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Assessing the bioaccumulation and translocation potential of vetiver grass for dioxins phytoremediation in Bien Hoa airbase, Viet Nam 评估香根草在越南边和空军基地二恶英植物修复中的生物累积和转移潜力
Pub Date : 2024-05-10 DOI: 10.15625/2525-2518/19478
Thi Thuy Huong Ngo, Thi Thanh Thao Nguyen
Dioxins (PCDD/Fs) are well-known toxic organic pollutants that accumulate in the environment and the food chain, imposing a risk to human health and the ecosystem. Due to the use of dioxin-contaminated herbicides during the US-Vietnam War, there are several hotspots in Vietnam with very high levels of dioxins. Phytoremediation has been increasingly developed in recent decades because of its low cost and environmental-friendly aspect. Vetiver grass is a plant that can remediate both organic and inorganic agents. In this study, the uptake and translocation of dioxins in Vetiver grass (Chrysopogon zizanioides) from the dioxin-contaminated soil was investigated in a field experiment on the Bien Hoa airbase, Vietnam. An experimental area was divided into six plots, of which three were planted with Vetiver grass and three served as control plots, with the initial dioxin concentrations as following: FC2>FC3>FC1>FT2>FT3>FT1. Vetiver grass had grown well on the dioxin-contaminated soils, yielding high biomass and the level of dioxins in the roots of vetiver grass was positively correlated (r2 = 0.67; p<0.01) with its growth rate. During the first year of cultivation, Vetiver grass had the greatest capacity to efficiently accumulate dioxin. Accumulation occurs in the roots, with BAF>1 throughout the entire experiment period for FT3, and in the first year for FT1 and FT2. The dioxin translocation from the roots to the shoots was significantly lower than the BAF and less than one (TF<1), with the first and second sampling times having the highest values compared to the others. Dioxin concentrations do not provide a reliable indicator of its bioavailability but numerous other factors, such as physicochemical properties of the soil and microbes. Our study aims to contribute significant insights to capability of Vetiver grass to accumulate and translocate dioxins, hence the arsenal of dioxin remediation. Furthermore, we envisage translating our findings into practical applications in other areas, considering optimized planting techniques, growth conditions, and long-term sustainability.
二恶英(多氯二苯并对二恶英和多氯二苯并呋喃)是众所周知的有毒有机污染物,会在环境和食物链中累积,对人类健康和生态系统造成危害。由于美越战争期间使用了受二恶英污染的除草剂,越南有几个热点地区的二恶英含量非常高。近几十年来,植物修复因其低成本和环境友好方面的优势而得到越来越多的发展。香根草是一种既能修复有机物又能修复无机物的植物。本研究在越南边和空军基地进行了一项田间试验,调查了香根草(Chrysopogon zizanioides)从受二恶英污染的土壤中吸收和转移二恶英的情况。实验区被划分为六个小区,其中三个种植香根草,三个作为对照小区,二恶英的初始浓度如下:FC2>FC3>FC1>FT2>FT3>FT1。香根草在二恶英污染的土壤上生长良好,生物量高,香根草根部的二恶英含量与 FT3 在整个实验期间以及 FT1 和 FT2 在第一年的二恶英含量呈正相关(r2 = 0.67;p1)。二恶英从根部向嫩芽的转移明显低于 BAF,且小于 1 (TF<1),与其他时间相比,第一次和第二次采样时间的二恶英转移值最高。二恶英的浓度并不能作为衡量其生物利用率的可靠指标,土壤和微生物的物理化学特性等其他因素也会影响二恶英的生物利用率。我们的研究旨在帮助人们深入了解香根草积累和转移二恶英的能力,从而为二恶英的修复提供帮助。此外,考虑到优化种植技术、生长条件和长期可持续性,我们设想将我们的研究成果转化为其他领域的实际应用。
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引用次数: 0
Biochar from waste green coffee extracted bioactive compounds as materials for ammonium adsorption 从废弃绿咖啡中提取生物活性化合物作为铵吸附材料的生物炭
Pub Date : 2024-03-01 DOI: 10.15625/2525-2518/17989
Hoai Linh Nguyen, Kim Chi Ngo, Le Minh Tran, Ngoc Phuong Dang, Xuan Tung Nguyen, Thuy Tien Do, Hong Minh Pham Thi
This study investigates the adsorption potential of AC-GCB biochar, obtained by pyrolyzing green coffee extracted bioactive compounds at 400 ºC, for ammonium removal from groundwater. The biochar's microstructure was characterized using scanning electron microscope (SEM), Fourier-transform infrared spectroscopy (FTIR), and Energy dispersive spectrometry (EDS) Mapping. Optimal adsorption conditions were observed at an initial pH range of 4 to 8, an initial NH4+ concentration of ≤ 25 mg.L-1, and a biochar dose of 10 g.L-1. The ammonium adsorption of AC-GCB was consistent with both Langmuir and Freundlich's adsorption theories (R2 > 0.92). The AC-GCB biochar obtained the maximum adsorption capacity Qm was 14,48 mg.g-1, higher than the control BC-GCB biochar that pyrolysised without bioactive compound extracted with Qm was only 5.41 mg.g-1.
本研究探讨了 AC-GCB 生物炭的吸附潜力,这种生物炭是通过在 400 ºC 高温下热解绿咖啡中提取的生物活性化合物而获得的,用于去除地下水中的铵。研究人员使用扫描电子显微镜(SEM)、傅立叶变换红外光谱(FTIR)和能量色散光谱(EDS)对生物炭的微观结构进行了表征。在初始 pH 值为 4 至 8、初始 NH4+ 浓度≤ 25 mg.L-1、生物炭剂量为 10 g.L-1 的条件下,观察到了最佳吸附条件。AC-GCB 对铵的吸附符合 Langmuir 和 Freundlich 吸附理论(R2 > 0.92)。AC-GCB 生物炭获得的最大吸附容量 Qm 为 14,48 mg.g-1,高于未提取生物活性化合物的热解 BC-GCB 生物炭,后者的 Qm 仅为 5.41 mg.g-1。
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引用次数: 0
ISOLATION, CHARACTERIZATION, AND NITRIC OXIDE PRODUCTION INHIBITORY ACTIVITIES OF THE METABOLITES FROM PSIDIUM GUAJAVA L. 番石榴代谢物的分离、特征和一氧化氮生成抑制活性
Pub Date : 2024-03-01 DOI: 10.15625/2525-2518/18298
Hieu Ngo, Tuan Anh Hoang Le, Cong Pham
Thirteen compounds, including catechin (1), gallocatechin (2), quercetin (3), myricetin (4), kaempferol 3-O-α-ʟ-arabinofuranoside (5), avicularin (6), guaijaverin (7), quercetin-3-O-β-ᴅ-galactopyranoside (8), quercetin-3-O-β-ᴅ-glucopyranoside (9), quercetin-3-O-β-ᴅ-glucuronide (10), casuarinin (11), ursolic acid (12), and 4-methoxy-3,5-dihydroxybenzoic acid (13) were isolated from the leaves of Psidium guajava. The structures of these compounds were elucidated by modern spectroscopic methods (MS, 1H/13C-NMR) and compared with those reported data. Additionally, all isolated compounds were evaluated for their inhibitory effects on NO production. Among them, compounds 3, 8, 10, and 11 showed inhibitory effects on NO production within IC50 values of 19.30 – 42.86 µM. Compound 13 was firstly isolated from Psidium guajava.
从番石榴叶中分离出了槲皮素-3-O-β-ᴅ-吡喃葡萄糖苷(9)、槲皮素-3-O-β-ᴅ-葡萄糖醛酸苷(10)、番荔枝素(11)、熊果酸(12)和 4-甲氧基-3,5-二羟基苯甲酸(13)。通过现代光谱方法(质谱、1H/13C-NMR)阐明了这些化合物的结构,并与已报道的数据进行了比较。此外,还评估了所有分离化合物对 NO 生成的抑制作用。其中,化合物 3、8、10 和 11 对 NO 生成具有抑制作用,IC50 值在 19.30 - 42.86 µM 之间。化合物 13 首先是从番石榴中分离出来的。
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引用次数: 0
SYNTHESIS OF NICKEL-DOPED BIVO4 MATERIALS BY HYDROTHERMAL METHOD AND EVALUATE THE PHOTOCATALYTIC ABILITY TO DECOMPOSE METHYLENE BLUE UNDER VISIBLE LIGHT 用水热法合成掺镍的 bivo4 材料并评估其在可见光下分解亚甲基蓝的光催化能力
Pub Date : 2024-03-01 DOI: 10.15625/2525-2518/17140
Van Thinh Pham, Thi Bach Tuyet Dao, Thi Kim Ngan Tran, Ngoc Quyen Tran, Long Giang Bach
Ni-doped BiVO4 photocatalysts were successfully synthesized by hydrothermal method. The catalytic samples were characterized by scanning electron microscopy (SEM), UV-vis diffuse reflection spectroscopy (DRS), photoluminescence spectroscopy (PL) and X-ray diffraction (XRD). Based on the results of PL spectrum analysis, the electron-hole recombination phenomenon is limited by the presence of the second metal Ni in the structure at Bi3+ positions. The catalyst materials at the Ni doping ratios all have the monoclinic-scheelite BiVO4 structure as shown by the XRD and Raman methods. The photocatalytic ability of methyl blue (MB) on the Ni/BiVO4 catalyst was studied under visible light irradiation in order to contribute to reducing the current environmental pollution problem. The removal efficiency of MB varies with the doping ratio of Ni/BiVO4, reaching the highest decomposition efficiency of 84.77% in the 5% mol Ni sample, which is 30% higher than that of the BiVO4 sample. The BiVO4 material modified with Ni gives a high photocatalytic efficiency of organic pigment decomposition under visible light indicates the potential improvement in the efficiency of a material for existing applications and exploit many new applications in the future.
采用水热法成功合成了掺镍 BiVO4 光催化剂。通过扫描电子显微镜(SEM)、紫外-可见漫反射光谱(DRS)、光致发光光谱(PL)和 X 射线衍射(XRD)对催化样品进行了表征。根据光致发光光谱分析结果,电子-空穴重组现象受限于结构中 Bi3+ 位置第二金属 Ni 的存在。XRD 和拉曼方法显示,不同掺杂比例的催化剂材料均具有单斜闪长石 BiVO4 结构。在可见光照射下,研究了 Ni/BiVO4 催化剂对甲基蓝(MB)的光催化能力,以期为减少当前的环境污染问题做出贡献。甲基蓝的去除率随 Ni/BiVO4 的掺杂率而变化,5% mol Ni 样品的分解效率最高,达到 84.77%,比 BiVO4 样品的分解效率高 30%。用镍修饰的 BiVO4 材料在可见光下具有很高的光催化分解有机颜料的效率,这表明该材料在现有应用中的效率有可能得到提高,并在未来开发出许多新的应用。
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引用次数: 0
MODELING OF RELAY PROTECTION OF ELECTRIC POWER SYSTEM USING MATLAB/SIMULINK 使用 Matlab/Simulink 对电力系统继电保护进行建模
Pub Date : 2024-03-01 DOI: 10.15625/2525-2518/18250
Dũng Võ Tiến
This article presents the modeling of overcurrent and differential relays in MATLAB/Simulink. The overcurrent relay has the features of instantaneous, time-definite, and inverse definite minimum time (IDMT) characteristics according to IEC 60255 and IEEE C37.112-1996 standards. The 220 kV km transmission systems are selected as examples for fault simulation and relay testing for each relay model and the coordination protection. The simulation results are given and a description of how this case study can be used to compare protection schemes.
本文介绍了过流继电器和差动继电器在 MATLAB/Simulink 中的建模。根据 IEC 60255 和 IEEE C37.112-1996 标准,过流继电器具有瞬时、定时和反定最小时间(IDMT)特性。以 220 kV 千米输电系统为例,对每个继电器模型和协调保护进行了故障模拟和继电器测试。文中给出了仿真结果,并说明了如何利用该案例研究对保护方案进行比较。
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引用次数: 0
OCCURRENCE OF PM0.1 AND PM2.5 AT HIGH POLLUTING EVENT DAYS IN HANOI AND HEALTH IMPLICATION 河内高污染事件日 pm0.1 和 pm2.5 的发生率及其对健康的影响
Pub Date : 2024-03-01 DOI: 10.15625/2525-2518/18373
Thuy Bich Ly, Le-Ha T. Vo, Dieu Anh Van, Thu Hien Nguyen, Duy Nam Dao, Trung-Dung Nghiem, Quoc Dat Nguyen
High levels of fine (PM2.5) and ultrafine (PM0.1) particles in the atmosphere can cause adverse effects on the environment and human health. This study aims at determining the mass concentrations of PM and health risks on pollution event days (episodes) in Hanoi. Semi-daily samples (daytime and night-time) of PM2.5 and PM0.1 were collected at Hanoi University of Science and Technology, in December 2021. The daily PM2.5 concentrations were in the range of 42 – 204 µg/m3 (average of 123 µg/m3). Those of PM0.1 varied from 9 to 30 µg/m3 (average of 22 µg/m3). There is negligible change on daytime and night-time PM0.1 concentrations, whereas those levels of PM2.5 were remarkably different. PM2.5 daytime concentrations were in the range of 39 – 205 µg/m3 with an average of 107 µg/m3. The level ranges of night-time were slightly wider which varied from 39 to 230 µg/m3 (average of 132 µg/m3).  A prolonged episode of PM2.5 (which is defined by the criterion of PM2.5 > 50 µg/m3) was found with an intensity of 26 days in December. During the pollution episode, the Monte Carlo simulation showed that respirable doses were the highest for the adult (above 21 years) for chronic effects, whereas the highest doses for acute were observed in the children (0-3 years), which has implications in the adverse health effects for sensitive groups. The sensitive analysis finds the concentration of PM to be the most influencing factor in inhalation dose estimation.
大气中高浓度的细颗粒物(PM2.5)和超细颗粒物(PM0.1)会对环境和人类健康造成不利影响。本研究旨在确定河内污染事件日(事件)的可吸入颗粒物质量浓度和健康风险。2021 年 12 月,在河内科技大学收集了 PM2.5 和 PM0.1 的半日样本(白天和夜间)。PM2.5 的日浓度范围为 42 - 204 µg/m3(平均为 123 µg/m3)。PM0.1 的浓度范围为 9 至 30 微克/立方米(平均为 22 微克/立方米)。白天和夜间的 PM0.1 浓度变化微乎其微,而 PM2.5 的浓度水平则有显著不同。PM2.5 的日间浓度范围为 39 - 205 微克/立方米,平均为 107 微克/立方米。夜间的水平范围稍宽,从 39 微克/立方米到 230 微克/立方米不等(平均为 132 微克/立方米)。 在 12 月份,PM2.5(根据 PM2.5 > 50 µg/m3 的标准定义)出现了持续时间长达 26 天的污染。在污染事件中,蒙特卡罗模拟显示,成人(21 岁以上)的慢性效应可吸入剂量最高,而儿童(0-3 岁)的急性效应剂量最高,这对敏感群体的不良健康影响产生了影响。敏感性分析发现,可吸入颗粒物的浓度是吸入剂量估算的最大影响因素。
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引用次数: 0
SYNTHESIZING AND INVESTIGATING THE ELECTRICAL PROPERTIES OF CARBONIZED METAL–ORGANIC FRAMEWORKS 合成和研究碳化金属有机框架的电学特性
Pub Date : 2024-03-01 DOI: 10.15625/2525-2518/16311
T. Tu, Huy Q. Tran, Huong D. T. Nguyen, Nhung Thi Tran, Tung T. Nguyen, Long H. Ngo
The iron-based metal–organic frame (Fe-MOF), VNU-20, and its carbonized analogues were synthesized. Subsequently, this material was investigated for electrical properties in comparison with the carbonized samples from other MOFs and ZIFs (such as ZIF-8, ZIF-67, MOF-199, MIL-53). The experiments showed the results with the reversible cyclic voltammetry (CV) curve characterized by the redox oxidation reactions of Fe(II)/Fe(III). Furthermore, the electrode composed of carbonized VNU-20 shows a comparable capacitance with that of carbonized ZIF-67, the highest capacitance material recorded up to date for the same class of materials. While further experiments need to be carried out for the optimization, initial analyzes show the promising result for further investigation and use of carbonized VNU-20 as the electrode material for electro-catalysis and the supercapacitor.
我们合成了铁基金属有机框架(Fe-MOF)VNU-20 及其碳化类似物。随后,研究人员将这种材料与其他 MOF 和 ZIF(如 ZIF-8、ZIF-67、MOF-199 和 MIL-53)的碳化样品进行了电学特性比较。实验结果显示了以铁(II)/铁(III)氧化还原反应为特征的可逆循环伏安(CV)曲线。此外,由碳化 VNU-20 组成的电极显示出与碳化 ZIF-67 相当的电容,而碳化 ZIF-67 是迄今为止同类材料中电容最高的材料。虽然还需要进一步的实验来进行优化,但初步分析表明,碳化 VNU-20 作为电催化和超级电容器的电极材料,有望得到进一步的研究和应用。
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引用次数: 0
AdaL-PSO A New Adaptive Algorithm for the Multi-Skilled Resource-Constrained Project Scheduling Problem AdaL-PSO 一种针对多技能资源受限项目调度问题的新自适应算法
Pub Date : 2024-02-23 DOI: 10.15625/2525-2518/17919
Phan Thanh Toan, Do Van Tuan
MS-RCPSP is a combinatorial optimization problem that has many practical applications, this problem has been proven to belong to the NP-hard class, the approach to solving this problem is to use algorithms to find approximate solution. This paper proposed a New Adaptive Local Particle Swarm Optimization algorithm for the MS-RCPSP problem. The solution for the class of NP-Hard problems is to find approximate solutions using metaheuristic algorithms. However, most metaheuristic-based algorithms have a weakness that can be fallen into local extreme after a number of evolution generations. In this paper, we adopted a new adaptive nonlinear weight update strategy based on fitness value and new neighborhood topology for Particle Swarm Optimization algorithm, thereby helping to prevent PSO from falling into local extremes. The new algorithm is called AdaL-PSO. A numerical analysis is carried out using iMOPSE benchmark dataset and is compared with some other early algorithms. Results presented suggest the prospect of our proposed algorithm.
MS-RCPSP 是一个有很多实际应用的组合优化问题,该问题已被证明属于 NP-困难类,解决该问题的方法是使用算法寻找近似解。本文针对 MS-RCPSP 问题提出了一种新的自适应局部粒子群优化算法。NP-Hard 类问题的解决方案是使用元启发式算法找到近似解。然而,大多数基于元启发式的算法都有一个弱点,那就是在进化若干代后会陷入局部极端。在本文中,我们为粒子群优化算法采用了一种基于适应度值和新邻域拓扑的新自适应非线性权重更新策略,从而有助于防止 PSO 陷入局部极端。新算法被称为 AdaL-PSO。利用 iMOPSE 基准数据集进行了数值分析,并与其他一些早期算法进行了比较。结果表明,我们提出的算法前景广阔。
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引用次数: 0
Study ability of protection effect of organic acids for multi-metallic anti-corrosion additive system in ethylene glycol-water coolants 有机酸对乙二醇-水冷却剂中多金属防腐蚀添加剂体系的保护作用能力研究
Pub Date : 2024-02-23 DOI: 10.15625/2525-2518/17071
Pham Thi Mai, Huong, Nguyen Thi Huong
In this work, the electrochemical behavior of carbon steel, brass, bronze and aluminum alloys in the presence of various important organic acids (sebacic acid (SbA), terephthalic (TPA), 2-ethylhexanoic (E2C6A), and octanoic (C8A)) and the effect that these have on the growth and protectiveness of the alloys have been investigated. The results show that the presence of organic acids in the coolant increases the protective effect of the system by forming a film on the surface of the alloys. The EIS impedance results demonstrate the formation of active and passive protective layers on the surface of the alloys. The results of surveying 04 types of organic acids for the protection of different alloy substrates show that TPA and SbA acid additives are more effective than C8A and E2C5A. The additive C8A not only did not inhibit corrosion but also promoted this process strongly, especially with aluminum alloys and the TPA has the best anti-corrosion effect for steel, followed by C1 copper alloy and aluminum.
在这项工作中,研究了碳钢、黄铜、青铜和铝合金在各种重要有机酸(癸二酸 (SbA)、对苯二甲酸 (TPA)、2-乙基己酸 (E2C6A) 和辛酸 (C8A))存在下的电化学行为,以及这些有机酸对合金生长和保护性的影响。结果表明,冷却液中有机酸的存在会在合金表面形成一层薄膜,从而增强系统的保护效果。EIS 阻抗结果表明,合金表面形成了主动和被动保护层。对 04 种有机酸保护不同合金基材的调查结果表明,TPA 和 SbA 酸添加剂比 C8A 和 E2C5A 更有效。添加剂 C8A 不仅不能抑制腐蚀,反而会强烈促进腐蚀过程,尤其是对铝合金;TPA 对钢的防腐蚀效果最好,其次是 C1 铜合金和铝。
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引用次数: 0
Synthesis and characterization of PVP coated gadolinium oxide nanoparticles for imaging applications 用于成像应用的 PVP 涂层氧化钆纳米粒子的合成与表征
Pub Date : 2024-02-23 DOI: 10.15625/2525-2518/17349
Nguyen Thi Thuy Khue, Le Thi Thanh Tam, Ngo Thanh Dung, Nguyen Thi Ngoc Linh, Nguyen Huu Tuan Dung, Le The Tam, Le Trong Lu
In this work, we present the synthesis and applications of Gd2O3@PVP nanoparticles as an efficient contrast agent for MRI and CT techniques. Gd2O3@PVP nanoparticles have been successfully synthesized by the polyol method using ethylene glycol and poly(vinylpyrrolidone) as solvent and surfactant, respectively. The structure, morphology and characteristic properties of the materials are thoroughly investigated by SEM, TEM, UV-Vis, XRD, FTIR and DLS measurements. As an important result, NPs synthesized under optimized conditions have a diameter in the range of 12 nm and exhibit a good contrast signal in magnetic resonance imaging and computed tomography at relatively low concentration ([NPs] = 0.1 mM for MRI and 1.25 mg.mL-1 for CT). In particular, the concentration of Gd2O3@PVP nanoparticles used in CT is 10 times lower than that of the commercial Iobitridol product (i.e., 12.5 mg.mL-1) to achieve similar signal intensity. This result has an important implication for reducing the dose of contrast agent introduced into the body. The obtained results suggest that PVP-coated Gd2O3 nanoparticles can be applied as multifunctional contrast agents for imaging diagnostic applications in the near future.
在这项工作中,我们介绍了 Gd2O3@PVP 纳米粒子的合成和应用,它是核磁共振成像(MRI)和计算机断层扫描(CT)技术的一种高效造影剂。Gd2O3@PVP 纳米粒子以乙二醇和聚乙烯吡咯烷酮分别作为溶剂和表面活性剂,采用多元醇法成功合成。通过 SEM、TEM、UV-Vis、XRD、FTIR 和 DLS 测量,对材料的结构、形貌和特性进行了深入研究。一个重要的结果是,在优化条件下合成的 NPs 直径在 12 纳米范围内,并且在相对较低的浓度下(MRI 中的[NPs] = 0.1 mM,CT 中的[NPs] = 1.25 mg.mL-1),在磁共振成像和计算机断层扫描中表现出良好的对比信号。特别是在 CT 中使用的 Gd2O3@PVP 纳米粒子的浓度比商用 Iobitridol 产品(即 12.5 mg.mL-1)低 10 倍,就能获得相似的信号强度。这一结果对于减少进入人体的造影剂剂量具有重要意义。研究结果表明,在不久的将来,PVP 涂层 Gd2O3 纳米粒子可作为多功能造影剂应用于成像诊断。
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引用次数: 0
期刊
Vietnam Journal of Science and Technology
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