度大气变化的背景下讨论的。我们的研究结果表明,未来北大西洋涛动的平均状态将更加积极,同时北大西洋两个海平面压力中心的作用也将大幅东移。这与更频繁的中纬度阻塞和急流向北移动有关。这些变化有利于南欧人为城市PM2.5浓度高于预期,而对欧洲大陆北半部产生相反的影响。在未来的情景中,南欧大部分地区的PM浓度被发现超过世界卫生组织空气质量指南每日25 μg/m3的限制,每年有25天至50多天,并且在我们研究分析的30年中,超过80%的年指导值为10 μg/m3。我们的结论是,未来由严格的最大可行空气污染缓解措施以及温室气体排放引起的大气环流变化,将对欧洲大部分地区这些减排措施的有效性产生负面影响。这对未来的空气质量政策具有重要意义。
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引用次数: 4
Distributions and light absorption property of water soluble organic carbon in a typical temperate glacier, southeastern Tibetan Plateau 青藏高原东南部典型温带冰川水溶性有机碳的分布及光吸收特性
Pub Date : 2018-01-01 DOI: 10.1080/16000889.2018.1468705
H. Niu, Shi-chang Kang, Xixi Lu, Xiaofei Shi
Abstract Water-soluble organic carbon (WSOC) widely stored in glaciers from local and distant sources, and then released it to downstream environments under a warming climate. Climatic driven changes to glacial run-off are larger and represent an important flux of organic carbon. However, very few WSOC data are currently available to fully characterize WSOC variation in the temperate glacierized regions of the Tibetan Plateau (TP). This study first systematically evaluated the concentration characteristics and light absorbing property of WSOC, and insoluble particulate carbon (IPC) in snow and ice of a typical temperate glacier on Mt. Yulong. Average concentrations of WSOC were 0.61 ± 0.21 mg L−1 in Baishui glacier on Mt. Yulong. WSOC concentrations in surface aged snow were dramatically decreased with the time extension during the entire monsoon season due to extensive glacial melting and scavenging effects by meltwater. The MAC values of WSOC calculated at 365 nm was 6.31 ± 0.34 m2 g−1 on Mt. Yulong, and there exists distinct spectral dependence of MACwsoc within the wavelength range (260 – 700 nm). The low AAE330–400 values suggest the light absorption of WSOC is more spectrally neutral. The flux of WSOC in Baishui glacier was 0.99 gC m−2 yr−1, while the IPC flux was 4.77 gC m−2 yr−1. Total WSOC storage in the Baishui glacier was estimated to be 1.5 tone C and total IPC storage was 7.25 tone C (1 tone = 106 g). Moreover, glacial melting was reinforced by the soluble and insoluble light absorbing impurities (ILAIs) in glaciers, Baishui glacier can be considered as a fraction of carbon source under the scenario of a warming climate, more importantly, WSOC in snow and ice needs to be taken into account in calculating the radiative forcing of ILAIs and accelerating glacial melting.
在气候变暖的背景下,水溶性有机碳(WSOC)广泛储存在冰川中,并向下游环境释放。气候驱动的冰川径流变化更大,代表了有机碳的重要通量。然而,目前能够全面表征青藏高原温带冰川区WSOC变化特征的WSOC数据很少。本研究首次系统评价了玉龙山典型温带冰川冰雪中WSOC和不溶性颗粒碳(IPC)的浓度特征和吸光特性。玉龙山白水冰川WSOC平均浓度为0.61±0.21 mg L−1。在整个季风季节,由于广泛的冰川融化和融水的清除作用,地表陈年雪中WSOC浓度随着时间的延长而显著降低。在365 nm处,玉龙山WSOC的MAC值为6.31±0.34 m2 g−1,在260 ~ 700 nm波长范围内,MACwsoc存在明显的光谱依赖性。较低的AAE330-400值表明WSOC的光吸收光谱更为中性。白水冰川WSOC通量为0.99 gC m−2 yr−1,IPC通量为4.77 gC m−2 yr−1。白水冰川WSOC总储存量为1.5 tone C, IPC总储存量为7.25 tone C (1 tone = 106 g)。此外,冰川中可溶性和不溶性光吸收杂质(ILAIs)加强了冰川融化,白水冰川可以作为气候变暖情景下的一部分碳源,更重要的是,在计算ILAIs的辐射强迫和加速冰川融化时,需要考虑冰雪中的WSOC。
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引用次数: 12
Characteristics of chemical composition and role of meteorological factors during heavy aerosol pollution episodes in northern Beijing area in autumn and winter of 2015 2015年秋冬季北京北部地区气溶胶重污染事件中气象因子的化学成分特征及作用
Pub Date : 2017-01-01 DOI: 10.1080/16000889.2017.1347484
Zhouxiang Zhang, Xiaoye Zhang, Yangmei Zhang, Yaqiang Wang, Huai-gang Zhou, X. Shen, H. Che, Junying Sun, Luyuan Zhang
Abstract Heavy aerosol pollution episodes (HPEs) usually start from late autumn and become more serious in winter in Beijing and its vicinity (BIV). In this study, we examine the reasons for the formation and change of HPEs in the areas of northern BIV. The size-resolved chemical components of PM1 and meteorological conditions were investigated during HPEs in autumn and winter of 2015. Stable regional atmosphere and higher atmospheric condensation processes associated with southerly and lower speed wind led to the formation of HPEs. After the start of these HPEs, the concentration of fine particles increased more than twice in several hours. ~80% of the ‘explosive’ growth in PM mass can be considered as a positive feedback of meteorological factors that come from even more stable atmosphere and larger condensation rate of water vapour, which was derived from the interaction between formed aerosol pollution and the meteorological factors within boundary layer. Nitrate was the largest fraction of PM1 in autumn, and the most significantly increased component during HPEs relative to clean period during both of autumn and winter. The proportion of organic aerosol (OA) was similar to that of nitrate in autumn, but its rise in HPE was much smaller, mainly because of the high concentration of OA existed during clean periods. Compared with the largest increase of nitrate, the similar uplift was found for ammonium production, showing that a large amount of ammonium was mainly formed by the combination of in HPEs, rather than . In addition to the lower southerly wind carrying pollutants from southern part of BIV, westerly wind from central Inner Mongolia and north Shanxi can also bring air pollutants originating from coal combustion, contributing to the heavy pollution in the northern BIV area in winter, and resulting in higher sulphate, nitrate and OA masses.
北京及周边地区的重气溶胶污染事件通常从深秋开始,冬季加重。本研究探讨了华北地区hpe形成和变化的原因。研究了2015年秋冬两季HPEs中PM1的粒度分解化学成分和气象条件。稳定的区域大气和与偏南风和低速风相关的较高的大气凝结过程导致了hpe的形成。在这些hpe开始后,细颗粒浓度在几个小时内增加了两倍以上。PM质量“爆炸性”增长的80%可以认为是气象因子的正反馈,这些气象因子来自于更稳定的大气和更大的水蒸气凝结速率,这是形成的气溶胶污染与边界层内气象因子相互作用的结果。在秋季,硝态氮在PM1中所占比例最大,在秋冬两季,相对于清洁期,HPEs中硝态氮的增加最为显著。秋季有机气溶胶(OA)的比例与硝酸盐相似,但HPE的上升幅度要小得多,这主要是由于OA在清洁期存在高浓度。与硝态氮的最大增幅相比,铵的产量也出现了类似的上升,说明大量的铵主要是由hpe中的组合形成的,而不是由hpe中的组合形成的。除了下部偏南风携带BIV南部污染物外,内蒙古中部和山西北部的西风也能带来燃煤产生的大气污染物,造成BIV北部冬季污染较重,硫酸盐、硝酸盐和OA质量较高。
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引用次数: 18
Source appointment of nitrogen in PM2.5 based on bulk δ15N signatures and a Bayesian isotope mixing model 基于体δ15N特征和贝叶斯同位素混合模型的PM2.5中氮源确定
Pub Date : 2017-01-01 DOI: 10.1080/16000889.2017.1299672
Yan-Li Wang, Xue‐Yan Liu, Wei Song, Wen Yang, B. Han, Xiaoyan Dou, Xu-Dong Zhao, Zhaoliang Song, Cong‐Qiang Liu, Z. Bai
Abstract Nitrogen isotope (δ15N) has been employed to differentiate major sources of atmospheric N. However, it remains a challenge to quantify contributions of multiple sources based on δ15N values of the N mixture in atmospheric samples. This study measured δ15N of bulk N in PM2.5 at an urban site of Beijing during a severe haze episode of 22–30 January 2013 and a background site of Qinghai, north-western China from 6 September to 15 October 2013, then applied a Bayesian isotope mixing model (SIAR, Stable Isotope Analysis in R) to analyse the N sources. At Beijing site, δ15N values of PM2.5 (−4.1‰ to +13.5‰, +2.8 ± 6.4‰) were distributed within the range of major anthropogenic sources (including NH3 and NO2 from coal combustion, vehicle exhausts and domestic wastes/sewage). At Menyuan site, δ15N values of PM2.5 (+8.0‰ to +27.9‰, +18.5 ± 5.8‰) were significantly higher than that of potential sources (including NH3 and NO2 from biomass burning, animal wastes, soil N cycle, fertilizer application and dust N). High molar ratios of to and/or in PM2.5 at the background site suggested that the equilibrium of NH3 ↔ caused apparent 15N enrichments in ammonium. Results of the SIAR model showed that 39 and 32% of bulk N in PM2.5 of Beijing site were contributed from N emissions of coal combustion and vehicle exhausts, respectively, whereas N in PM2.5 at Menyuan site was derived mainly from N emissions of biomass burning (46%) and NH3 volatilization (34%). These results revealed that the stoichiometry between NH3 and acidic gases plays an important role in controlling the bulk δ15N signatures of PM2.5 and emissions of reactive N from coal combustion and urban transportation should be strictly controlled to advert the risk of haze episodes in Beijing.
氮同位素(δ15N)已被用于区分大气氮的主要来源,然而,基于大气样品中氮混合物的δ15N值来量化多种来源的贡献仍然是一个挑战。本研究测量了2013年1月22日至30日北京城市站点和2013年9月6日至10月15日中国西北青海省背景站点PM2.5中体氮的δ15N,然后应用贝叶斯同位素混合模型(SIAR, Stable isotope Analysis in R)分析了N源。北京站点PM2.5的δ15N值(−4.1‰~ +13.5‰,+2.8±6.4‰)分布在主要人为源(燃煤NH3和NO2、机动车尾气和生活垃圾/污水)范围内。在门源站点,PM2.5的δ15N值(+8.0‰~ +27.9‰,+18.5±5.8‰)显著高于潜在源(包括生物质燃烧产生的NH3和NO2、动物粪便、土壤N循环、施肥和粉尘N)。背景站点PM2.5中to和/或的高摩尔比表明NH3的平衡导致铵态氮明显富集。SIAR模型结果显示,北京站点PM2.5中散氮的39%和32%分别来自燃煤和机动车尾气的N排放,而门源站点PM2.5中的N主要来自生物质燃烧的N排放(46%)和NH3挥发(34%)。结果表明,NH3与酸性气体之间的化学计量在控制PM2.5的体δ15N特征中起重要作用,应严格控制燃煤和城市交通中活性N的排放,以降低北京雾霾的发生风险。
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引用次数: 36
Estimation of observation errors for large-scale atmospheric inversion of CO2 emissions from fossil fuel combustion 化石燃料燃烧CO2排放大尺度大气反演观测误差的估计
Pub Date : 2017-01-01 DOI: 10.1080/16000889.2017.1325723
Yilong Wang, G. Broquet, P. Ciais, F. Chevallier, F. Vogel, N. Kadygrov, Lin Wu, Yi Yin, Rong Wang, S. Tao
Abstract National annual inventories of CO2 emitted during fossil fuel consumption (FFCO2) bear 5–10% uncertainties for developed countries, and are likely higher at intra annual scales or for developing countries. Given the current international efforts of mitigating actions, there is a need for independent verifications of these inventories. Atmospheric inversion assimilating atmospheric gradients of CO2 and radiocarbon measurements could provide an independent way of monitoring FFCO2 emissions. A strategy would be to deploy such measurements over continental scale networks and to conduct continental to global scale atmospheric inversions targeting the national and one-month scale budgets of the emissions. Uncertainties in the high-resolution distribution of the emissions could limit the skill for such a large-scale inversion framework. This study assesses the impact of such uncertainties on the potential for monitoring the emissions at large scale. In practice, it is more specifically dedicated to the derivation, typical quantification and analysis of critical sources of errors that affect the inversion of FFCO2 emissions when solving for them at a relatively coarse resolution with a coarse grid transport model. These errors include those due to the mismatch between the resolution of the transport model and the spatial variability of the actual fluxes and concentrations (i.e. the representation errors) and those due to the uncertainties in the spatial and temporal distribution of emissions at the transport model resolution when solving for the emissions at large scale (i.e. the aggregation errors). We show that the aggregation errors characterize the impact of the corresponding uncertainties on the potential for monitoring the emissions at large scale, even if solving for them at the transport model resolution. We propose a practical method to quantify these sources of errors, and compare them with the precision of FFCO2 measurements (i.e. the measurement errors) and the errors in the modelling of atmospheric transport (i.e. the transport errors). The results show that both the representation and measurement errors can be much larger than the aggregation errors. The magnitude of representation and aggregation errors is sensitive to sampling heights and temporal sampling integration time. The combination of these errors can reach up to about 50% of the typical signals, i.e. the atmospheric large-scale mean afternoon FFCO2 gradients between sites being assimilated by the inversion system. These errors have large temporal auto-correlation scales, but short spatial correlation scales. This indicates the need for accounting for these temporal auto-correlations in the atmospheric inversions and the need for dense networks to limit the impact of these errors on the inversion of FFCO2 emissions at large scale. More generally, comparisons of the representation and aggregation errors to the errors in simulated FFCO2 gradients due to uncertainties in cur
发达国家在化石燃料消费过程中排放的国家年度二氧化碳清单(FFCO2)具有5-10%的不确定性,在年内尺度或发展中国家可能更高。鉴于目前国际社会为缓解行动所作的努力,有必要对这些清单进行独立核查。大气反演吸收大气CO2梯度和放射性碳测量可以提供一种独立的监测FFCO2排放的方法。一种策略是在大陆尺度的网络上部署这种测量,并针对国家和一个月尺度的排放预算进行大陆到全球尺度的大气逆温。高分辨率辐射分布的不确定性可能会限制这种大规模反演框架的技术。本研究评估了这种不确定性对大规模监测排放潜力的影响。在实践中,它更具体地致力于推导、典型量化和分析影响FFCO2排放反演的关键误差来源,并使用粗网格运输模型在相对粗的分辨率下求解它们。这些误差包括由于运输模式分辨率与实际通量和浓度的空间变异性不匹配造成的误差(即表示误差),以及由于在求解大尺度排放时,由于运输模式分辨率下排放的时空分布不确定造成的误差(即聚集误差)。我们表明,即使在运输模式分辨率下求解,聚合误差也表征了相应的不确定性对大尺度排放监测潜力的影响。我们提出了一种量化这些误差来源的实用方法,并将其与FFCO2测量精度(即测量误差)和大气输送建模误差(即输送误差)进行比较。结果表明,表示误差和测量误差都可能远大于聚合误差。表征和聚集误差的大小对采样高度和时间采样积分时间敏感。这些误差的组合可达到典型信号的50%左右,即被反演系统同化的站点间大气大尺度平均下午FFCO2梯度。这些误差具有较大的时间自相关尺度,而较短的空间相关尺度。这表明需要在大气反演中考虑这些时间自相关性,并且需要密集的网络来限制这些误差对大尺度FFCO2排放反演的影响。更一般地说,由于当前库存的不确定性,将表示和聚集误差与模拟FFCO2梯度的误差进行比较,表明使用全球粗分辨率模式(典型水平分辨率为两度)反演次大陆尺度FFCO2排放的潜力可能有限。具有较小表示误差的中尺度模式将有效地增加反演的潜力,以约束FFCO2排放估算。
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引用次数: 20
Characterization of fine particles during the 2014 Asia-Pacific economic cooperation summit: Number concentration, size distribution and sources 2014年亚太经合组织峰会期间细颗粒物特征:数量浓度、粒径分布及来源
Pub Date : 2017-01-01 DOI: 10.1080/16000889.2017.1303228
Zirui Liu, B. Hu, Junke Zhang, J. Xin, Fang-kun Wu, Wenkang Gao, Mingxing Wang, Yuesi Wang
Abstract To study the impacts of emission controls on aerosol physical and chemical properties, real-time measurements of size-resolved aerosol number concentration and chemical composition were conducted in urban Beijing during the 2014 Asia-Pacific Economic Cooperation (APEC) summit, in a period that a series of measures, for example shutting down or halting production from factories and power plants, and restricting the number of vehicles on the roads were implemented in Beijing and surrounding regions. Significantly, reductions in particle mass concentration (55% for PM2.5 and 48% for PM10) were observed during the APEC summit. A clear decrease in secondary inorganic aerosols (SIA), such as sulphate, nitrate and ammonium, was found during APEC, with the reduction ranged from 65.7 to 72.2% for PM1, in which sulphate showed the largest decrease compared with periods before APEC. As a comparison, organics showed a much smaller decrease of 44.3% for PM1 during APEC. These changes were mainly caused by large reductions in accumulation mode particles, which decreased by 36% compared with 19% for Aitken mode particles. The results from the positive matrix factorization (PMF) of particle number concentration indicate that regionally transported aerosols showed significant decreases (70%), similar to those of SIA during APEC, whereas primary factors from traffic and local combustion sources presented much smaller decreases, with the reduction ranged from 4 to 40%. The elevated contributions of these sources indicated the presence of strong local source emissions. The changes in particle chemical composition, size distribution and sources during the evolution of pollution episodes with and without emission controls are further illustrated. Our results highlight the importance of regional atmospheric transport in the formation of severe pollution episodes in Beijing, indicating that reducing the precursors of secondary aerosol over regional scales represent the key steps to reduce the urban particulate pollution. However, stricter emission controls on local source emissions are needed to further mitigate air pollution in Beijing.
为了研究排放控制对气溶胶物理和化学性质的影响,在2014年亚太经合组织(APEC)峰会期间,在北京城市进行了粒径分辨气溶胶数浓度和化学成分的实时测量,在此期间,一系列措施,如关闭或停止工厂和发电厂的生产,在北京及周边地区实施了车辆限行措施。值得注意的是,在APEC峰会期间,观察到颗粒物质量浓度下降(PM2.5下降55%,PM10下降48%)。在APEC期间,二次无机气溶胶(SIA),如硫酸盐、硝酸盐和铵,明显减少,PM1的减少幅度从65.7到72.2%不等,其中硫酸盐与APEC前相比下降幅度最大。相比之下,在APEC期间,有机物的PM1下降幅度要小得多,为44.3%。这些变化主要是由于堆积模式粒子的大量减少造成的,与艾特肯模式粒子的19%相比,堆积模式粒子减少了36%。颗粒数浓度的正矩阵分解(PMF)结果表明,亚太经合组织期间,区域输送的气溶胶显著减少(70%),与SIA相似,而交通和当地燃烧源的主要因素减少幅度要小得多,减少幅度在4%至40%之间。这些源的贡献增加表明存在强烈的本地源排放。进一步说明了在有排放控制和没有排放控制的情况下,污染事件演变过程中颗粒化学成分、大小分布和来源的变化。研究结果强调了区域大气输送在北京严重污染事件形成中的重要性,表明在区域尺度上减少二次气溶胶的前体是减少城市颗粒物污染的关键步骤。然而,为了进一步缓解北京的空气污染,需要对本地源排放进行更严格的排放控制。
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引用次数: 24
Impacts of aerosol-radiation feedback on local air quality during a severe haze episode in Nanjing megacity, eastern China 南京特大城市严重雾霾期间气溶胶辐射反馈对当地空气质量的影响
Pub Date : 2017-01-01 DOI: 10.1080/16000889.2017.1339548
Mengmeng Li, Tijian Wang, M. Xie, B. Zhuang, Shu Li, Yong Han, Pu-long Chen
Abstract Severe haze events and their radiation feedbacks exert a profound impact on the weather and tropospheric chemistry. Using the on-line-coupled Weather Research and Forecasting with Chemistry (WRF-Chem) model, this study investigates the impacts of direct aerosol-radiation feedbacks on local air quality (i.e. particulate matter and ozone photochemistry) during a severe autumn haze episode in Nanjing megacity, eastern China. Pronounced radiation feedbacks are found for the predictions of meteorological and chemical variables. In response to the negative radiative forcing of scattering-dominant anthropogenic haze aerosols, the instantaneous irradiance and temperature at the surface lower by 130 W m−2 and 1.1–1.4 °C, respectively, leading to a reduction of boundary layer height by 103.2–232.6 m (11–38%) and vertical wind speed by 0.1–0.8 mm s−1 (2–30% at mid-day) during this haze event. Such a stable atmosphere favours the accumulation of fine particles (30.5 μg m−3, 28.7%) and NO2 (6.0 ppb, 23.7%) in the urban pollution plume. The weaker turbulent mixing and photochemical activity associated with the enhanced titration loss, and reduced downward radiation and photolysis rate result in a 0.1−5.0 ppb (12.0%) reduction of near-surface ozone. The simulations highlight that the aerosol-radiation feedbacks play an important role in the atmospheric transport and chemistry of large urban pollution plumes.
严重雾霾事件及其辐射反馈对天气和对流层化学产生深远影响。利用WRF-Chem在线耦合模式,研究了南京特大城市秋季严重雾霾期间气溶胶-辐射直接反馈对当地空气质量(即颗粒物和臭氧光化学)的影响。对气象和化学变量的预测发现明显的辐射反馈。在以散射为主的人为雾霾气溶胶的负辐射强迫作用下,此次雾霾事件期间,地表瞬时辐照度和温度分别降低了130 W m−2和1.1 ~ 1.4℃,导致边界层高度降低103.2 ~ 232.6 m(11 ~ 38%),垂直风速降低0.1 ~ 0.8 mm s−1(2 ~ 30%)。这种稳定的大气有利于城市污染羽流中细颗粒物(30.5 μg m−3,28.7%)和NO2 (6.0 ppb, 23.7%)的积累。较弱的湍流混合和光化学活性与增强的滴定损失、降低的向下辐射和光分解速率相关,导致近地表臭氧减少0.1 ~ 5.0 ppb(12.0%)。模拟结果表明,气溶胶-辐射反馈在大型城市污染羽流的大气输送和化学过程中起着重要作用。
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引用次数: 39
Seasonal variability in atmospheric black carbon at three stations in South-Asia 南亚三个站点大气黑碳的季节变化
Pub Date : 2017-01-01 DOI: 10.1080/16000889.2017.1331102
J. Engström, C. Leck
Abstract Filter-based optical measurements of black carbon in air, a constituent of soot, have been determined with a 528 nm light source during the period from 1 June 2005 to 31 May 2009 on samples taken at Godavari in Nepal, Sinhagad in India and Hanimaadhoo in the Maldives. In order to reduce systematic errors due to the light scattering of non-absorbing particles co-deposited on the filter, such as inorganic salts and mineral dust, an additional sensor recording backscattered light was implemented. Two protocols of corrections (optical and chemical) were applied to the samples collected at the observatories. The Indian monsoon circulation with its two annual phases in combination with the location of the combustion sources and their contribution relative to other non-anthropogenic sources dominated the observed patterns of black carbon at two of the observatories: in India and the Maldives. The observatory in Nepal was however mainly influenced by combustion sources all year around concealing possible variability related to the monsoon circulation. At the receptor observatory in the Maldives, peak values in the black carbon absorption coefficient occurred during the winter season (December to April) when air was transported from the polluted Indian subcontinent out over the Indian Ocean. A close to two orders of magnitude lower values were recorded in air that had spent more than 10-days over the Indian Ocean during the monsoon season (July to September), suggested to be dominated by particulate matter from remote marine biogenic sources and not by combustion sources.
在2005年6月1日至2009年5月31日期间,利用528 nm光源对尼泊尔Godavari、印度Sinhagad和马尔代夫Hanimaadhoo的样品进行了基于滤光片的空气中黑碳(烟灰的一种成分)的光学测量。为了减少非吸收性粒子(如无机盐和矿物粉尘)在滤光片上的散射造成的系统误差,在滤光片上增加了一个记录背散射光的传感器。两种校正方案(光学和化学)应用于在天文台收集的样品。在两个观测站(印度和马尔代夫)观测到的黑碳模式主要受印度季风环流及其两个年相、燃烧源位置及其相对于其他非人为源的贡献的影响。然而,尼泊尔天文台全年主要受燃烧源的影响,掩盖了与季风环流有关的可能变化。在马尔代夫的感受器观测站,黑碳吸收系数的峰值出现在冬季(12月至4月),此时空气从受污染的印度次大陆输送到印度洋上空。在季风季节(7月至9月)在印度洋上空停留10多天的空气中记录到的数值低了近两个数量级,这表明主要是来自遥远海洋生物源的颗粒物,而不是燃烧源。
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引用次数: 5
Spatial variability of wind-induced air pressure fluctuations responsible for pressure pumping 风致气压波动的空间变异性负责压力泵送
Pub Date : 2017-01-01 DOI: 10.1080/16000889.2017.1361757
M. Mohr, T. Laemmel, M. Maier, D. Schindler
Abstract Small air pressure fluctuations in the atmosphere are responsible for the pressure pumping effect, which leads to an enhancement of soil gas transport. To investigate the spatial variability of these air pressure fluctuations, several high-precision differential pressure sensors were installed at the floor of a Scots pine forest. The alignment of the pressure sensors allowed for the determination of the propagation direction and speed of the observed air pressure fluctuations. Below-canopy and above-canopy airflow characteristics were monitored to find possible links between the air pressure fluctuations and the airflow. Results show that the propagation direction of the air pressure fluctuations observed at the forest floor correspond to the above-canopy and not to the below-canopy wind direction. Moreover, propagation speed of the air pressure fluctuations is higher than the below-canopy wind speed and corresponds to above-canopy wind speed. These findings indicate a connection between below-canopy air pressure fluctuations and above-canopy airflow. The air pressure fluctuations were found to be well correlated up to a distance of 15 m. With increasing distance, the correlation strongly decreases. However, the calculated pressure pumping coefficient, which quantifies the strength of the pressure pumping effect, yields similar values up to a distance of 90 m. This allowed specifying the range of influence of the air pressure fluctuations.
大气中微小的气压波动是产生压力泵送效应的原因,压力泵送效应导致土壤气体输运增强。为了研究这些气压波动的空间变异性,在苏格兰松林的地面安装了几个高精度差压传感器。压力传感器的校准允许确定观测到的空气压力波动的传播方向和速度。监测了冠层下和冠层上的气流特性,以发现气压波动和气流之间可能存在的联系。结果表明:在森林地面观测到的气压波动的传播方向与冠层上风向一致,与冠层下风向不一致;气压波动的传播速度高于冠层下风速,对应于冠层上风速。这些发现表明了冠层下气压波动和冠层上气流之间的联系。发现在15米的距离内,气压波动具有良好的相关性。随着距离的增加,相关系数明显降低。然而,计算出的压力泵送系数(用于量化压力泵送效果的强度)在距离为90 m时也得到了类似的值。这样就可以确定气压波动的影响范围。
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引用次数: 7
Negligible local-factor influences on tree ring cellulose δ18O of Qilian juniper in the Animaqing Mountains of the eastern Tibetan Plateau 青藏高原东部阿马清山祁连杜松树木年轮纤维素δ18O的局地因子影响可忽略不计
Pub Date : 2017-01-01 DOI: 10.1080/16000889.2017.1391663
Chenxi Xu, X. Shao, W. An, T. Nakatsuka, Yong Zhang, M. Sano, Zhengtang Guo
Abstract Tree ring cellulose oxygen isotopes (δ18O) were measured on 21 trees of Qilian juniper from the Animaqing Mountains, Tibetan Plateau, to investigate intra- and inter-tree variability, potential juvenile and elevation effects and climatic implications. There are no significant differences in mean and standard deviation of tree ring δ18O values at different heights in individual trees. Tree ring δ18O values from different directions show a high degree of coherence. The mean and standard deviation for vertical and circumferential δ18O time series are very similar, and δ18O data from different heights and directions are highly correlated (r > 0.88). The δ18O values of young trees are lower than those of old trees in the first 10 years of tree growth. Tree ring δ18O data from five different altitudes are highly correlated (r > 0.88) and share similar climatic signals. As such, an altitude effect on tree ring δ18O is not observed. Our results indicate that samples from one site, regardless of sampling height, direction or altitude, can be used to reconstruct a long-term δ18O record. Tree ring δ18O data from the Animaqing Mountains show a significant negative correlation (r = −0.67; p < 0.001) with May–July regional precipitation and appear to be a promising proxy for precipitation reconstruction.
摘要对青藏高原阿马清山祁连杜松21棵树的年轮纤维素氧同位素(δ18O)进行了测定,探讨了树内和树间的变异、潜在的幼树效应和海拔效应以及气候意义。不同高度树木年轮δ18O值的均值和标准差均无显著差异。不同方向的树木年轮δ18O值具有高度的一致性。垂直和周向δ18O时间序列的均值和标准差非常相似,不同高度和方向的δ18O数据高度相关(r > 0.88)。在树木生长的前10年,幼树的δ18O值低于老树。5个不同海拔的树木年轮δ18O数据高度相关(r > 0.88),具有相似的气候信号。因此,没有观测到海拔对树木年轮δ18O的影响。结果表明,无论取样高度、方向或海拔高度如何,同一地点的样品都可以重建长期的δ18O记录。阿尼玛青山树木年轮δ18O数据呈显著负相关(r = - 0.67;p < 0.001)与5 - 7月区域降水有关,似乎是一个有希望的降水重建指标。
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引用次数: 10
期刊
Tellus B: Chemical and Physical Meteorology
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