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Kinetics Study of The Ability of Compost Material for Removing 〖Cu〗^(2+) from Wastewater 堆肥材料去除废水中〖Cu〗^(2+)的动力学研究
Pub Date : 2018-09-26 DOI: 10.30955/gnj.002865
M. Al-Alawi
The objective of this study is to examine the ability of a compost material for removing {Cu}^{2+} from aqueous solutions with different parameters using continuous fixed-bed column. Compost was characterized by using Fourier transform infrared spectroscopy which revealed that the metal binding is mainly contributed to the ionic interaction of the metal cations with the carboxyl groups in the hemic substances. Scanning electron microscope images were utilized for morphological analysis of the adsorbent and has revealed that the changes in compost composition could be related to the mechanism of metal binding. Energy dispersive X-ray spectroscopy was used before and after the metal had loaded and gives a good evidence on compost adsorption of {Cu}^{2+} and the metals have its involvement in the interaction in the adsorption process. The influence of the initial {Cu}^{2+}concentration, flow rate, bed heights of the column, and ion exchange have been studied in this research. The adsorption kinetic models have revealed that the behaviour of the {Cu}^{2+ }adsorption is dependent on rate of concentration, flow rate, and bed heights.
本研究的目的是利用连续固定床柱研究堆肥材料从不同参数的水溶液中去除{Cu}^{2+}的能力。利用傅里叶变换红外光谱对堆肥进行了表征,发现金属结合主要是金属阳离子与化学物质中羧基的离子相互作用。利用扫描电镜对吸附剂进行了形态分析,发现堆肥成分的变化可能与金属结合机制有关。金属加载前后的能量色散x射线能谱分析结果表明,复合材料对{Cu}^{2+}有吸附作用,金属参与了吸附过程中的相互作用。研究了初始{Cu}^{2+}浓度、流速、柱层高度、离子交换等因素对反应的影响。吸附动力学模型表明,{Cu}^{2+}的吸附行为与浓度速率、流速和床层高度有关。
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引用次数: 1
Treatment of tannery wastewater using aluminium formate: influence of the formate over sulphate based coagulant 用甲酸铝处理制革厂废水:甲酸对硫酸盐基混凝剂的影响
Pub Date : 2018-09-26 DOI: 10.30955/gnj.002528
Tannery industries provoke the conspicuous quantity of deleterious effluent which has to be treated prior to discharge into the environment. Pre-treatment of tannery wastewater with aluminium sulphate is well known over decades, but due to the corrosive nature of sulphate this pre-treated water causes several issues in the biological treatment system. To overcome this issue a study was performed to understand the coagulant activity of aluminium formate and aluminium sulphate. The effect of coagulant activity as a function of pH and coagulant dose of Aluminium formate was studied and found that it surpassed aluminium sulphate in terms of Cr(VI), sulphate and COD removal by 10%, 6% and 10% respectively, while turbidity removal for both coagulants was found approximately equal. Possible mechanistic approach to the coagulation property of aluminium formate and aluminium sulphate could be inter particle bridging and sweep coagulation respectively. Formate [HCOO-] can be utilized as a counter anion in the place of commonly used sulphate anions as it is biodegradable, non-toxic and corrosive free compound. Therefore, Aluminium formate can be a promising coagulant for the pre-treatment of tannery wastewater.
制革工业产生了大量的有害废水,在排放到环境中之前必须进行处理。几十年来,用硫酸铝预处理制革厂废水是众所周知的,但由于硫酸盐的腐蚀性,这种预处理水在生物处理系统中会引起几个问题。为了解决这一问题,进行了一项研究,以了解甲酸铝和硫酸铝的混凝活性。研究了混凝剂活性与pH和混凝剂剂量的关系,发现甲酸铝的Cr(VI)去除率、硫酸盐去除率和COD去除率分别比硫酸铝高10%、6%和10%,而两种混凝剂的浊度去除率基本相等。影响甲酸铝和硫酸铝混凝性能的可能机理分别是粒子间桥接和扫络混凝。甲酸[HCOO-]是一种可生物降解、无毒、无腐蚀性的化合物,可以代替常用的硫酸盐阴离子作为反阴离子。因此,甲酸铝是一种很有前途的混凝剂,可用于制革废水的预处理。
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引用次数: 9
A sample study on nitrogen removal from polluted streams by using hybrid natural wastewater treatment systems 混合自然污水处理系统去除污水中氮的样本研究
Pub Date : 2018-09-26 DOI: 10.30955/gnj.002715
The ecological structure and function of the water reservoirs deteriorate dramatically because of streams fed by the excess nitrogen-containing wastewater. To protect the water reservoirs from polluted streams, structures such as natural wastewater treatment (NWT) systems to be created inside or outside streams may be a most suitable and economical solution method to overcoming the problem. In this study, a hybrid NWT system was installed to remove nitrogenous pollutants in Karasu creek (Nigde city, Turkey) in 2014. The system built near the creek consisted of feeding basin (FB), settlement basin (SB), free water surface-constructed wetland (FWS-CW), and overland flow (OF) system respectively. Despite quite high nitrogen loading rates, the system managed to reduce NH4+-N from average 29 mg/L to 12 mg/L and TN from 44 mg/L to 19 mg/L with an average removal efficiency of 57 %. Results revealed that hydraulic and nitrogen loading rate, temperature and seasonal variation, BOD/TKN ratio, hydraulic residence time (HRT), and the use of the filter material were effective on nitrogen removal. The results suggest that the hybrid NWT systems can be used as a low-cost wastewater treatment alternative to improve water quality in streams contaminated by nitrogenous pollutants in the similar areas.
过量含氮废水的流入使水库的生态结构和功能急剧恶化。为了保护水库不受河流污染,在河流内部或外部建造天然污水处理系统可能是最合适和最经济的解决方法。在这项研究中,2014年在卡拉苏河(土耳其尼德市)安装了一个混合NWT系统来去除含氮污染物。在溪旁建造的系统分别由饲养池(FB)、沉降池(SB)、自由水面人工湿地(FWS-CW)和坡面流(of)系统组成。尽管氮负荷率很高,但该系统仍能将NH4+-N从平均29 mg/L降至12 mg/L,将TN从44 mg/L降至19 mg/L,平均去除率为57%。结果表明,水力和氮负荷速率、温度和季节变化、BOD/TKN比、水力停留时间(HRT)和滤料的使用对氮的去除有影响。结果表明,混合NWT系统可以作为一种低成本的污水处理替代方案,用于改善类似地区含氮污染物污染的溪流的水质。
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引用次数: 2
Fugitive Methane and Odour Emission Characterization at a Composting Plant using Remote Sensing Measurements 利用遥感测量对堆肥厂的逸散甲烷和气味排放进行表征
Pub Date : 2018-09-26 DOI: 10.30955/gnj.002802
And Kranert
Gaseous emissions of biowaste treatment facilities have several adverse effects. In Germany, a law to collect biological waste separately was introduced in January 2015. Since then there is a discussion about greenhouse gases which could be emitted in a significant rate and exceed the positive aspects. Default factors for methane and nitrous oxide from biological treatments given by the Intergovernmental Panel on Climate Change (IPPC) suggests that fugitive emissions even from composting processes should not be neglected. The research work presents an innovative method to quantify fugitive methane and odour emissions at a composting plant. The proposed method uses a combination of a remote sensing measurements and the application of a backwards Lagrangian stochastic (bLs) based micrometeorological dispersion modelling. The remote sensing technology is based on the absorption of infrared light with a wavelength sensitive to the substance to be determined. With the downwind measured methane concentration deducted by the upwind measured background concentration and the known wind conditions, a gas dispersion is simulated back in time to estimate the gas emission rate of a plant. Using the methane emissions as a tracer for dispersion characteristics in the atmosphere it is even possible to estimate a more accurate odour emission rate from passive sources at composting plants.
生物废物处理设施的气体排放有几个不利影响。2015年1月,德国出台了一项单独收集生物废物的法律。从那时起,就有关于温室气体的讨论,温室气体可能以显著的速度排放,超过了积极的方面。政府间气候变化专门委员会(IPPC)给出的生物处理产生的甲烷和一氧化二氮的默认因子表明,即使是堆肥过程中的逸散排放也不应被忽视。这项研究工作提出了一种创新的方法来量化堆肥厂的逸散甲烷和气味排放。该方法采用遥感测量和基于倒向拉格朗日随机(bLs)的微气象弥散建模相结合的方法。遥感技术的基础是吸收波长对待测物质敏感的红外光。利用顺风测得的甲烷浓度减去顺风测得的本底浓度和已知的风况,及时模拟了一个气体扩散,估算了工厂的气体排放速率。利用甲烷排放作为大气中分散特性的示踪剂,甚至可以估算出堆肥厂被动源的更准确的气味排放率。
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引用次数: 0
Study of number of total mortality, cardiovascular and Respiratory mortality attributed to air pollutants of Tehran in 2005-2014 2005-2014年德黑兰空气污染物导致的总死亡率、心血管和呼吸系统死亡率研究
Pub Date : 2018-09-26 DOI: 10.30955/gnj.002459
J. JafariA., R. R. Kalantari
Over the last few decades, the evidence on the adverse effects on the health of air pollution has been raised. Mortality is the most important health effect of ambient air pollution. We studied the relation between mortality and criteria pollutant air in Tehran, one of the highly industrialized, densely populated area and most polluted cities of the reign, during 2005-2014. For this purpose, we applied the approach proposed by the World Health Organization using the AirQ 2.2.3 model. Hourly concentrations of pollutants were taken from the Tehran environmental protection agency and Air Quality Control Company. In this model, the attributable proportion of health outcome, the annual number of excess cases of mortality for all causes were estimated. According to results, the number of total mortality caused by exposure to O3, NO2, SO2, PM10, PM2.5 in the past decade was 8042, 15141, 8136, 17776 and 20015 cases, respectively. The number of cumulative total mortality was 53110 cases in ten years. Furthermore, the number of cumulative cardiovascular and respiratory mortality 33887 and 8168 cases was estimated in last decade. A large number of residents of Tehran have died as a result of exposure to air pollutants; therefore for control and management of air pollution, appropriate actions on health and the environment should be performed.
在过去的几十年里,关于空气污染对健康的不利影响的证据越来越多。死亡是环境空气污染对健康最重要的影响。我们研究了2005-2014年期间德黑兰的死亡率与标准污染物空气之间的关系,德黑兰是高度工业化、人口稠密地区和污染最严重的城市之一。为此,我们采用了世界卫生组织提出的使用AirQ 2.2.3模型的方法。每小时的污染物浓度取自德黑兰环境保护局和空气质量控制公司。在该模型中,估计了健康结果的归因比例,所有原因的年度超额死亡病例数。结果表明,近10年北京市O3、NO2、SO2、PM10、PM2.5暴露总死亡人数分别为8042、15141、8136、17776、20015例。10年累计死亡总人数为53110例。此外,在过去十年中估计心血管和呼吸系统累计死亡人数分别为33887例和8168例。大量德黑兰居民因接触空气污染物而死亡;因此,为了控制和管理空气污染,应采取适当的健康和环境行动。
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引用次数: 4
Optimization of process variables for treatment of food industry effluents by electrocoagulation 电凝法处理食品工业废水工艺变量的优化
Pub Date : 2018-09-26 DOI: 10.30955/gnj.002640
The present study investigates the process optimization for treatment of potato processing industry wastewater by electrocoagulation. Performance of treatability was evaluated by achieved chemical oxygen demand (COD) removal efficiencies. Response Surface Methodology was applied to determine individual and interactive impacts of the selected operation variables (pH, conductivity, current density and duration period) on COD removal. Optimization studies were also performed for energy consumption costs which still remain as the major drawback of the electrocoagulation applications. Interactions between dependent and independent process variables were interpreted by the relevant surface plots. Sufficient correlation coefficients were obtained for the predictive regression models of the optimization. Results of the ANOVA tests showed that both of the models are statistically significant. Impacts of the process parameters on response values have been evaluated numerically by Pareto analysis. Furthermore, validation studies were conducted to confirm the accuracy of the model developed for prediction of COD removal efficiencies.
研究了电絮凝法处理马铃薯加工废水的工艺优化。通过化学需氧量(COD)去除率来评价处理性能。响应面法用于确定所选操作变量(pH、电导率、电流密度和持续时间)对COD去除率的单独和交互影响。优化研究还进行了能源消耗成本,这仍然是电絮凝应用的主要缺点。相关的表面图解释了依赖和独立过程变量之间的相互作用。得到了充分的相关系数,建立了优化的预测回归模型。方差分析的结果表明,这两个模型都具有统计学意义。通过Pareto分析,数值计算了工艺参数对响应值的影响。此外,还进行了验证研究,以确认用于预测COD去除效率的模型的准确性。
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引用次数: 4
Assessment of the biodegradation capacity of Azolla on polycyclic aromatic hydrocarbons in crude oil 杜鹃对原油中多环芳烃的生物降解能力评价
Pub Date : 2018-09-26 DOI: 10.30955/gnj.002544
T. Kösesakal
In this study, the potential use of Azolla filiculoides Lam. for the bioremediative solution to polycyclic aromatic hydrocarbon (PAH) pollution due to crude oil spills in freshwater was investigated. The plants were grown in nitrogen-free Hoagland nutrient solution media containing 0.05%, 0.1%, 0.2%, 0.3%, 0.4% and 0.5% crude oil by volume for 15 days under greenhouse conditions. Relative growth rates of A. filiculoides decreased in the presence of crude oil in a concentration-dependent manner. The probable influence of A. filiculoides on the biodegradation of polycyclic aromatic hydrocarbons was measured by using synchronous UV fluorescence spectroscopy. GC-MS analysis were also carried out to elucidate the behavior of the oil in experimental and control samples. Although 1-2 rings PAHs have not been encountered in control or plant samples, the measured intensity for 3-4 ring PAHs in plant samples was remarkably lower in comparison to the control. Furthermore, these results demonstrated that the predominant efficacy of the A. filiculoides was for 3-4 ring PAHs at the range 0.05 to 0.2% crude oil concentrations. It could be concluded that the bioremediative potential of A. filiculoides for the removal of polycyclic aromatic hydrocarbons strongly depends on the amount of oil in the contaminated water resource. In other words, A. filiculoides could be used more effectively after the removal of excess crude oil in the spilled freshwater areas.
本研究探讨了杜鹃花的潜在利用价值。对淡水中原油泄漏造成的多环芳烃污染的生物修复溶液进行了研究。在温室条件下,在含0.05%、0.1%、0.2%、0.3%、0.4%和0.5%原油的无氮Hoagland营养液培养基中生长15 d。在原油的作用下,黄连的相对生长率呈浓度依赖性下降。采用同步紫外荧光光谱法测定了黄芪对多环芳烃生物降解的可能影响。采用气相色谱-质谱分析阐明了油在实验样品和对照样品中的行为。虽然在对照和植物样品中未检测到1-2环多环芳烃,但在植物样品中检测到的3-4环多环芳烃强度明显低于对照。结果表明,在0.05 ~ 0.2%原油浓度范围内,黄连对3 ~ 4环多环芳烃具有显著的抑制作用。综上所述,黄芪对多环芳烃的生物修复潜力与污染水源中油类的含量密切相关。也就是说,在淡水泄漏区去除多余的原油后,丝状芽孢杆菌可以更有效地利用。
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引用次数: 4
Uncertainty analysis in sizing rainwater harvesting tanks in an isolated island with limited water resources 水资源有限的孤岛集雨池规模的不确定性分析
Pub Date : 2018-09-26 DOI: 10.30955/gnj.002535
Koumoura K.Α, F. E.G
This research work focuses on the analysis of the involved uncertainty and the corresponding reliability in the sizing of rainwater harvesting systems. For this reason, an uncertainty analysis was carried out, based on 23 years of historic daily record of a station in Kimolos Island (Aegean, Greece). In order to produce the synthetic daily timeseries, a disaggregation procedure was followed. The resulting dataset was used in a rainwater harvesting tank balance model for the optimal sizing of the system. Three representative timeseries, as well as the historic one, were selected for further investigation, concerning two different scenarios. The results show that a rainwater harvesting system in the island of Kimolos does not show great reliability for small collection surface areas. For high reliability, relatively large water collection areas and lower daily water consumptions are required. A cost-benefit analysis was also conducted, which shows that a rainwater harvesting system is advantageous considering the state’s expenses for water transportation, but it is profitless for households, based on current pricing of water.
本文的研究重点是分析集雨系统规模的不确定性及其相应的可靠性。因此,基于基莫洛斯岛(希腊爱琴海)一个监测站23年的历史每日记录,进行了不确定性分析。为了得到合成的日时间序列,采用了分解过程。所得到的数据集用于雨水收集罐平衡模型,以获得系统的最佳规模。选择了三个具有代表性的时间序列,以及历史时间序列,对两个不同的场景进行了进一步的研究。结果表明,Kimolos岛的雨水收集系统在小的收集面积下不具有很高的可靠性。为了提高可靠性,需要较大的集水面积和较低的日用水量。还进行了成本效益分析,结果表明,考虑到国家的水运费用,雨水收集系统是有利的,但根据目前的水价,它对家庭是无利可图的。
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引用次数: 10
Treatment of textile wastewater using a novel electrocoagulation reactor design 新型电絮凝反应器处理纺织废水
Pub Date : 2018-08-29 DOI: 10.5772/INTECHOPEN.76876
A. Naje, M. A. Ajeel, P. Alaba, Shreeshivadasan Chelliapan
This study explored the best-operating conditions for a novel electrocoagulation (EC) reactor with the rotating anode for textile wastewater treatment. The influence of operating parameters like inter-electrode distance (IED), current density (CD), temperature, pH, operating time (RT), and rotation speed on the removal efficiency of the contaminant was studied. A comparative study was done using conventional model with static electrodes in two phases under same textile wastewater The findings revealed that the optimal conditions for textile wastewater treatment were attained at RT = 10 min, CD = 4 mA/cm2, rotation speed = 150 rpm, temperature = 25oC, IED = 1cm, and pH = 4.57. The removal efficiencies of colour, biological oxygen demand (BOD), turbidity, chemical oxygen demand (COD), and total suspended solid (TSS) were 98.50%, 95.55%, 96%, 98% and 97.10% within the first 10 min of the reaction. The results of the experiment reveal that the newly designed reactor incorporated with cathode rings and rotated anode impellers provide a superior treatment efficiency within a short reaction time. The novel EC reactor with a rotating anode significantly enhanced textile wastewater treatment compared to the conventional model. The values of adsorption and passivation resistance validated the pollutants removal rate.
研究了一种新型旋转阳极电絮凝反应器处理纺织废水的最佳操作条件。研究了电极间距(IED)、电流密度(CD)、温度、pH、操作时间(RT)、转速等操作参数对污染物去除率的影响。采用两相静态电极常规模型对同一纺织废水进行了对比研究,结果表明:最佳工艺条件为:RT = 10 min, CD = 4 mA/cm2,转速= 150 rpm,温度= 25℃,IED = 1cm, pH = 4.57。在反应前10 min,色度、生物需氧量(BOD)、浊度、化学需氧量(COD)和总悬浮固体(TSS)的去除率分别为98.50%、95.55%、96%、98%和97.10%。实验结果表明,新设计的阴极环与旋转阳极叶轮相结合的反应器在较短的反应时间内具有较高的处理效率。与传统反应器相比,新型旋转阳极EC反应器对纺织废水的处理效果显著提高。吸附和钝化阻力值验证了污染物的去除率。
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引用次数: 11
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