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The study of Cr3C2-25NiCr and 35WC-Co/65NiCrBSi-based HVOF coatings for high-temperature erosion resistance application Cr3C2-25NiCr和35WC-Co/65NiCrBSi基高温耐磨HVOF涂层的研究
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-08-13 DOI: 10.1080/17515831.2021.1951542
K. Raghavendra Naik, R. kumar, V. Saravanan, S. Seetharamu, P. Sampathkumaran
ABSTRACT This work concerns a technique to produce thermal sprayed coatings using HVOF (high-velocity oxy-fuel) method as it is a widely used application in high-temperature erosion and corrosion environment. Two types of hard coatings Cr3C2-25NiCr and 35WC-Co/65NiCrBSi were sprayed on an SS-347 steel substrate. The erosion tests were done using high-temperature jet erosion set up to study the effect of velocity, temperature and impact angles on the coatings produced. The surface morphology of the samples was characterized using 3D laser confocal microscopy, light microscopy, scanning electron microscopy with EDAX and X-ray diffraction. Microhardness, porosity level and roughness parameters were evaluated to infer a probable mechanism of material removal. The Cr3C2-25NiCr coating exhibited ∼3.3 times higher erosion resistance than 35WC-Co/65NiCrBSi coating at 90° and 30° impact angles. SEM and 3D laser confocal images on the eroded surface of the coatings reveal the combination of ductile and brittle fracture of coating. GRAPHICAL ABSTRACT
本工作涉及一种使用HVOF(高速氧燃料)法生产热喷涂涂层的技术,因为它在高温侵蚀和腐蚀环境中有着广泛的应用。在SS-347钢基体上喷涂了两种类型的硬质涂层Cr3C2-25NiCr和35WC-Co/65NiCrBSi。采用高温射流烧蚀装置进行了烧蚀试验,研究了速度、温度和冲击角对涂层性能的影响。使用3D激光共聚焦显微镜、光学显微镜、EDAX扫描电子显微镜和X射线衍射对样品的表面形态进行了表征。对显微硬度、孔隙率水平和粗糙度参数进行了评估,以推断材料去除的可能机制。在90°和30°冲击角下,Cr3C2-25NiCr涂层的耐腐蚀性是35WC-Co/65NiCrBSi涂层的约3.3倍。涂层侵蚀表面的扫描电镜和三维激光共聚焦图像揭示了涂层的韧性和脆性断裂相结合。图形摘要
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引用次数: 2
Experimental investigation on the performance of AISI 440C martensitic stainless steel against the formation of white etching areas under sliding dynamic loading AISI440C马氏体不锈钢在滑动动载荷作用下抗白色腐蚀性能的实验研究
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-08-08 DOI: 10.1080/17515831.2021.1951541
D. Linto, P. Ramkumar
ABSTRACT Bearings fail prematurely in transient operating conditions, as a result of flaking that causes changes in subsurface microstructure. In this type of failure, the formation of White Etching Cracks (WECs) is preceded by the formation of White Etching Areas (WEAs). Typically the WEAs are formed due to the dissolution of cementite into the matrix in AISI 52100 bearing steel. This feasibility work investigates the performance of AISI 440C steel against WEAs formation using dynamic load Pin-on-Disc tribometer. Experiments were performed at 4.5 Hz loading frequency, Hertzian pressure 2.02 GPa and sliding velocity of 0.2 ms-1 under the boundary lubrication using Poly Alpha Olefins (PAO). From post-test analysis, it is found that AISI 440C steel trapped more hydrogen than AISI 52100 bearing steel. The comprehensive analysis of materials and lubricants revealed that the performance of AISI 440C stainless steel against WEAs formation is better than that of AISI 52100 bearing steel. GRAPHICAL ABSTRACT
轴承在瞬态操作条件下过早失效,由于剥落导致地下微观结构的变化。在这种类型的失效中,白色蚀刻裂纹(WECs)的形成先于白色蚀刻区域(WEAs)的形成。典型地,在AISI 52100轴承钢中,由于渗碳体溶解到基体中而形成微晶合金。本可行性工作采用动载荷盘式销式摩擦计研究了AISI 440C钢抗WEAs形成的性能。实验采用聚α -烯烃(PAO)进行边界润滑,加载频率为4.5 Hz,赫兹压力为2.02 GPa,滑动速度为0.2 ms-1。从后测分析中发现,AISI 440C钢比AISI 52100轴承钢捕获了更多的氢。材料和润滑剂的综合分析表明,AISI 440C不锈钢抗WEAs形成的性能优于AISI 52100轴承钢。图形抽象
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引用次数: 3
Investigation on the role of microstructure and temperature on tribological characteristics of fine-grained ZE41 Mg alloy 微观组织和温度对细晶ZE41镁合金摩擦学特性影响的研究
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-07-27 DOI: 10.1080/17515831.2021.1951539
M. Venkataiah, T. Anup Kumar, K. Venkata Rao, S. Anand Kumar, R. Dumpala, B. Ratna Sunil
ABSTRACT In the current work, ZE41 Mg alloy was processed by friction stir processing (FSP) to achieve grain refinement. In addition to grain refinement, decreased intermetallic phase (MgZn) was also observed after FSP. Increased micro-hardness was observed for the processed ZE41 Mg alloy compared to the unprocessed base alloy. X-ray diffraction (XRD) studies demonstrated the texture characteristics in FSPed ZE41. Reciprocating wear studies conducted at three different temperatures, i.e. room temperature, 125 °C, and 250 °C showed lower mass loss for the processed alloy compared to that of the base alloy, particularly at elevated temperatures. This behavior can be understood by considering the benefit gained from the smaller grains and decreased amount of intermetallic phase in the processed alloy, which reduced the abrasion wear. Hence, the present study suggests that the grain refinement and decreased MgZn phase significantly improve the temperature-dependent tribological characteristics of ZE41 Mg alloy. GRAPHICAL ABSTRACT
摘要采用搅拌摩擦法(FSP)对ZE41镁合金进行了晶粒细化处理。除了晶粒细化外,FSP后还观察到金属间相(MgZn)的减少。与未加工的基体合金相比,加工后的ZE41镁合金显微硬度有所提高。x射线衍射(XRD)研究证实了FSPed ZE41的织构特征。在室温、125°C和250°C三种不同温度下进行的往复磨损研究表明,与基体合金相比,加工合金的质量损失更低,尤其是在高温下。考虑到加工合金中更小的晶粒和更少的金属间相所带来的好处,这种行为可以被理解为减少了磨损。因此,本研究表明,晶粒细化和MgZn相的减少显著改善了ZE41镁合金的温度依赖摩擦学特性。图形抽象
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引用次数: 2
Dry sliding wear characteristics of Al-7Si-0.3Mg alloy with minor additions of magnesium at high temperature 少量添加镁的Al-7Si-0.3Mg合金高温干滑动磨损特性
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-07-14 DOI: 10.1080/17515831.2021.1945861
M. S. Prabhudev, S. A. Kori
ABSTRACT In this paper, effect of minor additions of magnesium content in the form of master alloys on the high-temperature dry sliding wear behaviour for A356 alloy has been reported. Alloy composition, normal pressures and sliding distances on A356 alloy at constant temperature of 300°C was studied. The cast alloys and worn surfaces were characterized by SEM/EDX microanalysis. The results indicate that the wear rate of A356 alloy increases with an increase in normal pressures and sliding distances in all the cases and decreases when 0.7% Mg is added to A356 alloy. The decrease in wear rate after the addition of Mg is mainly due to changes in microstructure which lead to improvement in mechanical properties. Further, worn surface study indicates that the formation of iron-rich oxide layer between the mating surfaces during sliding improves sliding wear performance. GRAPHICAL ABSTRACT
本文研究了以中间合金形式添加少量镁元素对A356合金高温干滑动磨损性能的影响。研究了A356合金在300℃恒温下的合金成分、法向压力和滑动距离。采用SEM/EDX显微分析对铸态合金和磨损表面进行了表征。结果表明:在所有情况下,A356合金的磨损率均随法向压力和滑动距离的增加而增加,当添加0.7% Mg时,磨损率降低;添加Mg后磨损率的降低主要是由于微观组织的改变导致力学性能的改善。此外,磨损表面研究表明,在滑动过程中,在配合表面之间形成的富铁氧化层提高了滑动磨损性能。图形抽象
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引用次数: 0
Fretting fatigue behaviour of Ti–6Al–4V in contact with Alloy 718 Ti–6Al–4V与718合金接触的微动疲劳行为
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-07-04 DOI: 10.1080/17515831.2021.1930343
S. Srivathsan, S. Raman
ABSTRACT In studies on a material fretted with different contact pad materials having different hardness values, there will be effect of both chemical composition and hardness. In the present work, the effect of hardness was studied by keeping the chemical composition of the contact pad material the same. Test samples were made of Ti–6Al–4V and fretting pads were made of Alloy 718. By heat treatments (annealing and ageing), the hardness of the pads was changed. The effect of hardness of pads was observed only at higher contact pressure of 175 MPa and lower cyclic stresses, where annealed pads restricted the life of Ti–6Al–4V samples compared to aged pads. This is because the relatively softer Alloy 718 pads in annealed condition had relatively higher adhesion to the Ti–6Al–4V samples leading to higher tangential force coefficient values compared to that of harder pads in the aged condition. GRAPHICAL ABSTRACT
摘要在研究具有不同硬度值的不同接触垫材料对材料的磨损时,会受到化学成分和硬度的影响。在本工作中,通过保持接触垫材料的化学成分不变来研究硬度的影响。试样由Ti–6Al–4V制成,微动垫由718合金制成。通过热处理(退火和老化),焊盘的硬度发生了变化。只有在175 MPa的较高接触压力和较低的循环应力下才能观察到焊盘硬度的影响,与老化焊盘相比,退火焊盘限制了Ti–6Al–4V样品的寿命。这是因为退火条件下相对较软的718合金焊盘对Ti–6Al–4V样品具有相对较高的粘附力,导致与老化条件下较硬焊盘相比,切向力系数值更高。图形摘要
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引用次数: 0
Ultrasonic technique for measurement of oil-film thickness in metal cold rolling 金属冷轧油膜厚度的超声测量技术
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-07-01 DOI: 10.1080/17515831.2021.1944549
G. Adeyemi, R. Dwyer-Joyce, J. T. Stephen, A. Adebayo
ABSTRACT Lubrication is essential in metal cold rolling operation to regulate friction at the metal–roll interface, reduce energy loss and improve the product surface finish. A novel non-intrusive pitch-catch technique, based on the reflection of ultrasound, was employed on a pilot mill to evaluate oil-film thickness at the metal–roll interface during the metal cold rolling operation. During the metal rolling process, oil-film thickness was measured under varying rolling load and rolling speed. The oil-film thickness increases as the roll speed increases and reduces as the rolling load increases. The values of oil-film thickness obtained from this non-intrusive ultrasonic technique agree with theoretical values. This study is a proof of concept and has shown promising results. If further developed, the technique could be employed for in situ monitoring of lubricant during rolling operation in metal rolling industries. GRAPHICAL ABSTRACT
摘要在金属冷轧操作中,润滑对于调节金属-轧辊界面的摩擦、减少能量损失和改善产品表面光洁度至关重要。在中试轧机上采用了一种基于超声波反射的新型非侵入式沥青捕捉技术,以评估金属冷轧过程中金属-轧辊界面的油膜厚度。在金属轧制过程中,测量了在不同轧制载荷和轧制速度下的油膜厚度。油膜厚度随着轧辊速度的增加而增加,而随着轧制载荷的增加而减少。通过这种非侵入式超声技术获得的油膜厚度值与理论值一致。这项研究是一个概念验证,并显示出有希望的结果。如果进一步发展,该技术可用于金属轧制行业轧制操作过程中润滑剂的现场监测。图形摘要
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引用次数: 2
Effect of heat treatment on the wet abrasion resistance of WC-10Co4Cr coatings deposited onto stainless steel by HVOF 热处理对HVOF沉积不锈钢WC-10Co4Cr涂层湿磨耗性能的影响
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-07-01 DOI: 10.1080/17515831.2021.1938869
Milena Gallego, Stefany Carolina Chávez, J. de la Roche, A. Toro
ABSTRACT Heat treatments were carried out at 350, 450, 550 and 650°C on WC-10Co4Cr coatings deposited by High-Velocity Oxy-Fuel (HVOF) onto AISI 420 stainless steel substrate in order to study their influence on the abrasive wear resistance of the coatings. The thickness and microhardness of the coatings were measured while the microstructure was analysed with the aid of OM, SEM and XRD techniques. The X-ray diffraction results revealed the presence of W2C phase in the as-sprayed coatings, and WO3 and CoWO4 phases after the heat treatments. No significant degradation of the microstructure was observed in coatings treated at 350°C compared with the as-sprayed coatings. Coatings treated at temperatures above 450°C, on the other hand, showed significant changes related to density, microstructure and surface hardness. The coatings treated at 350°C showed the best wear resistance, while the coatings treated at 550°C presented the worst performance due to microstructural defects related to oxidation processes. GRAPHICAL ABSTRACT
摘要:采用350、450、550和650℃的高温对高速氧燃料(HVOF)沉积在AISI 420不锈钢基体上的WC-10Co4Cr涂层进行热处理,研究热处理对涂层耐磨性的影响。测定了涂层的厚度和显微硬度,并用OM、SEM和XRD分析了涂层的微观结构。x射线衍射结果表明,喷涂态涂层中存在W2C相,热处理后涂层中存在WO3和CoWO4相。与喷涂涂层相比,在350°C下处理的涂层没有观察到明显的微观结构退化。另一方面,在温度高于450°C时,涂层在密度、微观结构和表面硬度方面发生了显著变化。350℃处理的涂层耐磨性最好,而550℃处理的涂层由于氧化过程中出现的显微组织缺陷,耐磨性最差。图形抽象
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引用次数: 9
Tribological behavior of hybrid aluminum self-lubricating composites under dry sliding conditions at elevated temperature 混合铝自润滑复合材料在高温干滑动条件下的摩擦学行为
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-06-20 DOI: 10.1080/17515831.2021.1931771
P. D. Srivyas, M. Charoo
ABSTRACT In this study, the influence of n-Al2O3 (aluminum oxide) and graphene nanoplatelet (GNP) on the tribological properties of a eutectic Al–Si (aluminum silicon) alloy was investigated. For Al–Si/n-Al2O3 (advanced composite), the coefficient of friction (COF) decreased by 34.41% and the wear resistance enhanced by 43.75% compared with base matrix alloys under high temperature (HT) conditions. For Al–Si/n-Al2O3/GNP (hybrid composite), COF decreased by 61.41% and the wear resistance improved by 96.87% at HT compared with base matrixes (eutectic Al–Si alloy). This finding was attributed to enhanced lubrication through GNP, glazed layer, thin tribooxide film (TTL) and mechanical mixed layer (MML) present on wear scars. Melt wear caused by scuffing was the main wear mechanism for the base composition at 300 and 400°C, and adhesion abrasion, crack formation and delamination pits were the wear mechanisms observed for the advanced and hybrid composites at extreme temperature conditions. Highlights Al–Si/ n-Al2O3 and Al–Si/ n-Al2O3/GNP composites were fabricated through spark plasma sintering. The tribological performance of the fabricated composite samples was investigated under dry sliding at elevated operating temperatures (100–400°C). The coefficient of friction and wear resistance improved with an increase in the secondary GNP reinforcement. Transition in the wear regime occurred at approximately 0.8 of melting temperature. The self-lubrication mechanism of GNP was observed on the wear track, which significantly reduced scar surface roughness. GRAPHICAL ABSTRACT
本研究研究了n-Al2O3(氧化铝)和石墨烯纳米板(GNP)对共晶Al-Si(铝硅)合金摩擦学性能的影响。在高温条件下,Al-Si /n-Al2O3(高级复合材料)的摩擦系数(COF)比基基合金降低了34.41%,耐磨性提高了43.75%。Al-Si /n-Al2O3/GNP(杂化复合材料)与基体(共晶Al-Si合金)相比,在高温下COF降低了61.41%,耐磨性提高了96.87%。这一发现归因于磨损痕上存在的GNP、釉面层、三氧化二氮薄膜(TTL)和机械混合层(MML)增强了润滑。在300℃和400℃时,基体的主要磨损机制是摩擦引起的熔体磨损;在极端温度条件下,高级复合材料和混杂复合材料的主要磨损机制是黏附磨损、裂纹形成和脱层坑。采用火花等离子烧结法制备了Al-Si / n-Al2O3和Al-Si / n-Al2O3/GNP复合材料。在较高的工作温度(100-400℃)下,研究了制备的复合材料样品在干滑动下的摩擦学性能。摩擦系数和耐磨性随二次GNP增强量的增加而提高。磨损状态的转变发生在熔化温度的0.8℃左右。在磨损轨迹上观察到GNP的自润滑机制,显著降低了疤痕表面粗糙度。图形抽象
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引用次数: 10
Effect of in-situ tribo-oxide-layer on the non-lubricated tribological behaviours of LM27/SiCp composites 原位氧化摩擦层对LM27/SiCp复合材料非润滑摩擦学行为的影响
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-06-01 DOI: 10.1080/17515831.2022.2058797
Pardeep Kumar Nagpal, Suresh Kumar, Ranvir Singh Panwar, J. Sharma, N. Singla, S. Mahla
ABSTRACT In this study, the influence of the in-situ tribo-oxide-layer on non-lubricated tribological behaviours of LM27/SiCp composites was studied at different applied loads. For this purpose, LM27/SiCp composites were manufactured by stir casting route with reinforcement of different amounts (3–12 wt.%) and different sizes (fine: 1–20 µm and coarse: 106–125 µm) of SiCp. A comprehensive characterization of the friction and wear mechanisms ranging from mild to severe wear for oxidative and delamination at a contact pressure of 0.125–0.624 MPa was discussed. Results indicate that the friction and wear behaviour is strongly influenced by the morphology and the nature of the oxide scale on the wear track. In-situ formation of oxide layers on the contact region of the specimen supports the self-lubrication which supports better wear performance of LM27/SiCp composites. However, these study portraits that composite with 12wt. % fine size SiCp exhibits better wear performance in comparison to the other developed composites. GRAPHICAL ABSTRACT
摘要在本研究中,研究了原位摩擦氧化物层对LM27/SiCp复合材料在不同外加载荷下非润滑摩擦学行为的影响。为此,LM27/SiCp复合材料是通过搅拌铸造工艺制造的,具有不同数量(3–12 wt.%)和不同尺寸(细:1–20 µm和粗糙:106–125 µm)的SiCp。在0.125–0.624的接触压力下,从轻度到重度的氧化和分层摩擦和磨损机制的综合表征 对MPa进行了讨论。结果表明,磨损轨迹上氧化皮的形态和性质对摩擦磨损行为有很大影响。在试样的接触区域原位形成氧化物层支持自润滑,这支持LM27/SiCp复合材料更好的磨损性能。然而,这些研究肖像与12wt.%与其他开发的复合材料相比,细尺寸SiCp表现出更好的磨损性能。图形摘要
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引用次数: 2
Investigation of the top compression ring power loss and energy consumption for different engine conditions 不同发动机工况下顶压环功率损失及能耗的研究
IF 1.3 Q4 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2021-04-14 DOI: 10.1080/17515831.2021.1907682
A. Zavos, P. Nikolakopoulos
ABSTRACT The engine power losses and sealing behaviour through compression rings have become a priority for engine manufactures in view of future stringent emissions standards. Historically, compression rings have great application in small road vehicles and high-performance engines. The sealing behaviour of the compression ring has a significant effect on generated friction. Therefore, the lubrication conditions in the compression ring-liner conjunction should be addressed. This study comprises ring-liner mixed hydrodynamics using a two-phase flow and a gas blow-by model. This is implemented to investigate the characteristics of a high-performance top compression ring for different engine conditions. Low, medium, and high driving speeds are examined according to world-wide harmonized light vehicles test cycle. Additionally, the impact of lubricant temperature and compression ring width on power loss and fuel consumption are investigated to display the better engine performance. GRAPHICAL ABSTRACT
考虑到未来严格的排放标准,发动机的功率损失和压缩环的密封性能已成为发动机制造商的首要任务。从历史上看,压缩环在小型道路车辆和高性能发动机上有很大的应用。压缩环的密封性能对产生的摩擦有重要影响。因此,应解决压缩环-衬套连接处的润滑条件。本研究采用两相流和气吹模型进行环衬混合流体力学研究。这是为了研究高性能顶压环在不同发动机工况下的特性。低、中、高行驶速度按世界统一的轻型车测试周期进行测试。此外,还研究了润滑油温度和压缩环宽度对功率损失和油耗的影响,以显示更好的发动机性能。图形抽象
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引用次数: 8
期刊
Tribology - Materials, Surfaces & Interfaces
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