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Corrosion Resistance of Steels in Sulfuric Acid Solution. 钢在硫酸溶液中的耐蚀性。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.799
R. Matsuhashi
Sulfuric acid solution is the most common environment in various industrial processes and it is well known that the ion affect on the rate of corrosion of steels. In this paper, corrosion resistance of mild steels, low alloy steels, stainless steels and Ni-base alloys in such environment, are reviewed based on various studies. Types of stainless steels are developed for the environment and the evaluation of these steels is reported for both laboratory scale and field tests.
硫酸溶液是各种工业过程中最常见的环境,众所周知,离子对钢的腐蚀速度有影响。本文综述了低碳钢、低合金钢、不锈钢和镍基合金在这种环境下的耐蚀性。开发了适用于环境的各种不锈钢,并报告了实验室规模和现场试验对这些钢的评价。
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引用次数: 0
Depressing Effect of Raising Pulp Temperature on Pyrite Flotation. 提高矿浆温度对黄铁矿浮选的抑制作用。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.571
Hideyo Osanai, I. Matsuoka
The depressing effect of raising pulp temperature on pyrite flotation have been investigated by using diethyl dithiophosphate (ethyl aerofloat, E. A. F.) as a collector. The mechanism of depression have been studied in terms of collector adsorption and changes in concentration of sulfate, hydroxide and iron ions in pulp during conditioning, and the surface products after conditioning identified by diffuse reflectance infrared fourier transform spectroscopy (DRIFTS) and X-ray photo-electron spectroscopy (XPS).The results obtained are as follows:The flotation recovery of pyrite at pH 6 was only slightly decreased by raising pulp temperature from25°C to °C in the presence of large amounts of collector, but it was significantly depressed in moderate collector addition of the order of 200-300 g/t.There was no difference between collector adsorption at 25 °C and that at 60°C in the collector addition less than 500 g/t. Accordingly, the depression of pyrite by raising pulp temperature can not be explained by the decrease of collector adsorption.From the changes of the concentration of sulfate, hydroxide and iron ions before and after conditioning at 25°C or 60°C, it was suggested that basic iron sulfate was precipitated on pyrite surface during conditioning at either pulp temperature, but the amount precipitated at 60 t was much larger than that at 25°C, because the oxidation reaction of pyrite surface took place at 60°.The existence of sulfate on the pyrite surface after conditioning at 60 t was detected by DRIFTS and XPS.From the above experimental results, it is concluded that pyrite depression by raising pulp temperature is mainly attributed to the formation of hydrophilic basic iron sulfate which offsets the hydrophobization effect with collector adsorption.
以二硫代磷酸二乙酯为捕收剂,研究了提高矿浆温度对黄铁矿浮选的抑制作用。从捕收剂吸附、硫酸盐、氢氧化物和铁离子在调理过程中的浓度变化等方面研究了抑制机理,并利用漫反射红外傅立叶变换光谱(DRIFTS)和x射线光电子能谱(XPS)对调理后的表面产物进行了鉴定。结果表明:在ph6条件下,矿浆温度从25℃提高到25℃,在大量添加捕收剂的情况下,黄铁矿的浮选回收率略有下降,但在捕收剂添加量为200 ~ 300 g/t量级时,黄铁矿的浮选回收率明显下降。当捕收剂添加量小于500 g/t时,捕收剂在25°C和60°C时的吸附量没有差异。因此,提高矿浆温度对黄铁矿的抑制不能用捕收剂吸附的减少来解释。从25°C和60°C调质前后硫酸盐、氢氧化物和铁离子浓度的变化可以看出,无论在矿浆温度下调质,都有碱式硫酸铁在黄铁矿表面析出,但由于黄铁矿表面的氧化反应发生在60°C,因此60°t时的析出量远远大于25°C时的析出量。用DRIFTS和XPS检测了60 t条件下黄铁矿表面硫酸盐的存在。综上所述,提高矿浆温度对黄铁矿的抑制主要是由于亲水性碱式硫酸铁的形成抵消了捕收剂吸附对黄铁矿的疏水作用。
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引用次数: 0
Recycling. Extraction and Recovery Techniques. Solvent Extraction. 回收利用。提取和回收技术。溶剂萃取。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.940
Mikiya Tanaka
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引用次数: 2
Effect of Electrolytes on Solidification of Glass Beads by Hydrothermal Hot-Pressing. 电解液对热液热压玻璃微珠凝固的影响。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.67
S. Kimura, Shinobu Fujisaku, N. Tsuchiya, K. Nakatsuka
Soda lime glass beads were solidified by hydrothermal hot-pressing at 300°C for a period of 1 hour with NaOH, KOH, NaCl, KCl, Na2SO4, HCl solutions and deionized water, respectively. Shrinkage was monitored during experiment, and the solidified products were examined by SEM-EDX, XRD, FT-IR, TG and Shore hardness tester. The cross-section of the reacted glass bead showed three distinct layers of varying thickness that have undergone different degrees of alteration. The degree of alteration was higher approaching the surface of the glass beads. The surfaces of the glass beads were highly altered, deformed and cemented with each other. The final shrinkage increased in the order of acidic, neutral and alkali solution. The Shore hardness was found to increase with any increase in shrinkage for solutions containing same cation but was higher for Na+ solution than K+ solution. Thermogravimetric results indicated that the water contents in solidified products with K+ solutions were higher than the ones with Na+ solutions. This suggests that the drop in the hardness was caused by the presence of larger amount of water in solidified products with K+ than Na+.
用NaOH、KOH、NaCl、KCl、Na2SO4、HCl和去离子水分别在300℃水热压制下固化钠石灰玻璃微珠,固化时间为1小时。实验过程中监测了试样的收缩率,并采用SEM-EDX、XRD、FT-IR、TG和邵氏硬度计对固化产物进行了表征。反应后的玻璃珠的横截面显示出三个不同厚度的层,这些层经历了不同程度的变化。接近玻璃珠表面的变化程度更高。玻璃珠的表面被高度改变、变形并相互粘合。最终收缩率在酸性、中性、碱性溶液中依次增大。在相同阳离子的溶液中,邵氏硬度随收缩率的增加而增加,但Na+溶液的硬度高于K+溶液。热重分析结果表明,K+溶液固化产物含水量高于Na+溶液固化产物含水量。这表明,硬度的下降是由于K+固化产物中存在较多的水而不是Na+。
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引用次数: 1
Recycling. Extraction and Recovery Techniques. Electrolytic Processes. 回收利用。提取和回收技术。电解过程。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.945
Y. Umetsu
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引用次数: 1
Improvement of the Conical-ended Borehole Technique for Rock Stress Measurement with a High Accuracy. 高精度岩石应力测量锥形端孔技术的改进。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.825
Y. Obara, K. Imai, N. Nakamura, K. Sugawara
Knowledge of the rock stress is one of keys to design and construct rock structures. Thein-situstresses, therefore, have to be accurately measured. Since rock stress measurement is generally time consuming task, the new technique development is being expected to determine the complete stress state from a measurement in a single borehole. Thus, the stress relief method should be improved to meet its demand.Many stress relief methods to determine the complete state of stress have been proposed and developed. Among these methods, the CSIRO hollow inclusion stress cell has been most popular in the world, since it enables us to accurately measurein-situstresses. The eight-elements strain gauge, the hemispherical shaped strain cell and the conical shaped strain cell have been used in Japan. In these three methods, the conical-ended borehole technique with sixteen-elements conical shaped strain cell has an advantage to reduce the time, effort and cost for a series of rock stress measurements, combining the compact overcoring, the diameter of which equals to that of the pilot borehole.In the present study, the conical shaped strain cell has been modified and refined to improve the accuracy in rock stress measurement, increasing the number of strain measured on the conical bottom surface of the borehole with a cross typed strain gauge. This paper, firstly, shows how the stress tensor can be determined from the strains on a conical bottom surface of a single borehole. Then the accuracy of the proposed method was compared with that of existing method to confirm that the proposed method gives us more accurate results. Secondly, based on an in-siturock stress measurement, this paper indicates that the proposed method can be more effectively used forin-siturock stress measurements than the existing one. Also, process simulation of the strains and stresses on the conical bottom surface during the stress relieving gave well consistent results with measured data, which indicates that the proposed method is quite reliable forin-siturock stress measurements.
岩石应力知识是设计和施工岩石结构的关键之一。因此,他们的处境压力必须被精确测量。由于岩石应力测量通常是一项耗时的任务,因此人们期望新技术的发展能够从单个井眼的测量中确定完整的应力状态。因此,应改进应力消除方法以满足其需求。人们提出并发展了许多消除应力的方法来确定应力的完全状态。在这些方法中,CSIRO的空心包体应力传感器由于能够准确地测量现场应力而在国际上得到了广泛的应用。八元应变仪、半球形应变仪和锥形应变仪在日本已得到广泛应用。在这三种方法中,锥形端孔技术与16单元锥形应变单元相结合,覆盖层致密,直径与先导孔相当,具有减少一系列岩石应力测量的时间、精力和成本的优势。为了提高岩石应力测量的精度,本研究对锥形应变单元进行了改进和改进,增加了十字型应变片在钻孔锥形底面上测量应变的次数。本文首先说明了如何从单孔锥底面上的应变来确定应力张量。然后将本文方法的精度与现有方法的精度进行了比较,验证了本文方法给出的结果更加准确。其次,通过一次岩体应力测量,表明该方法比现有方法更能有效地进行岩体应力测量。对应力消除过程中锥形底板表面的应变和应力进行了过程模拟,结果与实测数据吻合较好,表明该方法对岩体应力测量是可靠的。
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引用次数: 2
Effect of Structure and Morphology of Kaolin Minerals on the Intercalation of Urea. 高岭土矿物结构形态对尿素插层的影响。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.211
Kinue Tsunematsu, H. Tateyama, K. Kimura, O. Ishibashi
The effect of the structural properties of kaolin minerals on the intercalation process of urea was investigated using kaolinite and two kinds of halloysite. The results are summarized as follow.(1) The urea intercalated gradually and regularly into the interlayer site of kaolinite with plate morphology, but intercalated immediately and irregularly into that of halloysite with tubular and spherical morphologies.(2) The decomposition temperature of the urea intercalated into kaolin minerals were lower than that of pure urea. The difference between the decomposition of the urea intercalated and that of pure urea was examined by IR spectrum analysis. The asymmetric and symmetric ν(NH2) stretching frequencies at 3, 504cm-1 and 3, 389cm-1 correspond to NH2 groups interacting with the oxygens located on the basal tetrahedral layer. Intercalation of urea within the kaolin minerals structure increased the ν(CN) stretching frequency from 1, 468cm-1 for the urea to 1, 477cm-1 for intercalated molecules. These results indicate that the hydrogen bonding of urea molecules intercalated into the interlayer site of kaolin minerals are weak as compared with the hydrogen bonding of pure urea molecules.(3) The ν(CN) stretching frequency of two kinds of halloysite showed broader pattern compared with that of kaolinite, but the ν(NH2) bending frequency of halloysites shifted to higher frequency than that of kaolinite. These results show that the hydrogen bonding of urea intercalated into the interlayer site of halloysite is different from the that of kaolinite.
以高岭土和两种高岭土为原料,研究了高岭土矿物结构性质对尿素插层过程的影响。结果表明:(1)尿素在具有板状形态的高岭土层间逐渐有规律地嵌入,而在具有管状和球形形态的高岭土层间则立即无规律地嵌入;(2)嵌入高岭土矿物的尿素的分解温度低于纯尿素。用红外光谱分析考察了插层尿素与纯尿素分解的差异。ν(NH2)在3,504 cm-1和3,389 cm-1处的不对称和对称拉伸频率对应于NH2基团与位于基四面体层上的氧相互作用。尿素在高岭土矿物结构中的插层使ν(CN)的拉伸频率从尿素的1468 cm-1增加到插层分子的1477 cm-1。(3)两种高岭土的ν(NH2)拉伸频率均比高岭石宽,而ν(NH2)弯曲频率则比高岭石高。结果表明,嵌入高岭石层间位置的尿素氢键与嵌入高岭石层间位置的尿素氢键不同。
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引用次数: 0
Fundamental Study on Early Detection of Underground Mine Fire Using Smell Detectors. Characteristics of the smell generated from the heated combustible materials. 矿井井下火灾气味探测器早期探测的基础研究。可燃材料加热后产生的气味特征。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.683
K. Ohga, Kiyoshi Higuchi, K. Mukai
coal mines, by using smell detectors in our laboratory. From the results of measurements, it is clear that there are significant differences between measured data from each different type of smell sensor for coal, rubber of belt conveyer, oil and wood.In order to discern the source of combustion gases, we developed and tested a distinction system using a neural network system. From the results of the tests, the neural network system enables the identification of the source of gases, whether it would be coal, wood, oil and rubber of belt conveyer.
在我们的实验室里使用气味探测器。从测量结果可以清楚地看出,不同类型的气味传感器对煤、带式输送机橡胶、油和木材的测量数据存在显著差异。为了识别燃烧气体的来源,我们开发并测试了一个使用神经网络系统的识别系统。从试验结果来看,该神经网络系统能够识别带式输送机的气体来源,无论是煤、木材、石油还是橡胶。
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引用次数: 0
The Relationship Between the Shape of a Disced Core and Three-Dimensional in-Situ Stresses Estimated by a Tensile Principal Stress Analysis. 用张主应力分析估算岩心切面形状与三维地应力的关系。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.317
K. Matsuki, K. Hongo, K. Sakaguchi
Based upon the assumption that core discing results from tensile stresses within and below a core during boring, the direction of the principal tensile stress was analyzed in detail for the stress conditions where core discing is likely to occur to investigate the relationship between the shape of a disced core and in-situ stresses for the case of a long disced core. Main results obtained in this study are summarized as follows: 1) In the central parts of the end surfaces, a relatively flat plane is formed. The azimuth of the normal direction of the plane coincides with that of the minimum principal stress, ƒÐ3. The inclination, Om of the normal direction from the core axis is approximately one thirds of that,.753 of ƒÐ3. By using the two equations, (1) and (3), a method for estimating more accurate ƒÓ3 (•}23%) was proposed. 2) By combining the additional equation, (1) on the magnitudes of ƒÐ3, the mean stress, um and the stress in the direction of the core axis, aZ with the previously proposed equation, (2), which is the condition of core discing, two of the above stresses can be determined if Om is measured and if one of them is determined independently. For the vertical borehole, by assuming uz to be an overburden pressure, um and u3 can be determined from the two equations. 3) When the difference between the maximum principal stress, ƒÐ1 and the intermediate principal stress, σ2 is large enough, a saddle shaped disc is formed and the shape becomes more distinct with the difference.For
基于钻孔过程中岩心内部和下方的拉应力导致岩心剥离的假设,详细分析了可能发生岩心剥离的应力条件下的主拉应力方向,以研究长岩心剥离的岩心形状与地应力之间的关系。本研究的主要结果总结如下:1)在端面的中心部分形成了一个相对平坦的平面。平面法向的方位角与最小主应力的方位角重合,ƒÐ3。法线方向从核心轴的倾斜度,大约是它的三分之一。753的ƒÐ3。利用(1)和(3)两个方程,提出了一种更准确的ƒÓ3(•}23%)估计方法。2)将附加式(1)ƒÐ3的大小、平均应力um和岩心轴向应力aZ与先前提出的公式(2)相结合,即岩心盘化的条件,即测量Om和单独确定其中一个时,可以确定上述两个应力。对于垂直井眼,假设uz为上覆岩层压力,可由这两个方程确定um和u3。(3)当最大主应力ƒÐ1与中间主应力σ2的差值足够大时,形成鞍状盘,且形状随着差值的增大而更加明显。为
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引用次数: 3
Psychometrical Evaluation on Landscape of Mined-out Quarry Reclaimed by Revegetating. 采空区绿化复垦景观的心理计量学评价。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.543
N. Otsuka, Y. Sekimoto, Mitsugu Saito, Takeshi Kamata
Landscape destruction caused by open-cut mining makes an impact on the environmental issue. Landscape evaluation of mined-out quarry becomes necessary from the view point of environmental protection. In this study, we investigated on landscape of mined-out quarry that was reclaimed by revegetating. Three kinds of revegetation, namely herbaceous planting, woody planting and herbaceous + woody planting, were simulated using a color image processing technology with a personal computer. Two psychometrical evaluation tests, rating-scale method and semantic differential method, were conducted using color photomontages as variable stimulus.In the quantitative analysis by a rating-scale method, it became clear for the landscape reclamation of mined-out quarry that herbaceous planting was better than woody planting when it was seen at a short distance, and woody planting was better than herbaceous planting when it was seen at a long distance. In the factor analysis by a semantic differential method, it became clear that beauty and texture of revegetation were important factors to estimate the landscape evaluation of mined-out quarry.
露天采矿造成的景观破坏对环境问题产生了影响。从环境保护的角度出发,对采空场进行景观评价是必要的。本文对采石场采空区绿化后的景观进行了研究。利用个人计算机彩色图像处理技术,模拟了草本植被、木本植被和草本+木本植被三种植被类型。以彩色照片蒙太奇作为变量刺激,进行了两种心理测量评价测试:评定量表法和语义差异法。在评价量表法的定量分析中,对于采空区采石场的景观复垦,在近距离看草本植物优于木本植物,在远距离看木本植物优于草本植物。利用语义差分法进行因子分析,发现植被的美观性和纹理性是评价采空场景观评价的重要因素。
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引用次数: 2
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The Mining and Materials Processing Institute of Japan
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