首页 > 最新文献

The Mining and Materials Processing Institute of Japan最新文献

英文 中文
Effect of Internal Gas Pressure on Gas Permeability of Coal in Unsteady-State Gas Flow. Study on gas permeability of coal by crack network model (2nd Report). 非稳态瓦斯流动中瓦斯内压对煤渗透率的影响用裂隙网络模型研究煤的透气性(第二报告)。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.601
T. Imai, I. Nakajima, K. Asakura, T. Goto
The purpose of this study is to prove the effect of internal pore pressure on unsteady-state gas flow in coal. Practically, the gas permeation model of coal which consists of the gas permeable and non-permeable crack network was proposed. Then the numerical simulations of gas permeation by this model were carried out by changing the parameters such as inlet pressure in the crack network, confining pressure against coal, closing probability of cracks, etc.The results of these simulations on fluctuations of unsteady-state gas flow were in agreements with the experiments of gas permeation of coal. From these considerations it was found that the above gas permeation model was accurate enough for practically. Moreover, the results of the simulations on unsteady-state gas flow in coal gave an explanation to the deviation from the Darcy's law in the relationsbetween gas flow and difference pressure.
本研究的目的是为了证明内部孔隙压力对煤中非稳态气体流动的影响。在实际应用中,提出了由透气裂隙网络和不透气裂隙网络组成的煤层瓦斯渗透模型。在此基础上,通过改变裂隙网络的入口压力、对煤的围压、裂隙闭合概率等参数,利用该模型对瓦斯渗流进行了数值模拟,得到了非稳态瓦斯流动波动的模拟结果,与煤的瓦斯渗流实验结果相吻合。从这些方面考虑,发现上述气体渗透模型具有足够的精度,可以用于实际应用。此外,煤中非稳态瓦斯流动的模拟结果解释了瓦斯流动与压差关系偏离达西定律的原因。
{"title":"Effect of Internal Gas Pressure on Gas Permeability of Coal in Unsteady-State Gas Flow. Study on gas permeability of coal by crack network model (2nd Report).","authors":"T. Imai, I. Nakajima, K. Asakura, T. Goto","doi":"10.2473/SHIGENTOSOZAI.113.601","DOIUrl":"https://doi.org/10.2473/SHIGENTOSOZAI.113.601","url":null,"abstract":"The purpose of this study is to prove the effect of internal pore pressure on unsteady-state gas flow in coal. Practically, the gas permeation model of coal which consists of the gas permeable and non-permeable crack network was proposed. Then the numerical simulations of gas permeation by this model were carried out by changing the parameters such as inlet pressure in the crack network, confining pressure against coal, closing probability of cracks, etc.The results of these simulations on fluctuations of unsteady-state gas flow were in agreements with the experiments of gas permeation of coal. From these considerations it was found that the above gas permeation model was accurate enough for practically. Moreover, the results of the simulations on unsteady-state gas flow in coal gave an explanation to the deviation from the Darcy's law in the relationsbetween gas flow and difference pressure.","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"6 1","pages":"601-607"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87503721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of the Ultrasonic Propagation Time of a Core Sample for Stress Measurement of Underground Rocks. 超声传播时间在地下岩石应力测量中的应用。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.593
T. Goto, J. Kodama, K. Itakura, Y. Yoshida
Deformation rate analysis (DRA), although it has a poor theoretical basis, is a useful method for estimating rock stress in the laboratory using core samples. DRA is thought to be closely related to changes in the inner microstructure of rock samples undergoing a de formation process. Ultrasonic measurement is a useful technique for investigating structural changes in rocks. In this study, both methods were applied simultaneously to rock samples to confirm the applicability of ultrasonic measurement for the estimation of rock stress using a system of ultrasonic propagation time with accuracy in 10-2 nsec.In the experiments, core samples of sandstone were loaded up to a certain stress in order to artificially input memory of the stress into the samples, and the propagation time in the horizontal direction to the loading axis and the deformation rate were measured simultaneously. Consequently, the propagation time through the specimen was measured with high accuracy during deformation. Variations in the propagation time and lateral strain almost coincided during the loading-up process. Furthermore, the propagation time was drastically changed at the memorized stress corresponding to the deflection point of the deformation rate curve. These experimental results show that highly accurate measurement of the ultrasonic propagation time is useful, as is the DRA method using core samples, for examining changes in the microstructure inside rock samples under stress and applicable for estimating underground rock stress.
变形率分析(DRA)虽然理论基础较差,但在实验室中利用岩心样品估计岩石应力是一种有用的方法。DRA被认为与岩石试样在变形过程中的内部微观结构变化密切相关。超声波测量是研究岩石结构变化的一种有用技术。在本研究中,两种方法同时应用于岩石样品,以证实超声波测量在岩石应力估计中的适用性,超声波传播时间系统的精度在10-2 nsec。在实验中,将砂岩岩心试样加载到一定的应力,人为地将应力记忆输入到试样中,同时测量其在水平方向上到加载轴的传播时间和变形率。因此,可以高精度地测量变形过程中通过试样的传播时间。在加载过程中,扩展时间和侧应变的变化几乎一致。在变形速率曲线的挠曲点对应的记忆应力处,传播时间发生了剧烈变化。实验结果表明,超声传播时间的高精度测量与岩心样品的DRA方法一样,可用于检测应力作用下岩样内部微观结构的变化,并可用于估算地下岩石应力。
{"title":"Application of the Ultrasonic Propagation Time of a Core Sample for Stress Measurement of Underground Rocks.","authors":"T. Goto, J. Kodama, K. Itakura, Y. Yoshida","doi":"10.2473/SHIGENTOSOZAI.113.593","DOIUrl":"https://doi.org/10.2473/SHIGENTOSOZAI.113.593","url":null,"abstract":"Deformation rate analysis (DRA), although it has a poor theoretical basis, is a useful method for estimating rock stress in the laboratory using core samples. DRA is thought to be closely related to changes in the inner microstructure of rock samples undergoing a de formation process. Ultrasonic measurement is a useful technique for investigating structural changes in rocks. In this study, both methods were applied simultaneously to rock samples to confirm the applicability of ultrasonic measurement for the estimation of rock stress using a system of ultrasonic propagation time with accuracy in 10-2 nsec.In the experiments, core samples of sandstone were loaded up to a certain stress in order to artificially input memory of the stress into the samples, and the propagation time in the horizontal direction to the loading axis and the deformation rate were measured simultaneously. Consequently, the propagation time through the specimen was measured with high accuracy during deformation. Variations in the propagation time and lateral strain almost coincided during the loading-up process. Furthermore, the propagation time was drastically changed at the memorized stress corresponding to the deflection point of the deformation rate curve. These experimental results show that highly accurate measurement of the ultrasonic propagation time is useful, as is the DRA method using core samples, for examining changes in the microstructure inside rock samples under stress and applicable for estimating underground rock stress.","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"17 1","pages":"593-599"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86222395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Wettability of Cu Plate by a Sn-Bi Solder. 锡铋焊料对铜板的润湿性。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.205
T. Tanabe, Z. Asaki
For the development of lead-free solder, wettability of 41.2Sn-58.8Bi and 61.6Sn-38.4Pb solders was compared by use of meniscometer. It has been reported by several researchers that the wettability of Sn-Bi solder is poor as compared with Sn-Pb solder. In order to obtain fundamental data, no flux was used in this work because wettability of solder is significantly affected by the kind of flux and the available fluxes have been developed for Sn-Pb solder. Oxygen-free copper plate and copper alloy plate containing 0.3 mass % Cr, 0.1 mass % Zr and 0.02 mass % Si of 0.5mm in thickness and 10mm wide were immersed into the molten solders at the temperature range from 483 K to 543 K. It was found that wettability of both Sn-Bi and Sn-Pb solders to these plates was poor without use of flux. Then a parameter (surface tension) by cosine (contact angle) was used for the comparison of wettability of these solders. No significant difference in the parameter between these solders was observed. Consequently, it is thought that the Sn-Bi solder will be promising provided that flux suitable for this solder is developed.
为了研制无铅焊料,采用半月线计对41.2Sn-58.8Bi和61.6Sn-38.4Pb钎料的润湿性进行了比较。有研究表明,锡铋焊料的润湿性较锡铅焊料差。为了获得基本数据,本工作中没有使用助焊剂,因为焊剂的种类对焊料的润湿性有很大影响,并且已经开发了适用于Sn-Pb焊料的助焊剂。将厚度为0.5mm、宽度为10mm、含0.3质量% Cr、0.1质量% Zr和0.02质量% Si的无氧铜板和铜合金板在483 ~ 543 K的温度范围内浸入熔融焊料中。结果表明,在不使用助焊剂的情况下,Sn-Bi和Sn-Pb焊料对这些板的润湿性都很差。然后用余弦(接触角)参数(表面张力)来比较这些焊料的润湿性。这些焊料之间的参数没有显著差异。因此,认为只要研制出适合于锡铋焊料的助焊剂,锡铋焊料将是很有前途的。
{"title":"Wettability of Cu Plate by a Sn-Bi Solder.","authors":"T. Tanabe, Z. Asaki","doi":"10.2473/SHIGENTOSOZAI.113.205","DOIUrl":"https://doi.org/10.2473/SHIGENTOSOZAI.113.205","url":null,"abstract":"For the development of lead-free solder, wettability of 41.2Sn-58.8Bi and 61.6Sn-38.4Pb solders was compared by use of meniscometer. It has been reported by several researchers that the wettability of Sn-Bi solder is poor as compared with Sn-Pb solder. In order to obtain fundamental data, no flux was used in this work because wettability of solder is significantly affected by the kind of flux and the available fluxes have been developed for Sn-Pb solder. Oxygen-free copper plate and copper alloy plate containing 0.3 mass % Cr, 0.1 mass % Zr and 0.02 mass % Si of 0.5mm in thickness and 10mm wide were immersed into the molten solders at the temperature range from 483 K to 543 K. It was found that wettability of both Sn-Bi and Sn-Pb solders to these plates was poor without use of flux. Then a parameter (surface tension) by cosine (contact angle) was used for the comparison of wettability of these solders. No significant difference in the parameter between these solders was observed. Consequently, it is thought that the Sn-Bi solder will be promising provided that flux suitable for this solder is developed.","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"6 1","pages":"205-209"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83676422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Acid Leaching of Chalcopyrite Concentrate with Hematite Powder as an Effective Promoter. 赤铁矿粉作为有效促进剂的黄铜矿精矿酸浸。
Pub Date : 1997-01-01 DOI: 10.2473/shigentosozai.113.631
Ezequiel Cruz Sanchez, Yoshiaki Umetsc, F. Saito
Leaching of chalcopyrite concentrate having specific surface area of about 3 m2/g in 0.5 mol/dm3 HCl solution was conducted at 333 K using hematite (Fe2O3) and ferric chloride (FeCl3) powders, respectively. The leaching of the concentrate with Fe2O3 powder permits to achieve about 75 % copperextraction within 24 hours, while about 65 % copper is extracted by the leaching with FeCl3 powder. Theyield of copper in the leaching with Fe2O3 powder is twice or more higher than that without the promoters. High copper extraction can be achieved when much of the elemental sulfur is formed on thesolid residue after the leaching. Especially, the presence of Fe2O3 powder gives us the elemental sulfurprecipitates more than that of FeCl3 powder. Therefore, Fe2O3 can be an effective promoter inthe leaching of chalcopyrite concentrate using HCl solution.
采用赤铁矿(Fe2O3)粉和氯化铁(FeCl3)粉,在333 K条件下,在0.5 mol/dm3的HCl溶液中浸出比表面积约为3 m2/g的黄铜矿精矿。用Fe2O3粉浸出精矿,可在24小时内获得约75%的铜,而用FeCl3粉浸出精矿,可获得约65%的铜。用Fe2O3粉末浸出铜的产率比不添加促进剂的浸出铜的产率高2倍以上。当大部分单质硫在浸出后的固体残渣上形成时,可以实现高铜提取率。特别是,Fe2O3粉末的存在使我们得到比FeCl3粉末更多的单质硫析出物。因此,Fe2O3可以作为HCl溶液浸出黄铜矿精矿的有效促进剂。
{"title":"Acid Leaching of Chalcopyrite Concentrate with Hematite Powder as an Effective Promoter.","authors":"Ezequiel Cruz Sanchez, Yoshiaki Umetsc, F. Saito","doi":"10.2473/shigentosozai.113.631","DOIUrl":"https://doi.org/10.2473/shigentosozai.113.631","url":null,"abstract":"Leaching of chalcopyrite concentrate having specific surface area of about 3 m2/g in 0.5 mol/dm3 HCl solution was conducted at 333 K using hematite (Fe2O3) and ferric chloride (FeCl3) powders, respectively. The leaching of the concentrate with Fe2O3 powder permits to achieve about 75 % copperextraction within 24 hours, while about 65 % copper is extracted by the leaching with FeCl3 powder. Theyield of copper in the leaching with Fe2O3 powder is twice or more higher than that without the promoters. High copper extraction can be achieved when much of the elemental sulfur is formed on thesolid residue after the leaching. Especially, the presence of Fe2O3 powder gives us the elemental sulfurprecipitates more than that of FeCl3 powder. Therefore, Fe2O3 can be an effective promoter inthe leaching of chalcopyrite concentrate using HCl solution.","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"23 1","pages":"631-634"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82928207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Project for Stable Overseas Coal Supply. 稳定海外煤炭供应项目。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.768
T. Yuasa
{"title":"Project for Stable Overseas Coal Supply.","authors":"T. Yuasa","doi":"10.2473/SHIGENTOSOZAI.113.768","DOIUrl":"https://doi.org/10.2473/SHIGENTOSOZAI.113.768","url":null,"abstract":"","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"20 1","pages":"768-771"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79272659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of Mining Cost Data Base System. 采矿成本数据库系统的开发。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.738
H. Mirabediny
{"title":"Development of Mining Cost Data Base System.","authors":"H. Mirabediny","doi":"10.2473/SHIGENTOSOZAI.113.738","DOIUrl":"https://doi.org/10.2473/SHIGENTOSOZAI.113.738","url":null,"abstract":"","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"83 1","pages":"738-741"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90690121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recycling. Soil Recycling from Heavy Metal Contaminated Soil by Soil Washing Treatment. 回收利用。重金属污染土壤的洗土再循环
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.1115
Kenta Tabuchi, S. Kawakami, T. Shiratori, T. Saitoh
Soil washing treatment is a water based process for mechanically scrubbing soils ex situ to remove undesirable contaminants. The process remove contaminants by dissolving or suspending them in wash solution or by concentrating them into a smaller volume of soil through particle size separation techniques. This process together with biological treatment is relatively mild to soil nature compared thermal treatment, so adequate for recycling of soil.The concept of reducing contamination through the use of particle size separation is based on the finding that most inorganic or organic contaminants tend to bind to clay and silt soil particles. Washing processes that separate the clay and silt particles from sand and gravel soil particles effectively separate and concentrate the contaminants into a smaller volume of soil that can be further treated or disposed. The clean, larger fraction can be recycled.In this paper, we demonstrate our trials with four types of heavy metal contaminated soil by three methods. Those method are a laboratory size separation experiment, a pilot plant experiment and a full scale plant treatment.For one type of soil the results of the laboratory experiment were shown to be different from those of the pilot plant experiment. It was suggested that a laboratory test with small volume of soil would make a incorrect estimation for treatability caused by heterogeneity of soil.Another type of soil showed a result that heavy metals exist at higher concentration in coarse particles than fine ones. It was suggested that for this type of soil, simple soil washing treatments are not applicable.A full scale treatment process were shown, and practical quality control were emphasized.
土壤洗涤处理是一种以水为基础的过程,通过机械洗涤土壤以去除不需要的污染物。该工艺通过将污染物溶解或悬浮在洗涤溶液中,或通过粒度分离技术将其浓缩到较小体积的土壤中来去除污染物。该工艺与生物处理相比,对土壤性质的影响相对温和,适合土壤的循环利用。通过使用粒度分离来减少污染的概念是基于大多数无机或有机污染物倾向于与粘土和粉土颗粒结合的发现。将粘土和淤泥颗粒从砂土和砾石土颗粒中分离出来的洗涤过程有效地将污染物分离并浓缩到可以进一步处理或处置的较小体积的土壤中。干净的、较大的部分可以回收。本文用三种方法对四种重金属污染土壤进行了试验。这些方法是实验室规模的分离实验,中试工厂实验和全规模工厂处理。对于同一种土壤,室内试验结果与中试试验结果存在差异。结果表明,由于土壤的异质性,采用小体积的室内试验可能会对土壤的可处理性做出不正确的估计。另一种土壤的结果显示,重金属在粗颗粒中的浓度高于细颗粒。建议对这类土壤不宜采用简单的洗土处理。展示了一个完整的处理过程,并强调了实际的质量控制。
{"title":"Recycling. Soil Recycling from Heavy Metal Contaminated Soil by Soil Washing Treatment.","authors":"Kenta Tabuchi, S. Kawakami, T. Shiratori, T. Saitoh","doi":"10.2473/SHIGENTOSOZAI.113.1115","DOIUrl":"https://doi.org/10.2473/SHIGENTOSOZAI.113.1115","url":null,"abstract":"Soil washing treatment is a water based process for mechanically scrubbing soils ex situ to remove undesirable contaminants. The process remove contaminants by dissolving or suspending them in wash solution or by concentrating them into a smaller volume of soil through particle size separation techniques. This process together with biological treatment is relatively mild to soil nature compared thermal treatment, so adequate for recycling of soil.The concept of reducing contamination through the use of particle size separation is based on the finding that most inorganic or organic contaminants tend to bind to clay and silt soil particles. Washing processes that separate the clay and silt particles from sand and gravel soil particles effectively separate and concentrate the contaminants into a smaller volume of soil that can be further treated or disposed. The clean, larger fraction can be recycled.In this paper, we demonstrate our trials with four types of heavy metal contaminated soil by three methods. Those method are a laboratory size separation experiment, a pilot plant experiment and a full scale plant treatment.For one type of soil the results of the laboratory experiment were shown to be different from those of the pilot plant experiment. It was suggested that a laboratory test with small volume of soil would make a incorrect estimation for treatability caused by heterogeneity of soil.Another type of soil showed a result that heavy metals exist at higher concentration in coarse particles than fine ones. It was suggested that for this type of soil, simple soil washing treatments are not applicable.A full scale treatment process were shown, and practical quality control were emphasized.","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"2 1","pages":"1115-1120"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90893796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
The Masking of Cobalt by Sulfite Ion in Solvent Extraction. 溶剂萃取中亚硫酸盐离子对钴的遮盖作用。
Pub Date : 1997-01-01 DOI: 10.2473/shigentosozai.113.859
A. Inoue, M. Kawahara
After leaching cobalt crusts in an ammoniacal solution using sulfur dioxide gas as a reductant, the extraction of cobalt was held down in the solvent extraction process. The effects of sulfite ion on cobalt were studied by using nitroso R salt which forms a complex with cobalt. As a result, formation of cobalt complex salt was negligible in the solution of ammonium sulfite and sodium sulfite. It is supposed that sulfite ion acts as a masking reagent for cobalt.Solvent extraction of cobalt and nickel was carried out using LIX84-I as an extractant for the solution of ammonium sulfite. The effects of the ammonium sulfite concentration and retention time on the extraction of cobalt were investigated. Cobalt (10 ppm) was not extracted from the ammonium sulfite solution of concentration more than 0.5 M and the pH over 10.5. In the same condition, nickel (10 ppm) was extracted completely. Same studies were carried out by using PC-88A and D2EHPA, but superior separation of cobalt and nickel was not attained.An EDTA titration was carried out by addition of sodium sulfite or ammonium sulfite to the solution including cobalt and nickel. As a result, only nickel was titrated quantitatively inthe mixed solution containing up to 1 mg (20 ppm) of cobalt
用二氧化硫气体作为还原剂,在氨溶液中浸出钴结壳后,钴的提取在溶剂萃取过程中被抑制。采用亚硝基R盐与钴形成络合物,研究了亚硫酸盐离子对钴的影响。因此,在亚硫酸铵和亚硫酸钠溶液中,钴络合盐的形成可以忽略不计。亚硫酸盐离子可以作为钴的掩蔽剂。以LIX84-I为萃取剂,对亚硫酸铵溶液进行了钴和镍的溶剂萃取。考察了亚硫酸铵浓度和停留时间对钴提取的影响。在浓度大于0.5 M、pH大于10.5的亚硫酸铵溶液中,钴(10 ppm)不能提取。在相同条件下,镍(10ppm)被完全提取。用PC-88A和D2EHPA进行了同样的研究,但没有获得较好的钴镍分离效果。在含钴和镍的溶液中加入亚硫酸钠或亚硫酸铵,进行EDTA滴定。结果,在含有高达1mg (20ppm)钴的混合溶液中,只有镍被定量滴定
{"title":"The Masking of Cobalt by Sulfite Ion in Solvent Extraction.","authors":"A. Inoue, M. Kawahara","doi":"10.2473/shigentosozai.113.859","DOIUrl":"https://doi.org/10.2473/shigentosozai.113.859","url":null,"abstract":"After leaching cobalt crusts in an ammoniacal solution using sulfur dioxide gas as a reductant, the extraction of cobalt was held down in the solvent extraction process. The effects of sulfite ion on cobalt were studied by using nitroso R salt which forms a complex with cobalt. As a result, formation of cobalt complex salt was negligible in the solution of ammonium sulfite and sodium sulfite. It is supposed that sulfite ion acts as a masking reagent for cobalt.Solvent extraction of cobalt and nickel was carried out using LIX84-I as an extractant for the solution of ammonium sulfite. The effects of the ammonium sulfite concentration and retention time on the extraction of cobalt were investigated. Cobalt (10 ppm) was not extracted from the ammonium sulfite solution of concentration more than 0.5 M and the pH over 10.5. In the same condition, nickel (10 ppm) was extracted completely. Same studies were carried out by using PC-88A and D2EHPA, but superior separation of cobalt and nickel was not attained.An EDTA titration was carried out by addition of sodium sulfite or ammonium sulfite to the solution including cobalt and nickel. As a result, only nickel was titrated quantitatively inthe mixed solution containing up to 1 mg (20 ppm) of cobalt","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"49 1","pages":"859-864"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89820181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Some Aspects of Relationship between Output of Shearer Main Motor and Production Volume of Shearer Drum. 采煤机主电机输出功率与采煤机滚筒产量关系的几个方面。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.735
G. Wild, D. Prlce
{"title":"Some Aspects of Relationship between Output of Shearer Main Motor and Production Volume of Shearer Drum.","authors":"G. Wild, D. Prlce","doi":"10.2473/SHIGENTOSOZAI.113.735","DOIUrl":"https://doi.org/10.2473/SHIGENTOSOZAI.113.735","url":null,"abstract":"","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"21 1","pages":"735-737"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75080144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Axial Propagation Property of Oscillation in Water Jets. 水射流中振荡的轴向传播特性。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.565
F. Kiyono, T. Saito
In the field of water jet technology the improvement of cutting efficiency has been recognized as one of the most important research targets. To solve this problem an oscillating jet nozzle was developed. In this nozzle several piezo-electric transducers are attached to a vibration plate, and through this plate oscillation of piezoelectric transducers is propagated to inner high pressure water, then oscillating jets emanate from a nozzle outlet.To optimize the efficiency of the oscillating jet nozzle an appropriate frequency must be selected undergiven water jet velocity and jet diameter.In this paper the authors examine this problem from the point of hydrodynamic stability of oscillating jets. Firstly the diagram for selecting the optimum oscillation frequency is presented. Then experimental results are compared with theoretical results which were predicted by the hydrodynamic stability theory. Both results show qualitative agreement.
在水射流技术领域,提高切割效率一直是公认的重要研究目标之一。为了解决这一问题,研制了一种振荡射流喷嘴。在该喷嘴内,若干压电换能器连接在振动板上,通过振动板将压电换能器的振动传播到内部高压水中,然后从喷嘴出口喷出振荡射流。在一定的水射流速度和射流直径条件下,必须选择合适的频率以优化振荡射流喷嘴的效率。本文从振荡射流的水动力稳定性角度对这一问题进行了研究。首先给出了选择最佳振荡频率的框图。然后将实验结果与水动力稳定性理论预测结果进行了比较。两个结果在定性上一致。
{"title":"Axial Propagation Property of Oscillation in Water Jets.","authors":"F. Kiyono, T. Saito","doi":"10.2473/SHIGENTOSOZAI.113.565","DOIUrl":"https://doi.org/10.2473/SHIGENTOSOZAI.113.565","url":null,"abstract":"In the field of water jet technology the improvement of cutting efficiency has been recognized as one of the most important research targets. To solve this problem an oscillating jet nozzle was developed. In this nozzle several piezo-electric transducers are attached to a vibration plate, and through this plate oscillation of piezoelectric transducers is propagated to inner high pressure water, then oscillating jets emanate from a nozzle outlet.To optimize the efficiency of the oscillating jet nozzle an appropriate frequency must be selected undergiven water jet velocity and jet diameter.In this paper the authors examine this problem from the point of hydrodynamic stability of oscillating jets. Firstly the diagram for selecting the optimum oscillation frequency is presented. Then experimental results are compared with theoretical results which were predicted by the hydrodynamic stability theory. Both results show qualitative agreement.","PeriodicalId":22754,"journal":{"name":"The Mining and Materials Processing Institute of Japan","volume":"59 1","pages":"565-570"},"PeriodicalIF":0.0,"publicationDate":"1997-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83991536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
The Mining and Materials Processing Institute of Japan
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1