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Recycling. The Current Problem of Shredder Dust Derived from Automobiles and Home Electric Appliances. New system for dealing with shredder dust in the western part of Japan. 回收利用。汽车和家用电器产生的碎纸机粉尘的现状问题。日本西部处理碎纸机粉尘的新系统。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.1022
T. Nishiyama, Takeshi Yamanaka
It has recently become necessary to develop a system for dealing with the large amounts of shredder dust generated declining abandoned automobiles and home electric appliances because of landfill space nationwide and stringent regulations on leachate control. In 1992, about 1.2 million tonnes of shredders containing an estimated 36 thousand tonnes of copper, 3.6 thousand tonnes of lead, 6 thousand tonnes of zinc and 5, 400 Gcal were derived from automobiles. The shredders from home electric appliance disposal accounted for 230 thousand tonnes containing 22 thousand tonnes of copper. The amounts of shredder dust has been estimated to increase to 1.37 million tonnes by 2000, and to 1.56 million tonnes by 2005.A new project, the Recycle Mine Park (RMP) has been proposed to solve the problems of increasing amounts of automobile and home electric appliance scrap. The RMP uses technology to recover energy and metals. Since methods have been developed to recover energy and various kinds of metals including in base and hazardous metals, the largest problem of the project remains establishment of reasonable and economical system. About 30% of the shredder dust described above is generated in the western part of Japan.Smelters are located on the coast of the Inland Sea of Seto in this area, which reduces the cost of transportion. The recycing network in the western part of Japan excluding pretreatment combines the best features of being in the vicinity of a large amount of shredder dust, marine transportion and the presence of modern smelters. Pretreatment such as incineration or cracking which is additional treatment for the smelter feed is proved in small scale.Wehope that the unique system for recycing of shredder dust including collection, pretreatment, marine transportation and smeltering can be put into operation as soon as possible. The increasing costof suitable land for landfills, the stringent regulations on leachate control, and other costs makethis an attractive system.
最近,由于全国范围内的垃圾填埋场和严格的渗滤液管理规定,废弃汽车和家用电器产生的大量碎纸机粉尘有必要开发一种处理系统。1992年,来自汽车的碎纸机约有120万吨,其中估计含有36000吨铜、3600吨铅、6000吨锌和5400吨汞。家用电器处理的碎纸机占23万吨,含铜2.2万吨。到2000年,碎纸机粉尘的数量估计会增加到137万吨,到2005年则会增加到156万吨。为了解决汽车和家电废料日益增多的问题,提出了一个新的项目——回收矿园(RMP)。RMP利用技术回收能源和金属。由于回收能源和各种金属(包括贱金属和有害金属)的方法已经发展起来,该项目最大的问题是建立合理和经济的系统。上述碎纸机粉尘中约有30%是在日本西部产生的。冶炼厂位于该地区濑户内海沿岸,这降低了运输成本。除预处理外,日本西部的回收网络结合了大量碎纸机粉尘附近的最佳特征,海洋运输和现代冶炼厂的存在。预处理,如焚烧或裂解,是冶炼厂饲料的附加处理,已在小规模试验中得到证实。我们希望撕碎机粉尘收集、预处理、海运、冶炼等独特的回收系统能够尽快投入使用。合适的堆填土地的成本不断上升,对渗滤液控制的严格规定,以及其他成本,使这成为一个有吸引力的系统。
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引用次数: 1
Recycling. Recycling of Used Tires. 回收利用。回收旧轮胎。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.999
Yoshiki Sato
The present status on the production and waste treatment of used tires in Japan are summarized and the recent activities of research on the recycling of used tires are introduced.For recycling used tires, liquid-phase cracking was tried using various kinds of solvents under low pressure of N2-H2. Experiments were carried out using a 200ml autoclave with magnetic stirrer at 300-440°C, initial H2or N2pressure of 2.0-8.5 MPa, reaction time of 20-60 min with solvent to tire weight ratio of 1-2.5. When hydrogen donating solvent such as tetralin was used for cracking, almost all organic matter could be converted to light oil with very low sulfur content of 0.5 wt% by the reaction under low nitrogen pressure. Reaction residue can also be reused as carbon black for rubber manufacturing.
综述了日本废旧轮胎生产和废物处理的现状,介绍了近年来在废旧轮胎回收利用方面的研究活动。为回收废旧轮胎,在低压N2-H2条件下,采用多种溶剂进行液相裂解试验。实验采用200ml带磁力搅拌器的高压釜,温度300-440℃,初始H2or n2压力2.0-8.5 MPa,反应时间20-60 min,溶剂与轮胎重量比为1-2.5。当用四氢化萘等供氢溶剂进行裂解时,在低氮压力下,几乎所有的有机物都能转化为含硫量为0.5 wt%的轻质油。反应废渣还可以作为炭黑再利用,用于橡胶生产。
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引用次数: 2
A Basic Study of the Oxidizing Roasting in the Sintering Process of ISP. ISP烧结过程中氧化焙烧的基础研究。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.53
H. Kitahara, O. Ogawa
As a basic study of the oxidizing roasting in a Dwight-Lloyd sinterig machine in the ISP, lead-zinc concentrate, zinc concentrate, recycled sinter fines, and pulverized sinter fines were roasted in air, and behavior of sulfur-containing compounds was investigated.The results can be summarized as follows.1. The charge to the sintering machine is discharged before it is brought, as a whole, to equilibrium with the gas phase in the machine.2. The roasting reactions are complicated owing to competitive formation and/or decomposition of oxides, sulfates, and basic sulfates.3. Most sulfur remains in the sinter as basic sulfates of lead and zinc.4. Desulfurization of recycled sinter fines and pulverized sinter fines by roasting in air is slow at temperatures below 1, 200°C which prevail in the sintering machine.
作为在ISP的Dwight-Lloyd烧结机中氧化焙烧的基础研究,在空气中焙烧铅锌精矿、锌精矿、回收烧结粉和烧结粉粉,并对含硫化合物的行为进行了研究。结果可以总结如下:1。烧结机的装料在与烧结机内的气相整体达到平衡之前被排出。由于氧化物、硫酸盐和碱性硫酸盐的竞争性形成和/或分解,焙烧反应很复杂。大部分硫作为铅和锌的碱性硫酸盐留在烧结矿中。在烧结机中普遍存在的低于1200℃的温度下,在空气中焙烧再生烧结粉和粉碎烧结粉的脱硫很慢。
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引用次数: 3
Hydraulic fracturing experiment in granitic rock with scarce joints in China(3rd Report). Characteristics of Initiation, Reopening and Closing Behavior of Hydraulic Fractured Crack. 中国缺节理花岗质岩石水力压裂试验(第三次报告)。水力压裂裂缝起裂、重开和闭合特性研究
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.107
K. Shin, Fangquan Li, S. Okubo
Through an extensive hydraulic fracturing experiment in granitic rock with low frequencies of joints, the initiation, reopening and closing behaviors have been carefully examined. zn this 3 rd report, the features which have not been dealt with in the previous two reports are discussed; the fracture direction and two deflection points in a shut-in curve.A numerical analysis based on the weakest-link theory reveals that, with increase of the maximum compression stress SH, the mean and the variability of hydro-fracturing tensile strength T increases, while the variability of fracture direction decreases.In this study, the vertical crack with a circular periphery tends to extend passing through the packers. When sufficient rate of flow is supplied for reopening the crack, the crack tip is fully open. After closing the water valve, the pressure is continuously decreasing, and the first deflection point Pctc is observed at the cracktip closing. With further pressure decrease, the crack surface is closing gradually from the outer to inner part. When the part of crack extended passing through the packers is closed, the second deflection point Ps2 is observed. Considering the crack-closing process, Ps2 should be larger than (3Sh-SH)/2 while Pctc is equal to the minimum compression stress Sh.In this experiment, different values of Ps2 have been observed at two depths while the values of Pctc (=Sh) are almost the same. According to the crack closing mechanism described above, smaller Ps2 suggests larger SH. At a depth with smaller Ps2, the variability of crack direction is small and SH is large. This result suggests that the variability of crack direction and Ps2 possibly give useful information for stress estimation.
通过对具有低节理频率的花岗质岩石进行水力压裂试验,对其起裂、重开和闭合行为进行了细致的研究。在第三份报告中,讨论了前两份报告中未涉及的特点;关井曲线中的裂缝方向和两个挠度点。基于最弱环节理论的数值分析表明,随着最大压应力SH的增大,水力压裂抗拉强度T的均值和变异性增大,裂缝方向变异性减小。在本研究中,具有圆形边缘的垂直裂缝倾向于通过封隔器延伸。当有足够的流量使裂纹重新打开时,裂纹尖端是完全打开的。关闭水阀后,压力不断降低,在裂纹尖端关闭处观察到第一个挠度点Pctc。随着压力的进一步降低,裂纹表面由外向内逐渐闭合。当裂纹延伸穿过封隔器的部分关闭时,观察到第二个挠曲点Ps2。考虑到裂纹闭合过程,Ps2应大于(3Sh-SH)/2,而Pctc等于最小压缩应力Sh。在本实验中,两个深度的Ps2值不同,而Pctc (=Sh)的值基本相同。根据上述裂缝闭合机制,Ps2越小,SH越大。在Ps2越小的深度,裂缝方向变异性越小,SH越大。这一结果表明,裂纹方向和Ps2的变化可能为应力估计提供有用的信息。
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引用次数: 0
Recycling. Physical Separation Techniques. Evaluation of Separation Performance. 回收利用。物理分离技术。分离性能评价。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.929
Y. Okano
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引用次数: 1
Developments of New Longwall Plants for the 1SD System in Taiheiyo Coal Mine. 太黑窑煤矿1SD系统新长壁装置的研制。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.776
Akira Shimizu
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引用次数: 1
Resources and the Environment: their Problems Viewed from the Earth's History. 资源与环境:从地球历史看它们的问题。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.9
Testuya Shoji, H. Kaneda
The Earth has evolved since the birth at 4.6 Gy B. P. Especially, the evolution has been remarkable on the surface that is the boundary between the fluid sphere and the solid sphere. Many kinds of mineral and fuel deposits were formed in the process of the evolution, and are used as resources by human being. For most of the resources, reproduction rates in the Earth's history are slower than consuming ones in the human activity. This is the resources problem. All of the materials mined are dumped after using them. This process is a bypass which is added on the material cycle in the Earth. The bypass changes the evolution of the Earth. This is the environmental problem. The increasing carbon dioxide is one of the big environmental problems. In order to solve the problem many ideas are proposed, such as fixing by calcium carbonate, deep-sea disposal of liquid carbon dioxide, fixing by carbon dioxide hydrate, and storage in abandoned natu al gas reservoir. Any idea among them has not been evaluated from the viewpoint of the Earth's history. The lack of the evaluation based on this point of view should not guarantee the safety of the disposal processes of carbon dioxide.
地球自4.6 Gy b.p.诞生以来一直在进化,特别是在流体球体和固体球体之间的表面,进化是显著的。在演化过程中形成了多种矿物和燃料矿床,为人类提供了资源。对于大多数资源,地球历史上的繁殖速度比人类活动中的消耗速度要慢。这是资源问题。所有开采出来的材料在使用后都被倾倒。这个过程是地球物质循环的一个旁路。绕道改变了地球的演变。这就是环境问题。不断增加的二氧化碳是一个重大的环境问题。为了解决这一问题,人们提出了碳酸钙固定、深海处理液态二氧化碳、二氧化碳水合物固定、废弃天然气储层储存等方法。其中的任何想法都没有从地球历史的角度加以评价。缺乏基于这一观点的评价不应保证二氧化碳处置过程的安全性。
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引用次数: 1
Recent advance in the resources and material technology. Measures for increasing ore processing speed at Onahama smelter. 资源与材料技术的最新进展。提高小名滨冶炼厂矿石处理速度的措施。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.472
M. Nishiwaki
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引用次数: 0
Characterization of Geothermal Reservoirs by Acoustic Emission/Microseismic Technique. 利用声发射/微地震技术表征地热储层
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.301
H. Niitsuma
Acoustic emission (AE)/microseismic technique is employed in every modern geothermal development as the only means by which direct information about the state of the reservoir can be obtained at locations distant from the wellbores.The past few years has seen considerable improvement in their ability to analyze and interpret data obtained by the AE/microseismic measurements.But progress must still be made if the technique is to contribute characterizing geothermal reservoirs, providing usable information for borehole physics, rock mechanics and reservoir engineering.
每个现代地热开发项目都采用声发射/微地震技术,作为在远离井眼的位置获得储层状态直接信息的唯一手段。在过去的几年里,他们在分析和解释声发射/微地震测量数据方面的能力有了很大的提高。但是,如果这项技术要对地热储层的特征做出贡献,为井眼物理、岩石力学和储层工程提供有用的信息,还必须取得进展。
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引用次数: 3
The Development of Personal Computer of Explosive Gas Atmospheres. 爆炸性气体环境微机的研制。
Pub Date : 1997-01-01 DOI: 10.2473/SHIGENTOSOZAI.113.754
Tadashi Suzuki
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引用次数: 0
期刊
The Mining and Materials Processing Institute of Japan
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